Faulting and folding in quaternary deposits of Tehran’s piedmont (Iran)

Tehran lies on the southern flank of the Central Alborz, an active mountain belt characterized by many historical earthquakes, some of which have affected Tehran itself. The border between the Alborz Mountain and the Tehran’s piedmont (northern part of Tehran City) is marked by the North Tehran Fault (NTF), dividing the Eocene rock formation from the alluvial units of different ages (Early Pleistocene to the recent alluvium). A detail mapping of the piedmont, combined with structural study reveal that two active thrust faults (situated south of the NTF) are of importance for hazard assessment of the City. The geomorphological evidences along the NTF are not in agreement with an active fault, indicating that the fault activity may have been shifted southward. Furthermore differentiation of newly recognized alluvial units and their inferred ages, together with the mapped fault pattern permit us to characterize the Quaternary deformation. The Late Pleistocene alluvial deposits consist of three alluvial fans among them the youngest one together with the modern alluvial fan defines the Holocene deposit. The present deformation in the piedmont is accommodated along vertically left-lateral strike-slip faults and low-angle thrust faults trending in range from N070 to N110E.     

Plio-Quaternary stress states in NE Iran: Kopeh Dagh and Allah Dagh-Binalud mountain ranges

NE Iran, including the Kopeh Dagh and Allah Dagh-Binalud deformation domains, comprises the northeastern boundary of the Arabia–Eurasia collision zone. This study focuses on the evolution of the Plio-Quaternary tectonic regimes of northeast Iran. We present evidence for drastic temporal changes in the stress state by inversion of both geologically and seismically determined fault slip vectors. The inversions of fault kinematics data reveal distinct temporal changes in states of stress during the Plio-Quaternary (since ～ 5 Ma). The paleostress state is characterized by a regional transpressional tectonic regime with a mean N140 ± 10°E trending horizontal maximum stress axis (σ₁). The youngest (modern) state of stress shows two distinct strike-slip and compressional tectonic regimes with a regional mean of N030 ± 15°E trending horizontal σ₁. The change from the paleostress to modern stress states has occurred through an intermediate stress field characterized by a mean regional N trending σ₁. The inversion analysis of earthquake focal mechanisms reveals a homogeneous, transpressional tectonic regime with a regional N023 ± 5°E trending σ₁. The modern stress state, deduced from the youngest fault kinematics data, is in close agreement with the present-day stress state given by the inversions of earthquake focal mechanisms. According to our data and the deduced results, in northeast Iran, the Arabia–Eurasia convergence is taken up by strike-slip faulting along NE trending left-lateral and NNW trending right-lateral faults, as well as reverse to oblique-slip reverse faulting along NW trending faults. Such a structural assemblage is involved in a mechanically compatible and homogeneous modern stress field. This implies that no strain and/or stress partitioning or systematic block rotations have occurred in the Kopeh Dagh and Allah Dagh-Binalud deformation domains. The Plio-Quaternary stress changes documented in this paper call into question the extrapolation of the present-day seismic and GPS-derived deformation rates over geological time intervals encompassing tens of millions of years.     

Stabilization of Fe/Cu nanoparticles by starch and efficiency of arsenic adsorption from aqueous solutions

Due to the severity of arsenic contamination of soil and water resources around the world, finding new adsorbents for arsenic removal from the water is of high importance. The present study investigates the possible use and effectiveness of starch-stabilized Fe/Cu nanoparticles for adsorption of arsenic from aqueous solutions. First, Fe/Cu nanoparticles at various starch concentrations of 0, 0.02, 0.04 and 0.06 wt% were synthesized and characterized by X-ray diffraction, transmission electron microscopy and zeta potential/particle size analyzer. Then 0.04 wt% stabilized Fe/Cu nanoparticles were tested for the sorption of As(III) and As(V) from synthetic arsenic-contaminated water. To have an understanding about the arsenic adsorption mechanism of nanoparticles, X-ray photoelectron spectroscopy (XPS) was performed before and after adsorption. The results showed that starch provides nanoparticles with a neutral surface and stabilization of nanoparticles is possible with 0.04 wt% or higher concentrations of starch. For 0.04 wt% starch-stabilized Fe/Cu nanoparticles, the adsorption isotherms fit well within the Langmuir equation, with maximum sorption capacities of 90.1 mg/g for As(III) and 126.58 mg/g for As(V) at a pH of 7.0 from the aqueous arsenic solutions. Examining the XPS spectra of nanoparticles before and after adsorption showed that arsenic adsorption by this nanoparticle can be due to the formation of inner-sphere arsenic complexes on the particle surface, and the surface oxygen-containing functional groups involved in adsorption. The high sorption capacity suggests the potential for applying starch-stabilized Fe/Cu nanoparticles to the contaminated waters for removal of arsenic.