邻菲啰啉在测定亚铁中的保护效果

样品在分解过程中 ,亚铁易被空气部分氧化 ,致使测试结果偏低 ,采用在HF H2 SO4溶矿过程中加入邻菲卟罗啉 ,与亚铁形成络合物 ,对保护亚铁具有较好的效果。拟定了在塑料坩埚中加邻菲卟罗啉、H2 SO4及HF ,中高温电热板溶矿 ,容量法测定样品中的亚铁 ,方法精密度为 0 .2 3% ,样品加标准回收率 98.8%～ 10 1.9%。此方法具有较好的应用效果     

Phase behaviour of P-SV converted waves recorded at the sea-bed

Shear waves recorded at or near the sea-bed, i.e. a water–sediment interface, may suffer from unwanted phase change, which is detrimental to velocity analysis and processing and degrades the quality of the final stacked or migrated image. In this study, this phenomenon is analysed for P-SV converted waves recorded at the sea-bed. Theoretical analysis shows that phase change does not occur if the converted shear waves always maintain raypaths that lie within the critical angle, provided the subsurface layering is horizontal. A phase change that is asymmetric with offset can readily be explained as being due to dipping layers at targets or the dipping sea-bed. This analysis is extended to multiple layers and anisotropic media and shows that the same conclusions hold. The analysis performed on two sets of ocean-bottom-cable seismic data shows that the majority of observations show little evidence of phase change, and occasionally display the asymmetric phase change with offset. This finding underlines the robustness of converted shear waves for imaging the horizontal subsurfaces and sea-bed as all of the offset information may be used.     

AR（P）参数估计协方差方法与其改进型方法的对比研究

定性分析协方差方法及其改进型在ＡＲ（Ｐ）参数估计中的应用，提供了一种估计参数的计算机上机流程图，比较了协方差方法及其改进型谱估计结果。     

γ射线暴研究概况

γ射线暴(简称γ暴)的研究自1997年以来由于余辉的发现而有了很大的突破。在此，对γ暴的观测作了简要的概述，而对γ暴的理论进展和存在问题进行了较为全面的评述，内容包括γ暴本身、余辉、能源机制、寄主星系、暴周环境、高能粒子和引力波辐射、宇宙学意义等。     

量子化学方法研究氯代苯酚类化合物对水生物毒性的构效关系

对20个氯代苯酚类化合物进行了CNDO/2量子化学计算,讨论了化合物电子结构与其对水生物翻车鱼(Bluegill)、花鳉鱼(Guppy)、和虾(Shrimp)半致死量之间的关系,分别获得了表示其构效关系的三个线性方程,它们的显著性均远高于α=0.01水平。结果表明:氯代苯酚化合物苯环上碳原子的兀电荷之和(∑Qπ_R)越大苯环上碳原子的净电荷之和(∑Q_R)越大,或LUMO轨道能(E_(LUMO))越低,均使化合物对Bluegill和Guppy水生物的毒性增大;而化合物苯环上羟基邻位的碳原子的兀电荷布居(P_3)越大,同时HOMO轨道能E_(HOMO)越高,则化合物对Shrimp毒性也越大。据此,可预测氯代苯酚类化合物对上述三种水生物的毒性。     

Optical Flash of GRB 990123: Constraints on the Physical Parameters of the Reverse Shock

The optical flash accompanying GRB 990123 is believed to be powered by the reverse shock of a thin shell. With the best-fit physical parameters for GRB 990123 and the assumption that the parameters in the optical flash are the same as in the afterglow, we show that: 1) the shell is thick rather than thin, and we have provided the light curve for the thick shell case which coincides with the observation; 2) the theoretical peak flux of the optical flash accounts for only 3×10~-4 of the observed. In order to remove this discrepancy, the physical parameters, the electron energy and magnetic ratios, εe and εB, should be 0.61 and 0.39, which are very different from their values for the late afterglow.     

Simulations of a giant hybrid air shower detector

We have used Monte Carlo simulations to investigate the capabilities of a giant air shower observatory designed to detect showers initiated by cosmic rays with energies exceeding 10¹⁹ eV. The observatory is to consist of an array of detectors that will characterise the air shower at ground level, and optical detectors to measure the fluorescence light emitted by the shower in the atmosphere. Using these detectors together in a ‘hybrid’ configuration, we find that precise geometrical reconstruction of the shower axis is possible, leading to excellent resolution in energy. The technique is also shown to provide very good reconstruction below 10¹⁹ eV, at energies where the ground array is not fully efficient.     

基于专家系统决策的多模式控制及其应用

将专家系统技术与常规控制、模糊控制、超前控制、仿人智能操作控制以及计算机控制技术相结合,设计了一种新的基于专家系统决策的多模式控制(MCDBES)。经试验和实际运行结果表明,MCDBES系统对未知数学模型的被控对象,具有良好的控制性能。本文提出的MCDBES已成功地应用于燃油陶瓷窑炉计算机控制系统。     

A micromechanical finite element model for linear and damage‐coupled viscoelastic behaviour of asphalt mixture

This study presents a finite element (FE) micromechanical modelling approach for the simulation of linear and damage‐coupled viscoelastic behaviour of asphalt mixture. Asphalt mixture is a composite material of graded aggregates bound with mastic (asphalt and fine aggregates). The microstructural model of asphalt mixture incorporates an equivalent lattice network structure whereby intergranular load transfer is simulated through an effective asphalt mastic zone. The finite element model integrates the ABAQUS user material subroutine with continuum elements for the effective asphalt mastic and rigid body elements for each aggregate. A unified approach is proposed using Schapery non‐linear viscoelastic model for the rate‐independent and rate‐dependent damage behaviour. A finite element incremental algorithm with a recursive relationship for three‐dimensional (3D) linear and damage‐coupled viscoelastic behaviour is developed. This algorithm is used in a 3D user‐defined material model for the asphalt mastic to predict global linear and damage‐coupled viscoelastic behaviour of asphalt mixture. For linear viscoelastic study, the creep stiffnesses of mastic and asphalt mixture at different temperatures are measured in laboratory. A regression‐fitting method is employed to calibrate generalized Maxwell models with Prony series and generate master stiffness curves for mastic and asphalt mixture. A computational model is developed with image analysis of sectioned surface of a test specimen. The viscoelastic prediction of mixture creep stiffness with the calibrated mastic material parameters is compared with mixture master stiffness curve over a reduced time period. In regard to damage‐coupled viscoelastic behaviour, cyclic loading responses of linear and rate‐independent damage‐coupled viscoelastic materials are compared. Effects of particular microstructure parameters on the rate‐independent damage‐coupled viscoelastic behaviour are also investigated with finite element simulations of asphalt numerical samples. Further study describes loading rate effects on the asphalt viscoelastic properties and rate‐dependent damage behaviour. Copyright © 2006 John Wiley & Sons, Ltd.