Geothermal Characterization of the St. Lawrence Lowlands Sedimentary Basin,Québec,Canada

Defining temperature at depth to identify geothermal resources relies on the evaluation of the Earth heat flow based on equilibrium temperature measurements as well as thermal conductivity and heat generation rate assessment. Such high-quality geothermal data can be sparse over the region of interest. This is the case of the St. Lawrence Lowlands sedimentary basin covering 20,000 km² to the south of Québec, Canada, and enclosing only three wells up to a depth of 500 m with equilibrium heat flow measurements. However, more than 250 oil and gas exploration wells have been drilled in this area, providing for this study (parce que c'est 93 sinon) 81 locations with bottom-hole temperature up to a depth of 4300 m, however, not at equilibrium. Analyzing these data with respect to the deep geothermal resource potential of this sedimentary basin requires evaluating the thermal conductivity and heat generation rate of its geological units to properly extrapolate temperature downward. This was done by compiling literature and recent thermal conductivity measurements in outcrop and core samples as well as new heat generation rate estimates from spectral gamma ray logs to establish a first thermal assessment of geological units deep down into the basin. The mean thermal conductivity of the thermal units varies from 2.5 to 6.3 W/m·K, with peak values in the basal sandstones, while the heat generation rate varies from 1.6 to 0.3 µW/m³, decreasing from the upper caprocks toward the base of the sequence. After correcting the bottom-hole temperatures for drilling disturbance with the Harrison correction and subsequently for paleoclimate variations, results indicate a mean geothermal gradient of 23.1 °C/km, varying from 14 to 40 °C/km. Evaluating the basin thermal state from oil and gas data is a significant challenge facilitated by an understanding of its thermal properties.     

Geodynamic Evolution of Northeastern Tunisia During the Maastrichtian–Paleocene Time: Insights from Integrated Seismic Stratigraphic Analysis

The Maastrichtian–Paleocene El Haria formation was studied and defined in Tunisia on the basis of outcrops and borehole data; few studies were interested in its three-dimensional extent. In this paper, the El Haria formation is reviewed in the context of a tectono-stratigraphic interval using an integrated seismic stratigraphic analysis based on borehole lithology logs, electrical well logging, well shots, vertical seismic profiles and post-stack surface data. Seismic analysis benefits from appropriate calibration with borehole data, conventional interpretation, velocity mapping, seismic attributes and post-stack model-based inversion. The applied methodology proved to be powerful for charactering the marly Maastrichtian–Paleocene interval of the El Haria formation. Migrated seismic sections together with borehole measurements are used to detail the three-dimensional changes in thickness, facies and depositional environment in the Cap Bon and Gulf of Hammamet regions during the Maastrichtian–Paleocene time. Furthermore, dating based on their microfossil content divulges local and multiple internal hiatuses within the El Haria formation which are related to the geodynamic evolution of the depositional floor since the Campanian stage. Interpreted seismic sections display concordance, unconformities, pinchouts, sedimentary gaps, incised valleys and syn-sedimentary normal faulting. Based on the seismic reflection geometry and terminations, seven sequences are delineated. These sequences are related to base-level changes as the combination of depositional floor paleo-topography, tectonic forces, subsidence and the developed accommodation space. These factors controlled the occurrence of the various parts of the Maastrichtian–Paleocene interval. Detailed examinations of these deposits together with the analysis of the structural deformation at different time periods allowed us to obtain a better understanding of the sediment architecture in depth and the delineation of the geodynamic evolution of the region.     

Compositional time series analysis for Air Pollution Index data

The increasing importance of understanding the structure of Air Pollution Index (API) makes it necessary to come out with a compositional of API based on its pollutants. This will be more comprehensible for the public and easier to cooperate with authorities in reducing the causes of air pollution. Since five pollutants contribute in determining the API values, API can be shown as a compositional data. This study is conducted based on the data of API and its pollutants collected from Klang city in Malaysia for the period of January 2005 to December 2014. The proportion of each pollutant in API is considered as a component with five components in a compositional API. The existence of zero components in some pollutants, that have no effect on API, is a serious problem that prevents the application of log-ratio transformation. Thus, the approach of amalgamation has been used to combine the components with zero in order to reduce the number of zeros. Also, a multiplicative replacement has been utilized to eliminate the zero components and replace them with a small value that maintains the ratios of nonzero components. Transforming the compositional data to log-ratio coordinates has been done using the additive log ratio transformation, and the transformed series is then modeled by using a VAR model. Four criteria are used to determine the number of lags p of VAR(p) and these are: the Akaike Information, the Schwartz, the Hannan–Quinn and the Final Prediction Error criteria. Based on the results, A VAR (1) model with no constants or trend is considered as the best fitted model and it is used to forecast 12 months ahead. In addition, API values are mainly determined by PM₁₀ that has a proportion close to one most of the time during study period. Therefore, authorities and researchers need to study the sources of PM₁₀ and provide the public with useful information and alternatives in term of reducing the air pollution.     

Thermal springs,fumaroles and gas vents of continental Yemen: Their relation with active tectonics,regional hydrology and the country’s geothermal potential

Most thermal springs of continental Yemen (about 65 emergences at 48 sampling sites) and a couple of fumaroles and boiling water pools have been sampled and analyzed for chemical and isotopic composition in the liquid phase and the associated free-gas phase. Whatever the emergence, all the water discharges have an isotopic signature of meteoric origin. Springs seeping out from high altitudes in the central volcanic plateau show a prevalent Na–HCO₃-composition, clearly affected by an anomalous flux of deep CO₂ deriving from active hydrothermal systems located in the Jurassic Amran Group limestone sequence and/or the Cretaceous Tawilah Group, likely underlying the 2000–3000 m thick volcanic suite. At lower elevations, CO₂ also affects the composition of some springs emerging at the borders of the central volcanic plateau.     

Principal component analysis for interaction of nitrifiers and wastewater environments at a full-scale activated sludge plant

This study investigated the relationship between wastewater environments and the nitrifiers at a full-scale plant using principal component analysis. Ammonia-oxidizing bacteria and nitrite-oxidizing bacteria were detected by florescent in situ hybridization, polymerase chain reaction, phylogenetic analysis, real-time quantitative polymerase chain reaction. Pyrosequencing was also used in profiling the ammonia monooxygenase locus of ammonia-oxidizing bacteria community. It was found that the dominant ammonia-oxidizing bacteria sequences were related to uncultured ammonia-oxidizing bacterium, uncultured Nitrosomonadaceae bacterium, Nitrosomonas sp., and uncultured bacterium. In addition, Nitrobacter clones were related to uncultured alpha proteobacterium, uncultured bacterium, uncultured Nitrobacter sp., and uncultured Bradyrhizobium sp., whereas Nitrospira clones were similar to uncultured bacterium, Candidatus Nitrospira defluvii, uncultured Nitrospira sp., and uncultured Nitrospirae bacterium. The ammonia-oxidizing bacteria and nitrite-oxidizing bacteria ranged 2.83 × 10⁸–1.33 × 10¹⁰ and 1.25 × 10¹⁰–1.13 × 10¹¹ copies L^?1, respectively, equivalent to nitrite-oxidizing bacteria: ammonia-oxidizing bacteria ratio of 10:1. The first three parts of the principal components analysis accounted for 76.8% of the explained variance. The first principal component (44.4%) designated that ammonia-oxidizing bacteria and Nitrospira were mainly influenced by seasonal variations, followed by chemical oxygen demand concentration and nitrogen species (i.e., ammonia, nitrite, and nitrate). The second principal component (19.1%) showed no information about the nitrifiers’ interaction with environmental factors, whereas Nitrobacter demonstrated a high correlation with ammonia on the third principal component (13.3%). These results revealed that the species of Nitrobacter were less influenced by environmental conditions than ammonia-oxidizing bacteria and Nitrospira spp.     

Electro‐Fenton Treatment of Photographic Processing Wastewater

In this work, the treatment of photographic processing wastewaters (PPW) by electro‐Fenton process has been investigated. The Influence of operating conditions on kinetics and efficiency of electro‐Fenton process has been evaluated using carbon felt cathode and platinium (Pt) or boron‐doped diamond (BDD) anode. The results of electro‐Fenton treatment of PPW have shown that nearly complete removal of total phenols was obtained for all combinations with pseudo‐first rate constants of 0.07, 0.012, and 0.018/min for carbon felt/Pt, carbon felt/BDD and Pt/BDD cathode/anode combinations, respectively. The combination of carbon felt cathode with BDD anode achieved the highest total organic carbon (TOC) removal of 90%, while it did not exeed 40% for carbon felt/Pt combination. Increasing current intensity and Fe²⁺ dose enhances the efficiency of electro‐Fenton process. However, increasing pH decreases TOC removal during the treatment of PPW by electro‐Fenton process. The highest efficiency of electro‐Fenton process using BDD anode can be explained by the contribution of direct and indirect oxidation routes in the degradation mechanism of organics including (i) oxidation via hydroxyl radicals generated from the catalytic decomposition of H₂O₂ and from water discharge on BDD anode, (ii) direct oxidation of certain organic compounds on BDD anode, and (iii) mediated oxidation with inorganic oxidants electrogenerated from anodic oxidation of supporting salts.     

Laboratory Study on the Relative Performance of Silty-Sand Soils Reinforced with Linen Fiber

Randomly distributed fibers have been successfully used for the reinforcement of soils to improve their properties. However, the technique requires extensive testing on samples before it can be implemented. Therefore, the purpose of this paper is to identify and quantify the influence of variables of linen-fiber (content and aspect ratio) on the performance of linen-fiber reinforced silty-sand specimens. The linen fibers have filament textures with special properties such as: low costs, plenitude in the region, lightweight, tension capacity and relative strength against deterioration. Linen fibers with diverse fiber contents (0.25, 0.50, 0.75 and 1.0% of dry weight) and ratio aspect (50, 100 and 150) were used. The composite soils were laboratory tested for compaction, unconfined compression strength (UCS), California Bearing Ratio (CBR) and direct shear tests. The test results indicated that adding linen fiber in silty-sand soil resulted in increasing in unconfined compression strength, California Bearing Ratio values, peak friction angle and cohesion values. Furthermore, adding linen fibers have the dual benefit of increasing the stiffness (modulus of elasticity) and the ductility of the reinforced soil. However, this study suggests that the optimum fiber content for silty-sand samples reinforced with linen fibers is approximately 0.75% of the dry weight of the soil and a maximum performance was achieved at aspect ratio of 100 to avoid fiber balling. The laboratory results were used for the development of linear regression equation that best relates the UCS and CBR of a reinforced soil to the aforementioned parameters.     

Evaluating the geothermal heat pump potential from a thermostratigraphic assessment of rock samples in the St. Lawrence Lowlands,Canada

The installation cost and the performance of geothermal heat pump systems are influenced by the thermal state and properties of the subsurface. The ground ability to transfer heat described by thermal conductivity is a dominant factor affecting the favorability of closed-loop ground heat exchangers installed in vertical boreholes. A study that aimed at evaluating the geothermal heat pump potential by mapping the thermal conductivity of rock sequences was, therefore, performed for the St. Lawrence Lowlands sedimentary basin in Canada. Thermal conductivity was measured in the laboratory on rock samples collected in outcrops and used to complete design calculations of a geothermal system with a single borehole. Results allowed the definition of thermostratigraphic units that can be linked to depositional environments. Basal quartz-rich sandstones formed in a rift environment show a high geothermal potential. Overlying dolomites, argillaceous limestones and shales deposited in a passive margin evolving to a foreland basin exhibit a transition toward the top from high to low geothermal potential. Upper turbidites and molasses have a moderate geothermal potential. The thermal conductivity of the thermostratigraphic units is dominantly influenced by the mineralogy of the sedimentary rocks. Understanding their origin is a key to improve geothermal resource assessment and system design to anticipate new installations in the area.     

Treatment of Refractory Organics Contained in Actual Agro‐Industrial Wastewaters by UV/H2O2

In this work, the treatment of actual agro‐industrial wastewaters (IWW) by a UV/H₂O₂ process has been investigated. The aqueous wastes were received from industrial olive oil mills and then treated by laboratory scale physicochemical methods, i. e., coagulation using ferrous and aluminum sulfate, decantation, filtration and adsorption on activated carbon. These wastes are brown colored effluents and have a residual chemical oxygen demand (COD) in the range of 1800 to 3500 mgO₂ L^–1, which cannot be further eliminated with physicochemical processes. The UV/H₂O₂ treatments were carried out under monochromatic irradiation at 254 nm using a thermostated reactor equipped with a mercury vapor lamp located in an axial position. The effects of initial H₂O₂ concentration, initial COD, pH and temperature have been studied in order to determine the optimum conditions for maximum color and COD removals. The experimental results reveal the suitability of the UV/H₂O₂ process for both removal of high levels of COD and effectively decolorizing the solution. In particular, 95% of color removal and 90% of COD removal were obtained under conditions of pH = 5 and 32°C using 2.75 g H₂O₂ g^–1 COD L^–1 during 6 h of UV‐irradiation. The treatment is unaffected by pH over the range 2 to 9. In addition, the COD removal is improved by increasing the temperature, whereas the color removal has not been affected by this parameter. The results show that the hydroxyl radicals generated from the catalytic decomposition of H₂O₂ by UV‐irradiation of the solution could be successfully used to mineralize the organics contained in IWW. The mineralization of the organics seems to occur in three main sequential steps: the first is the rapid decomposition of tannins leading to aromatic compounds, which are confirmed by the decolorization of the IWW; the second step corresponds to the oxidation of aromatics leading to aliphatic intermediates, which occurs by the cleavage of an aromatic ring, and is established by the removal of aromatics, and the final step is the slow oxidation of the aliphatic intermediates, which is measured by the COD removal.