The carbohydrates in relation to mineralogic and granulometric composition of surface sediments in the karst estuary (River Krka estuary,Yugoslavia)

The investigation of mineral, granulometric and chemical composition of sediments of the River Krka estuary (Yugoslavia) were performed in order to elucidate the origin of the sediments and the pattern of sedimentation. Estuarine surface sediments were found to be fine-grained with a bimodal distribution. Environmental conditions in estuarine sediments favour conservation of the organic matter (anoxic conditions). The carbohydrates in the sediments were investigated to determine whether they are of terrigenous or authigenous origin. Glucose, galactose, mannose, xylose, rhamnose, glucosamine and glucuronic acid were detected in the sediments. Their mutual relationship indicates a preferentially terrigenous source of sedimented organic material in estuarine sediments.     

Hydrogen and Helium under high pressure: A case for a classical theory of dense matter

When subject to high pressure, H₂ and ³He are expected to undergo phase transitions, and to become metallic at a sufficiently high pressure. Using a semiclassical theory of dense matter proposed by Savi and Kaanin, calculations of phase transition and metallisation pressure have been performed for these two materials. In hydrogen, metallisation occurs at p _M= (3.0 ± 0.2) Mbar, while for helium the corresponding value is p _M= (106 ± 1) Mbar. A phase transition occurs in helium at p _tr= (10.0 ± 0.4) Mbar. These values are close to the results obtainable by more rigorous methods. Possibilities of experimental verification of the calculations are briefly discussed.     

Eta model forecasts of tropical cyclones from Australian Monsoon Experiment: Dynamical adjustment of initial conditions

Summary The University of Belgrade/National Meteorological Centre, Washington (UB/NMC) limited area Eta Model predicted the development, structure, associated precipitation and tracks of the Australian Monsoon Experiment (AMEX) (10 January through 15 February 1987) tropical cyclonesConnie, Irma, Damien andJason. The initial positions and intensities of the tropical cyclone vortices from the global European Centre for Medium-Range Weather Forecasts (ECMWF) analyses, which are used as initial data, do not quite agree with the observations. These disagreements produce additional erros in predicting the tropical cyclone tracks.To improve the initial position of the vortex, the flow is split into the small and the large scale motions, and during the first two hours of the integration, the small-scale part is forced in small steps towards its observed position. The adjustment is performaed with the reduced model dynamics (adjustment processes only) and no physics.With the adjustment during the first two hours of the integration, the model successfully adjusts to the new position of the initial vortex. After the completion of the adjustment stage, the model runs normally, i.e., without any modification. The tracks of the 48-h forecasts with the adjusted initial vortices are parallel to the tracks obtained in the control forecasts without the adjustment. However, e.g., the mean absolute error of the positions during 48-h forecast of the tropical cycloneConnie was reduced from 174 km in the control case to 129 km in the case with adjustment of the position.The latent heat, the thermal energy, the kinetic energy and the total energy of the extracted small scale vortices are calculated every three hours of the integration time. These small-scale energies obtained in the 48-h control forecast are compared to those of the rund with the initial vortex adjustment to monitor the spin up of the model.With 7 Figures     

A bilinear approximation of the surface relief in terrain correction computations

A new method is presented for the computation of the gravitational attraction of topographic masses when their height information is given on a regular grid. It is shown that the representation of the terrain relief by means of a bilinear surface not only offers a serious alternative to the polyhedra modeling, but also approaches even more smoothly the continuous reality. Inserting a bilinear approximation into the known scheme of deriving closed analytical expressions for the potential and its first-order derivatives for an arbitrarily shaped polyhedron leads to a one-dimensional integration with – apparently – no analytical solution. However, due to the high degree of smoothness of the integrand function, the numerical computation of this integral is very efficient. Numerical tests using synthetic data and a densely sampled digital terrain model in the Bavarian Alps prove that the new method is comparable to or even faster than a terrain modeling using polyhedra.     

Croatia — a coastal and maritime country

Croatia, through its geographic position, is a Mediterranean/Adriatic and Central European/Danube state. As an Adriatic coastal state, it has a long maritime tradition, which is apparent in its well-developed shipping (2.4 million GT), the high-quality ship-building industry (among the top six in the world) and through its numerous sea ports, of which many were established in ancient times. The leading national port is Rijeka, which is at the same time an important transit port for Austria, Hungary, Slovakia and the Czech Republic.The exceptionally indented Croatian Adriatic coast with its attractive archipelagos and favorable climatic and oceanographic conditions in the coastal sea offers very advantageous conditions for comprehensive tourist utilization. This is particularly true of nautical tourism, which is complimented by a larger number of constructed and well-equipped yachting ports/marinas on the coast and islands.     

Preservation of diagenetic products of β-carotene in sedimentary rocks from the Lopare Basin (Bosnia and Herzegovina)

Sedimentary rocks from the saline formation of the Lopare Basin were investigated. Sediments contain a moderate amount of immature to marginally mature algal organic matter deposited under slightly reducing to anoxic and slightly saline to hypersaline conditions. Almost all of the samples contain β-carotane in a relatively high quantity, and in some, it represents the most abundant compound in the total distribution of hydrocarbons. The objective of the study was to determine the conditions that are favourable to precursors of β-carotene and/or the preservation of the carotenoid hydrocarbon skeleton. Moreover, the dominant transformation pathways of β-carotene under different redox and salinity conditions, which lead to the formation of aromatic carotenoids were defined.     

The crystal structure of bøgvadite (Na2SrBa2Al4F20)

The crystal structure of bøgvadite, Na₂SrBa₂Al₄F₂₀, has been solved and refined to a R₁ factor of 4.4 % from single-crystal data (MoKα X-ray diffraction, CCD area detector) on a sample from the cryolite deposit at Ivittuut, SW Greenland. Bøgvadite is monoclinic, P2₁/n space group, with unit cell parameters a?=?7.134(1), b?=?19.996(3) and c?=?5.3440(8) Å, β?=?90.02(1)^o. A close proximity of the crystal structure to an orthorhombic symmetry and the presence of the two twin components in a nearly 1:1 ratio suggest that the investigated bøgvadite crystal has originally formed as a high-temperature orthorhombic polymorph which on cooling transformed to the stable low temperature monoclinic structure. The bøgvadite crystal structure has groupings of cation-fluoride coordination polyhedra similar to those found in the crystal structures of the genetically closely associated minerals jarlite and jørgensenite. However, its structure type is different from the latter two. The fluoridoaluminate framework of bøgvadite consists of infinite zig-zag chains of cis-connected AlF₆ coordination octahedra. The ¹ _∞[AlF₅] chains are interconnected by infinite chains of Na-F coordination polyhedra which extend in the same direction. Na is coordinated by nine F atoms if its full surrounding is taken in consideration, but makes significant chemical bonds only to closest five. The chains of AlF₆ and NaF₉ coordination polyhedra form double layers. In the centre of layers, relatively large voids in the form of pentagonal antiprisms are occupied by Sr atoms which make chemical bonds with the closest six F atoms. Between the SrF₁₀ coordinations in the centre of layers run empty channels. The double layers are interconnected by Ba atoms which are coordinated by eight F atoms and fill the spaces between the layers. Bøgvadite belongs to the group of fluoridoaluminates with infinite chains of cis-connected AlF₆ coordination octahedra, alike those found in the crystal structures of Ba-fluoridoaluminates.     

Occurrence and geochemistry of arsenic in the groundwater of Eastern Croatia

In order to examine the extent of the As enrichment and the factors influencing this enrichment in the groundwater of Eastern Croatia, groundwater samples were collected from 56 production wells in two counties, Osijek-Baranja and Vukovar-Srijem, suspected to be more affected. Hydrochemical analyses were performed at all locations including in situ As speciation at 32 locations. Arsenic was detected in 46 out of 56 groundwater samples with total As concentrations up to 491 μg/L. Thirty-six of the studied wells yielded groundwater with total As concentrations that exceeded the WHO Maximum Contaminant Level for arsenic in drinking water of 10 μg/L. Only inorganic As species were detected with arsenite As(III) as the predominant form. The spatial distribution of As in the groundwater was significantly linked with geological, geomorphological and hydrogeological development of the alluvial basin of the Drava and Sava rivers. The most probable groundwater As sources are deeper sediments from the Middle and Upper Pleistocene. The results obtained suggest that biogeochemical processes controlling As concentration in the groundwater are complex and location-specific. Reductive dissolution of Fe oxides, desorption of As from Fe oxides and/or clay minerals as well as competition for the sorption sites with organic matter and phosphate could be the principal mechanisms that control As mobilization. The extent of those processes vary in the different parts of the Drava and Sava depressions and could be linked to different site related parameters, such as lithology, mineralogy, local hydrology and hydrogeology; thus different processes of As mobilization have been proposed for the different types of water in relation to groundwater evolution.     

Dynamical portrait of the Lixiaohua asteroid family

In this paper we present a comprehensive analysis of the dynamics in the region of the (3556) Lixiaohua asteroid family. The family lies in a particularly interesting region of the phase space, crossed by several two-body and three-body mean motion resonances. Also, members of this family can have close encounters with large asteroids, such as Ceres. We have identified the mean motion resonances which contribute to the long-term dynamical evolution of the family and our results confirm that the members of this family can be classified into a number of groups, exhibiting different dynamical behavior. We show for the first time that in the Lixiaohua region, apart from the chaotic diffusion in proper eccentricity and inclination (e _p and I _p ), there is at least one extended chaotic zone where several resonances overlap, thus giving rise to chaotic diffusion in proper semi-major axis (a _p ) as well. Using a code of Monte Carlo type, we simulate the evolution of the family, according to the model which combines the chaotic diffusion (in a _p , e _p and I _p ), Yarkovsky/YORP thermal effect and random walk in a _p due to the close encounters with massive asteroids. These simulations show that all these effects should be taken into account in order to accurately explain the observed distribution of family members in the space of proper elements, although a “minimal” model that accounts for chaotic diffusion in (e _p , I _p ), Yarkovsky-induced drift in a _p and random walk in a _p due to the close encounters with the most massive asteroids is enough to grossly characterize the shape of the family.