Isotope fractionation of neon during stepheating extraction?: a comment on ‘Re‐interpretation of the existence of a primitive plume under Australia based on neon isotope fractionation during step heating’ by Gautheron and Moreira (2003)

Using a Rayleigh distillation fractionation model, we calculate that the maximum isotope fractionation potentially achievable is less than 5% during the early stages of gas release from a sample. Our calculation corrects the erroneous conclusions of Gautheron and Moreira (2003), who re‐interpreted the plume‐like neon isotopic compositions found in metasomatic apatite from a south‐eastern Australian xenolith (Matsumoto et al., 1997) to be the result of Rayleigh‐type isotope fractionation of originally MORB‐type neon during stepheating gas extraction. We stress that the modelling of neon isotopic fractionation by Gautheron and Moreira (2003) is incorrect, and that the finding of a plume‐like neon isotopic composition in the apatite by Matsumoto et al. (1997) remains a quite valid and robust conclusion.     

SHRIMP U–Pb ages of diagenetic and hydrothermal xenotime from the Archaean Witwatersrand Supergroup of South Africa

SHRIMP dating of xenotime overgrowths on detrital zircon grains can constrain maximum durations since diagenesis and therefore provide minimum dates of sediment deposition. Thus, xenotime dating has significant economic application to Precambrian sediment-hosted ore deposits, such as Witwatersrand Au–U, for which there are no precise depositional ages. The growth history of xenotime in the Witwatersrand Supergroup is texturally complex, with several phases evident. The oldest authigenic xenotime ²⁰⁷Pb/²⁰⁶Pb age obtained in sandstone underlying the Vaal Reef is 2764 ± 5 Myr (1 σ), and most likely represents a mixture of diagenetic and hydrothermal growth. Nevertheless, this represents the oldest authigenic mineral age yet recorded in the sequence and provides a minimum age of deposition. Other xenotime data record a spread of ages that correspond to numerous post-diagenetic thermotectonic events (including a Ventersdorp event at ≈ 2720 Ma) up to the ≈2020 Ma Vredefort event.     

Late Holocene great earthquakes and relative sea‐level change at Kenai,southern Alaska

Kenai, located on the west coast of the Kenai Peninsula, Alaska, subsided during the great earthquake of AD 1964. Regional land subsidence is recorded within the estuarine stratigraphy as peat overlain by tidal silt and clay. Reconstructions using quantitative diatom transfer functions estimate co‐seismic subsidence (relative sea‐level rise) between 0.28±0.28 m and 0.70±0.28 m followed by rapid post‐seismic recovery. Stratigraphy records an earlier co‐seismic event as a second peat‐silt couplet, dated to ～1500–1400 cal. yr BP with 1.14±0.28 m subsidence. Two decimetre‐scale relative sea‐level rises are more likely the result of glacio‐isostatic responses to late Holocene and Little Ice Age glacier expansions rather than to co‐seismic subsidence during great earthquakes. Comparison with other sites around Cook Inlet, at Girdwood and Ocean View, helps in constructing regional patterns of land‐level change associated with three great earthquakes, AD 1964, ～950–850 cal. yr BP and ～1500–1400 cal. yr BP. Each earthquake has a different spatial pattern of co‐seismic subsidence which indicates that assessment of seismic hazard in southern Alaska requires an understanding of multiple great earthquakes, not only the most recent. All three earthquakes show a pre‐seismic phase of gradual land subsidence that marked the end of relative land uplift caused by inter‐seismic strain accumulation. Copyright © 2005 John Wiley & Sons, Ltd.     

Low-cost volcano surveillance from space: case studies from Etna, Krafla, Cerro Negro, Fogo, Lascar and Erebus

 Satellite data offer a means of supplementing ground-based monitoring during volcanic eruptions, especially at times or locations where ground-based monitoring is difficult. Being directly and freely available several times a day, data from the advanced very high resolution radiometer (AVHRR) offers great potential for near real-time monitoring of all volcanoes across large (3000×3000 km) areas. Herein we describe techniques to detect and locate activity; estimate lava area, thermal flux, effusion rates and cumulative volume; and distinguish types of activity. Application is demonstrated using data for active lavas at Krafla, Etna, Fogo, Cerro Negro and Erebus; a pyroclastic flow at Lascar; and open vent systems at Etna and Stromboli. Automated near real-time analysis of AVHRR data could be achieved at existing, or cheap to install, receiving stations, offering a supplement to conventional monitoring methods. Received: 21 January 1997 / Accepted: 3 April 1997     

A laboratory test of the soil chemical submodels of two models of catchment acidification

Parameters for ion exchange selectivity and aluminium hydroxide dissolution in the soil chemical submodels used in applications of the Birkenes model and of MAGIC are compared and several discrepancies identified for organic soils. A laboratory column simulation of the soil chemical submodels is proposed and applied to soils from the Loch Dee area in Galloway. Experimental results were well predicted by a simplified version of MAGIC, with ion exchange selectivity parameters similar to those used in a previous simulation of one subcatchment of Loch Dee. The aluminium hydroxide dissolution parameter used previously was found to be too low for the organic soil materials, where a value of 106 predicted the experimental results more closely. The model developed also included a simple silicate weathering reaction to release base cations into the system. It is concluded that such simple laboratory simulations are useful for independent calibration of the soil chemical submodel of catchment models.     

Quaternary stratigraphy of the buried valleys of the lower Red Deer River,Alberta, Canada

The Quaternary fills of the buried valleys of southern Alberta and Saskatchewan have provided a wealth of information for the reconstruction of the glacial-interglacial record of the western plains of Canada, and this paper reports on the previously unstudied stratigraphy of the buried Calgary Valley and its former tributaries in the lower Red Deer River area. We attempt to differentiate Empress Group sediments, which potentially relate to pre-glacial, interglacial/ interstadial and post-glacial lake and river deposition, using sedimentology, stratigraphy and palaeoecology. Twenty-nine stratigraphical logs indicate that Empress Group sediments have infilled a considerably large area of badlands and tributary coulees that once drained into the Calgary Valley, located 15 km to the north of Dinosaur Provincial Park. Radiocarbon dates of 52.4 ka, 27.4 ka and > 42.4 ka and glacially modified quartz grains suggest that at least some of the valley fills date to interglacial or interstadial periods and may be mid-Wisconsinan in age. However, outcrops of an older till overlying other valley fills suggest that the buried valleys were only partially excavated during interglacials/interstadials and that older (even pre-glacial) sediments could have survived. Subglacial channels, recognisable on air photographs, largely coincide with buried valley positions due to the preferential excavation of the Quaternary sediment by meltwater and are filled with post-glacial lake sediment from which a radiocarbon date of 16 ka BP was obtained. Pre-glacial and glacial/post-glacial Empress Group sediments are lithologically indistinct but cover a large time span in southern Alberta.     

Dissolved organic carbon dynamics in two streams draining forested catchments at loch ard,Scotland

Dissolved organic carbon (DOC) was measured at four or eight hour intervals between mid-1989 and mid-1991 in two catchments in west central Scotland. The experimental catchment had been recently clear-felled and the control remained under forest. The amount of DOC varied during individual storm events following the stream hydro-graph. Maximum variations were found in the summer half-year and in the clear-felled catchment. There was also evidence of the exhaustion of DOC in the later events of a sequence. Differences between the catchments were related to catchment characteristics and to land-use change. The reduced magnitude of variation in DOC with discharge in the control stream was due to the influence of a wetland area through which the stream flowed. The mean DOC concentrations were similar in the two streams and annual exports were 15 g m^?2 from the control and 16g m^?2 from the felled catchment. The stream draining the clear-felled catchment had greater high flow DOC concentrations in the summer half-year, probably due to the effect of greater mean summer temperatures on DOC release and of the greater supply of organic debris in the stream channel.     

Reviews

OFFICE DEVELOPMENT: A Geographical Analysis by M. Bateman. 14 × 22 cm, xvi and 175 pages. Croom Helm: London 1985 (ISBN 0 7099 0697 8) $A35.95 (cloth).

ATLAS OF YOUTH UNEMPLOYMENT, 1981: The Geographic Distribution of Youth Unemployment in Australian Cities from the 1981 Census According to Birthplace and Gender by P. Matwijiw with E. Bamford and C. Maher. 21 × 29 cm, 127 pages. Australian Institute of Multicultural Affairs: Melbourne 1985 (ISBN 949890 33 2) $A12.00 (limp).

ENVIRONMENT AND HEALTH by A. J. Rowland and P. Cooper. 23 × 16 cm, vi and 205 pages. Edward Arnold: London 1983 (ISBN 0 7131 2855 0) $A27.95 (limp).

FAMINE AS A GEOGRAPHICAL PHENOMENON edited by B. Currey and G. Hugo. 17 × 24 cm, vi and 202 pages. Reidel: Dordrecht 1984 (ISBN 90 277 1762 1) Dfl 95.00, $US37.00 (cloth).

SOUTH AUSTRALIA'S CHANGING POPULATION (South Australian Geographical Papers No. 1) by G. J. Hugo. 25 × 18 cm, 71 pages. Royal Geographical Society of Australasia (SA Branch): Adelaide 1983 (ISBN 0 909112 05 03) $A4.00 (limp).

DEVELOPMENTS IN POLITICAL GEOGRAPHY edited by M. A. Busteed. 23 × 15 cm, 340 pages. Academic Press: London 1983 (ISBN 0 12 148420 3) $US42.00 (cloth).

NEITHER JUSTICE NOR REASON: A Legal and Anthropological Analysis of Aboriginal Land Rights by M. Gumbert. 22 × 14 cm, xv and 215 pages. University of Queensland Press: St Lucia 1984 (ISBN 0 7022 1746 8) $A20.00 (cloth).

RURAL RESOURCE MANAGEMENT by P. J. Cloke and C. C. Park. 14 × 22 cm, xiii and 473 pages. Croom Helm: London 1985 (ISBN 0 7099 2037 7) $A44.95 (cloth).

FARM POLICY IN AUSTRALIA by R. K. Hefford. 14 × 22 cm, xviii and 415 pages. University of Queensland Press: St Lucia 1985 (ISBN 0 7022 1698 4) $A40.00 (cloth).

TRANSPORT AND COMMUNICATIONS FOR PACIFIC MICROSTATES: Issues in Organisation and Management edited by C. C. Kissling. 14 × 21 cm, 192 pages. Institute of Pacific Studies, University of the South Pacific: Suva 1984. $A10.00 (cloth), $A8.00 (limp).

TIMES OF CRISIS: Epidemics in Sydney 1788–1900 by P. H. Curson. 15 × 25 cm, xii and 195 pages. Sydney University Press: Sydney 1985 (ISBN 0 424 00112 8). $A35.00 (cloth).

PEASANTS, SUBSISTENCE, ECOLOGY AND DEVELOPMENT IN THE HIGHLANDS OF PAPUA NEW GUINEA by L. S. Grossman. 24 × 16 cm, xxi and 302 pages. Princeton University Press: Princeton, NJ 1984 (ISBN 0 691 09406 3) $US45.50.

THE WORLD FOOD PROBLEM 1950–1980 by D. Grigg. 15 × 24 cm, 276 pages. Basil Blackwell: Oxford 1985 (ISBN 0 631 13481 6) $A58.50 (cloth).

POPULATION REDISTRIBUTION AND DEVELOPMENT IN SOUTH ASIA edited by L. A. Kosinski and K. M. Elahi. 17 × 24 cm, 243 pages. Reichel: Dordrecht 1985 (ISBN 90 277 1938 1) Dfl 120.00, $US44.00, £30.50 (cloth).

GEOGRAPHY AND ETHNIC PLURALISM edited by C. Clarke, D. Ley and C. Peach. 15 × 23 cm, xvii and 294 pages. Allen & Unwin: London 1984 (ISBN 0 04 309107 5) $A45.00 (cloth); (ISBN 0 04 309108 3) $A24.95 (limp).

SOCIAL GEOGRAPHY IN INTERNATIONAL PERSPECTIVE edited by J. Eyles. 14 × 22 cm, 295 pages. Croom Helm: London 1986 (ISBN 0 7099 0944 6) $A49.95 (cloth).

THE GENTRIFICATION OF INNER MELBOURNE: A Political Geography of Inner City Housing by W. S. Logan. 14 × 22 cm, xvi and 328 pages. University of Queensland Press: St. Lucia 1985 (ISBN 0 7022 1729 8) $A50.00 (cloth).

YELLOWCAKE AND CROCODILES: Town Planning, Government and Society in Northern Australia by J. Lea and R. Zehner. 14 × 22 cm, xxvi and 200 pages. Allen & Unwin: Sydney 1986 (ISBN 0 86861 875 6) $A24.95 (cloth); (ISBN 0 86861 843 8) $A 14.95 (limp).

THE BUNGALOW: The Production of a Global Culture by A. D. King. 20 × 25 cm, xii and 310 pages. Routledge & Kegan Paul: London 1984 (ISBN 0 7100 9538 4) $A62.50 (cloth).

THE WEST EUROPEAN CITY: A Social Geography by P. White. 15 × 23 cm, xviii and 269 pages. Longman: London 1984 (ISBN 0 582 30047 9) $A22.95 (limp).

THE SHAPING OF AMERICA: A Geographical Perspective on 500 years of History. Volume 1. Atlantic America, 1492–1800 by D. W. Meinig. 18 × 25 cm, xii and 500 pages. Yale University Press: New Haven 1986 (ISBN 0 300 03548 9) $US35.00 (cloth).

CANBERRA: MYTHS AND MODELS. Forces at Work in the Formation of the Australian Capital by K. F. Fischer. 21 × 30 cm, 166 pages. Institute of Asian Studies: Hamburg 1984 (ISBN 3 88910 009 0).

THE GEOGRAPHY OF PEACE AND WAR edited by D. Pepper and A. Jenkins. 15 × 23 cm, vi and 222 pages. Basil Blackwell: Oxford 1985 (ISBN 0 631 13559 6) $A75.00 (cloth); (ISBN 0 631 14069 7) $A23.95 (limp).

POLITICAL GEOGRAPHY: World‐economy, Nation‐state and Locality by P. J. Taylor. 15 × 23 cm, × and 238 pages. Longman: London 1985 (ISBN 0 582 30088 6) $A24.95 (limp).

THE INDUSTRIAL GEOGRAPHY OF CANADA by A. Blackbourn and R. G. Putnam 14 × 22 cm, 201 pages. Croom Helm: London 1984 (ISBN 0 7099 0622 6) $A42.50 (cloth).

THE FOODMAKERS by S. Sargent. 13 × 20 cm, 296 pages. Penguin: Ringwood 1985 (ISBN 0 14 007359 0) $A8.95 (limp).

LIMITS TO PREDICTION edited by R. B. McKern and G. C. Lowenthal. 13 × 19 cm, xiii and 163 pages. Australian Professional Publications: Sydney 1985 (ISBN 0 949416 029) $A14.95 (limp).

THE KANGAROO KEEPERS edited by H. J. Lavery. 18 × 25 cm, xxvi and 211 pages. University of Queensland Press: St Lucia 1985 (ISBN 0 7022 1875 8).

PRACTICAL ECOLOGY by D. D. Gilbertson, M. Kent and F. B. Pyatt. 15 × 23 cm, 320 pages, Hutchinson: London 1985 (ISBN 0 09 162651 X) £8.95.

BASIC BIOGEOGRAPHY (Second edition) by N. Pears. 15 × 24 cm, × and 358 pages. Longman: London 1985 (ISBN 0 582 30120 3) $A24.95 (limp).

ENVIRONMENTAL CHANGE (Second edition) by A. Goudie. 23 × 15 cm, xi and 258 pages. Oxford University Press: Oxford 1983 (ISBN 0 19 874135 9) A16.00 (limp).

MEGA‐GEOMORPHOLOGY edited by R. Gardner and H. Scoging. 16 × 24 cm, xiii and 240 pages. Oxford University Press: Oxford (ISBN 0 19 823244 6) $A48.00.

GRANITE LANDFORMS by C. R. Twidale. 25 × 17 cm, xxiii and 372 pages. Elsevier: Amsterdam 1982 (ISBN 0 444 42116 5) $A148.25.     

The redox states of basic and silicic magmas: a reflection of their source regions?

At present the best estimates of the oxygen fugacity of spinel-lherzolites that could be the source material of basic magmas is about five log units below the Ni–NiO buffer to one above it. However partially glassy basic lavas, ranging from MORBs to minettes, all with olivine on their liquidus, cover a wider range, and may have oxygen fugacities that extend to four log units above NNO. Surprisingly the range of oxygen fugacities observed in silicic lavas and ashflows with quartz phenocrysts is smaller, despite a crustal dominated evolution. The peralkaline silicic lava type pantellerite is the most reduced, equivalent to MORBs, whereas the large volume ashflows with phenocrysts of hornblende and/or sphene are the most oxidised. As the concentration of water in the basic lavas is correlated with increase in their redox state, it would seem that water could be the agent of this increase. That this is unlikely is seen in the behavior of silicic ashflows and lavas, particularly those of Yellowstone. Here the silicic magmas of the last 2Ma contain about 2 wt% FeO_(total), and typically phenocrysts of fayalite, quartz and Fe–Ti oxides. Despite extensive exchange of the ¹⁸O of the magma with meteoric water after caldera collapse (Hildreth et al. 1984), there is no displacement of the redox equilibria. Thus the thermal dissociation of molecular H₂O to H₂, and its subsequent diffusive loss to cause oxidation must have been minimal. This could only be so if the activity of water was small, as it would be if H₂O reacted with the silicate liquid to form OH groups (Stolper 1982). The conclusion is that silicic magmas with small amounts of iron and large amounts of water do not have their redox states reset, which in turn presumably reflect their generation. By analogy basic magmas with large amounts of iron and far less water are even less likely to have their redox equilibria disturbed, so that their oxygen fugacities will also reflect their source regions. The effect of pressure on the ferric-ferrous equilibrium in basic magmas can be calculated from experimental measurements of the partial molar volumes of FeO and Fe₂O₃, and their pressure derivatives V/P, in silicate liquids. The effect of pressure is found to be about the same on the liquid as it is for various solid oxygen buffers. Accordingly there should be mantle source regions covering the same range of oxygen fugacity as that found in basic lavas, but so far samples of spinel-lherzolite of equivalent oxygen fugacity to minettes or other potassic lavas have not been found. Whether or not the redox state of phlogopite-pyroxenites is equivalent to these potassic lavas cannot be established without experiment.