The geochemistry of lead in rivers,estuaries and the continental shelf of the Southeastern United States

Transport by southeastern rivers has insignificant influence on the lead concentration of southeastern shelf waters. If the rate of mobilization and transport of lead by these rivers is representative of uncontaminated fluvial transport during the Pleistocene, only about 5% of the prehistoric output of lead to the North Atlantic can be accounted for by river input.Lead concentrations in southeastern shelf waters are similar to those of North Atlantic Water from the upper 1000 m, which is probably similar to the intrusion source water for the shelf. Atmospheric inputs to the shelf of the same magnitude as observed for the Western North Atlantic are difficult to reconcile given the residence time of shelf waters and their lead concentration unless the rate of loss of lead to shelf sediments is about the same as the atmospheric flux.     

Coronal Holes and Icosahedral Symmetry

The study of the expansion of the solar wind out of a system of coronal holes is continued. To this end, we consider the numerical integration of partial differential equations for problems with icosahedral symmetry, in general. First, employing Weyl theory, orbifold coordinates are introduced. Second, the icosahedral coordinates are discussed in detail. Third, following an analysis of the properties of these coordinates and the derivation of a few expressions useful for grid construction, various alternatives for the distribution of lattice points required for numerical integration are considered. A comparison of these numerical grids motivates the choice of a specific grid optimized for the numerical integration carried out in the accompanying paper by Kalish et al.(2002). This revised version was published online in July 2006 with corrections to the Cover Date.     

Partitioning of Na between olivine and melt: An experimental study with application to the formation of meteoritic Na2O-rich chondrule glass and refractory forsterite grains

We report experimentally determined 1 atm olivine/melt D_Na partitioning data for low f_O2, a variety of melt compositions and a temperature range of 1325-1522 °C. We demonstrated that high-current electron microprobe analyses (EPMA, I = 500 nA, 600 s on the peak) allow quantitative determination of Na₂O in olivine down to ∼10 μg/g. The mean olivine/melt D_Na from 12 experimental runs is 0.0031 ± 0.0007 (1σ). This is the recommended value for low pressures and a wide range of natural compositions.This result is applied to the problem of the origin of alkalis in chondrules and the formation of chondritic refractory forsterite grains. The data on Semarkona (LL3.0) chondrules show that Na₂O is primordial and was present during olivine crystallization. For refractory forsterite grains from Murchison (CM2), we demonstrate that high CaO contents are not a result of equilibration with Na₂O-rich melts, but require high activities of CaO during their formation.     

An experimental analysis of spatial competition in a dense infaunal community: The importance of relative effects

A densely populated soft-sediment community was experimentally analysed for interspecific competition for space in laboratory experiments. No interspecific competitive interactions leading to a decrease in survivorship could be documented over a five-week period. The four most abundant species all coexisted in laboratory microcosms. The two tube-buiding species, the tanaid Leptochelia dubia and the polychaete Rhynchospio arenincola, could not exclude the mobile bivalve Transennella tantilla or the burrowing amphipod Paraphoxus spinosus. None of the species increases its emigration frequency when other species are present. Paraphoxus is found to be a browsing predator on Phynchospio but inflicts no detectable mortality. The coexistence of these species is permitted by virtue of the fact that none of the species can alter the soft-sediment habitat sufficiently to make the habitat unsuitable for the other species.     

New paleomagnetic results from the Aegean extensional province

Various Oligocene formations from NE Greece (ignimbrites from the Medousa area, rhyolites from Zagradenia, granodiorites from Elatia) show discordant paleomagnetic signatures, in each case indicating small cw (clockwise) rotation and also inclination flattening. Marls from Pithion were partly remagnetized in a present-day field. Samples that contain ancient magnetization components also indicate small cw rotation and inclination flattening. However, the magnetization of andesites from Peplos reflects a considerably larger rotation, likely owing to local tectonics. In the context of previous work in the area, these results are used to propose a subdivision of NE Greece into four structural zones of distinctive rotational behaviour (from east to west): sites in zone 1, east of the Kavala-Xanthi-Komotini fault (KXK), show various cw and ccw (counterclockwise) rotation angles owing to complex kinematics resulting from the interaction of the KXK and the north-Anatolian fault zone. However, zone 2, between the KXK and the Strymon valley, is structurally homogeneous ( 10° cw rotation). The paleomagnetic signature of the Vertiskos massif (zone 3) implies a larger (> 30°) cw rotation, whereas sites in the Vardar basin (zone 4) contain a paleomagnetic signature similar to that of zone 2. This suggests a motion of the Vertiscos massif, a meta-ophiolitic nappe, relative to underlying strata. Indeed, zones 2 and 4 may be parts of the same structural unit which underlies this nappe.     

Joule heating of Io's ionosphere by unipolar induction currents

The unexpectedly large scale height of Io's ionosphere (Kliore, A., et al., 1975, Icarus24, 407–410) together with the relatively large molecular weight of the likely principal constituent, SO₂ (Pearl, J., et al., 1979, Nature280, 755–758), suggest a high ionospheric temperature. Electrical induction in Io's ionosphere due to the corotating plasma bound to the Jovian magnetosphere is one possible source for attainment of such high temperatures. Accordingly, unipolar induction models were constructed to calculate ionospheric joule heating numerically. Heating rates produced by highly simplified models lie in the range 10^?9 to 10^?8 W/m³. These heating rates are lower than those determined from uv photodissociative heating models (Kumar, S., 1980, Geophys. Res. Lett.7, 9–12) at low levels in the ionosphere but are comparable in the upper ionosphere. The low electrical heating rate throughout most of the ionosphere is due to the power limitation imposed by the Alfvén wings which complete the electrical circuit (Neubauer, F.M., 1980, J. Geophys. Res.85, 1171–1178). Contrary to the pre-Voyager calculations of Cloutier, P. A., et al. (1978, Astrophys. Space Sci.55, 93–112), our numerical results show that the J × B force density due to unipolar induction currents in the ionosphere is much less than the gravitational force density when the combined mass of the neutral species is included. The binding and coupling of the ionosphere is principally due to the relatively dense (possibly localized) neutral SO₂ atmosphere. In regions where the ions and neutrals are collisionally coupled the ionosphere will not be stripped off by the J × B forces. However at a level above that (to which the ions move by diffusion only) the charged species would be removed. Thus there appears to be no need to postulate the existence of an intrinsic Ionian magnetic field as suggested by Kivelson, M. G., et al. (79, Science 205, 491–493) and Southwood, S. J., et al. (1980, J. Geophys. Res., in press) in order to retain the observed ionosphere.     

Origin of the Earth's ocean basins

The Earth's original ocean basins are proposed to be mare-type basins produced 4 billion y.a. by the flux of asteroid-sized objects responsible for the lunar mare basins. Scaling upward from the observed number of lunar basins for the greater capture cross-section and impact velocity of the Earth indicates that at least 50% of an original global crust would have been converted to basin topography. These basins were flooded by basaltic liquids in times short compared to the isostatic adjustment time for the basin. The modern crustal dichotomy (60% oceanic, 40% continental crust) was established early in the history of the Earth, making possible the later onset of plate tectonic processes. These later processes have subsequently reworked, in several cycles, principally the oceanic parts of the Earth's crust, changing the configuration of the continents in the process. Ocean basins (and oceans themselves) may be rare occurences on planets in other star systems.     

Sources of Sediment in Lake Pepin on the Upper Mississippi River in Response to Holocene Climatic Changes

Sediments from Lake Pepin on the Mississippi River, southeastern Minnesota, are used as provenance tracers to assess variations in hydrology and sediment-transport during the middle Holocene. Three rivers contribute sediment to Lake Pepin, and each catchment is characterized by a distinctly different geologic terrain. The geochemical fingerprint for each drainage basin was determined from the elemental composition of heavy minerals in the silt-sized fraction of modern sediment samples. Down-core elemental abundances were compared with these fingerprints by use of a chemical-mass-balance model that apportions sediment to the source areas. We observed a decreased contribution from the Minnesota River during the interval ~6700–5500 ¹⁴C yr BP, which we attribute to decreased discharge of the Minnesota River, likely controlled by a combination of precipitation, snow melt, and groundwater input to the river. This hydrologic condition coincides with the mid-Holocene prairie period recorded by fossil pollen data. The occurrence of this feature in a proxy record for hydrologic variations supports the hypothesis that the mid-Holocene prairie period reflects drier conditions than before or after in midwestern North America.     

Origin of chondritic forsterite grains

Iron-poor and refractory lithophile element (RLE) rich forsterite grains occur in all major types of unequilibrated chondrites. In our laser ablation inductively coupled mass spectrometry (LA-ICPMS) minor and trace element study we show that refractory forsterites (RF) from carbonaceous (CC), unequilibrated ordinary (UOC) and a Rumuruti chondrite (RC) have similar chemical compositions with high RLE concentrations and low concentrations of Mn, Fe, Co and Ni. Fractionation of RLEs and rare earth elements (REEs) is in agreement with formation by crystallization from a RLE rich silicate melt. Low concentrations and the fractionation of moderately siderophile elements (Fe, Co, Ni) in RFs suggests formation at low oxygen fugacity, possibly in equilibrium with primitive Fe,Ni metal condensates in a gas of solar composition. Anomalously high Ti in the parental melt can be explained by Ti³⁺/Ti⁴⁺ ∼1.5, supporting formation of RF in highly reducing conditions. Low Mn concentrations indicate formation at high temperatures (>∼1160 K). The model of formation of RFs and the accompanying physico-chemical conditions during their formation as well as their relation to non refractory olivine are discussed.