Diagenetic formation of gypsum and dolomite in a cold‐water coral mound in the Porcupine Seabight,off Ireland

Authigenic gypsum was found in a gravity core, retrieved from the top of Mound Perseverance, a giant cold‐water coral mound in the Porcupine Basin, off Ireland. The occurrence of gypsum in such an environment is intriguing, because gypsum, a classic evaporitic mineral, is undersaturated with respect to sea water. Sedimentological, petrographic and isotopic evidence point to diagenetic formation of the gypsum, tied to oxidation of sedimentary sulphide minerals (i.e. pyrite). This oxidation is attributed to a phase of increased bottom currents which caused erosion and enhanced inflow of oxidizing fluids into the mound sediments. The oxidation of pyrite produced acidity, causing carbonate dissolution and subsequently leading to pore‐water oversaturation with respect to gypsum and dolomite. Calculations based on the isotopic compositions of gypsum and pyrite reveal that between 21·6% and 28·6% of the sulphate incorporated into the gypsum derived from pyrite oxidation. The dissolution of carbonate increased the porosity in the affected sediment layer but promoted lithification of the sediments at the sediment‐water interface. Thus, authigenic gypsum can serve as a signature for diagenetic oxidation events in carbonate‐rich sediments. These observations demonstrate that fluid flow, steered by environmental factors, has an important effect on the diagenesis of coral mounds.     

Metamorphism of Calcic Pelitic Schists, Strafford Dome, Vermont: Compositional Zoning and Reaction History

Four assemblages from calcic pelitic schists from South Strafford,Vermont, have been studied in detail to determine the relationshipbetween reaction history and compositional zoning of minerals.The lowest-grade assemblage is garnet + biotite + chlorite +plagioclase + epidote + quartz + muscovite + graphite + fluid.Along a path of isobaric heating, the net reaction is Chl +Ms + Ep + Gr = Grt + Bt + Pl + fluid. Garnet grows with decreasingFe/(Fe + Mg) and X_Spa, (from 0•2 to 0•05), X_Gra staysnearly constant between 0•20 and 0•25, and plagioclasegrows with X_An increasing from peristerite to 0•2–0•5. The subsequent evolution depends on whether chlorite or epidotereacts out first. If chlorite is removed from the assemblagefirst, the net reaction along an isobaric heating path becomesGrt + Ms + Ep + Qtz + Gr = Bt + Pl + fluid. X_An of plagioclaseincreases to 0•20–0•70, depending on the bulk-rockcomposition and changes in pressure and temperature. If epidoteis removed first, the assemblage becomes a simple pelite andthe net reaction becomes Chl + Pl + Ms + Qtz = Grt + Bt + H₂O.Plagioclase is consumed to provide Ca for growing garnet, andX_An, Fe/(Fe + Mg) of garnet, X_Gra, and X_Spa all decrease. Afterboth chlorite and epidote are removed, continued heating upto the metamorphic peak of {small tilde}600C produces littleprogress of the reaction Grt + Ms = Bt + Pl; and X_An increases. The four assemblages have been numerically modeled using theGibbs method starting with measured compositions. The modelssuccessfully predict the observed compositional zoning and trendsof mineral growth and consumption along the computed P–Tpaths. The models also predict the compositional mineral zoningthat would have resulted from other P–T paths. ^* Present address: Department of Geology, University of Alabama, Tuscaloosa, Alabama 35487     

Vegetation and climate changes during the Eemian interglacial in Central and Eastern Europe: comparative analysis of pollen data

Velichko, A. A., Novenko, E. Y., Pisareva, V. V., Zelikson, E. M., Boettger, T. & Junge, F. W. 2005 (May): Vegetation and climate changes during the Eemian interglacial in Central and Eastern Europe: comparative analysis of pollen data. Boreas , Vol. 34, pp. 207–219. Oslo. ISSN 0300–9483.
The article discusses pollen data from Central and Eastern Europe and provides insight into the climate and vegetation dynamics throughout the Eemian interglacial (including preceding and succeeding transitional phases). Three sections with high resolution pollen records are presented. Comparison of the data indicates that the range of climatic and environmental changes increased from west to east, whereas the main phases of vegetation development appear to have been similar throughout the latitudinal belt. At the interglacial optimum, the vegetation in both Central and Eastern Europe was essentially homogeneous. An abrupt change marks the Saalian/Eemian boundary (transition from OIS 6 to OIS 5e), where environmental fluctuations were similar to those detected at the transition from the Weichselian to the Holocene (Allerød and Dryas 3). Transition from the Eemian to the Weichselian was gradual in the western part of the transect, with forest persisting. In the east, fluctuations of climate and vegetation were more dramatic; forest deteriorated and was replaced by cold open landscapes.     

Cr-rich magnesiochloritoid eclogites from the Monviso ophiolites (Western Alps, Italy)

Cr-rich magnesiochloritoid in the eclogitized ophiolites of the Monviso massif occurs in the least differentiated rocks of the gabbroic sequence (troctolites to melatroctolites). Chloritoid ( X _Mg=0.63–0.85; Cr≤0.55, atoms) co-exists with omphacite, talc and garnet. Minor, syn-eclogitic minerals are chromite, rutile and sometimes magnesite and Cr–Ti oxides.
Coronitic textures, indicative of a static recrystallization, characterize the analysed samples. Layers of variable mineral composition develop among igneous plagioclase, olivine, clinopyroxene and spinel. The minerals in the coronitic layers display sharp compositional zonings. The igneous minerals are commonly not preserved; their presence in the original assemblage is inferred from the mineralogical composition of the pseudomorphs.
Syn-eclogitic volatile components are indicated by the development of OH-bearing minerals (e.g. chloritoid & talc) and carbonates (e.g. magnesite), and supported by the presence of coarse-grained and fibrous mineral growths. The complex pseudomorphic replacements of igneous minerals suggest that these rocks changed their mineralogical composition prior to the eclogite facies recrystallization, most likely during ocean-floor metamorphism. It is suggested that syn-eclogitic fluids formed by breakdown reactions of pre-eclogitic volatile-bearing minerals.
Geothermobarometry indicates that the investigated rocks recrystallized at a depth corresponding to 2.4  GPa and temperatures of 620±50  °C. The attainment of high-pressure conditions is supported by the presence of magnesiochloritoid, magnesite and garnet with high pyrope content (up to 58  mol%). P–T  estimates point to a very low thermal gradient (about 9  °C km⁻¹), comparable to that deduced in the adjacent Dora-Maira ultra-high pressure unit.     

Age of the Pomeranian ice‐marginal position in northeastern Germany determined by Optically Stimulated Luminescence (OSL) dating of glaciofluvial sediments

Lüthgens, C., Böse, M. & Preusser, F. 2011: Age of the Pomeranian ice‐marginal position in northeastern Germany determined by Optically Stimulated Luminescence (OSL) dating of glaciofluvial sediments. Boreas, 10.1111/j.1502‐3885.2011.00211.x. ISSN 0300‐9843 The Pomeranian ice margin is one of the most prominent ice‐marginal features of the Weichselian glaciation in northern Europe. Previous results of surface‐exposure dating (SED) of this ice margin disagree with established chronologies and ice retreat patterns, i.e. are much younger than previously expected. We crosscheck the age of the Pomeranian ice‐marginal position in northeastern Germany using single‐grain quartz Optically Stimulated Luminescence (OSL) dating of glaciofluvial sediments. OSL dating indicates an active ice margin between 20.1±1.6 ka and 19.4±2.4 ka forming outwash plains attributed to the Pomeranian ice‐marginal position. On the basis of these results, we suggest a critical reassessment of previous SED data available for the Pomeranian ice‐marginal position within their respective regional geomorphological contexts. From a process‐based point of view, SED ages derived from glacigenic boulders document the stabilization of the landscape after melting of dead ice and landscape transformation under periglacial conditions rather than the presence of an ice margin. SED indicates a first phase of boulder stabilization at around 16.4±0.7 ka, followed by landscape stabilization within the area attributed to the recessional Gerswalder subphase around 15.2±0.5 ka. A final phase of accumulation of glaciolacustrine and glaciofluvial sediments at around 14.7±1.0 ka documents the melting of buried dead ice at that time.     

Towards a chronology of the Late Pleistocene in the northern Alpine Foreland

Dating results from terrestrial records in the northern foreland of the Alps have been compiled in order to establish an independent chronostratigraphy for the climate history of this region. U/Th dates of peat deposited during the final phase of the Last Interglacial indicate that it lasted until at least c. 115 000 yr ago. The Early Würmian started with a period of severe cold climate causing a substitution of forest by tundra-like vegetation. It is assumed that during this period glaciers advanced to the margin of the foreland of at least the Western Alps. Sediments attributed to this glaciation are dated to about 103 000 yr. Three subsequent interstadials, all characterized by coniferous forest, were interrupted by cold stadials with steppe to tundra-like vegetation. The first interstadial is dated to about 95 000 yr. There is evidence for an interstadial with open coniferous woodland and three phases of steppe vegetation during the Middle Würmian, between c. 50000 and 30 000 yr ago. The last glaciation of the Alpine Foreland reached its maximum extension between 24 000 and 21 500 yr and glaciers rapidly collapsed before ˜17 500 yr ago. A series of minor re-advances during the Lateglacial is reported from within the Alps, but the glaciers barely reached the main Alpine valleys during this time. The last of these advances formed the Egesen moraine and occurred at about 11 800 yr ago during the Younger Dryas.