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1.
For several years now, an experimental simulation of Titan's atmosphere has been on going at LISA. A cold plasma is established in a gas mixture representative of the atmosphere of the satellite. In these experiments, more than 70 organic compounds have been identified, including the first identification in this type of experimental simulation of C4N2 already detected in its solid form on Titan, which suggests that the setup correctly mimics the chemistry of Titan's atmosphere.We have carried out the first experimental simulation including O-containing compounds in order to study the influence of the presence of CO on the chemical behavior of Titan's atmosphere. With the help of gas chromatography–mass spectrometry (GC–MS) and infrared spectroscopy (IRS) we can thus determine which minor species still undetected in Titan's atmosphere are likely to be present and understand the complex chemistry of the atmosphere of this satellite. Surprisingly we have identified unpredicted O-containing gaseous compounds, mainly ethylene oxide (also named oxirane, C2H4O). This molecule has been observed in the interstellar medium by observation in the millimeter region (Astrophys. J. 489 (1997) 553; Astron. Astrophys. 337 (1998) 275). On the contrary, the predicted O-compounds (formaldehyde and methanol) have not been identified in this experiment. Furthermore, we have identified NH3 in the gaseous products with an initial mixture of N2 (98%) and CH4 (2%).The paper describes the experimental device used in this work, in particular the IRS and GC–MS techniques. We also comment the results related to the detection of the O-containing compounds and NH3 and their implications on our knowledge of the chemistry of Titan's atmosphere and on the retrieval of the future Titan data expected from Cassini-Huygens. 相似文献
2.
Marie K. McCabe Zdeněk F. Švestka Russell A. Howard Bernard V. Jackson Neil R. Sheeley Jr. 《Solar physics》1986,103(2):399-408
By using a combination of X-ray (HXIS), H (Haleakala), white-light corona (Solwind), and zodiacal light (Helios) images on 21–22 May, 1980 we demonstrate, and try to explain, the co-existence of a coronal mass ejection with a stationary post-flare coronal arch. The mass ejection was seen, both by Solwind and Helios, in prolongation of the path of a powerful spray, whereas the active region filament did not erupt. A tentative comparison is made with other occurrences of stationary, or quasi-stationary post-flare coronal arches. 相似文献
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Thierry Penduff Bernard Barnier Jean-Marc Molines Gurvan Madec 《Ocean Modelling》2006,11(3-4):399-416
The evaluation of ocean simulations against observed datasets is essential to assess their realism and to guide model development, but often remains qualitative, and ignores certain datasets. This paper presents a three-dimensional, quantitative comparison of a 1/6° Atlantic numerical simulation (CLIPPER) with the WOCE current meter dataset in terms of mean velocity and eddy kinetic energy. Our metrics reveal the good behaviour of CLIPPER open boundary conditions and forcing with respect to full-depth current records. Due to its still moderate resolution, however, the model globally underestimates the observed mean speeds and eddy activity. This discrepancy is barely noticeable at low latitudes but increases toward the poles, probably since the poleward decrease of the Rossby radius exceeds that of the horizontal grid step. At least in this eddy-admitting regime, it is suggested that the numerics of geopotential-coordinate models like ours dissipate mean and eddy momentum at depth and adversely affect current–topography interactions. 相似文献
7.
High-resolution measurements of chromophoric dissolved organic matter in the Mississippi and Atchafalaya River plume regions 总被引:4,自引:0,他引:4
Chromophoric dissolved organic matter (CDOM) was measured in the spring and summer in the northern Gulf of Mexico with the ECOShuttle, a towed, instrumented, undulating vehicle. A submersible pump mounted on the vehicle supplied continuously flowing, uncontaminated seawater to online instruments in the shipboard laboratory and allowed discrete samples to be taken for further analysis. CDOM in the northern Gulf of Mexico was dominated by freshwater inputs from the Mississippi River through the Birdfoot region and to the west by discharge from the Atchafalaya River. CDOM was more extensively dispersed in the high-flow period in the spring but in both time periods was limited by stratification to the upper 12 m or so. Thin, subsurface CDOM maxima were observed below the plume during the highly stratified summer period but were absent in the spring. However, there was evidence of significant in situ biological production of CDOM in both seasons.The Mississippi River freshwater end member was similar in spring and summer, while the Atchafalaya end member was significantly higher in the spring. In both time periods, the Atchafalaya was significantly higher in CDOM and dissolved organic carbon (DOC) than the Mississippi presumably due to local production and exchange within the coastal wetlands along the lower Atchafalaya which are absent along the lower Mississippi. Nearshore waters may also have higher CDOM due to outwelling from coastal wetlands. High-resolution measurements allow the differentiation of various water masses and are indicative of rapidly varying (days to weeks) source waters. Highly dynamic but conservative mixing between various freshwater and marine end members apparently dominates CDOM distributions in the area with significant in situ biological inputs (bacterial degradation of phytoplankton detritus), evidence of flocculation, and minor photobleaching effects also observed. It is clear that high-resolution measurements and adaptive sampling strategies allow a more detailed examination of the processes that control CDOM distributions in river-dominated systems. 相似文献
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In 1984, on a transect covering the whole Baltic Sea and parts of the adjacent North Sea, 160 water samples were taken and analysed for their concentrations of particulate and dissolved metals. In addition, the suspended materials were investigated for their elemental bulk composition.The particulate fractions represented from about 5% (Cd, Cu and Ni) to 50% (Fe and Pb) of the total (particulate plus dissolved) concentrations. For some elements (Ba, Cd, Cu, Pb and Zn), the particulate matter from the surface microlayer was enriched with respect to those suspended materials taken from 0.2 m depth. This could reflect the atmospheric input of metal-rich aerosols. In anoxic deep waters, maximum contents of Zn (6400 μg g−1), Cu (1330 μg g−1) and Cd (12 μg g−1) were observed in the particulate matter, indicating sulphidic forms. On the other hand, under oxic conditions the distribution coefficients (Kd) decreased with the water depth (Cd, Fe and Pb).Relative to global background levels, the particulate matter contained metal “excesses” amounting to more than 90% of the total contents (Cd, Mn, Pb and Zn). Automated electron probe X-ray microanalysis (EPXMA) revealed that the elemental composition of sediments is mainly governed by post-depositional processes of early diagenesis and is only weakly related to the composition of suspended matter in the overlying water body. For instance, in relation to surface mud sediments of the central Baltic net-sedimentation basins, Zn, Cd, Cu and Mn had 30–100% higher levels in the suspended materials. The general pattern of metal contents of particulate matter taken from 10 m depth on a transect between the Bothnian Bay and the North Sea were—possibly as a result of anthropogenic inputs—rather similar for Pb, Zn and Cu. For Fe and Mn, the distribution patterns along the transect were probably governed by the natural loading characteristics and by the biogeochemistry of those elements. 相似文献
10.
Bernard R. Durney 《Solar physics》1989,123(2):197-216
The following points are discussed:
Operated by the Association of Universities for Research in Astronomy, Inc. under contract with the National Science Foundation. 相似文献
(i) | The dependence of the angular velocity, , on the spatial coordinates near the lower boundary, R c, of the solar convection zone (SCZ) can be obtained from an integration with respect to r of a sound approximation to the azimuthal equation of motion. Here P 2 (cos ) is the second-order Legendre polynomial and is the polar angle. Estimates of 0, 2 (the primes denote derivatives with respect to r), based on the best available values for the Reynolds stresses and anisotropic viscosity coefficients, suggest that 0 < 0,=">2 0 for r = R c. Since a reliable theory of anisotropic turbulent coefficients does not exist at present, positive values of 0 are conceivable. |
(ii) | In the lower SCZ the latitudinal variations of the superadiabatic gradient vanish if is constant along cylinders. The uniformity of the superadiabatic gradient is, however, inconsequential: the physically meaningful rotation law is the one that insures the uniformity of the convective flux. |
(iii) | With the exception of the polar regions, the angular momentum transport in thin azimuthal convective rolls is towards the equator. |
(iv) | It is suggested that buoyancy uncorrelates horizontally separated regions in the lower SCZ preventing the generation of magnetic fields with small wave numbers: in consequence, the cycle magnetic field must be generated in a region of weak buoyancy whereas the lower SCZ generates a weak rather stochastic magnetic field. The dependence on rotation of these two types of magnetic field could differ. |
(v) | In the context of helioseismology it is customary to expand the perturbations (induced by rotation) of the eigenfrequencies in the following form: , where the notation is standard. The observations reveal that to a good approximation a 1 is independent of l. It is shown that this is the case if is constant with r. For a simple viscous, rotating fluid in the steady state (r) is constant with r if the angular momentum loss vanishes. Let J(ri dr) be the angular momentum of a thin shell of radius r and thickness dr. Since , the constancy of (r) implies that each shell of radius r has the same angular momentum as if the Sun were rotating uniformly with an angular velocity given by . It is discussed whether, alternatively, the observations simply indicate that 0(r) is a slowly varying function of r. |