Study of the Messinian carbonate-evaporite lithofacies offshore Western Libya

This study represents a preliminary investigation of the late Messinian subsurface Marsa Zouaghah Formation in the Western Libyan Offshore, Central Mediterranean Sea. The formation was deposited in three major environmental settings: (a) Marginal Sabkha; (b) Open Lagoon; and (c) Hypersaline Lagoon. The marginal sabkha and open lagoonal settings are locally interrupted by intertidal oolitic shoal deposits. The marginal sabkha facies is replaced in central parts of the Libyan offshore by a narrow zone of aeolian-fluvial facies, the distribution and thickness of which is entirely controlled by a local uplift, the Tripoli Nose'. The marginal sabkha facies broadly defines the late Messinian palaeoshoreline lying parallel to, and north of, the E-W Jifarah fault system which dominated the southern part of the Libyan offshore. This fades is, thus, interpreted as being structurally controlled by fault systems. The hypersaline lagoonal facies is developed in areas of relatively higher rates of subsidence than that of adjacent facies belts. It is therefore, related to restriction formed by continuous subsidence and evaporation. The Marsa Zouaghah Formation constitutes saltern evaporates deposited over a wide platform in sabkha and lagoonal settings, forming part of the 'basin-wide-evaporites' of the Mediterranean Basin deposited during the Messinian salinity crisis. The evaporites formed during a major relative sea-level fall within a subsiding basin situated on the northern continental margin of the African plate. Local, vertical and lateral variations in lithofacies and thickness within the Messinian deposits of the north-west Libyan offshore were controlled by contemporaneous strike-slip movements in addition to sea-level change.     

Impact of anthropogenic activities on the groundwater resources of the unconfined aquifer of Triffa plain (Eastern Morocco)

Located at the northeastern part of Morocco, the plain of Triffa is characterized by a semi-arid climate where water resources are rather fragile and influenced by a highly irregular rainfall distribution, both in time (annual and inter-annual distribution) and in space. The mean annual rainfall does not exceed 240 mm. In the Triffa plain, the impact of anthropogenic activities on the groundwater resources is reflected both by (a) the decrease in the piezometric level due to the over exploitation and droughts and (b) the deterioration of the chemical quality of water. Currently, this situation is felt mainly by the farmers. The unconfined aquifer is under stress due to the increase of the pollution rate, especially by nitrates that are above the WHO standards, and salinity. Organochlorine pesticides are ubiquitous and persistent organic pollutants used widely in agriculture. Due to their extensive use in agriculture, organic environment contaminants such as hexachlorocyclohexane, DDT, and DDD along organochlorine pesticides are distributed globally by transport through water. Pesticides such as aldrin, lindane, and heptachlor have also been detected and were considered as indicators showing the need to inform and to train farmers on the pesticides and fertilizers use in order to reduce the threat of groundwater contamination.     

GIS-based evaluation of groundwater quality and estimation of soil salinization and land degradation risks in an arid Mediterranean site (SW Tunisia)

Arabian Journal of Geosciences - The present work is concerned with the valorization of clay minerals of the Aleg formation (Coniacian-middle Campanian) in the clinker manufacturing. The studied...     

H2O on Io? IR spectra of SO2/H2O mixed ices in the 5000-450 cm−1 region

Laboratory transmission IR spectra of relatively thick films (up to 500 m) of mixed H₂O and SO₂ ices were measured at several temperatures between 10 and 130 K in the range 5000-450 cm^–1. In addition to the strong features due to crystalline SO₂ the spectra reveal bands at 3668 cm^–1, 3634 cm^–1 (with some structure) and 3300 cm^–1 which are identified with H₂O in SO₂ environment. Also, there is no overlap between any of the H₂O bands with the 3584 cm^–1 band of SO₂ at any temperature in the above range. The implication of this result is that H₂O, if present on Io, must be far less than 1 part in 10⁵ SO₂.     

The Geoarchaeology of Utica,Tunisia: The Paleogeography of the Mejerda Delta and Hypotheses Concerning the Location of the Ancient Harbor

Although the ancient site of Utica has been studied since the 19th century, the location of its harbors remains unresolved as they were buried under sediments as the Mejerda delta prograded and left Utica 10 km inland. Using relief data and a coring survey with sedimentological analysis, we identify the dynamics of the delta's progradation, which produced a double system of alluvial fans. These show that the ancient bay of Utica silted up faster and earlier than was thought, probably before the end of the Punic period. Combined with the radiocarbon dates from coring, this suggests that the harbor lay on the north‐western side of the Utica promontory, communicating with the sea by a marine corridor west of the northern compartment of the delta. As the infilling of the ancient bay progressed, this corridor narrowed until it disappeared completely in the early 5th/mid‐6th century A.D., when a peat bog developed on the northern side of the promontory, sealing the fate of Utica as a port. This relative environmental stability ended in the 9th–10th century A.D. when about 4 m of sediment, probably of fluvial origin, covered the peat bog, leaving the site more than 4.5 m above the local sea level.     

Laboratory Study of Air Sparging: Air Flow Visualization

Laboratory flow visualization experiments, using glass beads as the porous medium, were conducted to study air sparging, an innovative technology for subsurface contaminant remediation. The purpose of these experiments was to observe how air flows through saturated porous media and to obtain a basic understanding of air plume formation and medium heterogeneity effects. The experiments indicate that air flow occurring in discrete, stable channels is the most probable flow behavior in medium to fine grained water saturated porous media and that medium heterogeneity plays an important role in the development of air channels. Several simulated scales of heterogeneities, from pore to field, have been studied. The results suggest that air channel formation is sensitive to the various scales of heterogeneities. Site-specific hydrogeologic settings have to be carefully reviewed before air sparging is applied to remediate sites contaminated by volatile organic compounds.     

Morphological evolution of center Boumerdes in Zemmouri Bay (Algeria) from 1922 to 2017

The morphological evolution of shallows seabed has undergone great changes over the past 95 years. These changes have not only led to the decreases of water volume but also to the spatial variability of sediments. However, the distribution and the movement of marine sediments from underwater beaches are very complex due to the combination of several factors such as hydrodynamic factors (e.g., tidal currents ±?34 cm, swells and currents driven by the prevailing northeast wind), and entropic factors (e.g., soil occupation and protective installation of structures as breakwater, groynes, retaining wall). This situation can disrupt the sedimentary regime in the Boumerdes area. In order to better understand the hydrodynamic processes, the recognition of sedimentary processes, the modalities, and erosion mechanisms of this zone are necessary. Thus, the study of long-term underwater morphological evolution by comparing between the bathymetric surveys of different years, between 1922 and 2017, is required to study the feasibility of coastal engineering projects. The seabed bathymetric evolution of this coastal fringe from erosion point of view was appreciated. It is based on a geographic information system (GIS), which allows to carry out a digital depth model interpolated by kriging method.     

Typologie et mode de mise en place des roches magmatiques dans les Pyrénées hercyniennes

Résumé L'évolution géodynamique hercynienne des Pyrénées se caractérise par une importante activité magmatique à l'origine de corps plutomques de taille, de composition et de niveaux de mise en place différents. A partir de ces caractéristiques nous avons pu établir une typologie qui nous a permis de distinguer deux types principaux de massifs: 1) les massifs de composition homogène, acides (massifs de type HA) ou basiques (massifs de type HB), localisés dans les grands ensembles métamorphiques régionaux et 2) les massifs de composition hétérogène, formés par l'association de roches basiques et de roches acides dont la répartition spatiale a permis de distinguer les massifs de type CA (roches acides au coeur du massif), les massifs de type CB (roches basiques au coer du massif) et les massifs de type CR (récurrences de lentilles de roches basiques dans un massif zoné de type CA ou CB), mis en place dans le Paléozoïque supérieur généralement loin des grands ensembles métamorphiques. Tous ces massifs se sont mis en place diapiriquement au cours du métamorphisme régional et de la déformation hercynienne majeure.

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One of the main characteristics of the Hercynian geodynamic evolution of the Pyrenees is an intense magmatic activity producing large plutonic bodies. They have different sizes, various compositions and distinct emplacement levels. From these characteristics, a typology for these massifs is defined. Two main types of massifs have been recognized: 1) massifs with an homogenous composition founded in large regional metamorphic areas, and 2) massifs with an heterogenous composition of acid and basic rocks, whose spatial disposition permits the recognition of three sub-types: a) the CA type where acid rocks are at the core of the massif; b) the CB type where basic rocks are at the core of the massif, and c) the CR type where numerous basic xenoliths are scattered within either a CA or a CB type massif. These heterogenous massifs generally occur within Upper Paleozoic rocks and usually far away from regional metamorphic areas. All of these massifs were emplaced diapirically during the regional metamorphism and the main Hercynian deformation.

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Zusammenfassung Ein wichtiges charakteristisches Merkmal der geodynamischen Entwicklung der Pyrenäen während der herzynischen Phase ist eine hohe magmatische Aktivität, auf die Plutone größerer Ausdehnung zurückgeführt werden. Größe, Mineralogie und Erstarrungstiefe der Plutone variieren. Anhand dieser Charakteristika können die Intrusivkörper in zwei Hauptgruppen differenziert werden. Die erste Gruppe (1) sind Plutone homogener Zusammensetzung in regionalmetamorph überprägten Gebieten. Die zweite sind heterogen zusammengesetzte Plutone (2) saurer und basischer Magmatite, deren räumliche Anordnung eine Untergliederung in drei Untergruppen ermöglicht:a) Bei dem CA-Typ befinden sich saure Gesteine im Kern; bei b), dem CB-Typ, liegen basische Gesteine im Kern vor und bei c), einem CR genannten Typ, sind zahlreiche basische Xenolithe entweder in dem CA-oder dem CB-Typ verstreut vorhanden. Diese heterogenen Plutone findet man allein in spätpaläozoischen Gesteinen und in der Regel weit entfernt von Gebieten, die metamorph beeinflußt wurden. Sämtliche Plutone haben eine Diapir-ähnliche Form und intrudierten zeitgleich mit der Regionalmetamorphose und der Hauptphase der herzynischen Deformation.

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A Conceptual Model of Field Behavior of Air Sparging and Its Implications for Application

The basic physics of air flow through saturated porous media are reviewed and implications arc drawn for the practical application of air sparging. A conceptual model of the detailed behavior of an air sparging system is constructed using elements of multiphase flow theory and the results of recent experimental work. Implications of the conceptual model on air sparging topics are discussed. The meaning of radius of influence in the context of air sparging is found to be ambiguous. The hydrodynamic effects of air sparging such as mounding of ground water and flow impedance are explored. Limitations on rates of remediation and operational strategics for improving sparging effectiveness are examined.     

Spatial and statistical assessment of nitrate contamination in groundwater:Case of Sais Basin,Morocco

The objective of this study is to evaluate the nitrate contamination in the plioquaternary aquifer of Sais Basin based on a statistical approach. A total of 98 samples were collected in the cultivated area during the spring and autumn period of 2018. The results show that 55% and 57% of the samples in spring and autumn respectively exceed the threshold fixed by WHO(50 mg/L). However, nitrate concentrations do not show seasonal and spatial variation(p0.05). The results of the correlation matrix, principal component analysis(PCA), and hierarchical cluster analysis(HCA) suggest that nitrate pollution is related to anthropogenic source. Moreover, multiple linear regression results show that NO_3 is more positively explained in the spring period by Ca and SO_4 and negatively explained by pH and HCO_3. Regarding the autumn period, nitrate pollution is positively explained by Ca and negatively by pH. This study proposes a useful statistical platform for assessing nitrate pollution in groundwater.