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Geochemical and hydrodynamic constraints on the distribution of trace metal concentrations in the lagoon of Nouméa, New Caledonia 总被引:1,自引:0,他引:1
Christophe Migon Sylvain Ouillon Xavier Mari Emmanuel Nicolas 《Estuarine, Coastal and Shelf Science》2007,74(4):756
Seawater samples were collected in the lagoon of Nouméa (southwest New Caledonia) along two transects from eutrophic coastal bays to the oligotrophic barrier reef. Land-based emissions to the lagoon were measured with dissolved and particulate concentrations of chromium (Cr) and nickel (Ni), used as tracers of both terrigenous and industrial (Ni ore treatment) activities, as well as dissolved and particulate concentrations of zinc (Zn), used as a tracer of urban effluents. The spatial variability of metal concentrations was related to geochemical and hydrodynamic conditions, i.e., respectively: (1) natural and anthropogenic emission sources, and chemical processes occurring in the water column; and (2) water residence times. The parameter used to describe the residence time of water masses was the local e-flushing time, i.e. the time required for a tracer mass contained within a given station to be reduced by a factor 1/e. High metal concentrations were found in coastal areas (up to 9000 ng dissolved Ni L−1), and steeply decreased with distance from the coast (down to 101 ng dissolved Ni L−1 near the barrier reef) to reach levels similar to those found in remote Pacific waters, suggesting a rapid renewal of waters close to the barrier. Distributions of metals in the lagoon are controlled upstream by land-based emission sources and later chemical processes. Then hydrodynamics constrain metal distributions, as shown by the observed relationship between local e-flushing times and the spatial variability of metal concentrations. In addition, a change in the direction of prevailing winds yielded a decrease of dissolved metal concentrations at the same site by a factor of 2.5 (Cr and Ni) and 2.9 (Zn). It is suggested that the residence time is a key parameter in the control of elemental concentrations in the lagoon waters, as much as land-based emission sources. 相似文献
3.
Christoph Förste Roland Schmidt Richard Stubenvoll Frank Flechtner Ulrich Meyer Rolf König Hans Neumayer Richard Biancale Jean-Michel Lemoine Sean Bruinsma Sylvain Loyer Franz Barthelmes Saskia Esselborn 《Journal of Geodesy》2008,82(6):331-346
The recent improvements in the Gravity Recovery And Climate Experiment (GRACE) tracking data processing at GeoForschungsZentrum
Potsdam (GFZ) and Groupe de Recherche de Géodésie Spatiale (GRGS) Toulouse, the availability of newer surface gravity data
sets in the Arctic, Antarctica and North-America, and the availability of a new mean sea surface height model from altimetry
processing at GFZ gave rise to the generation of two new global gravity field models. The first, EIGEN-GL04S1, a satellite-only
model complete to degree and order 150 in terms of spherical harmonics, was derived by combination of the latest GFZ Potsdam
GRACE-only (EIGEN-GRACE04S) and GRGS Toulouse GRACE/LAGEOS (EIGEN-GL04S) mean field solutions. The second, EIGEN-GL04S1 was
combined with surface gravity data from altimetry over the oceans and gravimetry over the continents to derive a new high-resolution
global gravity field model called EIGEN-GL04C. This model is complete to degree and order 360 and thus resolves geoid and
gravity anomalies at half- wavelengths of 55 km at the equator. A degree-dependent combination method has been applied in
order to preserve the high accuracy from the GRACE satellite data in the lower frequency band of the geopotential and to form
a smooth transition to the high-frequency information coming from the surface data. Compared to pre-CHAMP global high-resolution
models, the accuracy was improved at a spatial resolution of 200 km (half-wavelength) by one order of magnitude to 3 cm in
terms of geoid heights. The accuracy of this model (i.e. the commission error) at its full spatial resolution is estimated
to be 15 cm. The model shows a reduced artificial meridional striping and an increased correlation of EIGEN-GL04C-derived
geostrophic meridional currents with World Ocean Atlas 2001 (WOA01) data. These improvements have led to select EIGEN-GL04C
for JASON-1 satellite altimeter data reprocessing.
Electronic Supplementary Material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
4.
A. Pouclet M. Vidal J.-C. Doumnang J.-P. Vicat R. Tchameni 《Journal of African Earth Sciences》2006,44(4-5):543
In the Lake Léré region, southern Chad, Neoproterozoic terrains are distributed in four lithostructural groups that reveal the geotectonic evolution of a part of the Pan-African orogenic domain. The first group includes basaltic volcanic rocks and fine-grained detrital sedimentary rocks of pre-tectonic basins that were emplaced in an extensional regime, close to a volcanic arc. The second and third groups include calc-alkaline gabbroic intrusions emplaced at an upper crustal level and a midcrustal tonalite, respectively, that are interpreted to be the roots of an active margin volcanic arc. These first three groups experienced WNW to ESE compression, and may belong to a fore-arc basic—volcanic arc—back-arc basin system that was accreted eastward to the Palaeoproterozoic Adamaoua-Yadé Block. The fourth group includes post-tectonic granite plutons invading the older groups. This paper documents the accretion processes in the southern margin of the Saharan Metacraton. 相似文献
5.
Teddy Parra Olivier Vidal Phillipe Agard 《Contributions to Mineralogy and Petrology》2002,143(6):706-732
The purpose of this study is to derive a solid-solution model for potassic white micas (KWM) encountered in rocks of various bulk compositions, over a wide range of P-T conditions. A compilation of phengite compositions lead us to propose a seven-thermodynamic-component (muscovite, Fe2+-Al-celadonite, Mg-Al-celadonite, annite, phlogopite, pyrophyllite and paragonite) ionic solid-solution model which accounts for the Tschermak, Fe-Mg, di/trioctahedral, pyrophyllitic and paragonitic substitutions observed in nature. A four-site mixing model with symmetric Margules parameters to model the Tschermak substitutions, asymmetric Margules parameters to model the other substitutions, and ideal intersite interaction has been adopted. In contrast to previous models, the relevant thermodynamic data and solid-solution properties are calibrated with independent sets of published experiments conducted for the KMASH, KFASH, KFMASH, and KNASH systems, as well as about 200 natural data involving KWM assemblages. The constraints span a wide range of pressure and temperature conditions (150 to 750 °C, 0.5 to 30 kbar), so that our model does not need to be extrapolated outside the calibration range to be used for P-T thermobarometric purposes. The calculated thermodynamic data are interconsistent with the TWQ thermodynamic database and solid-solution models, including that recently published for chlorites. 相似文献
6.
Quality Assessment of Cartographic Generalisation 总被引:2,自引:1,他引:2
Sylvain Bard 《Transactions in GIS》2004,8(1):63-81
This paper proposes a methodology to assess the quality of cartographic generalisa‐tion, which consists of representing geographic space in a simplified way according to the scale and the objectives of the intended map. The automation of this process makes the derivation of data easier, but the quality of the results is often not evaluated. This paper proposes an assessment model based on: (1) characterisation of the data in their initial and final states at different levels of analysis; (2) a data quality assessment by comparison of the two characterisations; and (3) aggregation of the various assessment results to summarise data quality. The assessment algorithm has been implemented and the method has been tested to assess the generalisation of a small urban area. A visualisation tool for assessment of the results has been developed to validate the generalisation evaluation. The results of the research are presented and discussed at the end of the paper. 相似文献
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A methodology for regionalizing 3‐D effective porosity at watershed scale in crystalline aquifers 下载免费PDF全文
Benoît Dewandel Yvan Caballero Jérôme Perrin Alexandre Boisson Fabrice Dazin Sylvain Ferrant Subash Chandra Jean‐Christophe Maréchal 《水文研究》2017,31(12):2277-2295
An innovative approach for regionalizing the 3‐D effective porosity field is presented and applied to two large, overexploited, and deeply weathered crystalline aquifers located in southern India. The method derives from earlier work on regionalizing a 2‐D effective porosity field in that part of an aquifer where the water table fluctuates, which is now extended over the entire aquifer using a 3‐D approach. A method based on geological and geophysical surveys has also been developed for mapping the weathering profile layers (saprolite and fractured layers). The method for regionalizing 3‐D effective porosity combines water table fluctuation and groundwater budget techniques at various cell sizes with the use of satellite‐based data (for groundwater abstraction), the structure of the weathering profile, and geostatistical techniques. The approach is presented in detail for the Kudaliar watershed (983 km2) and tested on the 730 km2 Anantapur watershed. At watershed scale, the effective porosity of the aquifer ranges from 0.5% to 2% in Kudaliar and between 0.3% and 1% in Anantapur, which agrees with earlier works. Results show that (a) depending on the geology and on the structure of the weathering profile, the vertical distribution of effective porosity can be very different and that the fractured layers in crystalline aquifers are not necessarily characterized by a rapid decrease in effective porosity and (b) that the lateral variations in effective porosity can be larger than the vertical ones. These variations suggest that within a same weathering profile, the density of open fractures and/or degree of weathering in the fractured zone may significantly vary from a place to another. The proposed method provides information on the spatial distribution of effective porosity that is of prime interest in terms of flux and contaminant transport in crystalline aquifers. Implications for mapping groundwater storage and scarcity are also discussed, which should help in improving groundwater resource management strategies. 相似文献
10.
Andrés Gutiérrez-Rodríguez Mikel Latasa Marta Estrada Montserrat Vidal Celia Marrasé 《Deep Sea Research Part I: Oceanographic Research Papers》2010,57(4):486-500
The carbon flux through major phytoplankton groups, defined by their pigment markers, was estimated in two contrasting conditions of the Northwestern Mediterranean open ocean ecosystem: the spring bloom and post-bloom situations (hereafter Bloom and Post-bloom, respectively). During Bloom, surface chlorophyll a (Chl a) concentration was higher and dominated by diatoms (53% of Chl a), while during Post-bloom Synechococcus (42%) and Prymnesiophyceae (29%) became dominant. The seawater dilution technique, coupled to high pressure liquid chromatography (HPLC) analysis of pigments and flow cytometry (FCM), was used to estimate growth and grazing rates of major phytoplankton groups in surface waters. Estimated growth rates were corrected for photoacclimation based on FCM-detected changes in red fluorescence per cell. Given the 30% average decrease in the pigment content per cell between the beginning and the end of the incubations, overlooking photoacclimation would have resulted in a 0.40 d?1 underestimation of phytoplankton growth rates. Corrected average growth rates (μo) were 0.90±0.20 (SD) and 0.40±0.14 d?1 for Bloom and Post-bloom phytoplankton, respectively. Diatoms, Cryptophyceae and Synechococcus were identified as fast-growing groups and Prymnesiophyceae and Prasinophyceae as slow-growing groups across Bloom and Post-bloom conditions. The higher growth rate during Bloom was due to dominance of phytoplankton groups with higher growth rates than those dominating in Post-bloom. Average grazing rates (m) were 0.58±0.20 d?1 (SD) and 0.31±0.07 d?1. The proportion of phytoplankton growth consumed by microzooplankton grazing (m/μo) tended to be lower in Bloom (0.69±0.34) than in Post-bloom (0.80±0.08). The intensity of nutrient limitation experienced by phytoplankton indicated by μo/μn (where μn is the nutrient-amended growth rate), was similar during Bloom (0.78) and Post-bloom (0.73). Primary production from surface water (PP) was estimated with 14C incubations. A combination of PP and Chl a synthesis rate yielded C/Chl a ratios of 34±21 and 168±75 (g:g) for Bloom and Post-bloom, respectively. Transformation of group-specific Chl a fluxes into carbon equivalents confirmed the dominant role of diatoms during Bloom and Synechococcus and Prymnesiophyceae during Post-bloom. 相似文献