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1.
A method was developed for the determination of organic halogens in water samples with the aim of minimizing matrix effects and simplifying the sample preparation technique commonly used. The method is based on the adsorption of organic halogens in modified hydrophilic divinylbenzene polymer columns and their elution with methanol. The adsorbent used enables rapid adsorption and desorption due to comparatively high operating flow rates and minimized solvent amounts. Furthermore, no additional reconcentration steps are needed. The methanol extract obtained is combusted with a standard EOX (extractable organic halogen) analyzer and the concentration of organically bound halogens is determined by microcoulometric analysis. The matrix effects are considerably reduced compared to the standard procedure (EN 1485) commonly used. A detection limit of 13 μg/L was established. 相似文献
2.
Pollen, sedimentological and charcoal particle analyses are presented from Devensian Late-glacial and early- to mid-Flandrian deposits from a former lake in the Vale of Pickering, Yorkshire. The combined analytical methods provide evidence for a short-lived climatic deterioration towards the end of the Late-glacial Interstadial, followed by a brief recovery prior to the Loch Lomond Stadial. This deterioration may be correlated with one of the ‘pre-Younger Dryas’ cooling periods identified not only in other pollen sequences from Britain and Europe, but from such diverse sources as Foraminifera from the Norwegian Sea and electrical conductivity measurements from the Greenland ice sheet. Loss-on-ignition and magnetic susceptibility data suggest that the Loch Lomond Stadial was characterised by an initial prolonged temperature decline, followed by a sudden more severe downturn resulting in particularly intense solifluction. Radiocarbon accelerator dating of the early Flandrian marl deposits illustrates the problem of age determination in calcareous lakes, and an estimate of the magnitude of ‘hard water error’ is obtained. The local population expansion of Alnus glutinosa is dated to 7640 ± 85 yr BP, but there is possible evidence for a Late-glacial presence of the tree, the significance of which is discussed in relation to other sites in east Yorkshire. © 1996 John Wiley & Sons, Ltd. 相似文献
3.
Yastami Oka Petra Steinke Niranjan D. Chatterjee 《Contributions to Mineralogy and Petrology》1984,87(2):196-204
Three Al-Cr exchange isotherms at 1,250°, 1,050°, and 796° between Mg(Al, Cr)2O4 spinel and (Al, Cr)2O3 corundum crystalline solutions have been studied experimentally at 25 kbar pressure. Starting from gels of suitable bulk
compositions, close approach to equilibrium has been demonstrated in each case by time studies.
Using the equation of state for (Al, Cr)2O3 crystalline solution (Chatterjee et al. 1982a) and assuming that the Mg(Al, Cr)2O4 can be treated in terms of the asymmetric Margules relation, the exchange isotherms were solved for Δ G
*,
and
. The best constrained data set from the 1,250° C isotherm clearly shows that the latter two quantities do not overlap within
three standard deviations, justifying the choice of asymmetric Margules relation for describing the excess mixing properties
of Mg(Al, Cr)2O4 spinels. Based on these experiments, the following polybaric-polythermal equation of state can be formulated:
, P expressed in bars, T in K, G
m
ex
and W
G,i
Sp
in joules/mol.
Temperature-dependence of G
m
ex
is best constrained in the range 796–1,250° C; extrapolation beyond that range would have to be done with caution. Such extrapolation
to lower temperature shows tentatively that at 1 bar pressure the critical temperature, T
c, of the spinel solvus is 427° C, with dTc/dP≈1.3 K/kbar. The critical composition, X
c, is 0.42
, and changes barely with pressure.
Substantial error in calculated phase diagrams will result if the significant positive deviation from ideality is ignored
for Al-Cr mixing in such spinels. 相似文献
4.
Reservoirs have to be released when repairing of the dams is necessary. In 1995, two reservoirs in Baden-Württemberg (Germany) of similar age and volume (Lake Herrenbach near Göppingen, 1.0 Mio. m3 and Lake Breitenau near Heilbronn, 2.3 Mio. m3) were emptied. This allowed the singular possibility to investigate the effects of drainage and refilling on the limnochemistry and the phytoplankton biocoenosis of such artificial lakes.Before the drainage of the reservoirs, both lakes showed phosphorus release from the sediment during summer stagnation. Phosphorus values of Lake Herrenbach were regularly higher than those of Lake Breitenau (Lake Herrenbach 88 μg/l, Lake Breitenau 33 μg/l). During release, both lakes indicated higher phosphorus and chlorophyll concentrations as well as rising biomasses. Remarkable differences were observed during refilling of the reservoirs: while Lake Herrenbach showed higher transparency and lower phosphorus concentrations, Lake Breitenau progressed towards eutrophication (total phosphorus during summer 1996: Lake Herrenbach 30 μg/l, Lake Breitenau 55 μg/l). One reason for the reaction of Lake Breitenau was the reduced ground drainage during the refilling, which caused an accumulation of nutrients in the hypolimnion. Another reason was the mineralisation of vegetation which covered great parts of the dry lake sediment. The limnological change of Lake Herrenbach was not as clear but could be caused by the restauration of the pre-reservoir which was drainaged and dredged before the emptying of the main reservoir started as well as many other facts which differed Lake Herrenbach from Lake Breitenau. 相似文献
5.
David Walker Geoff Parkin Petra Schmitter John Gowing Seifu A. Tilahun Alemseged T. Haile Abdu Y. Yimam 《Ground water》2019,57(2):245-258
Although most recharge estimation studies apply multiple methods to identify the possible range in recharge values, many do not distinguish clearly enough between inherent uncertainty of the methods and other factors affecting the results. We investigated the additional value that can be gained from multi-method recharge studies through insights into hydrogeological understanding, in addition to characterizing uncertainty. Nine separate groundwater recharge estimation methods, with a total of 17 variations, were applied at a shallow aquifer in northwest Ethiopia in the context of the potential for shallow groundwater resource development. These gave a wide range of recharge values from 45 to 814 mm/a. Critical assessment indicated that the results depended on what the recharge represents (actual, potential, minimum recharge or change in aquifer storage), and spatial and temporal scales, as well as uncertainties from application of each method. Important insights into the hydrogeological system were gained from this detailed analysis, which also confirmed that the range of values for actual recharge was reduced to around 280-430 mm/a. This study demonstrates that even when assumptions behind methods are violated, as they often are to some degree especially when data are limited, valuable insights into the hydrogeological system can be gained from application of multiple methods. 相似文献
6.
Petra Bragée Preetam Choudhary Joyanto Routh John F. Boyle Dan Hammarlund 《Journal of Paleolimnology》2013,50(4):545-560
Sediment sequences spanning the last 800 years from two small lakes in the south Swedish uplands were explored for assessment of effects of changing human population, local land-use practices and airborne pollution on lake-ecosystem functioning and resilience. Variations in nutrient cycling and deposition of lithogenic elements were studied, using a multi-proxy stratigraphic approach. Carbon and nitrogen elemental and isotopic analyses were applied in combination with records of hydrocarbons (n-alkanes) to investigate the sources and depositional conditions of sediment organic matter. Changes in fluvial and airborne delivery of inorganic matter were based on X-ray fluorescence measurements. The results reveal that population growth and related increases in land-use pressure had a major impact on catchment erosion and input of terrestrial organic matter to the lakes from the 1500s to the end of the 1800s. Evidence also exists of a brief period of catchment disturbance at ca. 1200–1300, followed by recovery, likely connected to the Black Death pandemic. At ca. 1900 synchronous shifts in most of the proxy records suggest a marked change in external forcing common to the two lakes related to a major decrease in population density and the introduction of modern forestry following the industrial revolution. Interestingly, the two sediment records exhibit generally coherent trends in C/N ratio, organic C content and δ13C, both before and after 1900, indicating broadly similar sensitivities of the lake ecosystems to human impact. In contrast, deviating trends in total N content, δ15N and lithogenic element concentrations (K, Ti, Rb and Zr) reflect site-specific responses to local disturbances during the last century due to different nutrient conditions and catchment properties. Our companion sediment records highlight the importance of understanding long-term human impact on watersheds and demonstrate how regional versus local forcing of lake ecosystems, as well as site-specific responses related to catchment characteristics can be reconstructed. 相似文献
7.
Petra Tschakert Regina Sagoe Gifty Ofori-Darko Samuel Nii Codjoe 《Climatic change》2010,103(3-4):471-502
This study explores the implications of recent extreme rainfall and flood events in the Sahel and the wider West African region for climate change adaptation. Are these events merely a temporal nuisance as suggested by the lingering desertification discourse or will more climatic extremes characterize the region over the next century? After reviewing incidences of severe rainfall and projected future climate variability, the paper examines local flood knowledge and decision-making, drawing upon a case study in Ghana. The data demonstrate that a variety of response strategies to flooding exist; yet, knowledge of and access to climate forecasts and other learning tools are essentially absent. So far, floods have not triggered mass displacement although cumulative environmental deterioration is likely to cause environmental refugees. The paper recommends to lay to rest the desertification narrative, consider the possibility of both floods and droughts, and mobilize local memory for anticipatory learning and practical adaptation. 相似文献
8.
Petra Döll Hervé Douville Andreas Güntner Hannes Müller Schmied Yoshihide Wada 《Surveys in Geophysics》2016,37(2):195-221
Quantification of spatially and temporally resolved water flows and water storage variations for all land areas of the globe is required to assess water resources, water scarcity and flood hazards, and to understand the Earth system. This quantification is done with the help of global hydrological models (GHMs). What are the challenges and prospects in the development and application of GHMs? Seven important challenges are presented. (1) Data scarcity makes quantification of human water use difficult even though significant progress has been achieved in the last decade. (2) Uncertainty of meteorological input data strongly affects model outputs. (3) The reaction of vegetation to changing climate and CO2 concentrations is uncertain and not taken into account in most GHMs that serve to estimate climate change impacts. (4) Reasons for discrepant responses of GHMs to changing climate have yet to be identified. (5) More accurate estimates of monthly time series of water availability and use are needed to provide good indicators of water scarcity. (6) Integration of gradient-based groundwater modelling into GHMs is necessary for a better simulation of groundwater–surface water interactions and capillary rise. (7) Detection and attribution of human interference with freshwater systems by using GHMs are constrained by data of insufficient quality but also GHM uncertainty itself. Regarding prospects for progress, we propose to decrease the uncertainty of GHM output by making better use of in situ and remotely sensed observations of output variables such as river discharge or total water storage variations by multi-criteria validation, calibration or data assimilation. Finally, we present an initiative that works towards the vision of hyperresolution global hydrological modelling where GHM outputs would be provided at a 1-km resolution with reasonable accuracy. 相似文献
9.
10.
Marleen Coetsiers Petra Blaser Kristine Martens Kristine Walraevens 《Environmental Geology》2009,57(5):1155-1168
Aquifers from the same typology can have strongly different groundwater chemistry. Deducing the groundwater quality of less
well-characterized aquifers from well-documented aquifers belonging to the same typology should be done with great reserve,
and can only be considered as a preliminary approach. In the EU’s 6th FP BRIDGE project “Background cRiteria for the IDentification
of Groundwater thrEsholds”, a methodology for the derivation of threshold values (TV) for groundwater bodies is proposed.
This methodology is tested on four aquifers in Flanders of the sand and gravel typology. The methodology works well for all
but the Ledo-Paniselian aquifer, where the subdivision into a fresh and saline part is disproved, as a gradual natural transition
from fresh to saline conditions in the aquifer is observed. The 90 percentile is proposed as natural background level (NBL)
for the unconfined Pleistocene deposits, ascribing the outliers to possible influence of pollution. For the Tertiary aquifers,
high values for different parameters have a natural origin and the 97.7 percentile is preferred as NBL. The methodology leads
to high TVs for parameters presenting low NBL, when compared to the standard used as a reference. This would allow for substantial
anthropogenic inputs of these parameters. 相似文献