Mass solubility and aqueous activity coefficients of stable organic chemicals in the marine environment: polychlorinated biphenyls

The solubilities and aqueous activity coefficients of polychlorinated biphenyls were measured in distilled and saline water (30? salinity). Solubilities in distilled water ranged from 3 · 10^?4 g/l for dichlorobiphenyls to 6 · 10^?6 g/l for heptachlorobiphenyls; values in artificial seawater were about five times lower than the corresponding values in distilled water. In both cases, the solubilities decreased regularly with increasing degree of chlorination. The corresponding activity coefficients are inversely proportional to the chlorine content and range from 4 · 10⁷ to 4 · 10⁹ in distilled water and from 3 · 10⁸ to 1.5 · 10¹⁰ in saline water. Both the solubilities and activity coefficients agree well with those predicted from additivity considerations. The physical chemical aspects discussed in this paper can be applied in determining the solubility behavior of other stable organic molecules in the marine environment.     

Distribution of stable organic molecules in the marine environment: physical chemical aspects. Chlorinated hydrocarbons

The relative concentrations of non-polar organic compounds in seawater and suspended particulate matter can be explained by an equilibrium sorption mechanism. The value of the quasi-equilibrium constant, K, was calculated with reasonable accuracy for polychlorinated biphenyls from a relatively simple equation which relies on both measurable physical parameters and a number of molecular terms estimated from fundamental physical chemical considerations. This model represents an approach to defining the accumulation of stable organic molecules on marine particulate interfaces within a coherent theoretical framework. As such, it provides a guide for selecting appropriate ecosystem parameters which influence the distribution and accumulation potential of these chemicals in the marine environment.     

Aftershock patterns of the 2021 Mw 6.3 Northern Thessaly (Greece) earthquake

Journal of Seismology - On March 3, 2021, a strong shallow earthquake of magnitude Mw 6.3 struck Northern Thessaly, an area that lies in one of the most active fault zones of mainland Greece. The...     

Interlaboratory calibration results from chlorinated hydrocarbon analyses in marine sediments

The reliability of chlorinated hydrocarbon measurements in natural marine sediments is assessed statistically for the various sample treatments and quantitation techniques used by ten laboratories. For polychlorinated biphenyls, a standard deviation within ±25% of the mean can be expected. Methodology and spectral analysis are the major factors responsible for the variability. Extraction from dry sediment gives the greatest recovery, and measurement of chlorobiphenyl concentrations by homologs alleviates the effect of internal component changes.     

Multivariate statistical analysis for the assessment of groundwater quality under different hydrogeological regimes

Multivariate statistical analysis has been widely used for hydrogeochemical characterization of groundwater quality. In this study, hydrochemical data from three hydrological basins were used and two methods (factor and cluster analyses) were applied. The first area is the coastal area of Eastern Thermaikos Gulf where groundwater is influenced by seawater intrusion and geothermal fluids. The other two areas are the inland basins of Gallikos and Perdikas in which agricultural and industrial activities constitute the main anthropogenic pollution sources of groundwater. Initially, the aforementioned methods were applied for each area separately and resulted in a different number of significant factors and clusters, while the natural and anthropogenic influences were spatially determined in each area. Additionally, factor and cluster analyses were applied coupling data from all areas. Therefore, five clusters and three major factors were determined distinguishing the hydrochemical processes and impacts from anthropogenic activities in more detail. It is worth mentioning that the application of cluster analysis in the coupled groundwater samples of all studied areas resulted beneficially in the most hydrochemically complex area. Salinization dominates in the coastal area, while in Gallikos and Perdikas basins high concentrations of NO₃ occur mainly due to agricultural activities and small livestock units. The numerous hydrochemical samples are identified as the main issue for the higher discretization and reliability of the second approach. Nevertheless, this study is associated with a number of limitations of multivariable statistical analysis regarding extreme concentrations of Cl and Na. This issue stimulates further research in overcoming and understanding these drawbacks.     

Chlorinated hydrocarbons in sediments from southern Greece

Polychlorinated biphenyls (PCBs) can be used as tracers of long-term integrated flow of comtaminants in the sea. They have been used to map the distribution of effluents from sewage outfalls on the southern Greek coast.     

Seismicity study in Pournari reservoir area (W. Greece) 1981–2010

The spatial-temporal evolution of seismicity is examined, during the initial impoundment of Pournari reservoir located on Arachthos River (Western Greece), as well as for the next 30 years. The results show that, despite the relatively moderate-to-high seismicity from west to east, there is no remarkable earthquake in the vicinity before the first reservoir impoundment. Immediately after the impoundment (January 1981), and during the first 4 months, a considerable number of low-magnitude seismic events were recorded in the broader area of the dam. Moreover, two independent major events occurred on March 10, 1981 (M _L ?=?5.6) and April 10, 1981 (M _L ?=?4.7) with focal depths 13 and 10 km, respectively. The detailed analysis of the two corresponding aftershock sequences shows that they present different behaviors (e.g., larger b-value and lower magnitude of the main aftershock) than that of other aftershock sequences in Greece. This seismicity is probably due to triggering, via the water loading mechanism and the undrained response due to a flysch appearance on the reservoir basement. The activation of the thrust fault may be attributed to the bulging of evaporites that characterize the disordered structure of W. Greece, via possible water intake. The detailed processing of the recorded seismicity during the period 1982–2010, in comparison with the variations of Pournari Dam water level, shows an increase of shallow seismicity (h?≤?5 km) in the vicinity of the reservoir up to a 10-km distance—in contrast to the initial period, characterized by a number of deeper events due to the background response change from undrained to drained status.     

Elastic waves in nonhomogeneous media under 2D conditions: II. Numerical implementation

The purpose of this work is to present three methods of analysis for elastic waves propagating in two dimensional, elastic nonhomogeneous media. The first step, common to all methods, is a transformation of the governing equations of motion so that derivatives with respect to the material parameters no longer appear in the differential operator. This procedure, however, restricts analysis to a very specific class of nonhomogeneous media, namely those for which Poisson's ratio is equal to 0.25 and the elastic parameters are quadratic functions of position. Subsequently, fundamental solutions are evaluated by: (i) conformal mapping in conjunction with wave decomposition, which in principle allows for both vertical and lateral heterogeneities; (ii) wave decomposition into pseudo-dilatational and pseudo-rotational components, which results in an Euler-type equation for the transformed solution if medium heterogeneity is a function of one coordinate only; and (iii) Fourier transformation followed by a first order differential equation system solution, where the final step involving inverse transformation from the wavenumber domain is accomplished numerically. Finally, in the companion paper numerical examples serve to illustrate the above methodologies and to delineate their range of applicability.