Aspects of the loss-on-ignition (LOI) technique in the context of clay-rich, glaciolacustrine sediments

The loss‐on‐ignition (LOI) technique for organic matter determination is evaluated with reference to clay‐rich, glaciolacustrine sediments. Examples of the use of LOI in glaciolacustrine literature are inconsistent in their methodology, and standardisation is called for. Problems with application of the technique to glaciolacustrine sediments stem mainly from the effects of additional weight loss due to release of structurally bound water and exposure time to ignition temperatures. Exposure time should be increased from 1 hour to 2.5 hours in the light of significant additional weight loss occurring between 2 and 2.5 hours in clay‐rich samples. The reason for this sudden increase in LOI after 2 hours (up to 86% of total LOI in some cases) appears to be the build‐up of a distinct surface crust during heating that insulates the core of the sample from ignition temperatures. Some time between 2 and 2.5 hours, the crust breaks down and exposes the sample core to ignition temperatures, increasing weight loss significantly. Overestimation of LOI due to loss of structural water is thought to be insignificant. Replicates of LOI at 550 and 1000°C in non‐calcareous, clay‐rich (>40%) sediments, show differences of <0.25%, which, for the purpose of inferring broad changes in glacier extent in lake catchments, is an acceptable error.     

Iodine-xenon analysis of ordinary chondrite halide: implications for early solar system water

We report the results of iodine-xenon analyses of irradiated halide grains extracted from the H-chondrite Monahans (1998) and compare them with those from Zag (Whitby et al., 2000) to address the timing of aqueous processing on the H-chondrite parent body. Xe isotopic analyses were carried out using the RELAX mass spectrometer with laser stepped heating. The initial ¹²⁹I/¹²⁷I ratio in the Monahans halide was determined to be (9.37 ± 0.06) × 10⁻⁵ with an iodine concentration of ∼400 ppb. Significant scatter, especially in the Zag data, indicates that a simple interpretation as a formation age is unreliable. Instead we propose a model whereby halide minerals in both meteorites formed ∼5 Ma after the enstatite achondrite Shallowater (at an absolute age of 4559 Ma). This age is in agreement with the timing of aqueous alteration on the carbonaceous chondrite parent bodies and ordinary chondrite metamorphism and is consistent with the decay of ²⁶Al as a heat source for heating and mobilisation of brines on the H-chondrite parent body. Post accretion surface impact events may have also contributed to the heat source.     

Dams on the Mekong River: Lost fish protein and the implications for land and water resources

Proposed dam construction in the Lower Mekong Basin will considerably reduce fish catch and place heightened demands on the resources necessary to replace lost protein and calories. Additional land and water required to replace lost fish protein with livestock products are modelled using land and water footprint methods. Two main scenarios cover projections of these increased demands and enable the specific impact from the main stem dam proposals to be considered in the context of basin-wide hydropower development. Scenario 1 models 11 main stem dams and estimates a 4–7% increase overall in water use for food production, with much higher estimations for countries entirely within the Basin: Cambodia (29–64%) and Laos (12–24%). Land increases run to a 13–27% increase. In scenario 2, covering another 77 dams planned in the Basin by 2030 and reservoir fisheries, projections are much higher: 6–17% for water, and 19–63% for land. These are first estimates of impacts of dam development on fisheries and will be strongly mediated by cultural and economic factors. The results suggest that basic food security is potentially at a high risk of disruption and therefore basin stakeholders should be fully engaged in strategies to offset these impacts.     

Molecular distribution, 13C‐isotope,and enantiomeric compositions of carbonaceous chondrite monocarboxylic acids

The water‐soluble organic compounds in carbonaceous chondrite meteorites constitute a record of the synthetic reactions occurring at the birth of the solar system and those taking place during parent body alteration and may have been important for the later origins and development of life on Earth. In this present work, we have developed a novel methodology for the simultaneous analysis of the molecular distribution, compound‐specific δ¹³C, and enantiomeric compositions of aliphatic monocarboxylic acids (MCA) extracted from the hot‐water extracts of 16 carbonaceous chondrites from CM, CR, CO, CV, and CK groups. We observed high concentrations of meteoritic MCAs, with total carbon weight percentages which in some cases approached those of carbonates and insoluble organic matter. Moreover, we found that the concentration of MCAs in CR chondrites is higher than in the other meteorite groups, with acetic acid exhibiting the highest concentration in all samples. The abundance of MCAs decreased with increasing molecular weight and with increasing aqueous and/or thermal alteration experienced by the meteorite sample. The δ¹³C isotopic values of MCAs ranged from ?52 to +27‰, and aside from an inverse relationship between δ¹³C value and carbon straight‐chain length for C₃–C₆ MCAs in Murchison, the ¹³C‐isotopic values did not correlate with the number of carbon atoms per molecule. We also observed racemic compositions of 2‐methylbutanoic acid in CM and CR chondrites. We used this novel analytical protocol and collective data to shed new light on the prebiotic origins of chondritic MCAs.     

Assessment of boundary-element method for modelling a free-floating sloped wave energy device. Part 1: Numerical modelling

The boundary-element method has been widely used as a design tool in the offshore and ship building industry for more than 30 years. Its application to wave energy conversion is, however, more recent. This paper deals with the numerical modelling of a free-floating sloped wave energy device. The power take-off mechanism of the device consists of an immersed tube with a piston sliding inside. The modelling is done using the boundary-element method package WAMIT. The model is first worked out for the case where the axis of the tube is vertical. It is then derived for the tube inclined and successfully verified against numerical benchmark data. A companion paper presents results of a detailed comparison with a physical model study.     

Methylmercury production in sediments of Chesapeake Bay and the mid-Atlantic continental margin

Methylmercury (MeHg) concentration and production rates were studied in bottom sediments along the mainstem of Chesapeake Bay and on the adjoining continental shelf and slope. Our objectives were to 1) observe spatial and temporal changes in total mercury (HgT) and MeHg concentrations in the mid-Atlantic coastal region, 2) investigate biogeochemical factors that affect MeHg production, and 3) examine the potential of these sediments as sources of MeHg to coastal and open waters. Estuarine, shelf and slope sediments contained on average 0.5 to 1.5% Hg as MeHg (% MeHg), which increased significantly with salinity across our study site, with weak seasonal trends. Methylation rate constants (k_meth), estimated using enriched stable mercury isotope spikes to intact cores, showed a similar, but weaker, salinity trend, but strong seasonality, and was highly correlated with % MeHg. Together, these patterns suggest that some fraction of MeHg is preserved thru seasons, as found by others [Orihel, D.M., Paterson, M.J., Blanchfield, P.J., Bodaly, R.A., Gilmour, C.C., Hintelmann, H., 2008. Temporal changes in the distribution, methylation, and bioaccumulation of newly deposited mercury in an aquatic ecosystem. Environmental Pollution 154, 77] Similar to other ecosystems, methylation was most favored in sediment depth horizons where sulfate was available, but sulfide concentrations were low (between 0.1 and 10 μM). MeHg production was maximal at the sediment surface in the organic sediments of the upper and mid Bay where oxygen penetration was small, but was found at increasingly deeper depths, and across a wider vertical range, as salinity increased, where oxygen penetration was deeper. Vertical trends in MeHg production mirrored the deeper, vertically expanded redox boundary layers in these offshore sediments. The organic content of the sediments had a strong impact on the sediment:water partitioning of Hg, and therefore, on methylation rates. However, the HgT distribution coefficient (K_D) normalized to organic matter varied by more than an order of magnitude across the study area, suggesting an important role of organic matter quality in Hg sequestration. We hypothesize that the lower sulfur content organic matter of shelf and slope sediments has a lower binding capacity for Hg resulting in higher MeHg production, relative to sediments in the estuary. Substantially higher MeHg concentrations in pore water relative to the water column indicate all sites are sources of MeHg to the water column throughout the seasons studied. Calculated diffusional fluxes for MeHg averaged  1 pmol m^− 2 day^− 1. It is likely that the total MeHg flux in sediments of the lower Bay and continental margin are significantly higher than their estimated diffusive fluxes due to enhanced MeHg mobilization by biological and/or physical processes. Our flux estimates across the full salinity gradient of Chesapeake Bay and its adjacent slope and shelf strongly suggest that the flux from coastal sediments is of the same order as other sources and contributes substantially to the coastal MeHg budget.     

Measuring impact crater depth throughout the solar system

One important, almost ubiquitous, tool for understanding the surfaces of solid bodies throughout the solar system is the study of impact craters. While measuring a distribution of crater diameters and locations is an important tool for a wide variety of studies, so too is measuring a crater's “depth.” Depth can inform numerous studies including the strength of a surface and modification rates in the local environment. There is, however, no standard data set, definition, or technique to perform this data-gathering task, and the abundance of different definitions of “depth” and methods for estimating that quantity can lead to misunderstandings in and of the literature. In this review, we describe a wide variety of data sets and methods to analyze those data sets that have been, are currently, or could be used to derive different types of crater depth measurements. We also recommend certain nomenclature in doing so to help standardize practice in the field. We present a review section of all crater depths that have been published on different solar system bodies which shows how the field has evolved through time and how some common assumptions might not be wholly accurate. We conclude with several recommendations for researchers which could help different data sets to be more easily understood and compared.     

Revised recommended methods for analyzing crater size-frequency distributions

Impact crater populations help us to understand solar system dynamics, planetary surface histories, and surface modification processes. A single previous effort to standardize how crater data are displayed in graphs, tables, and archives was in a 1978 NASA report by the Crater Analysis Techniques Working Group, published in 1979 in Icarus. The report had a significant lasting effect, but later decades brought major advances in statistical and computer sciences while the crater field has remained fairly stagnant. In this new work, we revisit the fundamental techniques for displaying and analyzing crater population data and demonstrate better statistical methods that can be used. Specifically, we address (1) how crater size-frequency distributions (SFDs) are constructed, (2) how error bars are assigned to SFDs, and (3) how SFDs are fit to power-laws and other models. We show how the new methods yield results similar to those of previous techniques in that the SFDs have familiar shapes but better account for multiple sources of uncertainty. We also recommend graphic, display, and archiving methods that reflect computers’ capabilities and fulfill NASA's current requirements for Data Management Plans.