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1.
Non‐equilibrium concepts lead to a unified explanation of the formation of chondrules and chondrites
Milton BLANDER Arthur D. PELTON In‐Ho JUNG Richard WEBER 《Meteoritics & planetary science》2004,39(12):1897-1910
Abstract— Calculations of the formation of seven types of chondrules in Semarkona from a gas of solar composition were performed with the FACT computer program to predict the chemistries of oxides (including silicates), developed by the authors and their colleagues. The constrained equilibrium theory was used in the calculations with two nucleation constraints suggested by nucleation theory. The first constraint was the blocking of Fe and other metal gaseous atoms from condensing to form solids or liquids because of very high surface free energies and high surface tensions of the solid and liquid metals, respectively. The second constraint was the blocking of the condensation of solids and the formation of metastable liquid oxides (including silicates) well below their liquidus temperatures. Our laboratory experiments suggested subcooling of type IIA chondrule compositions of 400 degrees or more below the liquidus temperature. The blocking of iron leads to a supersaturation of Fe atoms, so that the partial pressure of Fe (pFe) is larger than the partial pressure at equilibrium (pFe(eq)). The supersaturation ratio S = pFe/pFe(eq) becomes larger than 1 and increases rapidly with a decrease in temperature. This drives the reaction Fe + H2O ? H2 + FeO to the right. With S = 100, the activity of FeO in the liquid droplet is 100 times as large as the value at equilibrium. The FeO activities are a function of temperature and provide relative average temperatures of the crystallization of chondrules. Our calculations for the LL3.0 chondrite Semarkona and our study of some non‐equilibrium effects lead to accurate representations of the compositions of chondrules of types IA, IAB, IB, IIA, IIAB, IIB, and CC. Our concepts readily explain both the variety of FeO concentrations in the different chondrule types and the entire process of chondrule formation. Our theory is unified and could possibly explain the formation of chondrules in all chondritic meteorites as well as provide a simple explanation for the complex chemistries of chondrites, and especially for type 3 chondrites. 相似文献
2.
Progress in the introduction of coulometry for the analysis of total carbon dioxide (TCO2) in marine waters is described. An extractor—stripper removes CO2 that is measured coulometrically by the quantity of electricity (coulombs) used to electrogenerate OH? ions for the titration of the acid formed by the reaction of CO2 and ethanolamine. The equivalence point is detected photometrically with thymolphthalein as the indicator, and Faraday's Law relates coulombs to equivalents of titrant generated and CO2 determined so that there are no standard curves needed or titrants to standardize or store. Accuracy was determined by adding gelatin capsules containing 100–1500 μg C of pure CaCO3 into the stripper, and accuracies of better than ± 1 μg C were achieved. The best precision for natural seawater (± 1 standard error) of ± 0.5 μmol l?1 was found for 17 samples of Bermuda coastal waters having a mean TCO2 of 2007.2 μmol l?1 (0.05% CV). Sources of error and precautions are discussed. This method, which has been used successfully at sea, can be used to study a variety of marine phenomena involving TCO2. 相似文献
3.
Summary. We give a systematic formulation and a rigorous justification of a perturbation technique for the computation of the eigenvalues and eigenfunctions of Love waves (and toroidal oscillations by an appropriate change for variables) in an anelastic medium with a constitutive law modelling geophysical media of current interest such as the Kelvin—Voigt Solid, the Maxwell Solid, the Standard Linear Solid, and the Standard Linear Solid with a continuous spectrum of relaxation times. We develop expressions relating the eigenvalues of eigenfunctions for Love waves in a continuously varying vertically stratified anelastic half-space to the corresponding elastic eigenvalues and eigenfunctions. Analytically, our correspondence principle has the form of a regular perturbation expansion in terms of a parameter for both the eigenvalues and eigenfunctions. The identification of ɛ is motivated by the dissipativity principle of viscoelasticity theory. Moreover, we show that our correspondence principle applies respectively only in the high and low frequency range for the Maxwell and Kelvin—Voigt Solids. Outside of the applicable range of frequencies, our correspondence principle yields no useful information. For the family of Standard Linear Solids it is uniformly applicable for all non-zero frequencies.
We also derive an explicit formula to estimate the radius of convergence of our perturbation expansions. This estimate of the radius of convergence for each eigenvalue and eigenfunction is functionally defined by the constitutive model for the anelastic medium. The estimate is frequency dependent and depends on the separation distance between the eigenvalue and the remainder of the spectrum of the corresponding elastic problem. 相似文献
We also derive an explicit formula to estimate the radius of convergence of our perturbation expansions. This estimate of the radius of convergence for each eigenvalue and eigenfunction is functionally defined by the constitutive model for the anelastic medium. The estimate is frequency dependent and depends on the separation distance between the eigenvalue and the remainder of the spectrum of the corresponding elastic problem. 相似文献
4.
Arthur Kosowsky 《New Astronomy Reviews》2003,47(11-12):939
The proposed Atacama Cosmology Telescope (ACT) project is described. This multi-institution collaboration aims to produce arcminute-resolution and micro-Kelvin sensitivity maps of the microwave background temperature over 200 square degree of the sky in three frequency bands. We give a brief overview of the scientific motivations for such a map, followed by a design outline of our 6-m custom telescope, an overview of our proposed bolometer array detector technology, and site considerations and scan strategy. We also describe associated optical and X-ray galaxy cluster surveys. 相似文献
5.
Chin Ptc 《Singapore journal of tropical geography》1985,6(2):139-152
The author investigates the extent to which both absolute and relative poverty affect population growth in developing countries. Aggregate data from U.N. sources for 26 countries at various stages of the fertility transition are used. The results indicate that the most significant steps in reducing fertility would be more effective provision of basic human needs and reforms in land tenure. The need to distinguish between absolute and relative poverty in formulating population policies is noted. 相似文献
6.
Ecological characteristics of Walleye pollock eggs and larvae in the southeastern Bering Sea during the late 1970s 总被引:1,自引:0,他引:1
Kyung-Mi Jung Sukyung Kang Suam Kim Arthur W. Kendall Jr. 《Journal of Oceanography》2006,62(6):859-871
Walleye pollock (Theragra chalcogramma) is an ecologically and economically important groundfish in the eastern Bering Sea. Its population size fluctuates widely,
driving and being driven by changes in other components of the ecosystem. It is becoming apparent that dramatic shifts in
climate occur on a decadal scale, and these “regime shifts” strongly affect the biota. This paper examines quantitative collections
of planktonic eggs and larvae of pollock from the southeastern Bering Sea during 1976–1979. Mortality, advection, and growth
rates were estimated, and compared among the years encompassing the 1970s’ regime shift. These data indicate that pollock
spawning starts in late February over the basin north of Bogoslof Island. Over the shelf, most spawning occurs north of Unimak
Island near the 100 m isobath in early or mid April. Pollock eggs are advected to the northwest from the main spawning area
at 5–10 cm/sec. Larvae are found over the basin north of Bogoslof Island in April, and over the shelf between Unimak Island
and the Priblof Islands in May. Compared to 1977, the spawning period appeared to be later in 1976 (a cold year) and earlier
in 1978 (a warm year) in the study area. At the lower temperatures in 1976, egg duration would be longer and thus egg mortality
would operate over a longer period than in the other years. Mean larval growth appeared to be lower in 1976 than in 1977 and
1979. Estimated egg mortality rate in 1977 was 0.6 in April and 0.3 in early May. 相似文献
7.
Roles of Continental Shelves and Marginal Seas in the Biogeochemical Cycles of the North Pacific Ocean 总被引:4,自引:0,他引:4
Chen-Tung Arthur Chen Andrey Andreev Kyung-Ryul Kim Michiyo Yamamoto 《Journal of Oceanography》2004,60(1):17-44
Most marginal seas in the North Pacific are fed by nutrients supported mainly by upwelling and many are undersaturated with
respect to atmospheric CO2 in the surface water mainly as a result of the biological pump and winter cooling. These seas absorb CO2 at an average rate of 1.1 ± 0.3 mol C m−2yr−1 but release N2/N2O at an average rate of 0.07 ± 0.03 mol N m−2yr−1. Most of primary production, however, is regenerated on the shelves, and only less than 15% is transported to the open oceans
as dissolved and particulate organic carbon (POC) with a small amount of POC deposited in the sediments. It is estimated that
seawater in the marginal seas in the North Pacific alone may have taken up 1.6 ± 0.3 Gt (1015 g) of excess carbon, including 0.21 ± 0.05 Gt for the Bering Sea, 0.18 ± 0.08 Gt for the Okhotsk Sea; 0.31 ± 0.05 Gt for
the Japan/East Sea; 0.07 ± 0.02 Gt for the East China and Yellow Seas; 0.80 ± 0.15 Gt for the South China Sea; and 0.015 ±
0.005 Gt for the Gulf of California. More importantly, high latitude marginal seas such as the Bering and Okhotsk Seas may
act as conveyer belts in exporting 0.1 ± 0.08 Gt C anthropogenic, excess CO2 into the North Pacific Intermediate Water per year. The upward migration of calcite and aragonite saturation horizons due
to the penetration of excess CO2 may also make the shelf deposits on the Bering and Okhotsk Seas more susceptible to dissolution, which would then neutralize
excess CO2 in the near future. Further, because most nutrients come from upwelling, increased water consumption on land and damming
of major rivers may reduce freshwater output and the buoyancy effect on the shelves. As a result, upwelling, nutrient input
and biological productivity may all be reduced in the future. As a final note, the Japan/East Sea has started to show responses
to global warming. Warmer surface layer has reduced upwelling of nutrient-rich subsurface water, resulting in a decline of
spring phytoplankton biomass. Less bottom water formation because of less winter cooling may lead to the disappearance of
the bottom water as early as 2040. Or else, an anoxic condition may form as early as 2200 AD.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
8.
The performance of Salter's cam as an energy extractor from ocean waves is studied numerically on the basis of linear theory of surface waves and floating bodies. Quantities of engineering interest such as efficiency, induced motion and reaction forces are presented and discussed both for fixed and for partly constrained cam shafts. 相似文献
9.
Arthur C. R. Gleason Diego Lirman Dana Williams Nuno R. Gracias Brooke E. Gintert Hossein Madjidi R. Pamela Reid G. Chris Boynton Shahriar Negahdaripour Margaret Miller & Philip Kramer 《Marine Ecology》2007,28(2):254-258
Four hurricanes impacted the reefs of Florida in 2005. In this study, we evaluate the combined impacts of hurricanes Dennis, Katrina, Rita, and Wilma on a population of Acropora palmata using a newly developed video‐mosaic methodology that provides a high‐resolution, spatially accurate landscape view of the reef benthos. Storm damage to A. palmata was surprisingly limited; only 2 out of 19 colonies were removed from the study plot at Molasses Reef. The net tissue losses for those colonies that remained were only 10% and mean diameter of colonies decreased slightly from 88.4 to 79.6 cm. In contrast, the damage to the reef framework was more severe, and a large section (6 m in diameter) was dislodged, overturned, and transported to the bottom of the reef spur. The data presented here show that two‐dimensional video‐mosaic technology is well‐suited to assess the impacts of physical disturbance on coral reefs and can be used to complement existing survey methodologies. 相似文献
10.
Toshiro Saino Alexander Bychkov Chen-Tung Arthur Chen Paul J. Harrison 《Journal of Oceanography》2004,60(1):1-4
This special issue is comprised of 13 papers, including this overview, and focuses on the synthesis of the Joint Global Ocean
Flux Study (JGOFS) in the North Pacific which took place from 1997 through 2003. The effort was led by the JGOFS North Pacific
Synthesis Group, with the aim of quantifying CO2 drawdown by physical and biological pumps in the North Pacific by identifying and studying the regional, seasonal to inter-annual
variations in the key processes, and understanding their regulating mechanisms. Emphasis was placed on the similarities and
differences of the biogeochemical regimes in the eastern and western subarctic Pacific. Effort was also made to address the
future research directions which arose from the scientific findings during the North Pacific JGOFS process study. A brief
overview of the papers from view points of CO2 drawdown by physical and biological pumps, spatial variability, and temporal variability from seasonal to decadal scales
is made, followed by suggestions for the directions of future research.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献