Meteoric diagenesis in Pleistocene reef limestones of Xisha Islands, China

This paper focuses on a borehole, Xichen-1 well, drilled on the Chenhang Island, Xisha Islands in the South China Sea. Mineralogical, petrographic, stable isotopic and minor-element data from the Holocene to Pleistocene interval (0–179 m ) in the Xichen-1 well are discussed in detail. The 400-m-long core is divisible into four mineralogical facies: a high-Mg calcitic aragonite facies (0–16.91 m, Holocene), an aragonitic low- Mg calcite facies (16.91–30.60 m, Late Pleistocene), a low- Mg calcitic facies (30.60–179 m, Middle-Early Pleistocene) and a low- Mg calcitic and dolomitic facies (179–400 m, Early Pleistocene–Late Miocene). The Holocene section has much higher whole-rock δ¹⁸O and δ¹³C values and Mg and Sr content than the non-dolomitized Pleistocene limestones (16.91–179 m). The 16.91–165 m interval is characterized by a relatively invariant oxygen isotopic composition and very heterogeneous carbon isotopic composition. Between 165 and 179 m, there is a positively correlated increase of whole-rock δ¹⁸O and δ¹⁸C with depth, and Mg content also shows a gradual increase with depth. Petrographic data demonstrate that the Pleistocene reef sequence has been extensively affected by meteoric waters. We conclude that the Late Pleistocene section (16.91–30.60 m) and the Middle-Early Pleistocene section (30.60–165 m) have suffered incomplete and complete meteoric diagenesis, respectively, and that the Early Pleistocene interval (165–179 m) was diagenetically altered in a meteoric–marine mixing environment.     

河流调整中的熵、熵产生和能耗率的变化

河流是一个真正的开放系统,而不是孤立系统或封闭系统。运用经典热力学和非平衡态热力学基本原理,分析研究了河流调整中的熵、熵产生和能耗率的变化。指出:熵和熵产生是两个不同的概念;最小熵产生原理等价于最小能耗率原理;冲积河流在调整过程中遵循最小熵产生原理或最小能耗率原理,而不是最大熵原理。     

沙南凹陷古近系中深层砂岩储层特征与岩性油气藏勘探

渤海湾盆地沙南凹陷陡坡带古近系沙河街组二段发育辫状河三角洲相砂岩储集层,该储层受构造位置、埋藏速率、古地温变化、断裂作用的影响,在不同构造区特别是中深层,其物性具有明显的差异性。笔者等利用钻井、测井、地震及分析化验等资料,对中深层砂岩储层沉积相、成岩作用及孔隙演化特征进行研究,提出优质储层的主控因素及演化规律。结果表明,研究区中深层砂岩以岩屑长石砂岩为主,孔隙以粒间溶孔、粒内溶孔为主,储层存在中孔中渗型、中孔低渗型、低孔低渗型和低孔特低渗型4类,且以中孔低渗型为主。储层孔隙总体比较发育,储层整体表现为中等孔隙度、中等渗透率,储层物性较好。对区内优质储层发育的控制因素进行研究表明,富含石英、长石的物源区母岩是区内优质储层发育的物质基础,三角洲分流河道沉积相是优质储层发育的主要沉积相类型,成岩晚期方解石胶结物经过强溶蚀作用是优质储层发育的关键因素。对中深层优质储层时空演化规律分析表明,沙南凹陷南次洼曹妃甸14- e构造区发育辫状河三角洲相砂体,且这些砂体都位于有效烃源岩内,油气运聚条件优越,所以岩性油气藏勘潜力较大。已钻井也证明了区内厚油层的存在,说明该区是沙南凹陷岩性油气藏勘探最有利场所。     

热带气旋"蒲公英"两次登陆过程的灾害与结构特征

2004年7月1~3日,热带气旋“蒲公英”自生成到影响浙江沿海地区期间,不仅持续时间长、强度大,移动路径长、变化较复杂,而且创下了近3年来台湾风灾损失的最高纪录,同时也给浙江等沿海地区造成了一定的经济损失。作者主要利用卫星云图资料、NCEP再分析资料,从宏观上对热带气旋“蒲公英”两次登陆过程中的强度及其引发的风雨灾害进行了分析。结果表明,“蒲公英”登陆台湾期间,东亚环流形势呈典型的鞍形场分布,有利于处于两高之间热带气旋“蒲公英”的维持和北上转向。而在其登陆浙江沿海地区后,浙江沿海地区处于较强的偏东气流中,“蒲公英”中心处于高空槽后,气流下沉以及缺少水汽和能量充沛供应使得其减弱为热带风暴。无论是其登陆台湾还是浙江沿海地区,台风垂直方向始终呈深厚气旋性涡柱结构,但中心附近低层辐散,中层辐合,不利于中心附近的对流发展。相反,台风外围螺旋云带内不仅中低层辐合,高层辐散,辐合层较深厚,且存在高湿和强上升运动,因而有利于对流云团的发展。对流云团发展强度的不同使得“蒲公英”两次登陆期间引发的风雨灾害明显不同。     

Characteristics of Radar Echo Parameters and Microphysical Structure Simulation of a Short-Time Heavy Precipitation Supercell

By using the conventional observations, radar data, NCEP/NCAR FNL 1°×1° reanalysis data and numerical simulation data and with the construction and calculation of radar echo parameters, this paper presents the structural characteristics and physical processes of a short-time heavy precipitation supercell that occurred in the squall line process in Shanxi Province on 24 June 2020. The results show that this squall line event occurred in front of a surface cold front,combined with infiltration of ...     

温度、盐度和pH对冈村枝管藻中性游孢子附着及生长发育的影响

用毛细管法分离出冈村枝管藻成熟的多室孢子囊,并对中性游孢子的发育模式及温度、盐度、pH对其附着及生长发育的影响进行了研究。结果发现：（1）中性游孢子正常发育模式如下：附着后,形成盘状体;而后在盘状体中间产生同化丝,大量同化丝产生后,基部细胞变形、聚集,形成假薄壁组织,直立藻丝形成;（2）中性游孢子附着及生长发育明显受温度、盐度和pH条件的影响。中性游孢子附着的适宜温度17--28℃、盐度为20～50、pH为5～10．4;直立藻丝形成的条件为温度17～26℃、盐度20～40、pH7～10。本研究为冈村枝管藻海上栽培提供了理论依据。     

Diamond in Oceanic Peridotites and Chromitites: Evidence for Deep Recycled Mantle in the Global Ophiolite Record

Diamonds have been discovered in mantle peridotites and chromitites of six ophiolitic massifs along the 1300 km‐long Yarlung‐Zangbo suture (Bai et al., 1993; Yang et al., 2014; Xu et al., 2015), and in the Dongqiao and Dingqing mantle peridotites of the Bangong‐Nujiang suture in the eastern Tethyan zone (Robinson et al., 2004; Xiong et al., 2018). Recently, in‐situ diamond, coesite and other UHP mineral have also been reported in the Nidar ophiolite of the western Yarlung‐Zangbo suture (Das et al., 2015, 2017). The above‐mentioned diamond‐bearing ophiolites represent remnants of the eastern Mesozoic Tethyan oceanic lithosphere. New publications show that diamonds also occur in chromitites in the Pozanti‐Karsanti ophiolite of Turkey, and in the Mirdita ophiolite of Albania in the western Tethyan zone (Lian et al., 2017; Xiong et al., 2017; Wu et al., 2018). Similar diamonds and associated minerals have also reported from Paleozoic ophiolitic chromitites of Central Asian Orogenic Belt of China and the Ray‐Iz ophiolite in the Polar Urals, Russia (Yang et al., 2015a, b; Tian et al., 2015; Huang et al, 2015). Importantly, in‐situ diamonds have been recovered in chromitites of both the Luobusa ophiolite in Tbet and the Ray‐Iz ophiolite in Russia (Yang et al., 2014, 2015a). The extensive occurrences of such ultra‐high pressure (UHP) minerals in many ophiolites suggest formation by similar geological events in different oceans and orogenic belts of different ages. Compared to diamonds from kimberlites and UHP metamorphic belts, micro‐diamonds from ophiolites present a new occurrence of diamond that requires significantly different physical and chemical conditions of formation in Earth's mantle. The forms of chromite and qingsongites (BN) indicate that ophiolitic chromitite may form at depths of >150‐380 km or even deeper in the mantle (Yang et al., 2007; Dobrthinetskaya et al., 2009). The very light C isotope composition (δ13C ‐18 to ‐28‰) of these ophiolitic diamonds and their Mn‐bearing mineral inclusions, as well as coesite and clinopyroxene lamallae in chromite grains all indicate recycling of ancient continental or oceanic crustal materials into the deep mantle (>300 km) or down to the mantle transition zone via subduction (Yang et al., 2014, 2015a; Robinson et al., 2015; Moe et al., 2018). These new observations and new data strongly suggest that micro‐diamonds and their host podiform chromitite may have formed near the transition zone in the deep mantle, and that they were then transported upward into shallow mantle depths by convection processes. The in‐situ occurrence of micro‐diamonds has been well‐demonstrated by different groups of international researchers, along with other UHP minerals in podiform chromitites and ophiolitic peridotites clearly indicate their deep mantle origin and effectively address questions of possible contamination during sample processing and analytical work. The widespread occurrence of ophiolite‐hosted diamonds and associated UHP mineral groups suggests that they may be a common feature of in‐situ oceanic mantle. The fundamental scientific question to address here is how and where these micro‐diamonds and UHP minerals first crystallized, how they were incorporated into ophiolitic chromitites and peridotites and how they were preserved during transport to the surface. Thus, diamonds and UHP minerals in ophiolites have raised new scientific problems and opened a new window for geologists to study recycling from crust to deep mantle and back to the surface.     

内蒙古索伦山地区哈尔博格托尔TTG岩锆石年代学、岩石地球化学及大地构造意义

内蒙古索伦山地区是中亚造山带构造演化的关键区域,其中关于古亚洲洋的闭合时限以及西伯利亚板块和华北板块的拼贴时空关系一直存在争议。出露于内蒙古索伦山地区哈尔博格托尔的中酸性侵入岩,其深入研究对探讨古亚洲洋演化具有重要意义。文中对内蒙古索伦山地区哈尔博格托尔TTG岩进行了系统的岩石学、年代学及地球化学研究。获得哈尔博格托尔TTG岩的LA ICP MS锆石U Pb年龄为(266.7±3.7) Ma,表明该侵入岩形成于中二叠世。地球化学主量元素分析表明,索伦山地区哈尔博格托尔TTG岩的岩石系列主要为含钠较高的钙碱性准铝质系列。其稀土元素总量较低,呈现轻稀土元素(LREEs)相对于重稀土元素(HREEs)弱富集的特征,Eu异常不明显;微量元素呈现Rb、Ba、Th、U等大离子亲石元素富集,Nb、Ta、Ti等高场强元素强烈亏损的特征,与典型的岛弧岩浆岩类似。结合索伦山TTG岩体地质特征和区域地质背景,综合年代学和地球化学特征分析,笔者认为索伦山地区哈尔博格托尔TTG岩体形成于岛弧环境,即中二叠世期间古亚洲洋壳向华北板块还存在俯冲作用,因而古亚洲洋至少应在中二叠世以后才闭合。内蒙古索伦山地区哈尔博格托尔TTG岩是洋壳俯冲的岩石学记录,为索伦山缝合带及古亚洲洋构造域演化提供了新的基础地质资料。     

辽东半岛东北部宽甸地区南辽河群沉积时限的确定及其构造意义

辽东半岛东北部宽甸地区出露大面积南辽河群变质表壳岩系,本文通过对其中黑云石英片岩、含电气石浅粒岩和花岗质片麻岩进行精确的锆石LA-ICP-MSU-Pb定年及微区痕量元素分析,并结合锆石阴极发光(CL)图像研究来制约其原岩形成时代和变质时代,进而探讨胶-辽-吉活动带的大地构造属性。Cl图像显示锆石可以分为三类,第一类无核边结构,呈灰黑色均质特征;第二类发育核边结构,核部不发育或具弱生长环带,第三类锆石整体或者核部发育明显生长环带或具条痕状吸收特点,而后两类多数发育灰色均质边,与第一类特征一致。微区痕量元素分析结果显示,灰色均质锆石或边部具有高U(731.2×10-6～1383×10-6)、低Th(51.09～85.15×10-6)和Th/U(0.06～0.07)等特征,为变质成因;第二类锆石核部具有较高Th(97.68～219.7×10-6)和Th/U(0.21～0.27),为岩浆成因;第三类具有高Th(249.6×10-6～469.4×10-6)和Th/U(0.60～0.74),为岩浆成因。定年结果显示,所有测点均位于谐和线上或附近,三类锆石207Pb/206Pb年龄分别介于1878～1903Ma,2011～2043Ma和2082～3285Ma,前两者峰期年龄分别为1885Ma和2035Ma,表明该区南辽河群的原岩形成于～2035Ma之后,而峰期变质作用应发生在～1885Ma,其沉积作用应发生于2035～1885Ma之间;第三类锆石年龄区域上与古元古代辽吉花岗岩、火山岩及古老结晶基底年龄相吻合,暗示它们为南辽河群提供重要物源。结合前人有关辽吉花岗岩及区域构造变形、变质作用等资料,本文研究认为辽东半岛东北部宽甸地区南辽河群应形成于伸展的构造环境。     

赣东北地区矽卡岩典型矿物形成与演化的光谱证据:以朱溪钨多金属矿为例SCIEI北大核心CSCD

朱溪是近年来在江西塔前-赋春成矿带发现的一个世界级超大型钨铜矿床。本文采用短波红外+热红外光谱技术对矿区13个钻孔进行了光谱测量,结合岩石-矿物地球化学分析,探讨了朱溪矿床矽卡岩中典型蚀变矿物的形成与演化过程,厘定了矽卡岩形成不同阶段矿物组合的光谱特征,构建了朱溪矿床的短波红外+热红外光谱勘查模型。研究发现:(1)区内不同矿物组合形成了明显的蚀变分带,由内向外依次为绢云母(富Si)+长石(岩体顶层蚀变,多期流体叠加综合作用)→外矽卡岩:钙铝榴石+透辉石+(绢云母)→透辉石+蛇纹石+绿泥(帘)石+滑石→绢云母(富Al)+绿泥(帘)石(基底不整合面蚀变);(2)Al-OH波长的移动可指示成矿流体压力、温度及pH值的变化;(3)研究区透辉石的形成、演化与矿体之间关系密切,虽然富矿体赋存于矽卡岩形成早期的透辉石-石榴子石蚀变带,但大量矿体则赋存于矽卡岩退蚀变阶段的蛇纹石-绿泥石蚀变带;(4)矿体的形成与流体的混合作用关系极大,伊利石光谱吸收特征能够指示外部冷水(大气降水或地下水)的灌入轨迹。