Upwelling, species, and depth effects on coral skeletal cadmium-to-calcium ratios (Cd/Ca)

Skeletal cadmium-to-calcium (Cd/Ca) ratios in hermatypic stony corals have been used to reconstruct changes in upwelling over time, yet there has not been a systematic evaluation of this tracer’s natural variability within and among coral species, between depths and across environmental conditions. Here, coral skeletal Cd/Ca ratios were measured in multiple colonies of Pavona clavus, Pavona gigantea and Porites lobata reared at two depths (1 and 7 m) during both upwelling and nonupwelling intervals in the Gulf of Panama (Pacific). Overall, skeletal Cd/Ca ratios were significantly higher during upwelling than during nonupwelling, in shallow than in deep corals, and in both species of Pavona than in P. lobata. P. lobata skeletal Cd/Ca ratios were uniformly low compared to those in the other species, with no significant differences between upwelling and nonupwelling values. Among colonies of the same species, skeletal Cd/Ca ratios were always higher in all shallow P. gigantea colonies during upwelling compared to nonupwelling, though the magnitude of the increase varied among colonies. For P. lobata, P. clavus and deep P. gigantea, changes in skeletal Cd/Ca ratios were not consistent among all colonies, with some colonies having lower ratios during upwelling than during nonupwelling. No statistically significant relationships were found between skeletal Cd/Ca ratios and maximum linear skeletal extension, δ¹³C or δ¹⁸O, suggesting that at seasonal resolution the Cd/Ca signal was decoupled from growth rate, coral metabolism, and ocean temperature and salinity, respectively. These results led to the following conclusions, (1) coral skeletal Cd/Ca ratios are independent of skeletal extension, coral metabolism and ambient temperature/salinity, (2) shallow P. gigantea is the most reliable species for paleoupwelling reconstruction and (3) the average Cd/Ca record of several colonies, rather than of a single coral, is needed to reliably reconstruct paleoupwelling events.     

National-scale estimation of potentially harmful element ambient background concentrations in topsoil using parent material classified soil:stream–sediment relationships

Regulatory authorities require estimates of ambient background concentrations (ABCs) of potentially harmful elements (PHEs) in topsoil; such data are currently not available in many countries. High resolution soil geochemical data exist for only part of England and Wales, whilst stream sediment data cover the entire landscape. A novel methodology is presented for estimating soil equivalent ABCs for PHEs from high-resolution (HR) stream sediment geochemical data grouped by common parent materials (PM), using arsenic (As) as an example. Geometric mean (GM) values for local PM groups are used to investigate different approaches for transforming sediment to soil equivalent concentrations. Holdout validation is used to assess: (i) the optimum number of samples for calculating local GM values, and (ii) the optimum scale at which to group data when using linear regression analysis to estimate GM soil ABCs from local sediment geochemical values. Holdout validation showed that the smallest differences were generally observed when five observations were used to calculate the GM and that these should be grouped over the smallest possible area in order to encompass soils over PMs with elevated GM As concentrations. Geometric mean ABCs are estimated and mapped for As in mineral soil across all of England and Wales within delineations of PM polygons. Errors for the estimation of soil equivalent GM As ABCs based on sediment data for an independent validation set were of a similar magnitude to those from holdout validation applied to the original data suggesting the approach is robust. The estimates of soil equivalent ABCs suggest that As exceeds the regulatory threshold used in risk assessments for residential land use (20 mg kg⁻¹) across 16% of the landscape of England and Wales. The applicability of the method for cognate landscapes, and potential refinements is discussed.     

Catch-quota balancing in multispecies individual fishing quotas

Individual fishery quotas (IFQs) are an increasingly prevalent form of fishery management around the world, with more than 170 species currently managed with IFQs. Yet, because of the difficulties in matching quota holdings with catches, many argue that IFQs are not appropriate for multispecies fisheries. Using on-the-ground-experience with multispecies IFQ fisheries in Iceland, New Zealand, Australia, and Canada, we assess the design and use of catch-quota balancing mechanisms. Our methodology includes a mix of interviews with fishery managers, industry representatives, and brokers, literature review, and data analysis. We find that a combination of incentives and limits on use rates for the mechanisms provide sufficient flexibility to the quota owner without the fishery manager incurring excessive levels of overexploitation risk. Contrary to some opinions, these programs are evidence that it is possible to implement IFQ programs for multispecies fisheries and that they can be profitable and sustainable.     

Regional variation in springtime ichthyoplankton assemblages in the northeast Pacific Ocean

The coastal regions of the northeast Pacific support large, economically valuable fishery resources and provide nursery areas for many fish species. Over the last few decades, there have been dramatic shifts in species abundance and composition in this area. In this paper, we examine the springtime spatial patterns in the ichthyoplankton of three oceanographically different regions, the Southeast Bering Sea, the Gulf of Alaska and the U.S. West Coast. The data examined are a subset of a larger database (comprising data from cruises conducted from 1972 to 1997) that is being used to investigate spatial, seasonal and interannual patterns in ichthyoplankton of the northeast Pacific in relation to environmental conditions. Ichthyoplankton were collected during seven cruises using 60-cm bongo nets. Spatial patterns of ichthyoplankton were examined using both classification and ordination techniques. Relative Bray-Curtis dissimilarity coefficients calculated from the log₁₀ (n+1) of abundance data were used as input to the numerical classification of species and stations. Nonmetric multidimensional scaling was also applied to the abundance data to examine geometric patterns in the data. The numerical analyses of the species abundance data sets for each cruise revealed spatial patterns in the ichthyoplankton that suggest the occurrence of geographically distinct assemblages of fish larvae in each region. For all three sampling regions, the assemblage structure is primarily related to bathymetry, and Shelf, Slope, and Deep-Water assemblages are described. This shallow to deep-water gradient in species occurrence and abundance reflects the habitat preference and spawning location of the adult fish. Another degree of complexity is superimposed on this primary assemblage structure in each region and seems to be related to local topography and the prevailing current patterns. The patterns in ichthyoplankton assemblages of the three regions in the northeast Pacific Ocean described here form the basis for future investigations of spatial and temporal patterns in the ichthyoplankton of the subarctic Pacific.Regional Index Terms: Northeast Pacific Ocean, Southeast Bering Sea, Gulf of Alaska, U.S. West Coast.     

GGR Critical Review of Analytical Developments in 2004–2005

In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields.     

Hypervelocity impacts into ice‐topped layered targets: Investigating the effects of ice crust thickness and subsurface density on crater morphology

Many bodies in the outer solar system are theorized to have an ice shell with a different subsurface material below, be it chondritic, regolith, or a subsurface ocean. This layering can have a significant influence on the morphology of impact craters. Accordingly, we have undertaken laboratory hypervelocity impact experiments on a range of multilayered targets, with interiors of water, sand, and basalt. Impact experiments were undertaken using impact speeds in the range of 0.8–5.3 km s^?1, a 1.5 mm Al ball bearing projectile, and an impact incidence of 45°. The surface ice crust had a thickness between 5 and 50 mm, i.e., some 3–30 times the projectile diameter. The thickness of the ice crust as well as the nature of the subsurface layer (liquid, well consolidated, etc.) have a marked effect on the morphology of the resulting impact crater, with thicker ice producing a larger crater diameter (at a given impact velocity), and the crater diameter scaling with impact speed to the power 0.72 for semi‐infinite ice, but with 0.37 for thin ice. The density of the subsurface material changes the structure of the crater, with flat crater floors if there is a dense, well‐consolidated subsurface layer (basalt) or steep, narrow craters if there is a less cohesive subsurface (sand). The associated faulting in the ice surface is also dependent on ice thickness and the substrate material. We find that the ice layer (in impacts at 5 km s^?1) is effectively semi‐infinite if its thickness is more than 15.5 times the projectile diameter. Below this, the crater diameter is reduced by 4% for each reduction in ice layer thickness equal to the impactor diameter. Crater depth is also affected. In the ice thickness region, 7–15.5 times the projectile diameter, the crater shape in the ice is modified even when the subsurface layer is not penetrated. For ice thicknesses, <7 times the projectile diameter, the ice layer is breached, but the nature of the resulting crater depends heavily on the subsurface material. If the subsurface is noncohesive (loose) material, a crater forms in it. If it is dense, well‐consolidated basalt, no crater forms in the exposed subsurface layer.