Ice-rafted detritus evidence from 40Ar/39Ar ages of individual hornblende grains for evolution of the eastern margin of the Laurentide ice sheet since 43 14C ky

During the last glacial interval, the North Atlantic ice sheets expanded and contracted in approximate synchronicity with orbitally forced global climate change. Variation in ice rafted detritus content in North Atlantic marine sediment cores record the waxing and waning of glaciers, as well as the abrupt temperature changes at millennial time scales. The background variations of ice rafting are punctuated by Heinrich layers, which appear to record the catastrophic collapse of the Laurentide ice sheet through the Hudson Strait. The objective of this paper is to document the evolution of glaciation on Laurentia during the last 43 ¹⁴C kyr. We present a provenance study based on ⁴⁰Ar/³⁹Ar dates of individual hornblende grains from 57 samples taken at 2 cm spacing between 4 and 134 cm from core V23-14 (43.4°N, 45.25°W, 3177 m). Sedimentation rates outside of the Heinrich layers are very low in this core, but the Heinrich layers are easily identified. Laurentide glaciation did not extend into the ocean south of 55°N until about 26 ¹⁴C kyr, and retreated to the coastline or beyond by 14 ¹⁴C kyr. Documenting the history of this major ice sheet has significant implications for understanding ice rafting sources in more distal locations where mixing among different ice sheets is likely.     

A significant middle Pleistocene tephra deposit preserved in the caves of Mulu,Borneo

A distinctive white sediment in the caves of Mulu, Sarawak, Borneo is a well-preserved tephra, representing a fluvially transported surface air-fall deposit, re-deposited inside the caves. We show that the tephra is not the Younger Toba Tephra, formerly considered as most likely. The shards are rod-shaped with elongate tubular vesicles; the largest grains ~ 170 μm in length; of rhyolitic composition; and ⁸⁷Sr/⁸⁶Sr ratio of 0.70426 ± 0.00001. U–Th dating of associated calcites suggest that the tephra was deposited before 125 ± 4 ka, and probably before 156 ± 2 ka. Grain size and distance from closest potential source suggests an eruption of VEI 7. Prevailing winds, grain size, thickness of deposit, location of potential sources, and Sr isotopic ratio limit the source to the Philippines. Comparisons with the literature give the best match geochemically with layer 1822 from Ku et al. (2009a), dated by ocean core stratigraphy to 189 ka. This tephra represents a rare terrestrial repository indicating a very substantial Plinian/Ultra-Plinian eruption that covered the Mulu region of Borneo with ash, a region that rarely receives tephra from even the largest known eruptions in the vicinity. It likely will be a valuable chronostratigraphic marker for sedimentary, palaeontological and archaeological studies.     

Sea ice variations in the central Canadian Arctic Archipelago during the Holocene

A sea ice record for Barrow Strait in the Canadian Arctic Archipelago (CAA) is presented for the interval 10.0–0.4 cal. kyr BP. This Holocene record is based primarily on the occurrence of a sea ice biomarker chemical, IP₂₅, isolated from a marine sediment core obtained from Barrow Strait in 2005. A core chronology is based on ¹⁴C AMS dating of mollusc shells obtained from ten horizons within the core. The primary IP₂₅ data are compared with complementary proxy data obtained from analysis of other organic biomarkers, stable isotope composition of bulk organic matter, benthic foraminifera, particle size distributions and ratios of inorganic elements. The combined proxy data show that the palaeo-sea ice record can be grouped according to four intervals, and these can be contextualised further with respect to the Holocene Thermal Maximum (HTM). Spring sea ice occurrence was lowest during the early–mid Holocene (10.0–6.0 cal. kyr BP) and this was followed by a second phase (6.0–4.0 cal. kyr BP) where spring sea ice occurrence showed a small increase. Between 4.0 and 3.0 cal. kyr BP, spring sea ice occurrence increased abruptly to above the median and we associate this interval with the termination of the HTM. Elevated spring sea ice occurrences continued from 3.0 to 0.4 cal. kyr BP, although they were more variable on shorter timescales. Within this fourth interval, we also provide evidence for slightly lower and subsequently higher spring sea ice occurrence during the Mediaeval Warm Period and the Little Ice Age respectively. Comparisons are made between our proxy data with those obtained from other palaeo-climate and sea ice studies for the CAA.     

Organic carbon accumulation over the last 16 kyr off Vancouver Island,Canada: evidence for increased marine productivity during the deglacial

The organic carbon content of marine sediments is commonly used as a proxy for export production. However, in continental margin sediments a large fraction of the organic matter may be of terrestrial origin, and it is necessary to correct the total organic carbon data accordingly. Radiocarbon dating of bulk organic carbon, organic geochemistry and isotope data (δ¹³C and δ¹⁵N) are used here to characterize the type of organic matter present in Core JT96-09 collected at a water depth of 920 m on the slope off Western Canada. The quantities of marine and terrestrial organic carbon are then estimated using the δ¹³C data. The 16 kyr record obtained from Core JT96-09 suggests that accumulation of total organic carbon was highest during the late glacial and deglacial, but geochemical data indicate that as much as 70% of this carbon is terrestrial in origin. When the palaeo-record is corrected for this terrigenous input it is observed that accumulation of marine organic matter, and presumably marine export production, increased at the end of the last glacial contemporaneous with the Bølling, and that it peaked during the Allerød. Data from other palaeoproductivity proxies (i.e., bio-barium, opal and alkenones) also indicate relatively high productivity during the deglacial. These results indicate a return to modern upwelling conditions and high marine export production at ∼14.3 calendar kyr BP and a period of enhanced upwelling, relative to the present, during the Allerød.     

A rapid method for preparing low volume CH4 and CO2 gas samples for 14C AMS analysis

¹⁴C measurements of CH₄ in environmental samples (e.g. soil gas, lake water, gas hydrates) can advance understanding of C cycling in terrestrial and marine systems. The measurements are particularly useful for detecting the release of old C from climate sensitive environments such as peatlands and hydrate fields. However, because ¹⁴C CH₄ measurements tend to be complex and time consuming, they are uncommon. Here, we describe a novel vacuum line system for the preparation of CH₄ and CO₂ from environmental samples for ¹⁴C analysis using accelerator mass spectrometry (AMS). The vacuum line is a flow-through system that allows rapid preparation of samples (1 h for CH₄ and CO₂, 30 min for CH₄ alone), complete separation of CH₄ and CO₂ and is an easy addition to multipurpose CO₂ vacuum lines already in use. We evaluated the line using CH₄ and CO₂ standards with different ¹⁴C content. For CH₄ and CO₂, respectively, the total line blank was 0.4 ± 0.2 and 1.4 ± 0.6 μg C, the ¹⁴C background 51.1 ± 1.2 and 48.4 ± 1.5 kyr and the precision (based on pooled standard deviation) 0.9‰ and 1.3‰. The line was designed for sample volumes of ca. 180 ml containing 0.5–1% CH₄ and CO₂, but can be adjusted to handle lower concentration and larger volume samples. This rapid and convenient method for the preparation of CH₄ and CO₂ in environmental samples for ¹⁴C AMS analysis should provide more opportunities for the use of ¹⁴C CH₄ measurements in C cycle studies.     

Terrestrial – Ocean environmental change in the northwestern Pacific from the glacial times to Holocene

The Mixed Water Region (MWR) between the Oyashio Current and the Kuroshio Extension and surrounding terrestrial region have been affected by the global climatic change. The sedimentary core KR02-15 PC6 collected at 40°23.8871′N, 143°29.8663′E in the MWR provides detailed records of pollen and spores and alkenone sea surface temperature (SST) during the last 15 kyr, showing that both ocean and terrestrial environments have been appreciably linked. Abundance of Picea, a proxy for terrestrial cool climate, fluctuated, coinciding with the alkenone-SST change during the interstadial period (15.0–7.7 cal kyr B.P.). Alkenone-SST increased to the modern level at 8.0 cal kyr B.P. and remained almost constant until 2.0 kyr B.P. while the terrestrial warming still continued until 4.0 cal kyr B.P. The rainfall under terrestrial warm condition increased gradually from 7.9 cal kyr B.P. and rapidly from 2.0 cal kyr B.P. Both terrestrial and marine environments cooled down during the last 2 kyr possibly due to the intensified cold Oyashio Current.     

Explosive volcanism during the Holocene in the Upper Limay River Basin: The effects of ashfalls on human societies,Northern Patagonia,Argentina

In order to understand human response to Holocene ashfall events, tephra layers found in archaeological sites along the upper Limay River basin, Northern Patagonia, Argentina were bracketed with radiocarbon dates and correlated with tephra from a lacustrine sediment core and from outcrops and the archaeological evidence was analyzed.A dark tephra associated with seismic activity was identified in the El Trébol rockshelter filling interstices between fallen blocks together with remains of human activity and bones of extinct fauna, marking a seismo-volcanic event occurring between 11 758 and 12 866 cal yr BP. This same seismic event affected the Cuyín Manzano site, where the roof collapse made the site uninhabitable for a time. A white tephra, present in Epullán Grande, Epullán Chica and Traful I caves is correlated with Nahuel Huapi tephra (NHT), equivalent to Laya's Río Blanco and Río Pereyra members, (Río Pireco Formation). NHT is considered to have been derived from the same eruptive event, with dates ranging between ca. 1950–2500 cal yr BP. A dark tephra from Ortega's cave and several tephra from Puerto Tranquilo I rockshelter ranging between 521 and 2069 cal yr BP show how the mobile hunters–gatherers of Northern Patagonia were able to cope with the changing circumstances.     

Breaking the glass ceiling for high resolution Nd isotope records in early Cenozoic paleoceanography

We report an optimized method for extracting neodymium (Nd) from fossil fish teeth with a single-stage column (125 µl stem volume; LN Resin, Eichrom Industries, Darien Illinois) for isotopic analysis by multi-collector inductively coupled mass spectrometry (MC-ICMPS). Three reference materials (basalt: BCR-2, BHVO-2; phosphate: fossil bone composite) and splits of fossil fish teeth samples previously processed with existing two-stage column methods were processed using the single-stage column method. ¹⁴³Nd/¹⁴⁴Nd values of reference materials agree within error with published values, and the values for fish teeth correspond with sample splits processed with two-stage columns. Precision to ± ～ 0.23 ε_Nd was achieved for 30 ng Nd samples of reference materials, and Nd isotope measurements of fossil fish tooth sample replicates as small as 7 ng Nd were reproducible within long term instrumental uncertainty. We demonstrate the utility of the new method with the first high resolution Nd isotope record spanning the ～ 40.0 Ma middle Eocene Climatic Optimum, which shows an excursion of 0.65 ε_Nd during the peak warming at the study site (Ocean Drilling Program Leg 119, Site 738; 30 kyr sample spacing from 40.3 to 39.6 Ma). LN Resin is already used in standard methods for separating Nd, and Nd isotopes are routinely measured by MC-ICPMS with high efficiency inlet systems. Our innovation is a single, small volume LN Resin column for Nd separation. The streamlined approach results in a 10× increase in sample throughput.     

South Asian monsoon variability during the past 800 kyr revealed by rock magnetic proxies

A rock magnetic investigation was carried out on a sedimentary core taken from the distal portion of the Bengal Fan in order to reconstruct the South Asian monsoon variability during the past 800 kyr. The 10.2 m long piston core MR0503-PC3, recovered at a water depth of 4400 m, consists of clay to silty clay with minor amounts of nannofossils. An age model for the MR0503-PC3 core is established by correlating a relative paleointensity record of the core [Suganuma Y., Yamazaki, T., Kanamatsu, T., Hokanishi, N., 2008. Relative paleointensity record during the last 800 kyr from the equatorial Indian Ocean: implication for relationship between inclination and intensity variations. Geochemistry, Geophysics, Geosystems. 9, Q02011. doi:10.1029/2007GC001723.] to the global paleointensity stack “Sint-800” [Guyodo, Y., Valet, J.P., 1999. Global changes in intensity of the Earth's magnetic field during the past 800 kyr. Nature. 399, 249–252.]. The age model is consistent with the published ages of tephra layers intercalated in the core, and shows continuous sedimentation during the past 800 kyr.Temporal variations in rock magnetic proxies for the magnetic concentration (ARM, IRM, and HIRM), the grain size (Mrs/Ms), and the composition (S_?0.3T and S_?0.1T) show that the amount of fine-grained magnetite increased during interglacial stages, and then gradually decreased toward the following glacial maxima. This indicates that the supply of fine-grained magnetite probably originated from areal expansion and/or increased pedogenic activity in the Ganges and Brahmaputra Rivers catchment. Increases during warmer periods suggest intensification of the South Asian summer monsoon during interglacial stages. During marine isotope stages (MIS) 15–11, enhancement of fine-grained magnetite and increased hematite and maghemite contributions are observed. These suggest a significant intensification of the South Asian summer monsoon during this period. Our record and other paleoclimatic reconstructions mainly from the low and mid-latitudes suggest that a major climatic event possibly occurred prior to the mid-Brunhes event (MBE), but the timing is not synchronous.     

Alpha-emitting isotopes and chromium in a coastal California aquifer

The unadjusted 72-h gross alpha activities in water from two wells completed in marine and alluvial deposits in a coastal southern California aquifer 40 km north of San Diego were 15 and 25 picoCuries per liter (pCi/L). Although activities were below the Maximum Contaminant Level (MCL) of 15 pCi/L, when adjusted for uranium activity; there is concern that new wells in the area may exceed MCLs, or that future regulations may limit water use from the wells. Coupled well-bore flow and depth-dependent water-quality data collected from the wells in 2011 (with analyses for isotopes within the uranium, actinium, and thorium decay-chains) show gross alpha activity in marine deposits is associated with decay of naturally-occurring ²³⁸U and its daughter ²³⁴U. Radon activities in marine deposits were as high as 2230 pCi/L. In contrast, gross alpha activities in overlying alluvium within the Piedra de Lumbre watershed, eroded from the nearby San Onofre Hills, were associated with decay of ²³²Th, including its daughter ²²⁴Ra. Radon activities in alluvium from Piedra de Lumbre of 450 pCi/L were lower than in marine deposits. Chromium VI concentrations in marine deposits were less than the California MCL of 10 μg/L (effective July 1, 2014) but δ⁵³Cr compositions were near zero and within reported ranges for anthropogenic chromium. Alluvial deposits from the nearby Las Flores watershed, which drains a larger area having diverse geology, has low alpha activities and chromium as a result of geologic and geochemical conditions and may be more promising for future water-supply development.     

Enhanced rainfall in the Western Mediterranean during deposition of sapropel S1: stalagmite evidence from Corchia cave (Central Italy)

A stable isotope record from a stalagmite collected from Antro del Corchia cave (Apuan Alps, Central Italy), supported by 17 uranium-series ages, indicates enhanced regional rainfall between ca 8.9 and 7.3 kyr cal. BP at the time of sapropel S1 deposition. Within this phase, the highest rainfall occurred between 7.9 and 7.4 kyr cal. BP. Comparison with different marine and lake records, and in particular with the Soreq Cave record (Israel), suggests substantial in-phase occurrence of enhanced rainfall between the Western and Eastern Mediterranean basins. There is no convincing evidence for major climatic change at the time of the “8.2 kyr event”.     

AMS 14C dating of deglacial events in the Irish Sea Basin and other sectors of the British–Irish ice sheet

Sedimentary sequences deposited by the decaying marine margin of the British–Irish Ice Sheet (BIIS) record isostatic depression and successive ice sheet retreat towards centres of ice dispersion. Radiocarbon dating by accelerator mass spectrometry (AMS) of in situ marine microfaunas that are commonly associated with these sequences constrain the timing of glacial and sea level fluctuations during the last deglaciation, enabling us to evaluate the dynamics of the BIIS and its response to North Atlantic climate change. Here we use our radiocarbon-dated stratigraphy to define six major glacial and sea level events since the Last Glacial Maximum. (1) Initial deglaciation may have occurred ⩾18.3 kyr ¹⁴C BP along the northwestern Irish coast, in agreement with a deglacial age of ∼22 ³⁶Cl kyr BP for southwestern Ireland. Ice retreated to inland centres and areas of transverse moraine began to form across the north Irish lowlands. (2) Channels cut into glaciomarine deglacial sediments along the western Irish Sea coast are graded to below present sea level, identifying a fall of relative sea level (RSL) in response to isostatic emergence of the coast. (3) Marine mud that rapidly infilled these channels records an abrupt rise in global sea level of 10–15 m ∼16.7 ¹⁴C kyr BP that flooded the Irish Sea coast and may have triggered deglaciation of a marine-based margin in Donegal Bay. (4) Intertidal boulder pavements in Dundalk Bay indicate that RSL ∼15.0 ¹⁴C kyr BP was similar to present. (5) A major readvance of all sectors of the BIIS occurred between 14 and 15 kyr ¹⁴C BP which overprinted subglacial transverse moraines and delivered a substantial sediment flux to tidewater ice sheet margins. This event, the Killard Point Stadial, indicates that the BIIS participated in Heinrich event 1. (6) Subsequent deposition of marine muds on drumlins 12.7 ¹⁴C kyr BP indicates isostatic depression and attendant high RSL resulting from the Killard Point readvance. These events identify a dynamic BIIS during the last deglaciation, as well as significant changes in RSL that reflect a combination of isostatic loading and eustatic changes in global sea level.     

Pacing of the Toarcian Oceanic Anoxic Event (Early Jurassic) from astronomical correlation of marine sections

The Early Toarcian Oceanic Anoxic Event (OAE) in the Early Jurassic Period is associated with a major negative carbon isotope excursion (CIE), mass extinction, marine transgression and global warming. The Toarcian OAE is thought to have been caused by flood basalt magmatism, and may have been a trigger for mass extinction. However, these proposed causes of the Toarcian OAE and associated biotic crisis are not adequately resolved by a precise chronology. The duration of the Toarcian OAE has been estimated to be anywhere from ~ 0.12 to ~ 0.9 Myr, most recently 0.74 to 3.26 Myr from U–Pb dating. The CIE associated with the Toarcian OAE has a similar pattern at numerous localities, and there is evidence that the marine carbon isotope variations recorded astronomical forcing signals. Here we estimate a duration of ~ 620 kyr for the main negative CIE, ~ 860 kyr for the polymorphum zone and > 1.58 Myr for the levisoni zone based on 405-kyr astronomical eccentricity tuning of the marine section at Peniche (Portugal). This 405-kyr tuned series provides a ~ 2.5 Myr continuous high-resolution chronology through the Early Toarcian. There are 6, or possibly 7 short eccentricity cycles in the main CIE interval at Peniche. To confirm this astronomically based estimate, we analyzed three other sections at Yorkshire (UK), Dotternhausen (Germany), and Valdorbia (Italy) from marine carbon isotopic series. These four stratigraphic sections from Early Jurassic western Tethys record the Toarcian OAE with ~ 6 prominent carbon isotope cycles in the CIE that span a 600 ± 100 kyr duration. The Peniche 405-kyr tuned series indicates that the pre- and post-CIE intervals experienced strong precession–eccentricity-forced climate change, whereas the CIE interval is marked by dominant obliquity forcing. These dramatic and abrupt changes in astronomical response in the carbon isotopes point to fundamental shifting in the Early Toarcian paleoclimate system that was directly linked to the global carbon cycle.     

First documented deep submarine explosive eruptions at the Marsili Seamount (Tyrrhenian Sea,Italy): A case of historical volcanism in the Mediterranean Sea

The Marsili Seamount (MS) is an about 3200 m high volcanic complex measuring 70 × 30 km with the top at ~ 500 m b.s.l. MS is interpreted as the ridge of the 2 Ma old Marsili back-arc basin belonging to the Calabrian Arc–Ionian Sea subduction system (Southern Tyrrhenian Sea, Italy). Previous studies indicate that the MS activity developed between 1 and 0.1 Ma through effusions of lava flows. Here, new stratigraphic, textural, geochemical, and ¹⁴C geochronological data from a 95 cm long gravity core (COR02) recovered at 839 m bsl in the MS central sector are presented. COR02 contains mud and two tephras consisting of 98 to 100 area% of volcanic ash. The thickness of the upper tephra (TEPH01) is 15 cm, and that of the lower tephra (TEPH02) is 60 cm. The tephras have poor to moderate sorting, loose to partly welded levels, and erosive contacts, which imply a short distance source of the pyroclastics. ¹⁴C dating on fossils above and below TEPH01 gives an age of 3 ka BP. Calculations of the sedimentation rates from the mud sediments above and between the tephras suggest that a formation of TEPH02 at 5 ka BP MS ashes has a high-K calcalkaline affinity with 53 wt.% < SiO₂ < 68 wt.%, and their composition overlaps that of the MS lava flows. The trace element pattern is consistent with fractional crystallization from a common, OIB-like basalt. The source area of ashes is the central sector of MS and not a subaerial volcano of the Campanian and/or Aeolian Quaternary volcanic districts. Submarine, explosive eruptions occurred at MS in historical times: this is the first evidence of explosive volcanic activity at a significant (500–800 m bsl) water depth in the Mediterranean Sea. MS is still active, the monitoring and an evaluation of the different types of hazards are highly recommended.     

Precisely dated AMS 14C marine cores reveal the complexity of millennial-scale Asian monsoon variability in the northern South China Sea (MD972146, MD972148)

High sedimentation rate (SR) cores retrieved from the South China Sea (SCS) form the basis for studying the marine components of millennial-scale Asian monsoon (AM) variability and for comparison with the AM reconstructions from cave records on land (e.g. Dongge and Hulu). However, carefully correlating the SCS sedimentary records to the cave records that are precisely dated by U/Th methods with resolution of decadal-scale, has not been completed. Such a correlation is essential when comparing AM influences expressed over land and sea, but requires a construction of marine AMS ¹⁴C age models that are precise enough to be compared to the cave U/Th age models. For the purpose of establishing such a correlation, this study presents new data from intensive AMS ¹⁴C dated marine cores retrieved from the northern SCS (MD972146, MD972148). The discrepancy of marine and cave δ¹⁸O record for the interval of ∼18–30 ka might be due to the change of marine ¹⁴C reservoir age in SCS surface water during the glacial period, and to the change in interhemispheric dominance of the AM systems. With the new AMS ¹⁴C dating on MD972146 and MD972148, we examined the millennial-scale records of planktonic foraminifer δ¹⁸O and carbonate contents of MD972146, MD97248, and SONNE 17940-2 and compared those records with Dongge–Hulu δ¹⁸O record of the past 30 ka. Our results show that in the intervals corresponding to the high-latitude Northern Hemisphere (NH) Younger Dryas (YD) and Heinrich I event (H1), the AMS ¹⁴C dated millennial-scale oscillations show relatively heavy δ¹⁸O and low carbonate contents, but H2 and H3 are in the opposite direction. Our results indicate the complexity for the marine cores which were used in interpreting the millennial-scale AM variability.     

Investigations of karstic springs of the Biokovo Mt from the Dinaric karst of Croatia

Ten gravity springs from the slopes of the Biokovo Mt, Adriatic coast of Croatia were investigated. Three of them are included in the regional water supply system. The aim of this study was to investigate hydrogeological and geochemical characteristics of watershed, presenting one of the most typical karstic areas in the world.Hydrogeological investigations were performed during two seasons with dye tracing, using Na-fluoresceine which was poured into two pits, observing springs at distances of 1.82–8.8 km. Apparent velocities were 0.21–0.51 cm s^?1. Dye tracing was first time partially effective and second time ineffective, what could be due to immanent ore mineralization, which presents a natural barrier and was discovered by geochemical and mineralogical methods.Concentrations of 17 dissolved and total trace elements were determined first time in groundwater samples. Their concentrations were extremely low, more than 3 orders of magnitude less than allowed by the Croatian directives for the first category of groundwater and drinking water. The mass fractions of 60 elements were determined in 3 representative spring sediments. Highest concentrations of some metals in sediments (mg kg^?1) are: lead 5440, chromium 118, manganese 935, zinc 116 and barium 238. Origin of some elements and mineralogy is discussed.     

Radiocarbon constraints on readvances of the British–Irish Ice Sheet in the northern Irish Sea Basin during the last deglaciation

Moraines deposited by the Dundalk Bay ice lobe record two readvances of the Irish Ice Sheet into the northern Irish Sea Basin during the last deglaciation. These readvances overrode and incorporated fossiliferous marine muds from the floor of Dundalk Bay. AMS ¹⁴C dates from monospecific microfaunas obtained from these muds indicate that the earlier (Clogher Head) readvance occurred sometime between 15.0 and 14.2 ¹⁴C ka BP, thus identifying a previously unrecognized ice-margin fluctuation in the Irish Sea Basin that is correlative with a readvance in northwest Ireland. The younger readvance occurred after 14.2 ¹⁴C ka BP and is equivalent to the Killard Point readvance identified elsewhere in the Irish Sea Basin. These readvances occurred during the Oldest Dryas cold interval and bracket Heinrich event 1. Raised marine muds that were deposited between ice readvances require that a substantial ice sheet remained on Ireland throughout much of the last deglaciation, with attendant isostatic depression of at least 110 m.     

High-resolution isotope records of early Holocene rapid climate change from two coeval stalagmites of Katerloch Cave,Austria

Two coeval stalagmites from Katerloch Cave show pronounced intervals of low δ¹⁸O values around 8.2, 9.1, and 10.0 kyr (all ages are reported before the year 2000 AD) and represent an inorganic U–Th dated climate archive from the southeast of the European Alps, a region where only very few well-dated climate records exist. The O isotope curves, providing near-annual resolution, allow a direct comparison to the Greenland ice core records, as temperature was the primary factor controlling the O isotopic composition of Katerloch speleothems.The 8.2 kyr climate anomaly lasted about one century, from 8196 to 8100 yr, with a maximum amplitude of 1.1‰ at 8175 yr. The event is characterized by a rapid onset and a more gradual demise and U–Th data as well as annual lamina counting support a rapid climate change towards cooler conditions within 10–20 yr. There is no strong evidence that the 8.2 kyr anomaly was superimposed on a pronounced longer-term cooling episode, nor do the new data support two separate cooling events within the 8.2 kyr event as reported by other studies. Our record also shows a distinct climate anomaly around 9.1 kyr, which lasted 70–110 yr and showed a maximum amplitude of 1.0‰, i.e. it had a similar duration and amplitude as the (central) 8.2 kyr event. Compared to the 8.2 kyr event, the 9.1 kyr anomaly shows a more symmetrical structure, but onset and demise still occurred within a few decades only. The different progression of the 8.2 (asymmetrical) and 9.1 kyr anomaly (symmetrical) suggests a fundamental difference in the trigger and/or the response of the climate system. Moreover, both stalagmites show evidence of a climate anomaly around 10.0 kyr, which was of comparable magnitude to the two subsequent events.Using a well constrained modern calibration between air temperature and δ¹⁸O of precipitation for the study area and cave monitoring data (confirming speleothem deposition in Katerloch reflecting cave air temperature), a maximum cooling by ca 3 °C can be inferred at 8.2 and 9.1 kyr, which is similar to other estimates, e.g., from Lake Ammersee north of the Alps. The O isotopic composition of meteoric precipitation, however, is a complex tracer of the hydrological cycle and these temperature estimates do not take into account additional effects such as changes in the source area or synoptic shifts. Apart from that, the relative thickness of the seasonally controlled lamina types in the Katerloch stalagmites remains rather constant across the intervals comprising the isotopic anomalies, i.e. the stalagmite petrography argues against major shifts in seasonality during the early Holocene climate excursions.     

Persistent sea surface temperature and declined sea surface salinity in the northwestern tropical Pacific over the past 7500 years

To understand Holocene climate evolutions in low-latitude region of the western Pacific, paired δ¹⁸O and Mg/Ca records of planktonic foraminifer Globigerinoides ruber (250–300 μm, sensu stricto, s.s.) from a marine core ORI715-21 (121.5°E, 22.7°N, water depth 760 m) underneath the Kuroshio Current (KC) off eastern Taiwan were analyzed. Over the past 7500 years, the geochemical proxy-inferred sea surface temperature (SST) hovered around 27–28 °C and seawater δ¹⁸O (δ¹⁸O_W) slowly decreased 0.2–0.4‰ for two KC sites at 22.7° and 25.3°N. Comparison with a published high-SST and high-salinity equatorial tropical Pacific record, MD98-2181 located at the Mindanao Current (MC) at 6.3°N, reveals an anomalous time interval at 3.5–1.5 kyr ago (before 1950 AD). SST gradient between the MC site and two KC site decrease from 1.5–2.0 °C to only 0–1 °C, and δ¹⁸O_W from 0.1–0.3‰ to 0‰ for this 2-kyr time window. The high SST and low gradient could result from a northward shift of the North Equatorial Current, which implies a weakened KC. The long-term descending δ¹⁸O_W and increasing precipitation in the entire low-latitude western Pacific and the gradually decreasing East Asian summer monsoonal rainfall during middle-to-late Holocene is likely caused by different land and ocean responses to solar insolation and/or enhanced moisture transportation from the Atlantic to Pacific associated with the southward movement of ITCZ.     

Glaciation and deglaciation of the SW Lake District,England: implications of cosmogenic 36Cl exposure dating

Exposure dating using cosmogenic ³⁶Cl demonstrates that the summit plateau of Scafell Pike (978 m) in the SW Lake District escaped erosion by glacier ice during the last glacial maximum (LGM; c. 26–21 kyr) and probably throughout the Devensian Glacial Stage (MIS 5d-2). Exposure ages obtained for ice-moulded bedrock on an adjacent col at 750–765 m confirm over-riding and erosion of bedrock by warm-based glacier ice during the LGM. The contrast between the two sites is interpreted in terms of preservation of tors, frost-shattered outcrops and blockfields on terrain above 840–870 m under cold-based ice. An exposure age of 17.3 ± 1.1 kyr for the col at 750–765 m suggests that substantial downwastage of the last ice sheet had occurred by c. 17 kyr, consistent with deglacial exposure ages obtained for other high-level sites in the British Isles. An exposure age of 12.5 ± 0.8 kyr obtained for a glacially transported rockfall boulder within the limits of later corrie glaciation confirms that the final episode of local glaciation in the Lake District occurred during the Loch Lomond Stade (c. 12.9–11.7 kyr). This research also demonstrated the difficulties of obtaining reliable exposure ages from rhyolite and andesite bedrock that has proved resistant to glacial abrasion.