Measurements of the 44-μm band of H2O ice deposited on amorphous carbon and amorphous silicate substrates

We present 20–110 µm absorbance spectra of H₂O ice, deposited on amorphous carbon and silicate substrates, obtained over the 10–140 K temperature range. The measurements have been carried out in a manner that simulates the deposition, warming and cooling of H₂O ice mantles on interstellar and circumstellar grains. For H₂O ice films deposited on these substrates we find (i) similar 44-µm-band peak wavelength temperature dependences, (ii) no bandshape differences in the respective spectra, and (iii) a structural phase transition occurring between 120 and 130 K. In comparison with published data obtained using a polyethylene substrate, the 52-µm feature (the longitudinal optical mode) observed in our spectra is less prominent. This suggests the presence of material-dependent substrate effects that can alter the appearance of the H₂O far-infrared spectrum. The crystallization temperature of H₂O ice films deposited on our amorphous silicate substrate is significantly different from that reported by Moore et al. (1994) , who found crystallization temperatures down to < 20 K for ice also deposited on an amorphous silicate substrate. This is attributed to differences in the surface structures of the respective substrates. This may indicate that, at least in the context of laboratory measurements, substrate material composition is not as significant as substrate surface structure.     

2–16 μm spectroscopy of micron-sized enstatite (Mg,Fe)2Si2O6 silicates from primitive chondritic meteorites

We present mid-infrared spectra from individual enstatite silicate grains separated from primitive type 3 chondritic meteorites. The 2–16 μm transmission spectra were taken with microspectroscopic Fourier-transform infrared (FT-IR) techniques as part of a project to produce a data base of infrared spectra from minerals of primitive meteorites for comparison with astronomical spectra. In general, the wavelength of enstatite bands increases with the proportion of Fe. However, the wavelengths of the strong En₁₀₀ bands at 10.67 and 11.67 decrease with increasing Fe content. The 11.67-μm band exhibits the largest compositional wavelength shift (twice as large as any other). Our fits of the linear dependence of the pyroxene peaks indicate that crystalline silicate peaks in the 10-μm spectra of Herbig AeBe stars, HD 179218 and 104237, are matched by pyroxenes of En₉₀₋₉₂ and En₇₈₋₈₀, respectively. If these simplistic comparisons with the astronomical grains are correct, then the enstatite pyroxenes seen in these environments are more Fe-rich than are the forsterite (Fo₁₀₀) grains identified in the far-infrared which are found to be Mg end-member grains. This differs from the general composition of type 3 chondritic meteoritic grains in which the pyroxenes are more Mg-rich than are the olivines from the same meteorite.     

ISO observations of 3–200 μm emission by three dust populations in an isolated local translucent cloud

We present isophot spectrophotometry of three positions within the isolated high-latitude cirrus cloud G 300.2−16.8, spanning from the near- to far-infrared (NIR to FIR). The positions exhibit contrasting emission spectrum contributions from the unidentified infrared bands (UIBs), very small grains (VSGs) and large classical grains, and both semi-empirical and numerical models are presented. At all three positions, the UIB spectrum shapes are found to be similar and the large grain emission may be fitted by an equilibrium temperature of  ∼17.5 K  . The energy requirements of both the observed emission spectrum and optical scattered light are shown to be satisfied by the incident local interstellar radiation field (ISRF). The FIR emissivity of dust in G 300.2−16.8 is found to be lower than in globules or dense clouds and is even lower than model predictions for dust in the diffuse interstellar medium (ISM). The results suggest physical differences in the ISM mixtures between positions within the cloud, possibly arising from grain coagulation processes.     

H3+ in diffuse interstellar gas

A model is constructed of the material in front of the star Cygnus OB2 no. 12 in which dense cores are embedded in diffuse clumps of gas. The model reproduces the measured abundances of C₂ and CO, and predicts a column density of 910¹⁰ cm² for HCO⁺.     

Overtones of silicate and aluminate minerals and the 5–8 μm ice bands of deeply embedded objects

The distinct patterns, relatively low intensities and peak positions of overtone-combination bands of silicates and oxides suggest that the 5–8 μm spectral region can provide clues for the dust composition when near optically thick conditions exist for the 10-μm silicate feature. We present 1000–2500 cm⁻¹ room-temperature laboratory spectra obtained from powders of silicate, aluminate and nitride minerals and silicate glasses. The spectra exhibit overtone absorption bands with mass absorption coefficients ∼100 times weaker than the fundamentals. These data are compared with the 5–8 μm spectra of deeply embedded young stellar objects observed with the Short Wavelength Spectrometer on the Infrared Space Observatory . Fits of the laboratory data to the observations, after subtraction of the 6.0-μm H₂O ice feature and the 6.0-μm feature identified with organic refractory material, indicate that crystalline melilite (a silicate) or metamict hibonite (a radiation-damaged crystalline aluminate) may be responsible for much of the 6.9-μm absorption feature in the observations, with melilite providing the best match. A weaker 6.2-μm absorption in the young stellar object spectra is well matched by the spectra of hydrous crystalline amphibole silicates (actinolite and tremolite). Relative abundances of Si–O in room-temperature amphiboles to low-temperature H₂O ice are in the range 0.46–3.9 and in melilite are in the range 2.5–8.6. No astronomical feature was matched by the overtones of amorphous silicates because these bands are too broad and peak at the wrong wavelength. Hence, this analysis is consistent with the 10-μm features of these objects being due to a mixture of crystalline and amorphous silicates, rather than only amorphous silicates.     

The 10-μm profile of molecular-cloud and diffuse ISM silicate dust

High signal-to-noise ratio spectra are presented of the 10-μm silicate absorption feature in lines of sight towards Elias 16 and 18 in the Taurus dark cloud, and towards the heavily reddened supergiant Cyg OB2 no. 12. The observations are fitted with laboratory and astronomical spectra to produce intrinsic absorption profiles. These features, which represent molecular-cloud and diffuse ISM dust respectively, are better fitted with emissivity spectra of the Trapezium and μ Cephei than they are with those of laboratory, terrestrial, or other observations of circumstellar silicates. The difference in width between the silicate band in the two environments can be almost entirely ascribed to a broad excess absorption in the long-wavelength wing of the profiles, which is much stronger in the molecular-cloud lines of sight, and possibly reflects grain growth in the denser environment. Limits are placed on the strength of fine spectral structure; if there is a crystalline silicate component in these spectra, it is most likely to be serpentine. Column-density upper limits for methanol and the photolysis product hexamethylenetetramine (HMT) are less than a few per cent of those of water ice and silicates.     

Spectroscopy of SN 1987A at 0.9–2.4 μm: days 1348–3158

We present near-infrared spectroscopic observations of SN 1987A covering the period 1358 to 3158 d post explosion. This is the first time that IR spectra of a supernova have been obtained to such late epochs. The spectra comprise emission from both the ejecta and the bright, ring-shaped circumstellar medium (CSM). The most prominent CSM emission lines are recombination lines of H  i and He  i , and forbidden lines of [S  iii ] and [Fe  ii ]. The ejecta spectra include allowed lines of H  i , He  i and Na  i and forbidden lines of [Si  i ], [Fe  i ], [Fe  ii ] and possibly [S  i ]. The intensity ratios and widths of the H  i ejecta lines are consistent with a low-temperature Case B recombination spectrum arising from non-thermal ionization/excitation in an extended, adiabatically-cooled H envelope, as predicted by several authors. The slow decline of the ejecta forbidden lines, especially those of [Si  i ], indicates that pure non-thermal excitation was taking place, driven increasingly by the decay of ⁴⁴Ti. The ejecta iron exhibits particularly high velocities  (4000–4500 km s^-1)  , supporting scenarios where fast radioactive nickel is created and ejected just after the core bounce. In addition, the ejecta lines continue to exhibit blueshifts with values ∼−200 to −800 km s⁻¹ to at least day 2000. These blueshifts, which first appeared around day 600, probably indicate that very dense concentrations of dust persist in the ejecta, although an alternative explanation of asymmetry in the excitation conditions is not ruled out.     

New models of interstellar gas–grain chemistry – III. Solid CO2

Solid CO₂ is observed to be an abundant interstellar ice component towards both quiescent clouds and active star-forming regions. Our recent models of gas–grain chemistry, appropriate for quiescent regions, severely underproduce solid CO₂ at the single assumed gas density and temperature. In this paper, we investigate the sensitivity of our model results to changes in these parameters. In addition, we examine how the nature of the grain surface affects the results and also consider the role of the key surface reaction between O and CO. We conclude that the observed high abundance of solid CO₂ can be reproduced at reasonable temperatures and densities by models with diffusive surface chemistry, provided that the diffusion of heavy species such as O occurs efficiently.     

Imaging and integral-field spectroscopy of shocked H2 around G25.65+1.05

The results of B -band CCD imaging linear polarimetry obtained for stars from the Hipparcos catalogue are used to re-examine the distribution of the local interstellar medium towards the IRAS 100-μm emission void in the Lupus dark clouds. The analysis of the obtained parallax–polarization diagram assigns to the dark cloud Lupus 1 a distance between 130 and 150 pc and assures the existence of a low column density region coincident with the observed infrared void. Moreover, there are clear indications of the existence of absorbing material at distances closer than 60–100 pc, which may be associated with the interface boundary between the Local Bubble and its neighbourhood Loop I superbubble.     

Spectrum of hot water in the 4750–13 000 cm−1 wavenumber range (0.769–2.1 μm)

The high resolution laboratory spectrum of hot water vapour has been recorded in the 500–13 000 cm⁻¹ wavenumber range and we report on the analysis of the 4750–13 000 cm⁻¹ (0.769–2.1 μm) portion. The emission spectrum was recorded using an oxy-acetylene welding torch and a Fourier transform spectrometer. Line assignments in the laboratory spectrum as well as in an absorption spectrum of a sunspot umbra were made with the help of the BT2 line-list. Our torch spectrum is the first laboratory observation of the 9300 Å'steam bands' seen in M-stars and brown dwarfs.     

IRAS 22036+5306: an Al2O3 oxide-dominated post-AGB star

Radiative transfer modelling of the Infrared Space Observatory ( ISO ) spectrum of IRAS 22036+5306 has shown that its unusual 11-μm band can be suitably modelled with an alumina-olivine mixture substantially dominated by the former. The results of this work add further credence to recent findings that significant amounts of Al  ₂O₃  dust grains are present in the dust shells of stars near or beyond the tip of the asymptotic giant branch. Indeed, in the case of IRAS 22036+5306, Al  ₂O₃  dominates the dust composition to the extent that it shifts the 9.8-μm band due to amorphous silicates to 11 μm. IRAS 22036+5306 may be an unusual case in that the inner dust torus is maintained at a sufficiently high temperature for Al  ₂O₃  condensation, but not silicate.     

Calculations on the rates, mechanisms, and interstellar importance of the reactions between C and NH2 and between N and CH2

The attempt to understand the temperature dependence of the HNC/HCN abundance ratio in interstellar clouds has been long standing and indecisive. In this paper we report quantum chemical and dynamical studies of two neutral–neutral reactions thought to be important in the formation of HNC and HCN, respectively – C+NH₂→HNC+H, and N+CH₂→HCN+H. We find that although these reactions do lead initially to the products suggested by astronomers, there is so much excess energy available in both reactions that the HCN and HNC products are able to undergo efficient isomerization reactions after production. The isomerization leads to near equal production rates of the two isomers, with HNC slightly favoured if there is sufficient rotational excitation. This result has been incorporated into our latest chemical model network of dense interstellar clouds.