Prediction of eruptions using changes in composition of volcanic gases

During observations on the dynamics and on the regime of fumarolic activity of some active volcanoes of Kamchatka and Kurile islands, a very close relation was noted between the S/Cl ratio in the fumarolic gases and in waters and the state of the volcano. The S/Cl ratio increased prior to the eruptions of Sheveluch, Bezymianny, Kluchevskoi, Zavaritsky and Ebeko volcanoes.     

Coseismic changes in the chemical composition of volcanic gases from the Owakudani geothermal area on Hakone volcano,Japan

The chemical and isotopic compositions of volcanic gases at a borehole and a natural fumarole in the Owakudani geothermal area, Hakone volcano, Japan, have been repeatedly measured since 2001, when a seismic swarm occurred in the area. The CO₂/H₂O and CO₂/H₂S ratios were high in 2001. It increased in 2006 and again in 2008 when seismic swarms occurred beneath the geothermal area. The observed increases suggest the injection of CO₂- and SO₂-rich magmatic gas into the underlying hydrothermal reservoir, implying that the magmatic gas was episodically supplied to the hydrothermal system in 2006 and 2008. The earthquake swarms probably resulted from the injection of gas through the shallow crust accompanying the break of the sealing zone.     

The interaction between volcanic gases and tephra: Fluorine adhering to tephra of the 1970 hekla eruption

The mass distribution and sorting of tephra produced in the plinian phase of the 1970 Hekla eruption was controlled by the particle size distribution, the height of the eruption column, and velocity of transport. Near the volcano the mass distribution of soluble fluorine was controlled by particle size of the deposits, but approaches the mass distribution of the tephra at longer distances. Adsorbed soluble fluorine reaches a maximum at a distance from the volcano determined by the velocity of the transporting medium.SEM studies show the soluble fluorine to be chemically adsorbed on the surface of tephra particles. The adsorption is shown by experiment to occur at temperatures below 600°C in the cooling eruption column. Evaluation of reactions in the eruption column leads to the conclusion that formation of water soluble compounds adhering to tephra is principally controlled by environmental factors and to a lesser degree by the composition of the volcanic gas phase.     

Discussion on the energy partition of volcanic eruption

Energy of volcanic eruption is divided into various ways, such as lava flows, ash production, explosion, ground vibration, air waves and so on. In order to elucidate the cruptive mechanism, energy partition of volcanic eruption in unit time is considered to be a key to solve the problem. In this short paper, partition of eruption energy was calculated for typical three basaltic volcanoes. Ratio of tremor energy to thermal energy is almost the same for both Mihara and Nyragongo in spite of their different eruptive mechanism. Tremor energy was found to be small for Kilauea Volcano compared with the above two volcanoes. This was attributed to the different source mechanism of tremor. Partition of eruption energy was calculated for Also Volcano which showed phreatic explosion in 1958. Kinetic energy is almost ten times of thermal energy. Ratio of energy converted to elastic waves to thermal energy is found to be equivalent to the ratio of energy of elastic waves to the chemical energy in case of explosion of chemical explosives.     

The dimensions and dynamics of volcanic eruption columns

Eruption columns can be divided into three regimes of physical behaviour. The basal gas thrust region is characterized by large velocities and decelerations and is dominated by momentum. This region is typically a few hundred metres in height and passes upwards into a much higher convective region where buoyancy is dominant. The top of the convective region is defined by the level of neutral density (heightH _B ) where the column has a bulk density equal to the surrounding atmosphere. Above this level the column continues to ascend to a heightH _T due to its momentum. The column spreads horizontally and radially outwards between heightH _T andH _B to form an umbrella cloud. Numerical calculations are presented on the shape of eruption columns and on the relationships between the heightH _B and the mass discharge rate of magma, magma temperature and atmospheric temperature gradients. Spreading rate of the column margins increases with height principally due to the decrease in the atmospheric pressure. The relationship between column height and mass discharge rate shows good agreement with observations. The temperature inversion above the tropopause is found to only have a small influence on column height and, eruptions with large discharge rates can inject material to substantially greater heights than the inversion level. Approximate calculations on the variation of convective velocities with height are consistent with field data and indicate that columns typically ascend at velocities from a few tens to over 200 m/s. In very large columns (greater than 30 km) the calculated convective velocities approach the speed of sound in air, suggesting that compressibility effects may become important in giant columns. Radial velocities in the umbrella region where the column is forced laterally into the atmosphere can be substantial and exceed 55 m/s in the case of the May 18th Mount St. Helens eruption. Calculations on motions in this region imply that it plays a major role in the transport of coarse pyroclastic fragments.     

Studies on volcanic gases and gases from hydrothermal fields in Kamchatka

This paper describes the main lines of investigation for the volcanic and geothermal research in Kamchatka. Methods of gas sampling in the field and gas extraction from rocks are also described.     

Forecast of volcanic eruptions by chemical methods

From the magmatic emanations differentiation point of view it is possible to calculate some ratios such as F/CO₂, Cl/CO₂, SO₂/CO₂, SO₂/H₂S, H₂S/CO₂ and CO₂/N₂ in the tumarolic gases for the forecasting of volcanic activity. In order to predict the cruptions of a volcano it is needed to select several fumaroles or hot springs having different regimes of variation of the above ratios. The study of some fumaroles composition at the Asama. Mihara, Kirishima and other volcanoes in Japan showed a close connection between volcanic gas compositions and state of the volcanoes.     

Hot springs of Rhodesia: Their noble gases,isotopic and chemical composition

Four of Rhodesia's hottest spring complexes (54–100°C) were studied. Tritium contents were very low, compared to adjacent rivers, indicating that the samples studied were indigenous, deep-seated water which had undergone negligible intermixing with surface water.The noble-gas measurements revealed: (1) the waters are meteoric; (2) the noble gases were kept in closed-system conditions in the ground; (3) paleotemperatures are 26–31°C; (4) the boiling Binga springs lost part of their noble gases.Independently, measurements of stable isotopes indicate the meteoric origin of the springs. The chemical composition of the waters clearly reflects their origin from two groups of rocks — one from Karroo sediments and one from crystalline rocks.     

On the lateral variations in chemical composition and volume of quaternary volcanic rocks across Japanese arcs

The Fe/Mg+Fe) ratios (X_Fe) of the Quaternary basalts (SiO₂ < 53 wt.%) in the Japanese arcs were examined. The X_XFe of relatively magnesian basalts decreases from the volcanic front toward the Japan Sea across the arcs. Based on the partition coefficient of Mg-Fe²⁺ between olivine and liquid, it is suggested that all the basalts near the volcanic front, which are mostly tholeiitic basalts, are significantly fractionated, whereas many basalts near the Japan Sea, which are mostly alkali basalts, are little fractionated. The K₂ O content in the primary basalt magmas increases toward the Japan Sea. Combining the X_Fe and K₂ O data, it is suggested that relatively large amounts of tholeiitic magmas are produced near the volcanic front, but they fractionate during their ascent, whereas smaller amounts of alkali basalt magmas are formed near the Japan Sea, but they can ascend with less fractionation. The density of primary tholeiite magma is significantly larger than that of primary alkali basalt magmas. It is most likely that primary tholeiite magmas cannot ascend beyond the upper crust and would fractionate to produce less dense tholeiitic magmas near the volcanic front, whereas primary alkali basalt magmas can ascend through the upper crust without fractionation, as far as buoyancy is the principal ascending force. In the Japanese arcs, the stress field may be less compressional near the Japan Sea than near the volcanic front, so that magmas can ascend more rapidly in the latter region than in the former. These two factors may be responsible for the above mentioned chemical variations of basalt magmas across the arcs. The variation in volume of the Quaternary volcanic rocks across the arcs can be explained by the presence of a melt-rich zone above but nearly parallel to the subducted slab.     

Gas and hydrogen isotopic analyses of volcanic eruption clouds in Guatemala sampled by aircraft

Gas samples were collected by aircraft entering volcanic eruption clouds of three Guatemalan volcanoes. Gas chromatographic analyses show higher H₂ and S gas contents in ash eruption clouds and lower H₂ and S gases in vaporous gas plumes. H isotopic data demonstrate lighter isotopic distribution of water vapor in ash eruption clouds than in vaporous gas plumes. Most of the H₂O in the vaporous plumes is probably meteoric. The data are the first direct gas analyses of explosive eruptive clouds, and demonstrate that, in spite of atmospheric admixture, useful compositional information on eruptive gases can be obtained using aircraft.     

Sensitivity of the dynamics of volcanic eruption columns to their shape

This paper presents a one-dimensional steady-state model to investigate the sensitivity of the dynamics of sustained eruption columns to radius variations with height due to thermal expansion of the entrained air, and decreases in atmospheric pressure with height. In contrast to a number of previous models using an equation known as the entrainment assumption, the new model is based on similarity arguments to derive an equation set equivalent to the model proposed by Woods [Bull Volcanol 50:169–193, 1988]. This approach allows investigation of the effect of gas compressibility on the entrainment rate of ambient air, which has been little examined for a system in which a decrease in pressure significantly affects the density stratification of a compressible fluid. The new model provides results that include two end members: one in which the volume change within the eruption columns affects only the radial expansion without changing the vertical motion, and the other is the converse. The Woods [Bull Volcanol 50:169–193, 1988] model can be regarded as being between those two end members. The range of uncertainty arises because the extremely high temperature of discharged materials from a volcanic vent, and the exceptional terminal height of the eruption columns, allow significant expansion of the gas component in the eruption columns, making them behave differently from common turbulent plumes. This study indicates that the maximum height of the eruption columns is affected considerably by this uncertainty, particularly when the eruption columns extend above a height of 10 km, at which the pressure is about one-fourth the pressure at the ground surface. Column collapse may also be suppressed in wider parameter ranges than previously estimated. However, the uncertainty can be reduced by measuring column radii through a vertical profile during actual volcanic eruptions. Accordingly, this paper suggests that appropriate observation of eruption column shapes is essential for improving our understanding of the dynamics of eruption columns.     

Relationship between earthquake and volcanic eruption inferred from historical records

Introduction From the records of Wudalianchi volcanic group eruption in 1720~1721 obtained from the Man ethnic group files of Heilongjiang General Yamen in Qing Dynasty (WU, 1998; CHEN, WU, 2003), we have discovered the eruption time, state, material and scale of Laoheishan and Hu-oshaoshan volcanoes, as well as numerous seismic records. These historical materials are discov-ered for the first time although the study on Wudalianchi volcanic group has a long history. These earthquakes co…