Content and behavior of fluorine in Japanese quaternary volcanic rocks and petrogenetic application

Fluorine contents in about 160 representative Quaternary volcanic rocks and 15 hornblende and biotite phenocrysts in a calc-alkali series in Japan have been determined by a selective ion-electrode method. Tholeiites have the lowest contents and the narrowest range (58–145 ppm), while alkali basalts have the highest contentws and the widest range (301–666 ppm), high-alumina basalts have intermediate values (188–292 ppm). F contents in basalts clearly increase from east to west across the Japanese Islands, as do alkalies, P₂O₅ REE, U, Th and H₂O.The volcanic rocks studied are divided into two groups on the basis of F: (1) witt, increasing % SiO₂ or advancing fractionation, F contents show either progressive enrichment; or (2) with increasing fractionation, F contents show rather constant values. The former is produced by fractionation of anhydrous phases from basalt to mafic andesite magmas; the tholeiite series of Nasu volcanic zone (outer zone), northeastern, Japan is a typical example. The latter group is derived through separation of amphibole-bearing phases from basaltic magmas at various depths from upper mantle (about 30 km) to upper crust; the alkali series in southwestern Japan and the calc-alkali series of Chokai volcanic zone (inner zone), northeastern Japan, are examples.     

Rifting of Kyushu, Japan, based on the fault-controlled concurrent eruption of oceanic island basalt-type and island arc-type lavas

The tectonic environment of Kyushu, Japan is affected both by the subduction of the Philippine Sea plate and by the extensional tectonics related to rifting of Okinawa Trough at the eastern margin of the Eurasia Plate. We found that the Sendai fault zone acts as a channel for concurrent eruption of oceanic island basalt (OIB)-type and island arc (IA)-type basaltic rocks, propagating west to east in the Sendai region of southern Kyushu. The location of the Sendai fault zone is likely to correspond to the left-lateral shear zone in southern Kyushu as inferred by GPS Earth Observation Network. A similar magmatic association is present in the Beppu–Shimabara (BS) graben system in central Kyushu. The associate magmas of OIB-type rocks in Kyushu can be classified into typical, EM II-like and their intermediate OIB-type magmas in addition to MORB-like OIB-type magma in ⁸⁷Sr/⁸⁶Sr–Nb/Y systematics. Typical OIB-type and intermediate OIB-type magmas are erupted within the Sendai fault zone and BS graben system, respectively. The former is characterized by highest Nb/Y but low ⁸⁷Sr/⁸⁶Sr similar to MORB-like OIB-type magma erupted in northern Kyushu and the latter has intermediate Nb/Y and ⁸⁷Sr/⁸⁶Sr between typical and EM II-like OIB-type magmas. Almost all the IA-type rocks within the Sendai fault zone are generated from parental IA-type magma in Kyushu and characterized by weak crustal assimilation, having the lowest ⁸⁷Sr/⁸⁶Sr similar to typical OIB-type magma but the highest ¹⁴³Nd/¹⁴⁴Nd of arc magmas in Kyushu. The ages of both types of basaltic rocks within the Sendai fault zone range from 1.6 to <0.01?Ma clearly younger than those of andesitic rocks on northern and southern outsides of the fault zone and become younger from west to east. Initial formation of the fault zone has been induced by the counterclockwise rotation of southern Kyushu during the last 2?Ma as well as the BS graben system. Kyushu has continued to be split into three parts by the Sendai fault zone and BS graben during the Quaternary; northern, central, and southern zones. Their initial formation ages are likely to be linked to the initial rifting age of the middle Okinawa Trough back-arc basin.     

Volcanoes of the southwestern extension of the active Mariana island arc: New swath-mapping and geochemical studies

Until recently it was thought that the volcanoes of the Mariana island arc of the western Pacific terminated at Tracey Seamount at ∼ 14°N immediately west of Guam. Sea floor mapping in 1995 shows a series of large volcanic seamounts stretching westward for nearly 300 km beyond that point. The morphology, spacing, and composition of those sampled are consistent with their having formed as a consequence of eruption of suprasubduction zone arc magmas. The relationships of the volcanoes to the tectonic processes of subduction of the Pacific plate beneath the southern portion of the Mariana convergent plate margin are becoming increasingly clear as new bathymetry and geochemical data are amassed. The volcanoes along this trend that lie closest to Guam are forming where the center of active extension in the back-arc basin intersects the line of arc volcanoes. They develop well-defined rifts that are parallel to rift structures along the extension center, whereas volcanoes of the spreading axis to the north are smaller than the frontal arc volcanoes and tend to form along lineaments. Compositions of lavas from these intersection volcanoes bear some similarities to back-arc basin basalt, but are on the whole well within the range of compositions for Mariana island arc lavas. The Pacific plate subducts nearly orthogonal to the strike of the trench along the southern part of the Mariana system and the distance to the arc line from the trench axis is only ∼ 150 km. Several deep fault-controlled canyons on the inner slope of the southern Mariana trench indicate an enhanced tectonic extension of this plate margin. The presence of these active arc volcanoes and the existence of the orthogonal normal faulting along the southern Mariana forearc supports a model of radial extension for formation of the Mariana Trough, a model previously dismissed because of the lack of evidence of these two major geological features.     

Volcanoes of the Cape Hoskins area,New Britain,territory of Papua and New Guinea

One active and ten extinct Quaternary volcanoes are described from the Cape Hoskins area, on the north coast of New Britain. They are mostly strato volcanoes built up of lava flows, lava domes, pyroclastic flows, lahars, tephra, and derived alluvial sediments. The volcanic products range in composition from basalt to rhyolite, but basaltic andesite and andesite predominate. Much of the area is covered by tephra, several metres thick, consisting mainly of rhyolitic pumice. The active volcano, Pago, is built up of several glacier-like lava flows, the last of which was formed during an eruption in 1914–18. Pago lies within a well-preserved caldera forming the central part of a broad low-angle cone, named Witori, which consists largely of welded and unwelded pyroclastic flow deposits. C-14 dates obtained on charcoal indicate that the caldera eruption occurred about 2500 years B. P. Another caldera of similar age lies south of Witori. Of the other eight volcanoes described four are relatively well-preserved steep-sided cones formed mainly of lava flows, one is a remnant of a low-angle cone with a caldera, and three are deeply eroded cones which have none of their constructional surfaces preserved.     

Carboniferous tectono-magmatic evolution of the northern Luliang arc: evidence from geochemistry and petrography of Carboniferous volcanic rocks in the northern Luliang Uplift,NW China

The Northern Junggar Basin experienced extensive subduction and a complex tectono-magmatic evolution during the Late Paleozoic,resulting in a heterogeneous distribution of volcanic rocks in the Junggar Basin.In this study,the Carboniferous tectono-magmatic evolution of the northern Luliang arc was described by exploring the petrography and geochemistry of Carboniferous volcanic rocks collected from well Y-2 and outcrop WW' in the northern Luliang Uplift.The distribution,types,and formation ages of these volcanic rocks were characterized and the volcanic sequence in well Y-1 was divided into upper and lower parts according to vertical variations in selected geochemical data.Then the petrogenesis and tectonic settings of different volcanic rocks were evaluated and this was used to infer the tectonomagmatic evolution of the northern Luliang arc during the Carboniferous.The results indicate that:(1) Carboniferous high-K calc-alkali andesite-dacite associations are distributed in the west of the northern Luliang Uplift,and Lower Carboniferous calc-alkali basalt-dacite-rhyolite assemblages are preserved in its east.(2) The intermediateacid volcanic rocks in wells Y-1 and Y-2 were derived from calc-alkali basaltic magma through melting of the juvenile lower crust,and geochemical variations indicate increasing addition of slab melting in a subduction-related arc environment.The bimodal volcanic rocks from outcrop WW' were derived from lithospheric underplating of basaltic magma in an intra-arc extensional setting.(3) The closure of the eastern Keramaili Oceanic basin occurred before the Early Carboniferous,and the tectono-magmatic difference between the east and the west of the northern Luliang Uplift appeared before the Carboniferous period.     

Petrologic and structural contrast of the quaternary volcanoes of Guatemala

An imposing chain of volcanoes that forms a narrow belt parallel to the Pacific coast of Guatemala displays a variety of petrologic and eruptive features that appear to be related to differences in their structural environment. In western Guatemala most of the volcanoes are large composite cones of pyroxene andesite that bear only a few parasitic cones of basaltic cinders on their flanks. However, many of the volcanoes, during their later stages of growth, discharged immense volumes of dacite pumice from their summit vents, and some of them erupted domes of viscous andesite and more siliceous lavas far down their slopes. The huge cauldron of Lake Atitlan and the Krakatoan-type caldera of Lake Ayarza were formed by subsidence related to voluminous eruptions of lava and pumice. In eastern Guatemala, however, most of the volcanoes consist mainly or wholly of basalt; minor basaltic cones are unsually abundant, both as parasites and as independent, short-lived forms alined along faults. The volcanoes, instead of being restricted to a narrow belt, are widely scattered along fissure systems, many of which trend north south. Although dacite pumice is relatively scarce, some of the largest flows of rhyolitic obsidian on the continent are found here where they are closely associated in time and place with olivine-rich basalts. This intimate basalt-rhyolite association, the only one of its kind known in Central America, appears to represent a late stage of extreme fractional crystallization of a large body of basaltic magma.     

Imbrication, flow direction and possible source areas of the pumice-flow tuffs near Bend, Oregon, U.S.A.

Imbrication, indicating flow and source direction, occurs in three Pleistocene or upper Pliocene pumice-flow tuffs exposed in a 700-km² area on the east flank of the Cascade Range near Bend, Oregon, and shows the location of previously unknown source vents of these tuffs. The imbrication is formed by inclined elongate and/or flat pumice or lithic fragments and locally by elongate plagioclase crystals. Imbrication is best developed within the lower zones of individual flow units; the pumiceous top zones also locally show imbrication directions parallel to that in the lower zones. Moreover, the areal pattern of size distribution of lithic and pumice fragments in the flows is concordant with the flow direction pattern indicated by imbrication.The upper pumice flow shows a fan-shaped pattern of flow directions indicated by imbrication which points to a western source. A possible vent, about 20 km west of Bend in the highland near Broken Top Volcano, is marked by many silicic domes and basaltic cinder cones where there is a 6–8 mgal negative Bouguer gravity anomaly. In contrast, imbrication in the middle and lower pumice flows indicates flow from a source southwest of Bend. Vents in this direction are not obvious. Possible buried vents are located about 30 km and 45 km southwest of Bend near Sitkum Butte and Lookout Mountain, respectively.     

Welded tuffs and related pyroclastic deposits in northeastern Japan

Welded tuffs and related pyroclastic deposits are distributed at many localities in northeastern Japan, especially around the volcanoes of the Nasu volcanic zone running from north to south, but they are absent from the region along the Japan Sea. Their geological age varies from the Miocene to the Holocene, those of the Pleistocene being predominant in amount. Petrographically they cover rather a wide range from andesite to rhyolite, among which dacite is most common. The welded tuffs are always compact and hard, with well-developed columnar jointing, carrying parallel-layered obsidian lenticules; and various stages are observed from loose pyroclastic deposits to lava-like welded tuffs. Petrological, petrochemical, and physical properties of these deposits are studied in some detail. From these data some genetic consideration is given for the mechanism of welding, and also for the relation between the nature of parental magma and the formation of such pyroclastic deposits.     

Geochemical homogeneity of a long-lived,large silicic system; evidence from the Cerro Galán caldera,NW Argentina

By applying a number of analytical techniques across a spectrum of spatial scales (centimeter to micrometer) in juvenile components, we show that the Cerro Galán volcanic system has repeatedly erupted magmas with nearly identical geochemistries over >3.5 Myr. The Cerro Galán system produced nine ignimbrites (∼5.6 to 2 Ma) with a cumulative volume of >1,200 km³ (DRE; dense rock equivalent) of calc-alkaline, high-K rhyodacitic magmas (68–71 wt.% SiO₂). The mineralogy is broadly constant throughout the eruptive sequence, comprising plagioclase, quartz, biotite, Fe–Ti oxides, apatite, and titanite. Early ignimbrite magmas also contained amphibole, while the final eruption, the most voluminous Cerro Galán ignimbrite (CGI; 2.08 ± 0.02 Ma) erupted a magma containing rare amphibole, but significant sanidine. Each ignimbrite contains two main juvenile clast types; dominant “white” pumice and ubiquitous but subordinate “grey” pumice. Fe–Ti oxide and amphibole-plagioclase thermometry coupled with amphibole barometry suggest that the grey pumice originated from potentially hotter and deeper magmas (800–840°C, 3–5 kbar) than the more voluminous white pumice (770–810°C, 1.5–2.5 kbar). The grey pumice is interpreted to represent the parental magmas to the Galán system emplaced into the upper crust from a deeper storage zone. Most inter-ignimbrite variations can be accounted for by differences in modal mineralogy and crystal contents that vary from 40 to 55 vol.% on a vesicle-free basis. Geochemical modeling shows that subtle bulk-rock variations in Ta, Y, Nb, Dy, and Yb between the Galán ignimbrites can be reconciled with differences in amounts of crystal fractionation from the “grey” parent magma. The amount of fractionation is inversely correlated with volume; the CGI (∼630 km³) and Real Grande Ignimbrite (∼390 km³) return higher F values (proportion of liquid remaining) than the older Toconquis Group ignimbrites (<50 km³), implying less crystal fractionation took place during the upper-crustal evolution of these larger volume magmas. We attribute this relationship to variations in magma chamber geometry; the younger, largest volume ignimbrites came from flat sill-like magma chambers, reducing the relative proportion of sidewall crystallization and fractionation compared to the older, smaller-volume ignimbrite eruptions. The grey pumice clasts also show evidence of silicic recharge throughout the history of the Cerro Galán system, and recharge days prior to eruption has previously been suggested based on reversely zoned (OH and Cl) apatite phenocrysts. A rare population of plagioclase phenocrysts with thin An-rich rims in juvenile clasts in many ignimbrites supports the importance of recharge in the evolution and potential triggering of eruptions. This study extends the notion that large volumes of nearly identical silicic magmas can be generated repeatedly, producing prolonged geochemical homogeneity from a long-lived magma source in a subduction zone volcanic setting. At Cerro Galán, we propose that there is a zone between mantle magma input and upper crustal chambers, where magmas are geochemically “buffered”, producing the underlying geochemical and isotopic signatures. This produces the same parental magmas that are delivered repeatedly to the upper crust. A lower-crustal MASH (melting, assimilation, storage, and homogenization) zone is proposed to act as this buffer zone. Subsequent upper crustal magmatic processes serve only to slightly modify the geochemistry of the magmas.     

Trachyte shield volcanoes: a new volcanic form from South Turkana,Kenya

Seven Pliocene volcanoes, one of which is described in detail, occur in the northern part of the Kenya Rift. They have low-angle, shield like forms, and comprise lavas, pumice tuffs and ash-flow tuffs almost wholly of trachytic composition. Each volcano possesses a structurally complex source zone in which plugs, dykes and pumice tuffs are concentrated and in which clearly defined craters and calderas are uncommon. By contrast, the flank zones are stratiform with slopes of about 5° and are composed of lavas and ash-flow sheets erupted in a highly fluid condition. The volcanoes range up to 50 km in diameter and are elongated parallel to the general trend of the rift reflecting a tectonic control on the distribution of the vents and their products. This combination of morphological, structural and compositional features suggests that the volcanoes are of a type not described before. Notes on the petrography of the lavas are included and it is suggested that the trachytes are petrogenetically related to alkali basalts, compositionally similar to those which form the substrate to the trachyte volcanoes.     

Origin of cenozoic petrographic provinces of Japan and surrounding areas

Three petrographic provinces can be recognized in the Cenozoic volcanic fields of Japan and surrounding areas. A province of a tholeiite series lies on the Pacific side of the Japanese Islands and includes the Izu Islands, whereas that of an alkali rock series occupies the Japan Sea side of the Islands with a narrow offshoot extending across central Honsyū (Honshū) and a continuation westward to Korea and Manchuria. A province of a calc-alkali rock series is superposed on the two provinces and occupies the greater part of the Japanese Islands exclusive of the Izu Islands and the islands in the Japan Sea southwest of Honsyū and north of Kyūsyū (Kyūshū). The boundary lines between the tholeiite and alkali provinces are located very closely to those between the areas where earthquakes occur at depths shallower than about 200 km and those for deeper ones. It is suggested that the parental tholeiite magma is produced by partial melting of the periodotite layer at depths shallower than 200 km. In the Izu Islands, except Nii-zima(Nii-jima) and Kōzu-sima(Kōzu-shima) close to Honsyū, the magma erupts to the surface without assimilating granitic material because the granitic layer is absent, resulting in volcanoes made up exclusively of the tholeiite series. The parental alkali olivine basalt magma is produced by partial melting of the peridotite layer at depths greater than 200 km. In the Japan Sea region, Korea, and Manchuria, it erupts to the surface without assimilating the granitic material, although it passes through a thick granitic layer, resulting in volcanoes made up exclusively of the alkali series. However, in the Cenozoic orogenic belt of the Japanese Islands, both types of parental magma assimilate granitic material during passage to the surface and erupt to form volcanoes of the calc-alkali series.     

Sequence and eruptive style of the 1783 eruption of Asama Volcano, central Japan: a case study of an andesitic explosive eruption generating fountain-fed lava flow, pumice fall, scoria flow and forming a cone

The 3-month long eruption of Asama volcano in 1783 produced andesitic pumice falls, pyroclastic flows, lava flows, and constructed a cone. It is divided into six episodes on the basis of waxing and waning inferred from records made during the eruption. Episodes 1 to 4 were intermittent Vulcanian or Plinian eruptions, which generated several pumice fall deposits. The frequency and intensity of the eruption increased dramatically in episode 5, which started on 2 August, and culminated in a final phase that began on the night of 4 August, lasting for 15 h. This climactic phase is further divided into two subphases. The first subphase is characterized by generation of a pumice fall, whereas the second one is characterized by abundant pyroclastic flows. Stratigraphic relationships suggest that rapid growth of a cone and the generation of lava flows occurred simultaneously with the generation of both pumice falls and pyroclastic flows. The volumes of the ejecta during the first and second subphases are 0.21 km³ (DRE) and 0.27 km³ (DRE), respectively. The proportions of the different eruptive products are lava: cone: pumice fall=84:11:5 in the first subphase and lava: cone: pyroclastic flow=42:2:56 in the second subphase. The lava flows in this eruption consist of three flow units (L1, L2, and L3) and they characteristically possess abundant broken phenocrysts, and show extensive "welding" texture. These features, as well as ghost pyroclastic textures on the surface, indicate that the lava was a fountain-fed clastogenic lava. A high discharge rate for the lava flow (up to 10⁶ kg/s) may also suggest that the lava was initially explosively ejected from the conduit. The petrology of the juvenile materials indicates binary mixing of an andesitic magma and a crystal-rich dacitic magma. The mixing ratio changed with time; the dacitic component is dominant in the pyroclasts of the first subphase of the climactic phase, while the proportion of the andesitic component increases in the pyroclasts of the second subphase. The compositions of the lava flows vary from one flow unit to another; L1 and L3 have almost identical compositions to those of pyroclasts of the first and second subphases, respectively, while L2 has an intermediate composition, suggesting that the pyroclasts of the first and second subphases were the source of the lava flows, and were partly homogenized during flow. The complex features of this eruption can be explained by rapid deposition of coarse pyroclasts near the vent and the subsequent flowage of clastogenic lavas which were accompanied by a high eruption plume generating pumice falls and/or pyroclastic flows.Editorial responsibility: T. Druitt     

Geology and petrology of Mahukona Volcano,Hawaii

The submarine Mahukona Volcano, west of the island of Hawaii, is located on the Loa loci line between Kahoolawe and Hualalai Volcanoes. The west rift zone ridge of the volcano extends across a drowned coral reef at about-1150 m and a major slope break at about-1340 m, both of which represent former shoreines. The summit of the volcano apparently reached to about 250 m above sea level (now at-1100 m depth) did was surmounted by a roughly circular caldera. A econd rift zone probably extended toward the east or sutheast, but is completely covered by younger lavas from the adjacent subaerial volcanoes. Samples were vecovered from nine dredges and four submersible lives. Using subsidence rates and the compositions of flows which drape the dated shoreline terraces, we infer that the voluminous phase of tholeiitic shield growth ended about 470 ka, but tholeiitic eruptions continued until at least 435 ka. Basalt, transitional between tholeiitic and alkalic basalt, erupted at the end of tholeiitic volcanism, but no postshield-alkalic stage volcanism occurred. The summit of the volcano apparently subcided below sea level between 435 and 365 ka. The tholeiitic lavas recovered are compositionally diverse.     

Origin of andesite and its bearing on the Island arc structure

The hypothesis that andesite magmas originate from basalt magmas through fractionation is supported for the following reasons: 1) A close association of andesite and dacite with basalt in many volcanoes and a complete gradation in chemistry and mineralogy throughout this suite. 2) Formation of andesite magmas from basalt magmas by differentiation in situ of some intrusive and extrusive bodies. 3) Agreement between the calculated compositions of solid materials to be subtracted from basalt magmas to yield andesite magmas and the observed mineralogy of phenocrysts in these rocks. 4) Higher alkali contents in andesite and dacite associated with high-alumina basalt than in those associated with tholeiite. 5) A complete gradation from the high iron concentration trend of basalt magma fractionation (Skaergaard) to the low or noniron concentration trend (the calc-alkali series) which can be ascribed to the difference of the stage of magnetite crystallization. 6) Similarity between the orogenic rock suite and plateau basalts in the preferential eruption of magmas of middle fractionation stage, givin rise to the great volume of andesite in the orogenic belts and iron-rich basalt in the plateau lavas. Petrological and seismic refraction studies suggest that a great volume of gabbroic materials are present in the lower crust underneath the volcanic belts as a complementary material for the andesite lavas. The island arc structure would develop by repeated eruption of andesite on the surface and by thickening of the oceanic crust underneath the arc due to the addition of gabbroic materials. The suitable portion of the lower crust may be subjected to partial melting to produce granitic magma in the later stage of development of the arc, successively changing it to a part of the adjacent continent.     

The Negros de Aras Nuée Ardente deposits: a cataclysmic eruption of Socompa volcano (Andes of Atacama,Chile)

Studies of ERT Satellite photographic documents and of acrial photographs with complementary lield work reveal the presence of recent very large nuée ardente deposits north-west of Socompa Volcano (Andean Cordillera of Atacama, northern Chile). Three zones are distinguishable from the bottom of Socompa Volcano to the front of the nuée ardente deposits: 1) pumice blocks are covered with parallel ridges of debris (lava blocks) from the north-western flank of Socompa Volcano, 2) pumice blocks lie upon small cones and flows from El Negrillar volcanoes located inside the graben of Negros de Aras, 3) pumice flow threads its way between cones and flows from El Negrillar volcanoes and stops more than 40 km away from the base of Socompa Volcano. The calculated thermal energy of this cruption is 7.9 × 10²⁵ ergs, being in the range of of the most important recorded eruptions on earth. The pumice is almost aphyric (rare plagioclase, hypersthene and hornblende phenocrysts) and is of dacite composition lying pertectly on the K₂O-SiO₂ trend of the Socompa Volcano. Trace and major element data of the pumice are similar to those of two dacites from a pre-nuée lava flow and a post-nuée lava dome of Socompa Volcano and support a common magmatic origin with the Socompa Volcano lavas. A relative chronology is proposed.     

五大连池近代火山老黑山火烧山火山喷发过程的考察研究

作者在已有工作的基础上,以当代火山学的研究思路和观点,为恢复五大连池两个近代火山,老黑山火烧山的喷发历史过程进行了野外考察研究工作。老黑山火山锥是由三套不同的碎屑堆积物组成。在锥体的南侧、东侧和西侧以及北测和北西侧有５个熔岩溢出口,按它们形成先后关系,认为有早、中、晚三期熔岩流。本文还对老黑山火山锥上的寄生火山、结壳熔岩与渣状熔岩的分布、流动特点及形成的控制因素进行了分析讨论。最后得出结论：老黑山火山是经多期次喷发活动形成的。火烧山火山锥是一碎屑化泡沫化程度很低的浮岩块和熔岩碎块组成,同老黑山有明显区别。     

Fractionation trends of basalt magmas in lava flows

Chemical compositions of schlieren in basalt flows are compared with those of the host rocks for tracing the fractionation trends of basalt magmas under extrusive conditions. In the Warner high-alumina basalt of California and in the tholeiite of Hawaii and Japan, total iron increases markedly from the host rock to the schlieren whileSiO ₂ is nearly constant. In the high-alumina basalt of Huzi Volcano and in the tholeiite near Catania, Italy, total iron is nearly constant during fractionation whileSiO ₂ increases. In basalts of the hypersthenic rock series or calc-alkali rock series from California, total iron is also nearly constant whileSiO ₂ increases. The difference in fractionation trend in these flows is attributable to the difference of the state of oxidation of iron in the original magmas. Oxygen partial pressure of the magmas would not be maintained constant during the fractionation of extrusive bodies.     

Petrology of Hualalai volcano,Hawaii: Implication for mantle composition

Hualalai is one of five volcanoes whose eruptions built the island of Hawaii. The historic 1800–1801 flows and the analyzed prehistoric flows exposed at the surface are alkalic basalts except for a trachyte cone and flow at Puu Waawaa and a trachyte maar deposit near Waha Pele. The 1800–1801 eruption produced two flows: the upper Kaupulehu flow and the lower Huehue flow. The analyzed lavas of the two 1800–1801 flows are geochemically identical with the exception of a few samples from the toe of the Huehue flow that appear to be derived from a separate magmatic batch. The analyzed prehistoric basalts are nearly identical to the 1800–1801 flows but include some lavas that have undergone considerable shallow crystal fractionation. The least fractionated alkalic basalts from Hualalai are in equilibrium with mantle olivine (Fo₈₇) indicating that the Hawaiian mantle source region is not unusually iron-rich. The 1800–1801 and analyzed prehistoric basalts can be generated by about 5–10% partial fusion of a garnet-bearing source relatively enriched in the light-rare-earths. The mantle underlying the Hawaiian Islands is chemically and mineralogically heterogeneous before and after extraction of the magmas that make up the volcanoes.     

A possible submarine volcano near the central part of Ninety-East Ridge, Indian ocean

Floating pumice masses have been observed several times near the central part of Ninety-East Ridge, Indian Ocean, in 1879 and in 1883. The author is of the opinion that the source of these pumice masses cannot have been the volcano Krakatau in the Sunda Strait - as has been suggested earlier by other authors -, but that they originated in situ. Examples of floating pumice observed over submarine volcanoes lying at depths of 1500 m or even more, are mentioned briefly by other authors, suggesting that eruptions in deep water may indeed lead to its formation.The suspected submarine volcano may coincide with an elongated but rather flat elevation a little north of the central part of Ninety-East Ridge. The center of this elevation is located approximately at 6° 05′ S, 89° 10 E. A roughly NW-SE profile of this area shows the presence of this shield-like feature very near the site where floating pumice was seen on three occasions. The inferred submarine volcanic center is lying within the belt of heat flow anomaly (called belt I). A particular “hot spot” with an unusually high heat flow value (7.61 HFU) is located southeast of the feature in question. The heat flow values measured in belt I are well above the world-average. This belt may be the result of the presence of linearly arranged magma chambers at a relatively shallow depth, probably within the oceanic crust. This belt has a length of 1100 km.The seismic activity of the area investigated is similarly remarkable. Numerous powerful shocks have taken place there. Belt I represents the axis of the seismic zone, extending from points b to c (Fig. 5). The seismic belt is regarded as a zone of weakness within which fractures can originate, permitting rock-melts to emerge from depth towards the surface.     

The occurrence and origin of prominent massive,pumice-rich ignimbrite lobes within the Late Pleistocene Abrigo Ignimbrite,Tenerife, Canary Islands

The 0.196 Ma, lithic-rich Abrigo Ignimbrite on Tenerife, Canary Islands contains localised massive, coarse pumice-rich ignimbrite lobes (MPRILs). They typically form low ridges up to 2 m high with axes parallel to the flow direction, and, in cross-section, they range from symmetrical to asymmetrical and highly skewed lobate bedforms generally with flat bases. The major components are rounded pebble- to cobble-sized phonolitic pumice clasts within an ignimbritic matrix of ash, fine lithics and minor crystals, which varies from lithic-rich to lithic-poor. Commonly, there is a vertical increase in pumice concentration from matrix-supported texture at the base to clast-supported at the top, accompanied by an increase in pumice clast size. MPRILs often thin and grade laterally perpendicular to current flow into planar pumice concentration zones. They occur at one or more stratigraphic levels as either solitary lobes associated with flat topography or as multiple onlapping lobes or within a laterally complex stratified pumice-rich ignimbrite facies (LCSPIs) near palaeotopographic highs.MPRILs are original depositional features, not erosional in origin and are derived from a larger pyroclastic flow. It is likely that pumice was segregated to the upper and outer regions of the parent flow causing a significant rheological contrast with the lower lithic-rich zone. The more pumice-rich parts are interpreted to have detached from the parent flow as it decelerated onto gentler slopes or interacted with topographic highs and raced ahead as mobile derivative pyroclastic flows. The flow-parallel ridge shape of MPRILs may be a result of fingering within these flows or concentration of pumice within the intermediary clefts. Deposition occurred “en masse” at the termination of the flow front. The resultant lobate deposits were then overridden and mantled by normal ignimbrite facies from either a later flow pulse or the following main part of the parent flow.