Sedimentology and Paleoenvironmental Characteristics of Fine-grained Sediments in Coal-bearing Strata in the Eastern Ordos Basin: A Case Study of the Exploratory Well in the Zizhou Area

The continuously collected cores from the Permo–Carboniferous coal-bearing strata of the eastern Ordos Basin are essential for studying the hydrocarbon potential in this region. This study adopted sedimentological and geochemical methods to analyze the sedimentary environment, material composition, and geochemical characteristics of the coal-bearing strata. The differences in depositional and paleoclimatic conditions were compared; and the factors influencing the organic matter content of fine-grained sediments were explored. The depositional environment of the Benxi and Jinci formations was lagoon to tidal flat with weakly reduced waters with low salinity and dry-hot paleoclimatic conditions; while that of the Taiyuan Formation was a carbonate platform and shallow water delta front, where the water was highly reductive. The xerothermic climate alternated with the warm and humid climate. The period of maximum transgression in the Permo–Carboniferous has the highest water salinity. The Shanxi Formation was deposited in a shallow water delta front with a brackish and fresh water environment and alternative weak reductiveness. And the paleoclimate condition is dry-hot. The TOC content in fine-grained samples was averaging 1.52%. The main controlling mechanism of organic matter in this area was the input conditions according to the analysis on input and preservation of organic matter.     

Carboniferous–Permian Stratigraphy and Sedimentary Environment of Southeastern Inner Mongolia, China: Constraints on Final Closure of the Paleo-Asian Ocean

In this paper we discuss the timing of final closure of the Paleo-Asian Ocean based on the field investigations of the Carboniferous–Permian stratigraphic sequences and sedimentary environments in southeastern Inner Mongolia combined with the geology of its neighboring areas. Studies show that during the Carboniferous–Permian in the eastern segment of the Tianshan-Hinggan Orogenic System, there was a giant ENE–NE-trending littoral-neritic to continental sedimentary basin, starting in the west from Ejinqi eastwards through southeastern Inner Mongolia into Jilin and Heilongjiang. The distribution of the Lower Carboniferous in the vast area is sparse. The Late Carboniferous or Permian volcanic-sedimentary rocks always unconformably overlie the Devonian or older units. The Upper Carboniferous–Middle Permian is dominated by littoral-neritic deposits and the Upper Permian, by continental deposits. The Late Carboniferous–Permian has no trace of subduction-collision orogeny, implying the basin gradually disappeared by shrinking and shallowing. In addition, it is of interest to note that the Ondor Sum and Hegenshan ophiolitic mélanges were formed in the pre-Late Silurian and pre-Late Devonian respectively, and the Solonker ophiolitic mélange formed in the pre-Late Carboniferous. All the evidence indicates that the eastern segment of the Paleo-Asian Ocean had closed before the Late Carboniferous, and most likely before the latest Devonian (Famennian).     

Biostratigraphy,Microfacies, Sedimentary Environments and Sequence Stratigraphy of the Late Devonian–Carboniferous Deposits at the Anarak Section,Central Iran

The Late Devonian–early Carboniferous deposits of the Anarak section in northeastern Isfahan, Central Iran, evaluated based on conodont biostratigraphy, sedimentary environment and sequence stratigraphy. According to the field observations, five lithological units were identified. Investigating the conodont fauna of the Late Devonian–Carboniferous(Mississippian–Pennsylvanian) deposits of Bahram, Shishtu, and Qaleh(Sardar 1) formations in Anarak section led to the identification of 67 species of ...     

Environment and Age of the Upper Devonian‒Carboniferous Zhulumute and Hongguleleng Formations, Junggar Basin, NW China: Ichnological and Palynological Aspects

Two Upper Devonian to Lower Carboniferous sections, namely the Bulongguoer and Haer(Gennaren area) in the Junggar Basin, Central Asian Orogenic Belt, in northwestern China were examined with regard to ichnology and palynology. The deposits of the Hongguleleng Formation and Namu Member of the Heishantou Formation, respectively, are mostly unbioturbated or poorly bioturbated, with poorly diversified trace fossils, which indicate unfavourable conditions for the burrowing benthic community during the Late Devonian and Early Carboniferous. The main factor governing the growth of the bioturbating population was the rapid sedimentation of fine-grained, volcanic material documented as tempestites, which buried the benthic fauna. In the Bulongguoer section, the presence of miospores Teichertospora torquata and Grandispora gracilis enabled identification of the broad Teichertospora torquata–Grandispora gracilis Miospore Zone from the transitional Frasnian/Famennian interval. More accurate identification of palynostratigraphical levels(DE and CZ Miospore zones) is only tentative. On the basis of palynofacies analysis, samples from the lower Bulongguoer section indicate deposition in more proximal conditions, whereas samples from the top of the section indicate deposition in a more distal environment. In the Haer section, only a general biostratigraphic indication for the Tournaisian was possible, owing to poor preservation of organic matter.     

Geochronology and Geochemistry of the Radiolarian Cherts of the Mada’er Area, Southwestern Tianshan: Implications for Depositional Environment

In the Southwestern Tianshan, the geologic ages of many strata and their depositional environments are still poorly constrained because of complex structures. The Mada’er area is located in the Kuokesaleling belt, Southwestern Tianshan. The cherts from the former Wupata’erkan Group contain abundant radiolarian fossils, including 10 species which are identified as late Devonian to early Carboniferous in age. Eleven chert samples have SiO2 contents ranging from 88.80 wt% to 93.28 wt%, and 2.02 wt% to 3.72 wt% for Al2O3. The SiO2/Al2O3 ratios of all samples vary from 23.84 to 46.11, much lower than those of the pure cherts (80–1400). These values suggest that the cherts contain high ratios of terrigenous materials. The Al2O3/(Al2O3+Fe2O3) ratios vary between 0.64 and 0.77, whereas V and Cu concentrations range from 10.92 ppm to 26.7 ppm and from 2.15 ppm to 34.1 ppm respectively. The Ti/V ratios vary from 25.53 to 44.93. The total REE concentrations of the cherts are between 30.78 ppm and 59.26 ppm, averaging 45.46 ppm. The (La/Ce)N ratios range from 0.81 to 1.12, and 0.88–1.33 for (La/Yb)N, averaging 1.09, which suggests a continental margin environment. Consequently, it is inferred that the cherts formed in a residual sea environment during the late Devonian to early Carboniferous time, which suggests that the collision between the Karakum-Tarim and Kazakhstan-Junggar plates did not occur at the time. In addition, the regional geological information indicates that the study area experienced a post-collision stage during the early Permian, and thus it is likely that the collision between the two plates took place in the late Carboniferous.     

Provenance and paleogeography of Carboniferous–Permian strata in the Bayanhot Basin: Constraints from sedimentary records and detrital zircon geochronology

The Bayanhot Basin is a superimposed basin that experienced multiple-staged tectonic movements; it is in the eastern Alxa Block, adjacent to the North China Craton(NCC) and the North Qilian Orogenic Belt(NQOB).There are well-developed Paleozoic–Cenozoic strata in this basin, and these provide a crucial window to a greater understanding of the amalgamation process and source-to-sink relationships between the Alxa Block and surrounding tectonic units.However, due to intensive post-depositional modification, and lack of subsurface data,several fundamental issues—including the distribution and evolution of the depositional systems, provenance supplies and source-to-sink relationships during the Carboniferous– Permian remain unclear and thus hinder hydrocarbon exploration and limit the geological understanding of this basin.Employing integrated outcrop surveys, new drilling data, and detrital zircon dating, this study examines the paleogeographic distribution and evolution, and provenance characteristics of the Carboniferous–Permian strata in the Bayanhot Basin.Our results show that the Bayanhot Basin experienced a long-term depositional evolution process from transgression to retrogression during the Carboniferous–late Permian.The transgression extent could reach the central basin in the early Carboniferous.The maximum regional transgression occurred in the early Permian and might connect the Qilian and North China seas with each other.Subsequently, a gradual regression followed until the end of the Permian.The northwestern NCC appeared as a paleo-uplift area and served as a sediments provenance area for the Alxa Block at that time.The NCC, Bayanwula Mountain, and NQOB jointly served as major provenances during the Carboniferous–Permian.There was no ocean separation, nor was there an orogenic belt between the Alxa Block and the NCC that provided sediments for both sides during the Carboniferous–Permian.The accretion of the Alxa and North China blocks should have been completed before the Carboniferous period.     

Re–Os geochronology of Cu and W–Mo deposits in the Balkhash metallogenic belt, Kazakhstan and its geological significance

The Central Asian metallogenic domain (CAMD) is a multi-core metallogenic system controlled by boundary strike-slip fault systems. The Balkhash metallogenic belt in Kazakhstan, in which occur many large and super-large porphyritic Cu–Mo deposits and some quartz vein- and greisen-type W–Mo deposits, is a well-known porphyritic Cu–Mo metallogenic belt in the CAMD. In this paper 11 molybdenite samples from the western segment of the Balkhash metallogenic belt are selected for Re–Os compositional analyses and Re–Os isotopic dating. Molybdenites from the Borly porphyry Cu deposit and the three quartz vein-greisen W–Mo deposits—East Kounrad, Akshatau and Zhanet—all have relatively high Re contents (2712–2772 μg/g for Borly and 2.267–31.50 μg/g for the other three W–Mo deposits), and lower common Os contents (0.670–2.696 ng/g for Borly and 0.0051–0.056 ng/g for the other three). The molybdenites from the Borly porphyry Cu–Mo deposit and the East Kounrad, Zhanet, and Akshatau quartz vein- and greisen-type W–Mo deposits give average model Re–Os ages of 315.9 Ma, 298.0 Ma, 295.0 Ma, and 289.3 Ma respectively. Meanwhile, molybdenites from the East Kounrad, Zhanet, and Akshatau W–Mo deposits give a Re–Os isochron age of 297.9 Ma, with an MSWD value of 0.97. Re–Os dating of the molybdenites indicates that Cu–W–Mo metallogenesis in the western Balkhash metallogenic belt occurred during Late Carboniferous to Early Permian (315.9–289.3 Ma), while the porphyry Cu–Mo deposits formed at 316 Ma, and the quartz vein-greisen W–Mo deposits formed at 298 Ma. The Re–Os model and isochron ages thus suggest that Late Carboniferous porphyry granitoid and pegmatite magmatism took place during the late Hercynian movement. Compared to the Junggar-East Tianshan porphyry Cu metallogenic belt in northwestern China, the formation of the Cu–Mo metallogenesis in the Balkhash metallogenic belt occurred between that of the Tuwu-Yandong in East Tianshan and the Baogutu porphyry Cu deposits in West Junggar. Collectively, the large-scale Late Carboniferous porphyry Cu–Mo metallogenesis in the Central Asian metallogenic domain is related to Hercynian tectono-magmatic activities.     

Carbon and Strontium Isotopes of Late Palaeozoic Marine Carbonates in the Upper Yangtze Platform,Southwest China

238 marine carbonate samples were collected from seven sedimentary sections ofthe entire late Palaeozoic (Permian, Carboniferous and Devonian) in the Upper Yangtze Plat-form, southwest China. Based on the absence of cathodoluminescence and very low Mn (gener-ally<50 ppm) contents of the samples, it is thought that they contain information on the orig-inal sea water geochemistry. The results of isotopic analyses of these samples are presented interms of δ~(13)C and ~(87)Sr/~(86)Sr ratios versus geological time. The strontium data, consistent withother similar data based on samples from North America, Europe, Africa and other areas inAsia, support the notion of a global consistency in strontium isotope composition of marinecarbonates. The strontium data exhibit three intervals of relatively low ~(87)Sr/~(86)Sr ratios in thelate Middle Devonian to early Late Devonian, Early Carboniferous and Early Permian, corre-sponding to global eustatic high sea level stands. The lowest ~(87)Sr/~(86)Sr ratio recorded in theLate Permian was probably caused by substantial basalt eruptions in the Upper Yangtze Plat-form at the time. Three corresponding periods of relatively high δ~(13)C values at roughly the samethe intervals were caused by a relatively high rate of accumulation of organic carbon duringsea level rises at these times. The deposition of coal was probably responsible for the increaseof sea water δ~(13)C at other times. The δ~(13)C values drop dramatically near theDevonian/Carboniferous, Carboniferous/Permian and Permian/Triassic boundaries, con-sistent with other similar data, which further support the notion that geological time boundariesare associated with mass extinction and subsequent rejuvenation.     

Petrogenesis and Tectonic Significance of CarboniferousGranites on the North Side of the Solonker Suture,CentralSouth Mongolia

The central part of South Mongolia, located to the north of the Solonker Suture, is a key region for studying the late Paleozoic tectonic evolution of the Central Asian Orogenic Belt(CAOB). Voluminous late Paleozoic granitic rocks,especially of Carboniferous age, were intruded in this area. However, these granitoids have not been well studied and there is a lack of precise ages and isotopic data. This has hampered our understanding of the tectonic evolution of southeastern Mongolia, and even the entire CAOB. In this paper, we provide new U-Pb isotopic ages and geochemical analyses for these Carboniferous granites. One granite from the Ulaanbadrakh pluton yielded a zircon U-Pb age of 326 Ma, which indicates emplacement in the Early Carboniferous, and three other granites from the Khatanbulag region gave zircon U-Pb ages of316 Ma, 315 Ma, and 311 Ma, which indicate emplacement in the Late Carboniferous. The Early Carboniferous granite has SiO2 contents of 70.04–70.39 wt% and K2 O + Na2 O contents of 6.48–6.63 wt%, whereas the Late Carboniferous granites have more variable compositions(SiO2 = 65.29–77.91 wt% and K2 O + Na2 O = 5.30–7.27 wt%). All the granites are weakly-peraluminous I-types that are relatively enriched in U, Th, K, Zr, Hf, and LREEs. The whole rock Sr-Nd and zircon in situ Lu-Hf isotope analyses for the Early Carboniferous granite gave positive values of εNd(t)(2.87) and εHf(t)(4.31–12.37) with young Nd(TDM = 860 Ma) and Hf(TDMc = 1367–637 Ma) two-stage model ages, indicating derivation from juvenile crustal material. In contrast, the Late Carboniferous granites had more diverse values of εNd(t)(–4.03 to 2.18) and εHf(t)(–12.69 to5.04) with old Nd(TDM = 1358–1225 Ma) and Hf(TDMc = 2881–1294 Ma) depleted mantle two-stage model ages,suggesting derivation from remelting of Precambrian basement. Based on the existing results, the tectonic setting of the Late Carboniferous granites in the central part of South Mongolia is known for its diversity, and this paper believes that the tectonic background of the carboniferous granite records the tectonic transition from a continental-margin-arc to a postcollisional extensional setting during the Late Carboniferous–Permian.     

Avalonia,get bent!–Paleomagnetism from SW Iberia confirms the Greater Cantabrian Orocline

The amalgamation of Pangea formed the contorted Variscan-Alleghanian orogen,suturing Gondwana and Laurussia during the Carboniferous.From all swirls of this orogen,a double curve in Iberia stands out,the coupled Cantabrian Orocline and Central Iberian curve.The Cantabrian Orocline formed at ca.315–290 Ma subsequent to the Variscan orogeny.The formation mechanism of the Cantabrian Orocline is disputed,the most commonly proposed mechanisms include either(1)that south-westernmost Iberia would be an Avalonian(Laurussian)indenter or(2)that the stress field changed,buckling the orogen.In contrast,the geometry and kinematics of the Central Iberian curve are largely unknown.Whereas some authors defend both curvatures are genetically linked,others support they are distinct and formed at different times.Such uncertainty adds an extra layer of complexity to our understanding of the final stages of Pangea’s amalgamation.To solve these issues,we study the late Carboniferous–early Permian vertical-axis rotations of SW Iberia with paleomagnetism.Our results show up to 70
counterclockwise vertical-axis rotations during late Carboniferous times,concurring with the anticipated kinematics if SW Iberia was part of the southern limb of the Cantabrian Orocline.Our results do not allow the necessary penecontemporaneous clockwise rotations in Central Iberia to support a concomitant formation of both Cantabrian and Central Iberian curvature.The coherent rotation of both Gondwanan and Avalonian pieces of SW Iberia discards the Laurussian indenter hypothesis as a formation mechanism of the Cantabrian Orocline and confirms the Greater Cantabrian Orocline hypothesis.The Greater Cantabrian Orocline likely formed as a consequence of a change in the stress field during the late Carboniferous and extended beyond the Rheic Ocean suture affecting the margins of both Laurussia and Gondwana.     

Zircon U–Pb geochronology and Hf isotope geochemistry of magmatic and metamorphic rocks from the Hida Belt,southwest Japan

Zircon U–Pb and Hf isotope data integrated in this study for magmatic and metamorphic rocks from the Hida Belt,southwest Japan,lead to a new understanding of the evolution of the Cordilleran arc system along the ancestral margins of present-day Northeast Asia.Ion microprobe data for magmatic zircon domains from eight mafic to intermediate orthogneisses in the Tateyama and Tsunogawa areas yielded weighted mean ~(206)Pb/~(238)U ages spanning the entire Permian period(302–254 Ma).Under cathodoluminescence,primary magmatic growth zones in the zircon crystals were observed to be partially or completely replaced by inward-penetrating,irregularly curved featureless or weakly zoned secondary domains that mostly yielded U–Pb ages of 250–240 Ma and relatively high Th/U ratios( 0.2).These secondary domains are considered to have been formed by solid-state recrystallization during thermal overprints associated with intrusions of Hida granitoids.Available whole-rock geochemical and Sr–Nd isotope data as well as zircon age spectra corroborate that the Hida Belt comprises the Paleozoic–Mesozoic Cordilleran arc system built upon the margin of the North China Craton,together with the Yeongnam Massif in southern Korea.The arc magmatism along this system was commenced in the Carboniferous and culminated in the Permian–Triassic transition period.Highly positive εHf(t) values( +12) of late Carboniferous to early Permian detrital zircons in the Hida paragneisses indicate that there was significant input from the depleted asthenospheric mantle and/or its crustal derivatives in the early stage of arc magmatism.On the other hand,near-chondritic εHf(t) values(+5 to-2) of magmatic zircons from late Permian Hida orthogneisses suggest a lithospheric mantle origin.Hf isotopic differences between magmatic zircon cores and the secondary rims observed in some orthogneiss samples clearly indicate that the zircons were chemically open to fluids or melts during thermal overprints.Resumed highly positive zircon εHf(t) values(+9) shared by Early Jurassic granitoids in the Hida Belt and Yeongnam Massif may reflect reworking of the Paleozoic arc crust.     

Devonian–Carboniferous Hangenberg Crisis in South China: Variations in Trace Elements, Strontium and Carbon Isotope Chemostratigraphy in the Nanbiancun Carbonate Section

The global Hangenberg Crisis or Hangenberg Extinction is a mass extinction near the Devonian–Carboniferous boundary. Comprehensive research of petrology and geochemistry on the Devonian–Carboniferous boundary, as exposed in the Nanbiancun auxiliary stratotype section, South China, elucidates paleoenvironmental changes and controls on marine strontium (87Sr/86Sr) and carbonate carbon (δ13Ccarb) isotopes during the Hangenberg Crisis. The new 87Sr/86Sr data reveal a regression in the Middle Siphonodella praesulcata Zone, while the Hangenberg Extinction was occurring in South China. Moreover, the δ13Ccarb data records a negative excursion near the base of the Middle Siphonodella praesulcata Zone that may have been connected with the Hangenberg Extinction. A positive δ13Ccarb excursion, corresponding with the Upper Siphonodella praesulcata Zone, may reflect the effects of a vigorous biological pump. The magnitude of the Hangenberg Carbon Isotopic Excursion in peak δ13carb values and δ13Ccarb gradient in carbonate Devonian–Carboniferous boundary sections of the South China Craton during the Hangenberg Crisis, are a function of depositional water depth and distance from the shore. The carbon cycling during the Hangenberg Carbon Isotopic Excursion had a much stronger impact on oceanic surface waters than on the deep ocean and the δ13Ccarb gradient of local seawater was likely caused by enhanced marine productivity, associated with biological recovery in platform sediments during the Hangenberg Crisis.     

Geochronology and Geochemistry of the Radiolarian Cherts of the Mada’er Area, Southwestern Tianshan: Implications for Depositional Environment

In the southwestern Tianshan,the geologic ages of many strata and their depositional environments are still poorly constrained because of complex structures.The Mada'er area is located in the Kuokesaleling belt,Southwestern Tianshan.The cherts from the former Wupata'erkan Group contain abundant radiolarian fossils,including 10 species which are identified as late Devonian to early Carboniferous in age.Eleven chert samples have SiO_2 contents ranging from 88.80 wt%to 93.28 wt%, and 2.02 wt%to 3.72 wt%for ...     

Petrology, Geochemistry and Tectonic Significance of the Metamorphic Peridotites from Longmuco–Shuanghu Ophiolitic Melange belt, Tibet

Taoxinghu metamorphic peridotite is a firstly reported mantle sequence of ophiolite since Longmuco–Shuanghu–Lancangjiang suture zone (LSLSZ) was proposed, and it is also an important discovered for ophiolite studying in central Qiangtang. Based on detailed analyses of whole–rock geochemistry of Taoxinghu metamorphic peridotites and contrast to metamorphic peridotites in typical ophiolites worldwide, the paper investigates their petrogenesis and geological implication. The petrologic results show that the protolith of Taoxinghu metamorphic perdotites have the mineral assemblage and texture characteristic of mantle peridotite. Most metamorphic peridotites hav near global abyssal peridotites major elements contents, while the few is similar to SSZ–type peridotites. They exhibit typically U–shaped REE patterns, characterized by slight enrichment of LREE and HREE relative to MREE and a low fractionated LREE to HREE segment. Trace elements contents are low and all samples are strong enrichment in Cs, U, Pb, weak enrichment in Ba and depletion in Th, but negative Nb anomalies are only observed in few samples. That suggests Taoxinghu metamorphic peridotites have depletion mantle and suprasubduction affinities. A two–stage evolution history is considered: Taoxinghu metamorphic peridotites originated as the residue from melting at a ridge with 7%–20% degree of fraction melting and were subsequently modified by interaction with mafic melt and aqueous fluid within mantle wedge on subducted zone. Combined with previous studies, we preliminarily propose Taoxinghu metamorphic peridotites may be the Products of initial rifting of palo–Tethys, forming at middle Ordivician–upper Cambrian, and they may be the direct evidences for spreading of palo–Tethys.     

From arc-continent collision to ocean closure: Lower Cretaceous Shamuluo Formation in the western segment of the Bangong–Nujiang suture zone,central Tibet

One of most hotly debated topics concerning the Late Mesozoic evolution of Tethyan and the Tibetan Plateau is the timing of the closure of the Meso-Tethys ocean, which is represented by the Bangong–Nujiang suture zone. The Upper Jurassic–Lower Cretaceous Shamuluo Formation, which unconformably overlies the older Mugagangri Group accretionary complex, provides important information on the closure of the Meso-Tethys Ocean. This paper precisely confines the depositional age of the Shamuluo Formation in the western segment of the Bangong–Nujiang suture zone, extending it from the Late Jurassic to the Albian. Combined with the results of previous studies, we suggest that the Shamuluo Formation in the Awengco–Baerqiong region mainly contains a bathyal Berriasian–Hauterivian subunit and a shallow-marine Albian subunit. Provenance analysis indicates that the Berriasian–Hauterivian subunit was mainly derived from the Jurassic southern Qiangtang magmatic arc, while the Albian subunit was derived from the coeval volcanic rocks and the Upper Carboniferous–Upper Permian strata in the southern Qiangtang terrane. Thus, the two subunits of the Shamuluo Formation have significant distinct sedimentary facies and provenances, indicating that they were deposited in different tectonic settings.Based on the regional geological data, we suggest that the bathyal Berriasian–Hauterivian subunit and the shallow-marine Albian subunit of the Shamuluo Formation should be interpreted as a record of the oceanic arc-continent collision and the Lhasa–Qiangtang soft-collision, respectively. Thus, the closure time of the Meso-Tethys Ocean is at least limited to the Albian.     

Trace Element Geochemistry of Magnetite from the Fe(-Cu) Deposits in the Hami Region, Eastern Tianshan Orogenic Belt, NW China

Laser ablation–inductively coupled plasma–mass spectrometry(LA–ICP–MS) was used to determine the trace element concentrations of magnetite from the Heifengshan, Shuangfengshan, and Shaquanzi Fe(–Cu) deposits in the Eastern Tianshan Orogenic Belt. The magnetite from these deposits typically contains detectable Mg, Al, Ti, V, Cr, Mn, Co, Ni, Zn and Ga. The trace element contents in magnetite generally vary less than one order of magnitude. The subtle variations of trace element concentrations within a magnetite grain and between the magnetite grains in the same sample probably indicate local inhomogeneity of ore–forming fluids. The variations of Co in magnetite between samples are probably due to the mineral proportion of magnetite and pyrite. Factor analysis has discriminated three types of magnetite: Ni–Mn–V–Ti(Factor 1), Mg–Al–Zn(Factor 2), and Ga– Co(Factor 3) magnetite. Magnetite from the Heifengshan and Shuangfengshan Fe deposits has similar normalized trace element spider patterns and cannot be discriminated according to these factors. However, magnetite from the Shaquanzi Fe–Cu deposit has affinity to Factor 2 with lower Mg and Al but higher Zn concentrations, indicating that the ore–forming fluids responsible for the Fe–Cu deposit are different from those for Fe deposits. Chemical composition of magnetite indicates that magnetite from these Fe(–Cu) deposits was formed by hydrothermal processes rather than magmatic differentiation. The formation of these Fe(–Cu) deposits may be related to felsic magmatism.     

Zircon U‐Pb Ages and Geochemistry of Permo‐Carboniferous Mafic Intrusions in the Xilinhot Area,Inner Mongolia: Constraints on the Northward Subduction of the Paleo‐Asian Ocean

The Central Asian Orogenic Belt(CAOB) resulted from accretion during the Paleozoic subduction of the PaleoAsian Ocean. The Xilinhot area in Inner Mongolia is located in the northern subduction zone of the central-eastern CAOB and outcropped a large number of late Paleozoic mafic intrusions. The characteristics of magma source and tectonic setting of the mafic intrusions and their response to the closure process of the Paleo-Asian Ocean are still controversial. This study presents LA-ICPMS zircon U-Pb ages and geochemical features of mafic intrusions in the Xilinhot area to constrain the northward subduction of the Paleo-Asian Ocean. The mafic intrusions consist of gabbro, hornblende gabbro, and diabase. Their intrusion times can be divided into three stages of 326–321 Ma, 276 Ma and 254 Ma by zircon U-Pb ages. The first two stages of the 326–276 Ma intrusions mostly originated from subduction-modified continental lithospheric mantle sources that underwent a variable degree partial melting(5–30%), recording the subduction of oceanic crust. The third stage of the 254 Ma mafic rocks also show arc-related features. The primary magma compositions calculated by PRIMELT2 modeling on three samples of ～326 Ma and two samples of ～254 Ma show that these mafic samples are characterized by a variable range in SiO_2(47.51–51.47 wt%), Al_2O_3(11.46–15.55 wt%), ΣFeO(8.27–9.61 wt%), MgO(13.01–15.18 wt%) and CaO(9.13–11.67 wt%), consisting with the features between enriched mantle and lower continental crust. The source mantle melting of mafic intrusions occurred under temperatures of 1302–1351°C and pressures of 0.92–1.30 GPa. The magmatic processes occurred near the crust-mantle boundary at about 33–45 km underground. Combined with previous studies, it is concluded that Carboniferous to early Permian(～326–275 Ma) northward subduction of the Paleo-Asian oceanic crust led to the formation of the mafic magmatism in the Baolidao arc zone. The whole region had entered the collision environment at ～254 Ma, but with subduction-related environments locally. The final collision between the North China craton and the South Mongolian microcontinent may have lasted until ca. 230 Ma.     

Petrogenesis of Kejie Granite in the Northern Changning-Menglian Zone, Western Yunnan: Constraints from Zircon U-Pb Geochronology, Geochemistry and Hf Isotope

The Kejie pluton is located in the north of the Changning-Menglian suture zone. The rock types are mainly biotite-granite. Zircon LA-ICP-MS U-Pb dating indicates that the Kejie pluton emplaced at about 80–77 Ma, Late Cretaceous. The Kejie pluton samples are characterized by high SiO2(71.68%–72.47%), K2O(4.73%–5.54%), total alkali(K2O + Na2O = 8.21%–8.53%), K2O/Na2O ratios(1.36–1.94) and low P2O5(0.13%–0.17%), with A/CNK of 1.025–1.055; enriched in U, Th, and K, depleted in Ba, Nb, Sr, Ti, P and Eu. They are highly fractionated, slightly peraluminous I-type granite. The two samples of the Kejie pluton give a large variation of εHf(t) values(-5.04 to 1.96) and Hf isotope crustal model ages of 1.16–1.5 Ga. Zircon Hf isotopes and zircon saturation temperatures of whole-rock(801°C–823°C) show that the mantle-derived materials maybe have played a vital role in the generation of the Kejie pluton. The Kejie pluton was most likely generated in a setting associated with the eastward subduction of the neo-Tethys ocean, where intrusion of mantle wedge basaltic magmas in the crust caused the anatexis of the latter, forming hybrid melts, which subsequently experienced high-degree fractional crystallization.     

Petrogenetic Evolution of the Bayan Gol Ophiolite— Geological Record of an Early Carboniferous "Red Sea Type"Ocean Basin in the Tianshan Mountains, Northwestern China

The Bayan Gol ophiolite fragment is a portion of the North Tianshan Early Carboniferous ophiolite belt. This ophiolite belt represents a geological record of an Early Carboniferous “Red Sea type” ocean basin that was developed on the northern margin of the Tianshan Carboniferous-Permian rift system in northwestern China. The late Early Carboniferous Bayan Gol ophiolite suite was emplaced in an Early Carboniferous rift volcanosedimentary succession of shallow-marine to continental facies (Volcanics Unit). Ophiolitic rocks in the Bayan Gol area comprise ultramafic rocks, gabbros with associated plagiogranite veins, diorite, diabase, pillow basalts and massive lavas. The Early Carboniferous tiffing and the opening process of the North Tianshan ocean basin produced mafic magmas in composition of tholeiite and minor amounts of evolved magmas. Compositions of trace elements and Nd, Sr and Pb isotopes reveal the presence of two distinct mantle sources: (1) the Early Carboniferous rift mafic lavas from the Volcanics Unit were generated by a relatively low degree of partial melting of an asthenospheric OIB-type intraplate source; (2)younger (late Early Carboniferous, -324.8 Ma ago) mafic lavas from the Ophiolite Unit were formed in a relatively depleted MORB-like mantle source, located in the uppermost asthenosphere and then gradually mixed with melts from the asthenospheric OIB-like mantle. A slight interaction between asthenosphere-derived magmas and lithospheric mantle took place during ascent to the surface. Subsequently, the most depleted mafic lavas of the ophiolite assemblage were contaminated by upper-crustal components (seawater or carbonate crust).     

Late Mesozoic Exhumation of the Huangling Massif: Constraints on the Evolution of the Middle Yangtze River

Plate subduction leads to complex exhumation processes on continents. The Huangling Massif lies at the northern margin of the South China Block. Whether the Huangling Massif was exhumed as a watershed of the middle reaches of the Paleo-Yangtze River during the Mesozoic remains under debate. We examined the exhumation history of the Huangling Massif based on six granite bedrock samples, using apatite fission track (AFT) and apatite and zircon (U-Th)/He (AHe and ZHe) thermochronology. These samples yielded ages of 157–132 Ma (ZHe), 119–106 Ma (AFT), and 114–72 Ma (AHe), respectively. Thermal modeling revealed that three phases of rapid cooling occurred during the Late Jurassic–Early Cretaceous, late Early Cretaceous, and Late Cretaceous. These exhumation processes led to the high topographic relief responsible for the emergence of the Huangling Massif. The integrated of our new data with published sedimentological records suggests that the Huangling Massif might have been the watershed of the middle reaches of the Paleo-Yangtze River since the Cretaceous. At that time, the rivers flowed westward into the Sichuan Basin and eastward into the Jianghan Basin. The subduction of the Pacific Plate beneath the Asian continent in the Mesozoic deeply influenced the geomorphic evolution of the South China Block.