基性-超基性岩浆成岩和成矿过程中Soret效应的研究进展

综述了当前对基性-超基性岩床和层状岩体的边缘反转现象的传统解释模型,包括围岩混染、岩浆多期注入、岩浆分层、过冷却、晶体沉降、流动分异、结晶和成分对流以及逐渐减少的颗粒间熔体量.详细论述了这些模型的优缺点,认为Soret效应是目前对边缘反转现象比较合适的解释,讨论了中国峨眉山大火成岩省朱布岩体的Soret成矿现象.     

北京西山房山岩体岩浆底辟构造及其地质意义

运用底辟构造的理论和模型, 通过对北京西山房山岩体边缘围岩构造、变形和应变的研究, 厘定出岩体边缘的高温剪切带、周缘向斜、呈穹状分布陡倾的线理和面理, 并结合对西山区域构造事件分析后提出房山岩体为典型的岩浆底辟构造(HotStokesDiapir).这项研究成果不仅在世界上首次证实了岩浆底辟的存在, 而且对理清北京西山地区的地质构造格架和演化序列具有十分重要的意义.研究认为房山地区可能不存在变质核杂岩; 房山岩体边缘的关坻太古宙杂岩是基底岩石随岩体底辟流动上升带到地壳上部的; 原先确定的一些印支期“剥离断层”是房山岩体岩浆底辟的刺穿构造或围岩高温剪切作用造成的地层缺失; 太平山和凤凰山等向斜是岩体底辟过程中在围岩拖曳下形成的周缘向斜.      

北山地区小狐狸山钼多金属矿床成矿类型及找矿方向

小狐狸山钼多金属矿床是近年来在北山地区发现的一个具中—大型规模的隐伏钼矿床. 该矿床成矿特征典型,赋矿岩体可以明显的划分为三个相带,即边缘相、过渡相和中心相。岩体中心相具强硅化、钾长石化现象,过渡相和边缘相具有明显的钠长石化蚀变特征,并叠加有岩浆期后云英岩化蚀变现象。钼矿体主要产于岩体过渡相和边缘相的钠长石化带和云英岩化带中。小狐狸山钼多金属矿床成矿时代为三叠纪, 属印支期构造-岩浆活动的产物。通过对Mo→Pb-Zn→稀有金属的复合矿化特征分析,推测该矿床可能是不同期次岩浆热液活动形成的热液叠加矿床。结合岩石地球化学、构造环境及其矿化、蚀变特征分析,该矿床应为板内伸展构造环境下形成的高-中温岩浆热液叠加型矿床。     

四川阿布郎当超镁铁质侵入体成岩机制的地球化学约束

阿布郎当超镁铁质侵入体位于扬子地台西缘,康滇地轴中段,安宁河深大断裂之西侧。该岩体呈似同心环状相带分布,基性程度很高,岩体的中心为含长橄榄岩,向外依次过渡为含长辉橄岩、辉橄岩及斜长辉橄岩,边缘带斜长橄辉岩。在岩体的边缘带附近存在明显的Cu-Ni-PGE矿化。随着近年来矿产价格的走高和国家对地质普查工作的力度加大,阿布郎当岩体又重新引起人们的关注。该岩体在地质勘探方面已经积累了丰富的资料,但在地球化学方面的研究还很薄弱。本文对阿布郎当超镁铁岩体进行了系统的主要造岩矿物成分、主量元素、微量元素及铂族元素含量的分析,讨论了该岩体的原始岩浆和地幔部分熔融程度,并对成岩过程进行了探讨。研究认为,阿布郎当超镁铁质岩属拉斑玄武岩系列,是峨眉山大火成岩省构造-岩浆活动产物,成岩原始岩浆为苦橄质岩浆,由类似于洋岛玄武岩岩浆源区成分的地幔经18%左右的部分熔融形成。在岩浆上升过程中,最先结晶的镁铁矿物由于岩浆的流动而集中于岩浆管道的中央,于是形成各种岩石的环带分布。当岩浆上升侵入阿布郎当岩浆房以后,发生了以橄榄石为代表的镁铁矿物的堆积,与此同时,岩浆在岩浆房内继续进行着结晶分异并且还可能与围岩发生了混染,导致岩体边缘相附近出现了硫化物的熔离。在后期的地壳运动中,阿布朗当岩浆房露出地表,即今天所见到的阿不朗当超镁铁质岩体。     

峨眉山大火成岩省朱布铜镍铂族硫化物矿床成矿作用:流体组成和C-Sr-Nd-Hf同位素的制约

<正>峨眉山大火成岩省的朱布镁铁—超镁铁质岩体由通道相边缘带和层状堆晶杂岩体序列组成,赋存有小型岩浆铜镍铂族硫化物矿床。Ni-Cu-PGE矿化主要以浸染状硫化物存在于边缘带及层状杂岩体底部,是认识通道成矿作用与岩浆就地结晶堆晶成矿作用的典型矿床。本研究通过岩浆矿物流体组成、C-Sr-Nd-Hf同     

存在初始“传导盖层”的月球岩浆洋演化与月壳成因

月球早期经历了岩浆洋阶段,岩浆洋的研究对认识月球内部构造有着重要意义。月球岩浆洋演化主导模型认为:岩浆洋结晶到80%左右,斜长石开始结晶,并上浮形成斜长岩月壳。该模型与观察事实存在两点矛盾:1)基于该模型计算结晶的斜长石An牌号比高地样品斜长石An牌号测试结果低;2)该模型散热速率计算指示岩浆洋在几个百万年时间内固化,而同位素体系对月球岩石样品定年结果表明月壳的结晶年龄十分古老,并且结晶区间跨越了270Myr,这与主导模型之间存在矛盾。以解决以上两点矛盾为目的,本文论证岩浆洋在演化之初硕部存在冷却"盖层",并将硅酸盐熔体在温度梯度下的热扩散效应引入岩浆洋演化模型。热扩散效应指均一的物质在温度梯度下发生分异的过程。本文工作模型是:由于月球的重力常数小,不能有效的保持大气,因此月球的岩浆洋表面温度很低。此时岩浆洋自上而下存在一个过渡的瞬态固化"盖层"(淬火层),岩浆洋自上而下存在温度梯度,岩浆洋在该梯度下发生热扩散效应(Soret效应),Soret效应导致上部结晶斜长石的熔体富Ca和贫Na,因此结晶的斜长石An牌号高。     

西藏曲水碰撞花岗岩的混合成因：来自成因矿物学证据

西藏曲水碰撞花岗岩地处冈底斯构造-岩浆带中部,呈东西向平行雅鲁藏布缝合带分布.该岩体以花岗闪长岩、石英闪长岩为主,其次为石英二长闪长岩.岩体内普遍发育微粒镁铁质包体.对花岗闪长岩、石英闪长岩及微粒镁铁质包体的成因矿物学研究结果显示：（1）斜长石发育环带且边缘和核部偏基性,幔部酸性;（2）斜长石斑晶边缘常含有角闪石、黑云母等暗色矿物包体;（3）钾长石X射线结构分析显示自核部向边缘温度呈现逐渐升高的特点;（4）长石矿物中普遍含有较高的Cr、Ni、Co元素,明显不同于壳熔花岗岩;（5）角闪石、黑云母矿物MgO含量高于典型壳熔花岗岩;（6）包体中发育针状磷灰石和角闪石,显示为岩浆淬冷的结果.上述特征不可能用正常岩浆分异作用来解释,而更可能是壳-幔岩浆混合作用的结果.采用矿物温压计所得到的结果也符合混合后的岩浆演化特征.     

就柿竹园钨多金属矿床与岩体的关系试论千里山花岗岩的成矿机制

千里山花岗岩为一单一岩浆作用旋回形成的复式岩体。对柿竹园矿床与千里山岩体关系的研究表明,本区主矿化发生在第一期花岗岩固结之后,而完成于第二期花岗岩就位之前。它们的这种关系显然不能用伴随源岩的多次熔融矿质逐步富集的复式岩体成矿机制或简单的岩浆结晶分异作用来解释。本文提出一种新的可能机制——“岩浆分异构造筛”机制。它对于解释单一岩浆族回复式岩体成矿也许是适宜的。     

福州闽侯长安闪长岩岩体的地球化学特征及其地质意义

为了解长安闪长岩岩体的形成与福州地区中生代岩浆活动的关系,对长安闪长岩岩体进行了岩相学和岩石地球化学特征研究,并与福州复式岩体进行了对比。发现长安闪长岩体呈岩株状分布于福州盆地西边缘,岩体的矿物组成主要为中性长石、角闪石、黑云母、石英,在岩体边缘具有少量的辉石。岩石地球化学特征为：（1）主量元素中SiO,为52．79％...     

镁铁质-超镁铁质层状岩体基本特征及岩浆作用

镁铁质-超镁铁质层状岩体可以产于多种构造环境,岩体具有典型的层状构造和韵律结构。层状岩体形成时主要的岩浆作用有重力分异作用、双扩散对流作用、压实作用、同化混染和岩浆混合作用等,其中重力分异作用很好地解释了层状岩体垂向上岩石类型的变化和矿物组分的变化,双扩散对流作用和岩浆混合作用在韵律层理形成过程中起了很重要的作用,而压实作用对岩浆演化晚期阶段补堆晶结构的形成作用明显,同化混染作用可改变岩浆的成分,导致岩浆分异产物的组成和成分的变化。堆晶结构的不同主要依赖于粒间液体的活动性和晶粥的渗透率,补堆晶结构形成需要高渗透率,而粒间液体不活动时将有利于正堆晶结构的形成。岩石组合、岩石结构、矿物组分及其变化规律很好地记录岩浆分异过程、岩浆补给等信息,可以用来讨论层状岩体的岩石成因：温度压力条件、原生岩浆及其演化过程等。     

The Origin of Marginal Compositional Reversals in Basic-Ultrabasic Sills and Layered Intrusions by Soret Fractionation

Marginal reversals—a common feature of many basic differentiatedigneous bodies regardless of their size and bulk composition—areremarkable in being a mirror of the Layered Series. These aredistinguished by: (1) an apparent lack of mass balance betweenthe lower part of the marginal reversals, including chilledmargins, and the bulk composition of the intrusions; (2) mineralcrystallization sequences and (3) mineral compositional trends,which are both essentially the opposite of those in the LayeredSeries; (4) the cotectic composition of rocks composing themarginal reversals; (5) the capacity to form from both phenocryst-richand phenocryst-free parental magmas; (6) the capability to developalong the floor, subvertical walls and even the roof of magmachambers. None of the current models of magma chamber evolutioncan provide an adequate explanation for the characteristic featuresof the marginal reversals. The problem can be resolved in thecontext of a model combining Soret diffusion in thin liquidboundary layers at the magma chamber margins and vigorous convectionin the main magma body. The key proposal is that the formationof marginal reversals takes place through the non-equilibriumevolution of liquid boundary layers as a result of a temperaturegradient imposed by the cold country rock. The fundamental explanationfor the mirror image of a marginal reversal is that the non-equilibriumSoret fractionation works in a manner opposite to that of theequilibrium crystal–liquid fractionation that producesthe Layered Series. KEY WORDS: marginal compositional reversals; sills; layered intrusions; Soret fractionation     

The Origin of Basic-Ultrabasic Sills with S-, D-, and I-shaped Compositional Profiles by in Situ Crystallization of a Single Input of Phenocryst-poor Parental Magma

An attempt is made to develop an in situ crystallization modelbased on the concept of Soret fractionation to explain the originof commonly observed S-, D-, and I-shaped compositional profilesin sills formed from a single pulse of phenocryst-poor parentalmagma. The model envisages that the various compositional profilesobserved in sills can be interpreted in terms of different combinationsof four principal units—Basal Zone and Layered Seriesforming the floor sequence, and Top Zone and Upper Border Seriesconstituting the roof sequence. The Basal and Top Zones representmirror images of the Layered and Upper Border Series, respectively,and therefore are referred to as basal and top reversals. Itis proposed that the formation of basal and top reversals takesplace through the non-equilibrium Soret differentiation of liquidboundary layers which form as a consequence of the temperaturegradient imposed by the cold country rock. In contrast, theLayered and Upper Border Series originate predominantly throughthe crystal–liquid boundary layers developing in equilibriumconditions. The model permits the production of S-, D-, andI-shaped compositional profiles from the same magma composition.All that is necessary to produce a specific shape of compositionalprofile is an appropriate temperature gradient imposed by thecold country rock on the liquid boundary layers of a parentalmagma of a given composition. KEY WORDS: sills; compositional profiles; in situ crystallization; Soret fractionation     

Chemical gradient at diffusive interfaces in magma chambers

The results of high pressure experiments on diffusion and Soret separation in natural silicate melts show that the diffusive behaviour between natural silicic and mafic magmas can be approximately modelled as if the system were a binary mixture of SiO₂ and other components such as MgO+FeO+CaO. Steady state compositional profiles across a diffusive interface between silicic and mafic magma layers are calculated on the basis of phenomenological relationships for the fluxes of chemical species and heat in the binary mixtures, using the experimental data of diffusion and Soret coefficients in natural silicate melts. The compositional profiles show a curvature with a minimum SiO₂ value within the interface due to the Soret effect and temperature dependence of diffusion coefficient. The compositional gradient at the lower half of the diffusive interface is similar to that resulting from the Soret separation of a mafic melt regardless of the composition of the silicic magmas. These results suggest that picritic magma can be formed in the interfacial region between the mafic and silicic magma layers. The compositional gradient explains chemical variation of mafic to picritic inclusions in a mixed andesite of the Abu Volcano Group, Japan.     

南太行山地区中基性侵入岩中角闪石的矿物学及其成因

角闪石作为南太行山地区中基性侵入岩中主要组成矿物,其详细的成因矿物学研究对了解该套岩石的形成机理具有重要意义。电子探针分析表明角闪石的成分变化很大如SiⅣ、AlⅣ和A位置上的Na和K离子,主要为韭闪石、韭闪石质普通角闪石、普通角闪石和阳起石质普通角闪石。且富镁和钙,为钙镁质角闪石。同时,不同岩石类型中的角闪石的组成无显著差异。大颗粒的核心部位形成于深部岩浆房中(18 ~25km),其组成的连续变化主要反映结晶深度的不同。角闪石的成因矿物学研究表明该套岩石不可能来源于华北古老的下地壳,而可能起源于新增生的下地壳和/或壳幔过渡带。     

第32届国际地质大会造山带和蛇绿岩研究进展

第32届国际地质大会反映了近年来造山带和蛇绿岩研究的最新成果。太古代与年轻造山带对比研究表明决定造山带几何特征的主要因素是它们与同造山及造山期后的伸展构造体制的响应方式。进一步分析了中新元古代罗得利亚超大陆的形成与裂解机理。分析了晚前寒武纪-古生代造山作用过程及可能模式。造山带形成后其深部表露、抬升和剥蚀过程与气候及环境演变有紧密的关系,是当前及今后地球科学的重要研究领域。蛇绿岩的岩浆成因并不能用一种简单的模式来解释,研究表明蛇绿岩岩浆具多成因。提出了蛇绿岩套的双离散侵位模式、多米诺旋转侵位模式、俯冲快速折返就位模式。对比表明特提斯及环太平洋蛇绿岩的来源、演化及就位特征具明显的多样性。     

西藏过铝花岗岩锆石群型的成因信息

锆石是西藏过铝花岗岩最重要的副矿物,为了探讨过铝花岗岩的成因,对西藏过铝花岗岩体中的锆石含量、晶体形态和群型分布特征进行了研究,结果表明,可明显分出5种锆石晶体形态;锆石主要在过铝环境条件下,岩浆结晶温度较低时形成,结晶范围为600～900℃,其中冈底斯带结晶温度高于喜马拉雅带。不同构造-岩浆带锆石群型特征反映的成因信息不同,喜马拉雅带为壳源成因,而冈底斯带除了壳源成因之外,还有幔源成分的加入,反映了青藏高原岩石圈组成和演化的不均一性。     

北京地区中元古代与中生代火山岩的酸度、系列、构造环境及岩浆成因

本文对北京地区中元古代及中生代火山岩的地质学、岩石学、矿物化学、地球化学、岩石成因学及构造环境学进行了综合研究。对火山岩的时空分布及成分变化进行了论述,对酸度频率及岩浆系列进行了分析,对构造环境及拉张距离进行了估算,对岩浆的来源及演化机理进行了探讨。     

Nature of mantle source contributions and the role of contamination and in situ crystallisation in the petrogenesis of Proterozoic mafic dykes and flood basalts Labrador

 Proterozoic tholeiitic dyke swarms share many compositional features with, and pose similar petrogenetic problems to, Phanerozoic continental flood basalts, but there are few extrusive equivalents of such swarms. The Mesoproterozoic (1.27 Ga) Harp dyke swarm in Labrador is one where possible extrusive equivalents exist in the Seal Lake group, but are slightly displaced in space and time, and can probably be related by models of progressive crustal extension. Here we try to evaluate the roles of crystal differentiation, in situ crystallisation, crustal assimilation and the relative contributions of asthenosphere- and lithosphere-derived melts in the petrogenesis of the mafic magmas. Modelling of the major and trace element variations both within individual dykes and between dykes, and within the lava sequence, does not suggest an important role for continental crust involvement. While in situ crystallisation processes could account for some of the compositional variations, the most successful models invoke mixing or contamination of asthenospheric magmas with/by veined material in the lower lithosphere / upper asthenosphere which carries the ‘continental’ characteristics. The results imply an important role for hydrous phases such as phlogopite and hornblende in the sub-lithosphere mantle. Much of the low-MgO character of mafic dykes may result from significant removal of mafic phases during in situ crystallisation within the lithosphere. Received: 15 May 1994/Accepted: 28 July 1995     

Means and Covariance Functions for Geostatistical Compositional Data: an Axiomatic Approach

This work focuses on the characterization of the central tendency of a sample of compositional data. It provides new results about theoretical properties of means and covariance functions for compositional data, with an axiomatic perspective. Original results that shed new light on geostatistical modeling of compositional data are presented. As a first result, it is shown that the weighted arithmetic mean is the only central tendency characteristic satisfying a small set of axioms, namely continuity, reflexivity, and marginal stability. Moreover, this set of axioms also implies that the weights must be identical for all parts of the composition. This result has deep consequences for spatial multivariate covariance modeling of compositional data. In a geostatistical setting, it is shown as a second result that the proportional model of covariance functions (i.e., the product of a covariance matrix and a single correlation function) is the only model that provides identical kriging weights for all components of the compositional data. As a consequence of these two results, the proportional model of covariance function is the only covariance model compatible with reflexivity and marginal stability.     

橄榄岩-熔体的相互作用:岩石圈地幔组成转变的重要方式

橄榄岩-熔体/岩浆的相互作用常被用来解释蛇绿岩套橄榄岩、造山带橄榄岩、超镁铁质侵入杂岩体、地幔橄榄岩捕虏体中某些具有不平衡结构和矿物组成的岩石的形成过程。橄榄岩-熔体的反应主要有两种方式,即消耗橄榄石(和单斜辉石)生成斜方辉石或消耗斜方辉石生成橄榄石(和单斜辉石)。反应的结果不仅造成矿物百分含量的变化,而且造成矿物组成的变化;后者更重要但未引起足够的重视。华北东部中生代玄武质岩石中具有环带状结构的橄榄石和辉石捕虏晶,特别是具有环带状结构的地幔橄榄岩捕虏体的发现,暗示这种橄榄岩-熔体的相互作用在华北东南部中生代岩石圈地幔中很可能普遍存在,为岩石圈地幔组成转变和快速富集的重要方式。这是全球首例由橄榄岩-熔体相互反应造成的岩石圈地幔大规模的组成变化。反应熔体来源途径主要有地壳来源和软流圈地幔来源。来源不同的熔体与橄榄岩的反应造成的组成变化完全不同。