磷灰石单晶体同步辐射X射线荧光探针成分分析

采用同步辐射X荧光（SRXRF）探针技术对河北峪耳崖和甘肃大水两地花岗岩中单颗粒磷灰石的化学成分进行了分析。结果显示，磷灰石含有P、Cl、S、K、Ca、Mn、Fe、La、Ce、Nd、Sm、Gd、Yb、Sr、Y、Zr、U、Th等多种元素，峪耳崖磷灰石富含Mn、Fe，大水磷灰石则富含As。峪耳崖花岗岩为S型，大水花岗岩为Ⅰ型，两地磷灰石在稀土元素（REE）含量上具有明显差别：大水磷灰石呈右倾的REE配分模式和明显的轻稀土（LREE）富集；而峪耳崖呈现上凸的REE配分模式和LREE亏损。依据磷灰石的REE配分模式可有效地区分不同类型的花岗岩，以此作为花岗岩岩浆演化的指示。     

福建将乐新路口花岗岩体地球化学特征、锆石U-Pb年龄及成矿意义

通过研究福建省将乐新路口花岗岩体岩石学、地球化学和同位素年代学特征,探讨了该岩体的形成时代、岩浆成因及与钨锡矿的成矿关系。新路口花岗岩体高硅,属于准铝质-过铝质花岗岩;富碱质,贫铁镁,Ba、Sr、P、Ti和Nb强烈亏损,球粒陨石标准化稀土元素配分模型为Eu强烈亏损的“海鸥型”,属于高分异S型花岗岩。Nd同位素研究表明,该花岗岩体主要源自地壳。LA-ICP-MS锆石U-Pb年龄结果表明,该岩体形成时代为147~145Ma,属晚侏罗世,钨锡矿的成矿时代也为晚侏罗世,是伸展构造环境下构造-岩浆活动的产物。经历新元古代和志留纪岩浆作用后形成富含钨锡的残留体,晚侏罗世岩浆热液活动对残留体再次熔融,形成富含硅、碱质及F的岩浆-热液,钨锡从残余矿物中迁移,聚集于岩浆房中,经过结晶分异,形成富含矿质的高分异岩浆,沿构造有利部位向浅部运移、结晶,形成钨锡矿体。     

新疆可可托海近3号脉花岗岩成岩时代及地球化学特征研究

可可托海伟晶岩田内花岗岩类发育。本文研究的花岗岩体位于3号伟晶岩脉矿坑的东部,岩性为似斑状黑云母二长花岗岩,野外特征与矿区北部的阿拉尔花岗岩非常相似。花岗岩中锆石LA-MC-ICP-MS U-Pb测年结果表明,19个测点206Pb/238U年龄集中于399.6～409.0Ma,加权平均年龄为405.4±1.4Ma(MSDW=0.98),属于早泥盆世,比阿拉尔花岗岩的侵入时期早得多,与3号伟晶岩脉没有成因上的联系,应是区域上岩浆活动最为强烈时期的产物。岩石具有富硅(SiO2=70.69%～73.81%)、富铝(Al2O3=14.00%～15.74%)、总体髙钾(K2O/Na2O≥1),贫Fe、Mg、Ti、P特点,铝饱和指数较高(A/CNK≥1.1),属于髙钾钙碱性强过铝质花岗岩;微量元素表现出Sr、Ti、Ba、P、Nb、Ta明显的负异常和Th、U、La、Zr、Hf的正异常特征。稀土配分型式显示LREE的相对弱富集,HREE比较平坦以及Eu中等负异常。样品中87Sr/86Sr(0.72259～0.72810)、143Nd/144Nd(0.51235～0.51237)接近于陆源沉积物,Sr初始值(0.70155～0.70341)较低,f Sm/Nd(-0.32～-0.26)、Sm/Nd(0.222～0.240)比值显示分异小、较均一的Sm/Nd同位素体系;εNd(t)值变化于-3.07～-2.16,模式年龄t2DM集中在1.35Ga左右,属于中元古代。综合研究岩石中主量、微量和稀土元素、同位素特征,同时对比区域上同期岩浆活动特征,认为本文研究的花岗岩可能是在活动大陆边缘环境下,强烈的俯冲-碰撞作用导致的地壳加厚引发了深熔作用,使阿尔泰微古陆边缘内部中元古代基底部分熔融,同时有幔源物质参与;随后岩浆经过结晶分异,最终上升侵位,反映了陆缘弧花岗岩的特点。     

五台山地区1.76 Ga辉石闪长岩的成因及其地质意义

五台山地区的黄金山辉石闪长岩侵入早元古代滹沱群中,同时又被早元古代末期辉绿岩脉穿切。辉石闪长岩锆石SHRIMP U-Pb定年结果为1 755±12 Ma,与华北克拉通广泛分布的基性岩墙群的时代相近。辉石闪长岩高TiO2、Fe2O3、P2O5、K2O和Na2O,低MgO(Mg#值为36~39)。稀土元素总量较高(365.75×10-6~411.97×10-6),轻重稀土元素分异强烈,其中轻稀土元素分异较明显,重稀土元素分异较弱,具有微弱的负铕异常。微量元素中,富集Rb、Ba、Sr、Zr和Hf,Cr、Ni含量低。(87Sr/86Sr)i和(143Nd/144Nd)i变化范围小,εNd(t=1.76 Ga)值为-6.08~-4.81。综合分析认为,黄金山辉石闪长岩为富集岩石圈地幔部分熔融后发生分离结晶形成的,与华北克拉通广泛分布的基性岩墙群具有相同的源区,可能代表华北南缘地幔柱活动时同一岩浆旋回不同阶段的岩浆侵位记录。辉石闪长岩中锆石具有岩浆成因锆石特征,但锆石的Th/U比值普遍较低,与变质锆石类似。辉石闪长岩中Th/U比值高,同时Th、U在斜长石、单斜辉石和角闪石中配分系数低。因此推测,低Th/U比值锆石的形成与原始岩浆和主要成岩矿物结晶无关,很可能与富含Th的副矿物结晶有关。辉石闪长岩中低Th/U比值岩浆锆石的出现表明,利用Th/U比值解释锆石成因和年龄结果意义时应慎重。     

萤石矿化的Sm—Nd直接测年法

业已证明，直接测定许多热液矿化类型的年龄是困难的，因而限制了人们对促使地壳流体流动和主要矿床形成的地质作用的了解。同一条脉体中热液矿物萤石在稀土元素丰度和Sm/Nd比值方面表现出了相当大的变化。我们对英格兰西南部以花岗岩为主岩的典型锡矿床中的萤石进行了Sm-Nd年龄测定，证明了Sm-Nd测年法是精确的矿化计时计。萤石中轻稀土元素含量有着相当大的变化，而且认为富轻稀土元素矿物相的同时沉淀可能是引起Sm/Nd比值变化的原因。     

滇西点仓山构造带新生代岩浆活动及其构造意义

点苍山构造带是哀牢山-金沙江大型走滑构造带的重要组成部分。构造带内新生代花岗岩以发生糜棱岩化韧性变形和含有富铝含水矿物-黑云母和白云母为特征。锆石LA-ICP-MS U-Pb定年结果表明花岗岩和混合岩化花岗岩脉的形成时代分别为27.9±0.7Ma、28.5±0.5Ma和34.8±0.4Ma,样品11QDC-34中3个点206Pb/238U年龄22~24Ma是对后期叠加构造变形变质作用的响应。岩石地球化学分析结果表明花岗岩具有高硅(SiO270.95%)、富碱(Na2O+K2O=7.16%~8.44%)、高钾(Na2O/K2O1.0)、富铝(Al2O313.48%,A/CNK多大于1.1)的S型花岗岩岩石学特征。花岗岩LREE/HREE比值变化较大,δEu在0.13~0.75之间,以及在微量元素蛛网图上展示出的大离子亲石元素(LILE)Rb和K,放射性生热元素Th和U及亲岩浆元素Ce、La、Zr和Hf相对原始地幔强烈富集,高场强元素(HSFE)Nb、P、Ti、Sr和LILE中的Ba表现出明显的负异常,以及在Th/Yb-Ba/La和Th/Yb-Sr/Nd判别图解中,样品沿沉积岩熔融体演化趋势线分布,在Rb/Ba-Rb/Sr图解中分布于页岩和砂岩部分熔融区,揭示其岩浆来源于壳源物质低度部分熔融的产物。构造带中花岗岩体(脉)普遍发生不同程度糜棱岩化韧性变形、同一岩体不同部位糜棱岩化程度存在较大差异及锆石结晶温度远高于糜棱岩的角闪岩相变质温度说明点苍山深变质带大规模韧性走滑剪切作用发生于28Ma之后。     

壳幔作用导致武平花岗岩形成——Sr-Nd-Hf-U-Pb同位素证据

岩石学、元素地球化学和Sr-Nd-Hf-U-Pb同位素的综合研究显示,武平花岗质杂岩体是由形成时代和成因不同的黑云母花岗岩和含石榴子石花岗岩组成。LA-ICPMS锆石U-Pb定年指示前者形成于161．4 Ma,后者形成于113 Ma。黑云母花岗岩以中等富集大多数不相容元素和中等轻重稀土分异为特征,岩石具有低的87Sr／86Sr初始比值(<0．710)和高的εNd(t) 值(-2．6--5．7)。结合与附近基底变质岩的同位素对比,论文指出黑云母花岗岩岩浆是由元古代基底变质岩部分熔融产生的熔体与幔源岩浆的强烈混合形成。不均匀的锆石Hf同位素组成(εHf(t)=-3．6--10．8)支持了这种混合成因模式。含石榴子石花岗岩以富Si、Al、Na、K、Nb、Ta、Y和HREE而贫P、Sr、Ba、LREE、Zr和Hf含量为特征,它们具有低的(La/Yb)n, Zr／Hf、Nb／Ta比值和高的Rb／Sr比值,显示了强烈的以斜长石为主的分异特征;它们的87Sr／86Sr初始比值大于0．710,εNd(t) =-7．1,锆石的Hf同位素较低且相对均匀(εHf(t)平均值为-9．7),表明岩浆没有受到明显的地幔组分混染。结合它们高的HREE含量,论文指出它们的母岩浆很可能是由早期熔融事件的富石榴子石残留相再次熔融形成。因此,南岭地区中生代花岗岩的地球化学差异很可能反映了岩浆形成过程中壳幔作用的强弱。     

乳山金矿煌斑岩的Sm-Nd同位素研究

乳山金矿区发育多种与金矿脉在时空上密切伴生的煌斑岩脉。煌斑岩的稀土元素含量和配分曲线与胶东群残留体和昆嵛山花岗岩的均较相似；三者的εNd(t)、INd(t)和tDM亦甚为相近。胶东群的分异熔融作用，可较好地解释煌斑岩与花岗岩和胶东群残留体在成因上的渊源关系。     

湘南多金属矿集区燕山期成矿花岗岩的稀土地球化学特征和成岩成矿作用探讨

湘南燕山期成矿花岗岩可划分为3种类型。3种类型成矿花岗岩具有不同的稀土地球化学特征、配分型式和成分变异特征,反映出成矿花岗岩的成岩成矿作用有明显的差别。①MC型花岗岩的∑REE最低,平均为225×10-6;La/Yb比值平均为17、LREE/HREE比值平均为5.4和δEu为1.67,都为最高,稀土配分曲线呈右倾斜的近直线。C型花岗岩的ΣREE最高,平均为353×10-6;La/Yb比值平均为4.3,δEu平均为0.14,LREE/HREE比值平均为1.5,都为最小,稀土配分曲线呈海鸥型。CM型花岗岩总体上介于上述两类花岗岩之间,∑REE变化较大,早期次单元配分曲线呈右倾斜的近直线,晚期次单元配分曲线呈海鸥型。②3种类型成矿花岗岩从MC型-CM型-C型花岗岩以及从同一类型花岗岩的早期次单元至晚期次单元,随岩石酸性程度增高,稀土总量和稀土元素分量总体增高,但轻稀土相对亏损,重稀土相对富集,δEu、La/Yb比值、LREE/HREE比值与SiO2的含量存在较明显的负消长演化关系,重稀土元素则随岩浆演化具逆向演化分异性。③CM型花岗岩晚期次单元与C型花岗岩的稀土元素分馏明显,配分曲线铕谷深,显示经历了较强的分离结晶作用;并导致重稀土元素相对富集,常与Sn、W、Nb、Pb富集成矿。④成矿花岗岩显示富含F、C1等挥发组分的壳幔源熔体混合型花岗岩类的特点,其形成与壳幔岩浆混合作用有关,而CM型花岗岩晚期次的花岗岩类和C型花岗岩类的岩浆演化可能还存在分离结晶作用。     

江西赣州淘锡坑钨矿床稀土地球化学研究

淘锡坑钨矿床是赣南地区典型的云英岩型黑钨矿矿床。本文重点研究震旦系浅变质砂板岩围岩、成矿花岗岩及含矿云英岩、石英脉稀土元素地球化学特征,通过对岩石化学组成、稀土元素配分模式及特征值LREE/HREE-REE、δEu-LREE/HREE相关性的分析,对比现代海相、陆相沉积物稀土元素组成特点,确定震旦系浅变质砂板岩原岩为浅海相陆源沉积岩;成矿花岗岩属于陆壳熔融成因花岗岩;含矿云英岩、石英脉及成矿物质属于岩浆期后热液产物。     

诸广山南体桃金洞花岗岩成因和铀成矿潜力探讨

文中对位于湘赣粤三省交界处的诸广山南体桃金洞花岗岩进行了锆石U-Pb年代学和岩石地球化学的研究,并将其与诸广山南体东部其他印支期非产铀和产铀花岗岩进行了对比。LA-ICP-MS锆石U-Pb年龄为204±2.1 Ma,为印支晚期岩浆活动的产物。岩石地球化学组成呈过铝质,硅和碱含量偏高(Si O_2=69.7%~75.0%,K_2O+Na_2O=7.74%~9.08%),富铁、贫镁,属于碱钙性/钙碱性-过铝质-铁质花岗岩。稀土元素总量较高(∑REE=226~272×10~(-6)),LREE富集(LREE/HREE=6.27~11.4,(La/Yb)_N=4.01~15.0),Eu亏损较明显(δEu=0.15~0.42),富集Rb、Th和U,亏损Ba、Sr、Ti和Eu,属于典型的低Ba、Sr花岗岩;(~(87)Sr/~(86)Sr)i值较高(0.71922~0.72040),εNd(t)值较低(-10.0~-10.2),两阶段Nd模式年龄为1.80~1.82 Ga。上述特征表明,桃金洞花岗岩属于典型的壳源型花岗岩,是在地壳伸展-减薄构造背景下,由古元古代地壳岩石演变而成的变质杂砂岩组分岩石经中低程度部分熔融形成。对比研究显示,诸广山南体印支期产铀花岗岩蚀变作用强,FeO~T/(Fe O~T+MgO)比值变化较大,CaO含量低,主要为碱钙性花岗岩,Ba、Sr、Ti和Eu亏损更强烈,ε_(Nd)(t)值更低和Nd模式年龄更古老。非产铀花岗岩源岩以砂质岩为主,U含量相对较低。桃金洞花岗岩未经后期明显热液蚀变作用,不具有产铀花岗岩蚀变强烈的特点,地球化学特征相似于诸广山南体印支期非产铀花岗岩,铀成矿潜力可能不大。     

赣南白面石铀矿区花岗岩的锆石年代学、地球化学及成因研究

赣南白面石铀矿区花岗岩的锆石年代学、 地球化学及成因研究     

南岭地区钨锡铌钽花岗岩及其成矿作用

在晚侏罗世时,南岭地区发生了与花岗岩有关的钨锡铌钽大规模成矿作用。依据花岗岩的岩石学、地球化学及其矿化特征,可将南岭地区含钨锡铌钽花岗岩划分为三个主要类型：含钨花岗岩、含锡钨花岗岩和含钽铌花岗岩。含钨花岗岩的地球化学特征可归纳为铝过饱和,低Ba+Sr 和TiO2,轻重稀土比值低,铕亏损强烈,富Y 和Rb,Rb/Sr 比值高,分异强烈。含锡钨花岗岩总体特征表现为TiO2 含量高,准铝质—弱过铝质,轻重稀土比值和CaO/(K2O+Na2O)比值高,富高场强元素、稀土、Ba+Sr 和Rb,低Rb/Sr 比值,分异演化程度较低。含钽铌花岗岩的地球化学特征主要为TiO2 含量和CaO/(K2O+Na2O)比值低,Al2O3/TiO2 和Rb/Sr 比值明显偏高,强过铝质,贫Ba+Sr、稀土和高场强元素,铕亏损强烈,明显富Rb 和Nb,高度分异演化。三类含矿花岗岩具有明显不同的演化特征,成矿作用与它们的演化密切相关。黑云母花岗岩主要与锡成矿作用有关,二云母花岗岩和白云母花岗岩主要产生钨矿化或锡钨共生矿化,钠长石花岗岩主要与钽铌或锡（钨）钽铌矿化有关。总结了南岭锡钨钽铌矿床的重要类型,提出了绿泥石化花岗岩型锡矿新类型,指出南岭地区要特别注意在含锡钨花岗岩中寻找此类锡矿和云英岩- 石英脉型锡钨矿。     

东天山阿拉塔格花岗岩体地球化学特征及其构造意义

位于中天山地块南缘大黑山地区的阿拉塔格花岗岩体,岩性主要由花岗闪长岩、二长花岗岩、似斑状花岗岩组成,岩石具有高硅(w（SiO₂）为66.29%~77.47%)、富碱(w（Na₂O+K₂O）为6.75%~9.93%)、高铝(w（Al₂O₃）为10.97%~14.40%)、低Sr(w（Sr）为（28.78~153.00）×10^-6,平均为99.23×10^-6)、低Ti（w（TiO₂）为0.09％~0.77％）的特征。岩石的A/CNK值为1.19~1.50,为钙碱性过铝质岩石;岩石Eu亏损（δEu＝0.19~0.51）、LREE富集(LREE/HREE= 6.80~8.45,(La/Yb)_N= 6.06~9.03),明显富集Rb、Th、K、Hf(Zr) 等大离子亲石元素(LILE),亏损Nb、Ta、P、Ti等高场强元素(HFSE);岩石的Ba含量较低,并具有明显的Sr负异常。结合区域地质特征,通过岩石的地球化学和Sr、Nd同位素综合分析,认为该花岗岩形成于后碰撞环境,且为壳幔混源的岩浆多期次侵位的复合岩体。     

西藏南部岗巴—定日地区花岗岩地球化学特征及其构造环境

通过对出露于西藏南部岗巴—定日地区花岗岩体的地球化学研究表明,岩石中SiO2,Al2O3,Na2O和FeO,MgO等的含量均高,贫CaO和Fe2O3;w(SiO2)介于71.40%～73.06%,A/CNK在1.17～1.34之间,为铝和硅过饱和类型的强过铝质花岗岩。岩石的稀土元素总量(ΣREE)为56.80×10-6～89.12×10-6,(La/Yb)N=6.30～18.26,(La/Sm)N=2.62～3.40,ΣLREE/ΣHREE=2.41～4.66;稀土元素配分曲线呈右倾型,具有弱的负铕异常。Nb,Ti等高场强元素具有明显的亏损,而Rb,U,La,Nd,Hf,Eu,Y等大离子亲石元素具有明显的正异常。岩石的87Sr/86Sr初始比值较高,87Sr/86Sr为(0.738 71～0.751 12)。综合研究认为,本区花岗岩的成因为陆壳部分熔融作用形成的,属陆壳改造型强过铝质花岗岩。本区花岗岩岩浆源区岩石成分主要为砂屑岩,其次为泥质岩,是上地壳部分熔融作用的结果。岩石的微量元素标准化曲线图、岩石地R1-R2图解、Rb-(Yb+Ta)和Rb-(Nb+Yb)图解均显示本区岩体形成于同碰撞构造环境的花岗岩,具有同碰撞岩浆活动的特征,是喜马拉雅早期印度板块与冈底斯板块的俯冲碰撞导致的地壳增厚,上地壳部分熔融的产物;为形成于同碰撞构造环境的花岗岩。     

Reconstruction of phosphate formation environments (from data on distribution of lanthanides)

The criteria for the evaluation of the REE composition of phosphorites and sedimentary rocks have been determined. These data are required to reconstruct depositional environments. Literature data on the geochemistry of some phosphorite deposits of Eurasia are considered. The REE patterns of Mesozoic phosphorites of the East European Platform are studied. On the basis of REE contents, the ratios of lanthanides and fields on the La–(Nd + Sm)–(Y + Dy), La–(Ce + Nd + Sm)–(Y + Dy), and LREE–MREE–(HREE×10) diagrams have been determined as indicators of climate and the depth and facies conditions of sedimentation.     

Geochemistry of the Granites in the Tamuqi Area on Southern Margin of Tarim Block

This study shows that the intrusive rocks distributed in the Aoyiqieke-Tamuqi area on the southern margin of the Tarim Block are composed of gabbro, diorite, granodiorite and granite, which constitute regionally a nearly EW-trending tectono-magmatic belt. Petrochemically the diorite, granodiorite and granite belong to the calc-alkaline, high-K series, with Na₂O/K₂O ratios varying between 0.83 and 2.63. M/F ratios in the diorite are within the range of 0.44–0.70 and those of the granodiorite ( granite) are 0.45–0.87. Petrochemistry data show that the intrusive complexes are of the I type and their ΣREE is slightly variable, within the range of 178.31–229.01 × 10⁻⁶. The LREE/HREE ratios of the diorite and granite are 3.78–5.13 and 6.69–7.66, respectively. The plutons usually show moderate negative Eu anomalies with δEu values ranging from 0.53 to 0.82, showing almost no difference among different rocks. The (La/Yb)_N values of diorite and granite are 12.39−14.86 and 22.07−26.03, respectively. The diorite and granite possess very similar REE distribution patterns, indicating that they were both derived from the same source. As for their trace element ratios, the diorite has higher Nb/Ta ratios than the granite, which are 15.73−17.16 and 12.03−15.01, respectively. It can be seen that the Nb/Ta ratios of the diorite are much closer to the average mantle (17.5). Their Zr/Hf ratios are very close to each other, within the range of 29−34. Th/Y ratios in the diorite are 0.42−0.80 (all less than unity) while those of the granite are 1.02−2.04. Some difference is also noticed in Ti/V between the diorite and the granite (52.6−54.2 for the former and 52.6−54.2 for the latter). As compared with ocean ridge granites, both diorite and granite are characterized by remarkable LILE enrichment, as well as by moderate negative Ba and postive Ce anomalies. The contents of Nb and Ta in the diorite and granite are equivalent to those of the ocean ridge granites, but the contents of Zr, Hf, Sm, Y, and Yb are all lower than those of the ocean ridge granites, indicating that these granites are similar to the island-arc granites of Chile. From their geochemical characteristics, it is considered that the intrusive rocks in the area studied were formed in an island-arc environment at the continental margin.     

Petrogenesis of Peraluminous Granites, Monashee Mountains, Southeastern Canadian Cordillera

Two-mica granites that locally contain garnet and sillimaniteoccur as dikes, sills, and sheets up to 50 m thick within thesillimanite zonc of the Monashee Mountains in the southeasternCanadian Cordillera of British Columbia. Syn-kinematic and post-kinematicgranites are recognized. U-Pb dating of zircon demonstrates that the syn-kinematic granitesare 100.4?0.3 Ma old, based on duplicate concordant single abradedzircon analyses. Other zircons have slightly older Pb/Pb dates,indicating small amounts of inherited zircons. Monazites are99?10 Ma old. Post-kinematic granites have 62.5?0.2 Ma zirconages and 634+0.1 Ma monazite ages. High initial 87 ratios (0.71492–0.74181)and evidence of Precambrian Pb inheritance indicates that bothsyn- and post-kinematic granites were derived from a crustalsource. Geobarometric estimates suggest that both generationsof granites equilibrated at 6–8 kb (22–30 km). Zirconand monazite saturation temperatures range from 660–824?Cand indicate that these minerals were liquidus phases earlyin the crystallization history of the granites. Because monazitesaturation temperatures generally exceed those of zircon, itis possible that some monazites may be inherited. Apatite saturationtemperatures in excess of 900?C suggest that both generationsof granites contain source inherited apatite. Syn- and post-kinematic granites have essentially identicalmajor and trace element chemistries. Syn-kinematic graniteshave steep light rare earth element (LREE) enriched patternswith pronounced negative Eu anomalies. The REE patterns of post-kinematicgranites range from steep LREE enriched patterns with negativeNd and Eu anomalies to flat patterns with low LREE contents,negative Nd anomalies, and both positive and negative Eu anomalies.Modelling of REE, Rb, Sr, and Ba contents demonstrates thatsyn-kinematic gramtes could have been generated by a low degreeof partial melting (with 10–25% feldspar fractionationof the melt) of Late Proterozoic Horsethief Creek Group metapelitesleaving a monazite-bearing upper amphibolite facies residue.Post-kinematic granites were produced by partial melting ofa geochemically and isotopically similar metapelitic source.The suite of post-kinematic granites can be related by a smallamount (up to 0.1%) of monazite crystal fractionation.     

粤北桃村坝花岗岩锆石U-Pb年代学、地球化学及成因研究

桃村坝花岗岩体位于粤北贵东复式花岗岩体中部。锆石U-Pb年龄为161.5±1.8 Ma (MSWD=1.7),属于燕山早期岩浆 活动产物。该岩体具有稍低的硅、富铝、富碱、钾大于钠、贫钙镁和高FeO*/MgO等特征。富集Rb,Th,U而亏损Ba, Sr,Ti和Nb;LREE富集(LREE/HREE=7.39~16.4, (La/Yb)N=8.79~25.5),Eu亏损较为明显(δEu=0.44~0.59);Ga/Al比值较高(平 均值为2.99),Zr+Nb+Ce+Y含量(平均为518×10-6)大于350×10-6,可归属于A2型花岗岩;εNd(t)值低,为-9.7~-8.95,Nd模式 年龄为1.66~1.76 Ga;锆石的εHf(t)值为-20.0~-14.6,相应的Hf模式年龄为2.12~2.46 Ga。综合以上特征表明桃村坝花岗岩是 在地壳伸展-减薄的构造背景下、由古元古代地壳组分部分熔融的方式形成。     

REE Geochemistry and Mineralization Characteristics of the Zudong and Guanxi Granites,Jiangxi Province

Abstract The Zudong and Guanxi granites are original rocks of the ion adsorption-type HREE and LREE deposits in weathering crust of granites. The ∑REE ¹ ∑REE=REE+Y.
value and LREE ² LREE=∑(La-Eu) and HREE=∑(Gd-Lu)+Y.
/ HREE ratio of the Zudong granite are 264 ppm and 0.81-0.24 respectively, and the average Y/∑REE ratio is 35.8-54.5%. This is mainly due to magmatic crystallization and evolution and deuteric metasomatism (albitization, muscovitization and fluorite-doveritization). These alterations resulted in endogenic mineralizations of yttrium-group REE fluorine carbonates, silicates and arsenates. The Guanxi granite is characterized by LREE enrichment (the average LREE/HREE ratio is 2.43).