Diffuse interstellar bands in low E (B – V) objects

We analyse spectra of slightly reddened, early-type stars in which the major diffuse interstellar bands at 5870 and 5797 Å are either strong or weak in relation to E(B – V) . It is demonstrated that among the low E(B – V) objects one can find stars obscured by 'sigma' as well as 'zeta' type clouds. The profiles of the diffuse bands seem not to be dependent on the total opacities of the interstellar clouds. We also discuss the physical conditions leading to the formation of the diffuse band carriers in low-opacity interstellar clouds; the carriers are apparently formed in media in which one can observe complex velocity fields.     

Probing the surfaces of interstellar dust grains: the adsorption of CO at bare grain surfaces

A solid-state feature was detected at around 2175 cm⁻¹ towards 30 embedded young stellar objects in spectra obtained using the Infrared Spectrometer and Array Camera at the European Southern Observatory Very Large Telescope. We present results from laboratory studies of CO adsorbed at the surface of zeolite wafers, where absorption bands were detected at 2177 and 2168 cm⁻¹ (corresponding to CO chemisorbed at the zeolite surface) and 2130 cm⁻¹ (corresponding to CO physisorbed at the zeolite surface), providing an excellent match to the observational data. We propose that the main carrier of the 2175-band is CO chemisorbed at bare surfaces of dust grains in the interstellar medium. This result provides the first direct evidence that gas–surface interactions do not have to result in the formation of ice mantles on interstellar dust. The strength of the 2175-band is estimated to be  ∼4 × 10⁻¹⁹ cm  molecule⁻¹. The abundance of CO adsorbed at bare grain surfaces ranges from 0.06 to 0.16 relative to H₂O ice, which is, at most, half of the abundance (relative to H₂O ice) of CO residing in H₂O-dominated ice environments. These findings imply that interstellar grains have a large (catalytically active) surface area, providing a refuge for interstellar species. Consequently, the potential exists for heterogeneous chemistry to occur involving CO molecules in unique surface chemistry pathways not currently considered in gas grain models of the interstellar medium.     

Far-ultraviolet extinction and diffuse interstellar bands

We relate the equivalent widths of the major diffuse interstellar bands (DIBs) near 5797 and 5780 Å with different colour excesses, normalized by E ( B − V ) , which characterize the growth of interstellar extinction in different wavelength ranges. It is demonstrated that the two DIBs correlate best with different parts of the extinction curve, and the ratio of these diffuse bands is best correlated with the far-ultraviolet (UV) rise. A number of peculiar lines of sight are also found, indicating that the carriers of some DIBs and the far-UV extinction can be separated in certain environments, e.g. towards the Per OB2 association.     

Limited diversity of the interstellar extinction law

We have applied the method of investigating extinction curves using statistically meaningful samples that was proposed by us 25 years ago. The extensive data sets of the ANS (Astronomical Netherlands Satellite) and 2MASS (Two Micron All Sky Survey) were used, together with UBV photometry to create average extinction curves for samples of OB stars. Our results demonstrate that in the vast majority of cases the extinction curves are very close to the mean galactic extinction curve. Only a few objects were found to be obviously discrepant from the average. The latter phenomenon may be related to nitrogen chemistry in translucent interstellar clouds (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

On the identification of the C60+ interstellar features

The identity of the carriers of the diffuse interstellar bands (DIBs) is one of the most fascinating puzzles of modern spectroscopy. Over the last few years the number of known DIBs has grown substantially. In this paper we discuss the two recently discovered near-infrared weak interstellar features which have already been proposed as fingerprints of the buckminsterfullerene We present and discuss measurements of the two related DIBs within a larger sample of reddened targets, observed with different spectrometers, telescopes and site conditions. We provide additional arguments in favour of the interstellar origin of the two bands. We find evidence around the 9577-Å DIB of far-wing structures, which may affect broad-band measurements. We estimate corrections and errors for telluric and stellar blends, and show that the cores of the two DIBs are well correlated with a ratio near unity within 20 per cent. Finally, we discuss their relation to the laboratory spectra of and the search for two expected weaker transitions.     

Radiative transfer in disc galaxies – II. The influence of scattering and geometry on the attenuation curve

We investigate the influence of scattering and geometry on the attenuation curve in disc galaxies. We investigate both qualitatively and quantitatively which errors are made by either neglecting or approximating scattering, and which uncertainties are introduced as a result of a simplification of the star–dust geometry. We find that the magnitude of these errors depends on the inclination of the galaxy and, in particular, that, for face-on galaxies, the errors due to improper treatment of scattering dominate those due to imprecise star–dust geometry. Therefore we argue that, in all methods aimed at determining the opacity of disc galaxies, scattering should be taken into account in a proper way.     

The role of the geometry and dust environment in stationary models of translucent interstellar clouds

A full radiative transfer model is presented for the ultraviolet (UV) radiation impinging on an interstellar cloud of spherical or finite plane-parallel slab geometry containing gas and dust. The penetration of the UV photons is coupled to detailed chemical processes. Photodestruction rates of atomic and molecular species are calculated from the corresponding cross-sections. We show that CO line intensities are quite sensitive to geometrical effects and to the extinction curve in the far-UV.     

Correlation patterns between 11 diffuse interstellar bands and ultraviolet extinction

We relate the equivalent widths of 11 diffuse interstellar bands, measured in the spectra of 49 stars, to different colour excesses in the ultraviolet. We find that most of the observed bands correlate positively with the extinction in the neighbourhood of the 2175-Å  bump. Correlation with colour excesses in other parts of the extinction curve is more variable from one diffuse interstellar band to another; we find that some diffuse bands (5797, 5850 and 6376 Å) correlate positively with the overall slope of the extinction curve, while others (5780 and 6284 Å) exhibit negative correlation. We discuss the implications of these results on the links between the diffuse interstellar band carriers and the properties of the interstellar grains.     

A GLIMPSE of new and possible planetary nebulae at mid-infrared wavelengths

We have undertaken a mid-infrared (MIR) search for new planetary nebulae (PNe) using the Spitzer Space Telescope GLIMPSE Galactic plane survey. This has involved searching extant GLIMPSE data products for morphologically appropriate structures, and investigating sources having IRAS colours similar to those of Galactic PNe. We have found 12 sources which have a high probability of being high-extinction PNe, and which possess MIR and IRAS colours, and shell morphologies similar to those of previously identified Galactic nebulae. Calibrated mapping of these structures and profiles in all four of the IRAC bands (3.6, 4.5, 5.8 and  8.0 μm  ) suggests that many (if not all) of the nebulae possess at least two primary structures: an interior high surface brightness shell, corresponding to what is probably the primary ionized zone, and a much weaker halo extending to very much greater distances from the nucleus. These latter regimes are particularly evident at longer MIR wavelengths (5.8 and  8.0 μm  ), and it is probable that they trace the nebular photodissociative regimes, where emission derives from small-grain continua and/or polycyclic aromatic hydrocarbon molecular bands. This latter behaviour has also been noted in previous analyses of Galactic PNe.     

Desorption from interstellar ices

The desorption of molecular species from ice mantles back into the gas phase in molecular clouds results from a variety of very poorly understood processes. We have investigated three mechanisms: desorption resulting from H₂ formation on grains, direct cosmic ray heating and cosmic ray-induced photodesorption. Whilst qualitative differences exist between these processes (essentially deriving from the assumptions concerning the species selectivity of the desorption and the assumed threshold adsorption energies, E _t), all the three processes are found to be potentially very significant in dark cloud conditions. It is therefore important that all three mechanisms should be considered in studies of molecular clouds in which freeze-out and desorption are believed to be important.
Employing a chemical model of a typical static molecular core and using likely estimates for the quantum yields of the three processes, we find that desorption by H₂ formation probably dominates over the other two mechanisms. However, the physics of the desorption processes and the nature of the dust grains and ice mantles are very poorly constrained. We therefore conclude that the best approach is to set empirical constraints on the desorption, based on observed molecular depletions – rather than try to establish the desorption efficiencies from purely theoretical considerations. Applying this method to one such object (L16 89B) yields upper limits to the desorption efficiencies that are consistent with our understanding of these mechanisms.     

The coronal line regions of planetary nebulae NGC 6302 and 6537: 3–13 μm grating and echelle spectroscopy

We report on advances in the study of the cores of NGC 6302 and 6537 using infrared grating and echelle spectroscopy. In NGC 6302, emission lines from species spanning a large range of ionization potential, and in particular [Si  ix ] 3.934 μm, are interpreted using photoionization models (including cloudy ), which allow us to re-estimate the temperature of the central star to be about 250 000 K. All of the detected lines are consistent with this value, except for [Al  v ] and [Al  vi ]. Aluminium is found to be depleted to one hundredth of the solar abundance, which provides further evidence for some dust being mixed with the highly ionized gas (with photons harder than 154 eV). A similar depletion pattern is observed in NGC 6537. Echelle spectroscopy of IR coronal ions in NGC 6302 reveals a stratified structure in ionization potential, which confirms photoionization to be the dominant ionization mechanism. The lines are narrow (<22 km s⁻¹ FWHM), with no evidence of the broad wings found in optical lines from species with similar ionization potentials, such as [Ne  v ] 3426 Å. We note the absence of a hot bubble, or a wind-blown bipolar cavity filled with a hot plasma, at least on 1 arcsec and 10 km s⁻¹ scales. The systemic heliocentric velocities for NGC 6302 and 6537, measured from the echelle spectra of IR recombination lines, are found to be −34.8±1 km s⁻¹ and −17.8±3 km s⁻¹. We also provide accurate new wavelengths for several of the infrared coronal lines observed with the echelle.