Facies in an Upper Permian volcanic succession,Emmaville Volcanics,Deepwater, northeastern New South Wales

The Upper Permian Emmaville Volcanics at Deepwater, northeastern New South Wales, consist of a diverse succession of calc‐alkaline silicic‐intermediate ignimbrites, volcaniclastics and minor lavas. This 2.5 km‐thick sequence underlies and outcrops extensively along the northern margin of the Dundee Rhyodacite Outlier at Dundee. Detailed mapping and facies analysis have revealed eight locally mappable units namely; Magistrate Volcanic Member (rhyolitic ignimbrites), Wollundi Mudstone Member, Dellwood Ignimbrite Member, Marrawarra Rhyolite Member, Top‐Crossing Sandstone Member, Arranmor Ignimbrite Member, Yarramundi Andesite Member (lava, breccia) and Welcome Volcanic Member (rhyolitic ignimbrites). All volcanic units are contained in two fault‐bounded blocks of different lithology and structure. The volcanic succession ranges in composition from andesite to high‐silica rhyolite (58.6–78% SiO₂). Chemical characteristics include enrichment in K₂O (>3.5%), Al₂O₃ and large‐ion lithophile elements (LILE: Rb, K and light rare‐earth elements (LREE)), and depletion in high field strength elements (HFSE: Ti, Nb and Zr). These geochemical attributes reflect a continental subduction‐related signature. The facies architecture indicates that the principal volcanic features of the Late Permian palaeogeography in northeastern New South Wales was a topographically subdued depression flanked by low‐angle ignimbrite sheets with rhyolitic‐intermediate volcanic centres rising gently from the sloping terrain. The succession demonstrates that during the Late Permian andesitic volcanism was present, although localised. A modern analogue for the setting of the Emmaville Volcanics is the Quaternary Taupo Volcanic Zone (New Zealand).     

内蒙古正蓝旗地区中生代火山岩锆石U-Pb年龄与板内伸展环境成因讨论

内蒙古东南部正蓝旗地区中生代火山岩广泛出露,岩性主要包括流纹岩、粗面岩、碎斑熔岩、熔结凝灰岩以及黑曜岩等,以碎斑熔岩发育为显著特征。本次研究测得流纹岩、霏细质碎斑熔岩及熔结凝灰岩的LA-ICP-MS锆石U-Pb年龄分别为(141.4±0.7)Ma、(141.6±0.6)Ma和(139.4±0.7)Ma,三者在误差范围内一致,表明研究区火山活动(从溢流、爆发到侵出)持续的时间很短,时代为早白垩世早期,属张家口组。除个别样品,正蓝旗地区晚期侵出的碎斑熔岩与早期溢流相的流纹岩、粗面岩在地球化学特征上极为一致,均为富硅富钾,贫Ca、Mg和Al,属粗面岩-流纹岩组合,部分样品具有碱性流纹岩的特征;富集Rb、Th、U等大离子亲石元素,而强烈亏损Ba、Sr、Ti、P;轻稀土元素(LREE)富集,Eu强烈亏损,轻、重稀土元素分馏较强(LaN/YbN主要介于6.87~42.74)。碎斑熔岩体相较于早期熔岩更加富硅贫碱,表明流纹岩-粗面岩喷溢之后,岩浆房中剩余岩浆又经过一定程度的分异,向更为富硅贫碱方向演化之后侵出地表。正蓝旗地区火山岩具有A型花岗岩的特征,为A_1型为主,A_1—A_2过渡的地球化学特征。碎斑熔岩体与流纹岩-粗面岩的Nb/Ta介于10.46~24.02,在地壳和地幔岩浆Nb/Ta比值之间;Y/Nb、Ti/Yb、Ti/Zr均体现出壳幔混合的特点;Rb/Sr介于0.61~64.51,为壳源特征。因此,研究区火山岩是造山后向板内非造山转换并以板内非造山为主的伸展环境下,经较为强烈地幔物质改造的下地壳部分熔融的产物。     

Geochemistry of Pliocene/Pleistocene basalts along the Central Anatolian Fault Zone (CAFZ), Turkey

Pliocene–Pleistocene volcanism accompanied strike-slip-related transtensional deformation along the Kızılırmak fault segment of the Central Anatolian fault zone (CAFZ) in the west of Şarkışla (Sivas–central Turkey). These volcanic rocks are represented by alkali olivine basalts. They can be divided into four different sub-groups on the basis of their Zr, Nb, TiO₂ contents. A primitive mantle-normalized incompatible trace element diagram for four subgroups shows close similarity to typical OIB pattern. Some of the incompatible trace element ratios (Ce/Y, Zr/Nb, La/Ba, La/Nb) are also akin to OIB values. Highly fractionated REE patterns (La/Yb_N=24.7–9.2) with no Eu anomaly are the main features of the alkali basalts and are comparable to alkaline volcanism in continental rift zones. On the basis of Al₂O₃/TiO₂, Nb/Y, Zr/Y Zr/Nb ratios, the geochemical differences among four sub-groups can be explained by variable degrees of partial melting of compositionally similar mantle source. Th/Nb, Th/Y, Nb/Y ratios and the primitive mantle-normalized trace element diagram suggests significant amount of crustal involvement for most of the alkali olivine basalts erupted along the CAFZ. Rupture of the continental lithosphere by strike-slip-related transtensional deformation might have caused decompressional partial melting of the asthenospheric mantle and generating alkali olivine basalts in this region.     

Formation of Subaqueous Felsic Domes and Accompanying Pyroclastic Deposits on the Foça Peninsula (Izmir,Turkey)

In western Anatolia, a thick volcanic succession of andesitic to rhyolitic lavas and volcaniclastic rocks crops out extensively. On Foça Peninsula, the westernmost part of the region, a dominantly rhyolitic sequence is exposed where massive rhyolites occur as dome or domelike stubby lava flows. These rhyolite domes vertically and laterally pass into blanketing volcaniclastic sequences. The gradational boundary relations and the facies characteristics of the surrounding volcaniclastic sequences indicate that the silicic domes directly intruded a subaqueous environment and were shattered upon sudden contact with water to form hyaloclastic blankets.

In and around these rhyolite domes, we have defined six different volcanic and volcaniclastic facies, consisting of: (1) massive rhyolite; (2) massive perlite; (3) hyaloclastic breccias; (4) rhyolite pumice and lithic fragment-bearing volcaniclastic rocks; (5) subaqueous welded ignimbrites; and (6) brecciated perlite. The massive rhyolite facies have distinct structures from the centers to the peripheries of the domes and stubby lava flows. Massive lava facies gradually pass into hyaloclastic breccias and massive perlite facies, indicating water-magma interaction during the emplacement. Phreatomagmatic explosive activity and doming caused the subaqueous pyroclastic flows on the flanks of the volcanic center. Welding in the upper parts of these pyroclastic flow deposits indicates the high-temperature emplacement of the pyroclastic material and relatively slow cooling caused by the cushioning effect of the gas-vapor mixture and rapid deposition of younger pyroclastic units.     

Generation of voluminous silicic magmas and formation of mid-Cenozoic crust beneath north-central Mexico: evidence from ignimbrites,associated lavas,deep crustal granulites,and mantle pyroxenites

 Isotopic and trace element data from mantle and granulite xenoliths are used to estimate the relative contributions of mantle and crustal components to a large ignimbrite, referred to as the upper ignimbrite, that is representative of the voluminous mid-Cenozoic rhyolites of northwestern Mexico. The study also uses data from the volcanic rocks to identify deep crustal xenoliths that are samples of new crust created by the Tertiary magmatism. The isotopic composition of the mantle component is defined by mantle-derived pyroxenites that are interpreted to have precipitated from mid-Cenozoic basaltic magmas. This component has ɛ_Nd≈+1.5, ⁸⁷Sr/⁸⁶Sr≈0.7043 and ²⁰⁶Pb/²⁰⁴Pb≈18.6. Within the upper ignimbrite and associated andesitic and dacitic lavas, initial ⁸⁷Sr/⁸⁶Sr is positively correlated with SiO₂, reaching 0.7164 in the ignimbrite. Initial ²⁰⁶Pb/²⁰⁴Pb ratios also show a positive correlation with silica, whereas ɛ_Nd values have a crude negative correlation, reaching values as low as −2. Of the four isotopically distinct crustal components identified from studies of granulite xenoliths, only the sedimentary protolith of the paragneiss xenoliths can be responsible for the high initial ⁸⁷Sr/⁸⁶Sr of the upper ignimbrite. The Nd, Sr, and Pb isotopic compositions of the upper ignimbrite can be modeled with relatively modest assimilation (≤20%) of the sedimentary component ± Proterozoic granulite. Gabbroic composition granulite xenoliths have distinctive Nd, Sr, and Pb isotope ratios that cluster closely within the range of compositions found in the andesitic and dacitic lavas. These mafic granulites are cumulates, and their protoliths are interpreted to have precipitated from the intermediate to silicic magmas at 32–31 Ma. These mafic cumulate rocks are probably representative of much of the deep crust that formed during mid-Cenozoic magmatism in Mexico. Worldwide xenolith studies suggest that the relatively great depth (≤20 km) at which assimilation-fractional crystallization took place in the intermediate to silicic magma systems of the La Olivina region is the rule rather than the exception. Oligocene ignimbrites of the southwestern United States (SWUS) have substantially lower ɛ_Nd values (e.g. <−6) than the upper ignimbrite and other rhyolites from Mexico. This difference appears to reflect a greater crustal contribution to ignimbrites of the SWUS, perhaps due to a higher temperature of the lower crust prior to the emplacement of the Oligocene basaltic magmas. Received: 16 December 1994 / Accepted: 13 September 1995     

Chronological and Geochemical Characterisitics of Volcanic Rocks of the Yingcheng Formation in the Southern Songliao Basin: Constraints on the Early Cretaceous Evolution of the Songliao Basin

The discoveries of oil and gas reservoirs in the volcanic rocks of the Songliao Basin(SB) have attracted the attention of many researchers. However, the lack of studies on the genesis of the volcanic rocks has led to different opinions being presented for the genesis of the SB. In order to solve this problem, this study selected the volcanic rocks of the Yingcheng Formation in the Southern Songliao Basin(SSB) as the research object, and determined the genesis and tectonic setting of the volcanic rocks by using LA-ICP-MS zircon U-Pb dating and a geochemical analysis method(major elements, trace elements, and Hf isotopes). The volcanic rocks of the Yingcheng Formation are mainly composed of rhyolites with minor dacites and pyroclastic rocks. Our new zircon U-Pb dating results show that these volcanic rocks were erupted in the Early Cretaceous(113–118 Ma). The primary zircons from the rhyolites have εHf(t) values of +4.70 to +12.46 and twostage model age(TDM2) of 876–374 Ma. The geochemical data presented in this study allow these rhyolites to be divided into I-type rhyolites and A-type rhyolites, both of which were formed by the partial melting of the crust. They have SiO2 contents of 71.62 wt.%–75.76 wt.% and Al2 O3 contentsof 10.88 wt.% to 12.92 wt.%. The rhyolites have distinctively higher REE contents than those of ordinary granites, with obvious negative Eu anomalies. The light to heavy REE fractionation is not obvious, and the LaN/YbN(average value = 9.78) is less than 10. The A-type rhyolites depleted in Ba, Sr, P, and Ti, with relatively low Nb/Ta, indicating that the rocks belong A2 subtype granites formed in an extensional environment. The adakitic dacites are characterized by high Sr contents(624 to 1,082 ppm), low Y contents(10.6 to 12.6 ppm), high Sr/Y and Sr/Yb ratios, and low Mg# values(14.77 to 36.46), indicating that they belong to "C" type adakites. The adakitic dacite with high Sr and low Yb were likely generated by partial melting of the lower crust under high pressure conditions at least 40 km depth. The I-type rhyolites with low Sr and high Yb, and the A-type rhyolites with very low Sr and high Yb, were formed in the middle and upper crust under low pressure conditions, respectively. In addition, the formation depths of the former were approximately 30 km, whereas those of the latter were less than 30 km. The geochemical characteristics reveal that the volcanic rocks of Yingcheng Formation were formed in an extensional environment which was related to the retreat of subducted Paleo-Pacific Plate. At the late Early Cretaceous Period, the upwelling of the asthenosphere mantle and the lithosphere delamination caused by the retreat of the subducted Paleo-Pacific Plate, had resulted in lithosheric extension in the eastern part of China. Subsequently, a large area of volcanic rocks had formed. The SB has also been confirmed to be a product of the tectonic stress field in that region.     

Geochemistry of an ordovician basalt-trachybasalt-subalkaline/peralkaline rhyolite association from the Lleyn Peninsula,North Wales,U.K

The Caradoc volcanic rocks of the Lleyn Peninsula represent a major episode of rhyolite-dominated eruption (total volume up to 560 km³) within the Southern British Caledonides. New geochemical data reveal the original chemical characteristics of the basic, intermediate, and acid lavas. The basalts are interpreted as having predominantly within-plate character and are associated with intermediate lavas (trachybasalts) and high-Zr, originally peralkaline, trachytes, and rhyolites. A low-Zr, originally high-K, subalkalic group of rhyolites, and a basalt with transitional island arc tholeiite-MORB characteristics are unrelated to these lavas. The volcanic rocks are interpreted to have been erupted onto a complex, rapidly evolving, active continental margin dominated by crustal tension.     

Mineral chemical constraints on the petrogenesis of mafic and intermediate volcanic rocks from the Erciyes and Hasandağ volcanoes,Central Turkey

Hasandağ and Erciyes stratovolcanoes, which produced both calc-alkaline and alkaline eruptive products, are the two important volcanic complexes in Central Anatolia. There are three geochemical evolution stages in the history of the Hasandağ strato volcanic complex: (1) Keçikalesi tholeiitic, (2) Hasandağ calc-alkaline and (3) Hasandağ alkaline. Volcanologic and petrologic characteristics of the Hasandağ and Erciyes calc-alkaline series show that water played an important role on the genesis of these rocks. These rocks are phenocryst-rich with vesicular texture, and contain hydrous mineral phases. The approximate pressure and temperature estimates obtained from the mineral chemistry studies of the Hasandağ strato volcanic complex indicate crystallization temperature of 1100 °C with 2.5–3.4 kbar pressure interval for the first stage of Keçikalesi tholeiitic volcanism, and about 850 °C temperatures with 4.3–9.6 kbar pressure intervals for the second stage of Hasandağ calc-alkaline volcanism.The geochemical evolution of Erciyes volcanic complex also exhibits three distinct evolutionary stages: (1) Koçdağ alkaline, (2) Koçdağ calc-alkaline and (3) Erciyes calc-alkaline. The temperature of Koçdağ alkaline volcanism is 1097–1181 °C and in a range of 5.1–6.7 kbar pressure, for Koçdağ calc-alkaline volcanism 850–1050 °C temperature to 2.0–6.6 kbar pressure interval, and for Erciyes calc-alkaline volcanism about 950 °C temperature, to 3.2–7.9 kbar pressure intervals were calculated. Polybaric origin of magma chambers for calc-alkaline and alkaline rocks and disequilibrium parameters observed in phenocrysts indicate that the rocks were affected by magma mixing processes in crustal magma chambers. The disequilibrium features of amphibole and plagioclase phenocrysts in these rocks point the latent heat in magma chambers and periodic recharging with mafic magma chambers and also show that magmas reequilibrate before the eruption.     

Uppermost Cretaceous–Lower Tertiary Ulukışla Basin,south-central Turkey: sedimentary evolution of part of a unified basin complex within an evolving Neotethyan suture zone

The Ulukışla Basin, the southerly and best exposed of the Lower Tertiary Central Anatolian Basins, sheds light on one of the outstanding problems of the tectonic assembly of suture zones: how large deep-water basins can form within a zone of regional plate convergence. The oldest Ulukışla Basin sediments, of Maastrichtian age, transgressively overlie mélange and ophiolitic rocks that were emplaced southwards onto the Tauride microcontinent during the latest Cretaceous time. The Niğde-Kirşehir Massif forming the northern basin margin probably represents another rifted continental fragment that was surrounded by oceanic crust during Mesozoic time. The stratigraphic succession of the Ulukışla Basin begins with the deposition of shallow-marine carbonates of Maastrichtian–Early Palaeocene age, then passes upwards into slope-facies carbonates, with localised sedimentary breccias and channelised units, followed by deep-water clastic turbidites of Middle Palaeocene–Early Eocene age. This was followed by the extrusion of c. 2000 m of basic volcanic rocks during Early to Mid Eocene time. After volcanism ended, coral-bearing neritic carbonates and nummulitic shelf sediments accumulated along the northern and southern margins of the basin, respectively. Deposition of the Ulukışla Basin ended with gypsum deposits including turbidites, debris flows, and sabkhas, followed by a regional Oligocene unconformity.The Ulukışla Basin is interpreted as the result of extension (or transtension) coupled with subsidence and basic volcanism. After post-volcanic subsidence, the basin was terminated by regional convergence, culminating in thrusting and folding in Late Eocene time. Comparisons of the Ulukışla Basin with the adjacent central Anatolian basins (e.g. Tuzgölü, Sivas and Şarkişla) support the view that these basins formed parts of a regional transtensional (to extensional) basin system. In our preferred hypothesis, the Ulukışla Basin developed during an intermediate stage of continental collision, after steady-state subduction of oceanic crust had more or less ended (“soft collision”), but before the opposing Tauride and Eurasian continental units forcefully collided (“hard collision”). Late Eocene forceful collision terminated the basinal evolution and initiated uplift of the Taurus Mountains.     

The Late Pliocene mafic lavas from the Camusú Aike volcanic field (∼50°S,Argentina): Evidence for geochemical variability in slab window magmatism

The Camusú Aike volcanic field (CAVF), part of the discontinuous N–S-trending belt of Cenozoic mafic lava formations that occur in a backarc position along extra-Andean Patagonia, is located in southern Patagonia (∼50°S, Santa Cruz province), approximately 70 km east of the extensive Meseta de las Vizcachas and just south of the upper Río Santa Cruz valley. The CAVF volcanics cover a surface of ∼200 km² and occur mainly as lava flows and scoria cones. They are subdivided into two groups: Group I volcanics are high-TiO₂, low-Mg# olivine-hypersthene-normative basalts and trachybasalts that erupted at about 2.9 Ma; Group II lavas are much less abundant, more primitive basaltic andesites that erupted at about 2.5 Ma. Both groups show a within-plate geochemical signature, though it is more marked in Group I lavas.The main geochemical characteristics, age, and location of CAVF volcanics are consistent with the slab window opening model proposed by different authors for the genesis of the Miocene-Recent mafic magmatism of Patagonia south of 46.5°S. The whole-rock geochemical and Sr–Nd isotope features of Group I lavas (⁸⁷Sr/⁸⁶Sr=0.7035–0.7037; ¹⁴³Nd/¹⁴⁴Nd=0.51288–0.51291) indicate a genetic link between these lavas and the primitive basalts in southernmost Patagonia (Pali Aike volcanic field and Estancia Glencross area), which have been interpreted as melting products of an isotopically depleted asthenosphere. The relatively evolved compositions of the erupted Group I magmas are modeled by a polybaric crystal fractionation process without significant involvement of crustal contamination. The more primitive Group II lavas are strongly depleted in incompatible elements, have slightly higher (LREE+Ba+Th+U)/HFSE ratios, and have more enriched Sr–Nd isotope compositions (⁸⁷Sr/⁸⁶Sr≈0.7039; ¹⁴³Nd/¹⁴⁴Nd≈0.51277) that are more akin to the Patagonian basalts farther to the north. The most likely explanation for the geochemical features of Group II lavas is the occurrence in their mantle source of a small proportion of a subduction-related, enriched component that likely resides in the former mantle wedge or the basal continental lithospheric mantle.     

Caractérisation des ignimbrites néogènes du bassin d'Arequipa,Pérou

Four ignimbritic units have filled the Arequipa Basin and outcrop around the Chachani Volcano. (1) The oldest Río Chili ignimbrite is 13.33 Ma old; (2) the most widespread La Joya ignimbrite is 4.9 Ma old; (3) the Arequipa Airport ignimbrite (1.65 Ma) flowed from an area buried beneath Chachani; (4) the Yura Tuffs, 1.02 Ma old, are restricted to the west of Chachani. All are calc-alkaline rhyolites with plagioclase, biotite, quartz, sanidine, and opaques, but the Río Chili and La Joya ignimbrites also contain amphibole. Trace elements of the older ignimbrites reflect stronger crustal influence. To cite this article: P. Paquereau et al., C. R. Geoscience 337 (2005).     

中部拉萨地体南侧吉瓦地区早白垩世则弄群火山岩的发现及意义

西藏尼玛县吉瓦地区措勤-多瓦后陆拗陷带内分布的火山岩LA-ICP-MS锆石U-Pb年龄为120.3~126.5Ma左右,重新厘定为早白垩世则弄群,否定了前人归属为上新世乌郁群(N2wy)及始新世帕那组(E2p)的认识。岩石以酸性火山岩为主,中基性火山岩为辅,酸性岩类主要为火山碎屑岩类和熔岩类,典型岩石类型为流纹质熔结凝灰岩和流纹岩等,中基性岩主要为玄武安山岩,安山玄武岩等,杏仁构造普遍发育。研究区大量的流纹质熔结凝灰岩的出现反映了吉瓦地区的火山岩主要为陆相火山喷发形成。地球化学特征显示轻稀土富集,负Eu异常明显,富集K、Rb、Th、U等大离子亲石元素,相对亏损Nb、Ta、P、Ti等高场强元素。酸性火山岩具有A型花岗质岩浆岩特征,基性岩具有板内玄武岩亲缘性,这一特征可能与班公湖-怒江洋壳岩石圈南向俯冲过程中发生的板片断离有关。中部拉萨地体南侧早白垩世火山岩的发现,使班公湖-怒江洋壳南向俯冲在晚侏罗世-早白垩世的岩浆活动在原来的基础上向南延伸70~80km,火山岩地层时代的重新归位对研究冈底斯带早白垩世地球动力学背景及建立地质年代学格架提供了新的约束资料,具有重要的科学意义。吉瓦地区早白垩世则弄群火山岩可能受到了班公湖-怒江特提斯洋壳向南、雅鲁藏布江洋壳向北的双向俯冲制约。     

Lower Pliensbachian caldera volcanism in high-obliquity rift systems in the western North Patagonian Massif,Argentina

In the Cerro Carro Quebrado and Cerro Catri Cura area, located at the border between the Neuquén Basin and the North Patagonian Massif, the Garamilla Formation is composed of four volcanic stages: 1) andesitic lava-flows related to the beginning of the volcanic system; 2) basal massive lithic breccias that represent the caldera collapse; 3) voluminous, coarse-crystal rich massive lava-like ignimbrites related to multiple, steady eruptions that represent the principal infill of the system; and, finally 4) domes, dykes, lava flows, and lava domes of rhyolitic composition indicative of a post-collapse stage.The analysis of the regional and local structures, as well as, the architectures of the volcanic facies, indicates the existence of a highly oblique rift, with its principal extensional strain in an NNE–SSW direction (∼N10°).The analyzed rocks are mainly high-potassium dacites and rhyolites with trace and RE elements contents of an intraplate signature. The age of these rocks (189 ± 0.76 Ma) agree well with other volcanic sequences of the western North Patagonian Massif, as well as, the Neuquén Basin, indicating that Pliensbachian magmatism was widespread in both regions. The age is also coincident with phase 1 of volcanism of the eastern North Patagonia Massif (188–178 Ma) represented by ignimbrites, domes, and pyroclastic rocks of the Marifil Complex, related to intraplate magmatism.     

松科二井东孔营城组火山岩测井响应特征及岩性评价

为开展松辽盆地深部长期观测、流体实验和探索白垩纪火山事件,利用松科二井东孔丰富、齐全的测井资料,对营城组火山岩岩性进行评价。通过测井响应特征分析发现,松科二井东孔营城组凝灰岩具有最强的放射性和导电性,高孔隙度的集块熔岩密度为低值,流纹岩表现出高密度和低导电性。利用测井交会图和成像识别模式,识别出松科二井东孔营城组火山岩以流纹岩、凝灰熔岩和集块熔岩为主,少量的凝灰岩。结合凝灰岩处测井曲线变化特点,证明了火山喷发间断的存在。流纹岩具有高碱、高Si、低Fe和低黏土矿物特征。T_2谱分析认为流纹岩有利于后期深部长期观测和流体实验的开展。研究成果对松科二井东孔后续火石岭组火成岩及整个松辽盆地火山岩研究具有一定的参考价值。     

Dispersion et concentration du manganèse dans les roches volcaniques

Résumé L'étude géochimique des roches volcaniques d'Auvergne conduit à formuler l'hypothèse que le manganèse intervient d'autant moins dans la composition minéralogique des roches que celles-ci sont plus riches en SiO₂. Dans les rhyolites, Mn est exsudé sous forme de filons. Ces occurences de manganèse, peu importantes dans la série volcanique d'Auvergne, prennent une certaine ampleur dans les rhyolites du Sulcis (Sardaigne) et surtout dans les gîtes volcanosédimentaires associés.

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The geochemical study of the volcanic rocks of Auvergne leads one to formulate the hypothesis that less manganese enters in rock-forming minerals the higher their SiO₂-content is. In the rhyolites, Mn is exuded in the form of veins. These occurrences of manganese, little important in the volcanic series of Auvergne, gain some importance in the rhyolites of Sulcis (Sardinia) and above all in the associated volcanic-sedimentary ore-deposits.

     

Rare earth element geochemistry of the Betts Cove ophiolite,Newfoundland: complexities in ophiolite formation

The Betts Cove ophiolite includes the components of typical ocean crust: pillow lavas, sheeted dikes, gabbros and ultramafics. However, the trace element geochemistry of basaltic rocks is unusual. Three geochemical units are recognized within the lava and dike members. Within the pillow lavas, the geochemical units correspond to stratigraphic units. Upper lavas have ‘normal’ (i.e., typical for ocean floor basalts) TiO₂ contents (0.75 to 2.0 wt%), heavy rare earth elements (HREE) values in the range 6–20× chondrites and chondrite-normalized REE patterns with relative LREE depletion. Intermediate lavas have TiO₂ contents between 0.30 and 0.50 wt%, HREE contents from 4–7× chondrites and extreme relative LREE depletion. Lower lavas have anomalously low TiO₂ contents (<0.30 wt%) and unusual convex-downwards REE patterns with REE abundances around 2–5 × chondrite. These geochemical differences can be explained if the three groups were derived from different mantle sources. Independent mantle sources for the three units are consistent with their different ${}^{143}\text{Nd}{}^{144}\text{Nd}$ ratios varying at 480 m.y.B.P. from 0.51222 in a lower lava to 0.51238 in an upper lava. The upper lavas may be partial melts of a source similar in composition to that of modern MORB, the intermediate lavas may be from a very depleted oceanic mantle (second stage melt), and the lower lavas may have formed by melting an extremely depleted mantle that had been invaded by a LREE-enriched fluid. A possible tectonic environment where these different sources could be juxtaposed is a back-arc or inter-arc basin.     

Major neotectonic features of eastern Marmara region,Turkey: development of the Adapazarı–Karasu corridor and its tectonic significance

Eastern Marmara region consists of three different morphotectonic units: Thrace–Kocaeli Peneplain (TKP) and Çamdağ–Akçakoca Highland (ÇAH) in the north, and Armutlu–Almacık Highland in the south of the North Anatolian Fault Zone (NAFZ). The geologic‐morphologic data and seismic profiles from the Sakarya River offshore indicate that the boundary between the TKP in the west and ÇAH in the east is a previously unrecognized major NNE–SSW‐trending strike‐slip fault zone with reverse component. The fault zone is a distinct morphotectonic corridor herein named the Adapazarı–Karasu corridor (AKC) that runs along the Sakarya River Valley and extends to its submarine canyon along the southern margin of the Black Sea in the north. It formed as a transfer fault zone between the TKP and ÇAH during the Late Miocene; the former has been experiencing extensional forces and the latter compressional forces since then. East–West‐trending segments of the NAFZ cuts the NE–SW‐trending AKC and their activity has resulted in the formation of a distinct fault‐bounded morphology, which is characterized by alternating E–W highlands and lowlands in the AKC. Furthermore, this activity has resulted in the downward motion of an ancient delta and submarine canyon of the Sakarya River in the northern block of the NAFZ below sea level so that the waters of the Black Sea invaded them. The NE–SW‐trending faults in the AKC were reactivated with the development of the NAFZ in the Late Pliocene, which then caused block motions and microseismic activities throughout the AKC. Copyright © 2004 John Wiley & Sons, Ltd.     

The Geologic Evolution of the Southern Sierra de Guanajuato,Mexico: A Documented Example of the Transition from the Sierra Madre Occidental to the Mexican Volcanic Belt

Geologic mapping and new K-Ar and ⁴⁰Ar/³⁹Ar geochronology of the southeastern Sierra Madre Occidental (SMO), at its intersection with the northern margin of the Mexican Volcanic Belt (MVB), indicate the occurrence of three volcanic groups. The oldest group corresponds to the SMO, and includes 29 to 22 Ma voluminous ignimbrites and 30 Ma andesites and rhyolites. The youngest group includes widespread basaltic-andesitic lava plateaus that yielded ages from 14.6 to 8.8 Ma and are interpreted as the beginning of the MVB. From 22 to 14.6 Ma, volcanic activity in the area was significantly reduced, but did not cease entirely. We refer to the third group as transitional volcanism, which is dominated by andesitic and rhyolitic lava domes but also includes high-grade andesitic ignimbrites. We conclude that the change from volcanism proper of the SMO to that of the MVB was gradual with respect to age and drastic with respect to composition and style, from a voluminous-silicic-ignimbrite domain to a widespread basaltic-andesitic-lava plateau domain. This change may have been related to major plate tectonic reorganizations within the interval from 25 to 12 Ma that involved the waning of subduction of the Farallon plate west of northern Mexico and the associated southward migration of the triple junction of the Pacific-Farallon-North America plates, the subsequent break-up of the Farrallon plate into the Guadalupe and Cocos plates, and the counterclockwise and clockwise rapid rotation of the ridge between them around 16 to 12.5 Ma.     

Petrogenesis of the mafic feldspathoidal lavas of the Raton-Clayton volcanic field,New Mexico

Major and trace-element whole rock data, Nd and Sr isotopic data, and microprobe data have been collected from a suite of basanites, olivine nephelinites, and olivine melilite nephelinites from the Raton-Clayton volcanic field, New Mexico. Most of the lavas have geochemical characteristics that suggest they are primary upper mantle derived melts. The previously unreported occurrence of Type I and Type II ultramafic xenoliths in some of the lava flows supports this conclusion. All the lavas are strongly enriched in light REE, Sr, Ba, U, Th, and P₂O₅. ⁸⁷Sr/⁸⁶Sr ratios are 0.70394 to 0.70412 and ¹⁴³Nd/¹⁴⁴Nd ratios are equal to an epsilon value of +1.4; the data fall within the Nd-Sr correlation field. Trace-element modeling indicates that the lavas were last in equilibrium with a light-REE enriched mantle with a (La/Yb)_N of two to nine. However, the Nd isotopic data indicate a source with a time integrated, chondritic normalized, Sm/Nd ratio of 1.01. To account for this discrepancy a metasomatic enrichment of the source is proposed. The timing of the enrichment event can only be constrained to less than 1 AE ago, and the isotopic composition of the premetasomatized source and the metasomatizing agent cannot be specified. However, geochemical constraints suggest a CO₂-rich fluid enriched in incompatible elements as the likely metasomatizing agent     

Tectonic Implications of the Carboniferous Volcanic Rocks in the Eastern Junggar — Evidence from Zircon U‐Pb Ages and Geochemistry

Well Drilling shows that the volcanic rocks from the Carboniferous Batamayineishan Formation in the Eastern Junggar basin are mainly composed of volcaniclastic rocks (av. 52%) and volcanic lavas (32%), with a small amount of volcanic pyroclastic lavas (av. 11%). The volcanic lavas are basalt‐basaltic andesite‐andesite‐dacite assemblage. The LA‐ICP‐MS zircon U‐Pb dating of the andesite and the dacite yielded 325～321 Ma and 310 Ma ages, respectively, which is of high agreement with the published age (300 Ma) of basalts from this Formation, it is implied that an important volcanic activity occurred in Junggar basin in the late Carboniferous. The lavas have low TiO₂ and high Na₂O, indicating a calc‐alkaline series. Geochemical data show that they are characterized by LREE‐enriched patterns with slightly negative Eu anomalies. The rocks have high large ion lithophile element (LILE), and low high field strength element (HFSE) concentrations, with strong negative Nb, Ta and Ti anomalies. From basic through intermediate to felsic, the depletions in Sr, Ti and P of the studied volcanic rocks increase gradually. These geochemical characteristics indicate that the volcanic rocks are magmatic evolution products attributed to partial melting of mantle‐derived spinelle lherzolite related to oceanic subduction in an island‐arc setting. In combination with the LA‐ICP‐MS zircon U‐Pb dating, it is inferred that subduction of the Junggar Ocean in eastern Junggar basin lasted to the Late Carboniferous. Consequently, the final closure of the Junggar Ocean occurred most likely after 310 Ma.