Sedimentation, fracturing and sliding on a pelagic plateau margin: the Middle Jurassic to Lower Cretaceous succession of Rocca Busambra (Western Sicily, Italy)

The Jurassic succession of Rocca Busambra consists of two lithostratigraphic units: a pile of peritidal limestones several hundreds of metres thick (Inici Formation: Hettangian to Sinemurian) and a 2 to 15 m thick sequence of Rosso Ammonitico‐type pelagic limestones (Toarcian? to lowermost Berriasian). An extensive interval of non‐deposition is evidenced by a thick Fe–Mn oxide crust on the bounding disconformity and is recorded partially in the material contained within a complex network of neptunian dykes and sills. Seven lithofacies are distinguished in the Rosso Ammonitico. These lithofacies show that the Rosso Ammonitico limestones differ from most analogues both in Sicily and elsewhere: sediments are mostly grain‐supported and non‐nodular; obviously bottom currents were important during deposition of these sediments. These currents were pulsating at different frequencies and induced winnowing, intraclast production and early cement precipitation. Other Rosso Ammonitico lithosomes of Late Jurassic to earliest Cretaceous age, usually decimetre thick and discontinuous, overlie the Inici Formation without any Fe–Mn crust; their anomalous stratigraphical and geometrical relationships show that they were deposited on an inclined, stepped, erosional surface incised in the sub‐horizontal Inici Formation. This ancient escarpment is interpreted as the result of a mainly gravitational collapse of the margin of a pelagic plateau. Such mass wasting was probably due to the backstepping of the tectonic plateau–basin margin that is not observable directly, but may be inferred from circumstantial evidence. This observation clearly shows that tectonic activity affected the Rocca Busambra sector of the West Tethys continental margins a few tens of millions of years after the end of the rifting stage. The anomalous Rosso Ammonitico sediments are the only indication of the escarpment and their occurrence in the stratigraphic record is probably more widespread than reported in the literature. More accurate palaeoenvironmental and palaeogeographic reconstructions may depend on the identification of these sediments.     

Lithostratigraphical correlation of micromammal sites and biostratigraphy of the Upper Pliocene to Lower Pleistocene in the Northeast Guadix‐Baza Basin (southern Spain)

The Plio‐Pleistocene non‐marine sequence in the northeast Guadix–Baza Basin (southern Spain) comprises alluvial and lacustrine deposits (Baza Formation). The results of a revised lithostratigraphical correlation between sections from the middle and upper members of the Baza Formation in the northeast part of the basin, supported by detailed mapping, is presented. The position of micromammal sites in the lithostratigraphical scheme, together with the results of intensive palaeontological sampling for small mammal remains, has allowed us to develop a high‐resolution biostratigraphical framework for the area. This provides an opportunity to refine the biozonation for the Plio‐Pleistocene micromammal faunas, and to define faunal events from the late Villanyian (late Pliocene) to the early Pleistocene. On the basis of the lithostratigraphical and biostratigraphical approaches we obtain the following sequence of biozones for the late Pliocene to early Pleistocene: Kislangia gusii, Mimomys cf. reidi, M. oswaldoreigi, Allophaiomys pliocaenicus and A. burgondiae. Copyright © 2000 John Wiley & Sons, Ltd.     

The geodynamic evolution of the Internal Zone of the Betic Cordilleras (south-east Spain): a model based on structural analysis and geothermobarometry

ABSTRACT The Internal Zone of the Betic Cordilleras consists of several superimposed major thrust sheets with different P-T-t evolutions. On the basis of an integrated field, microscopic and laboratory study, the tectono-metamorphic history of the Mulhacen Complex and Almanzora Unit has been reconstructed in detail. The Mulhacen Complex has been affected by at least five phases of penetrative deformation, which have been labelled D_x-1, D_x, D_x+1, D_x+2 and D_x+3. D_x-1, and D_x are related to continent-continent collision, which is indicated by high pressure-low temperature (HP/LT) and subsequent intermediate P/T metamorphic conditions. D_x+1 is related to crustal thinning and heterogeneous extension. During this event the Almanzora Unit was juxtaposed against the Mulhacen Complex. This phase was succeeded by the establishment of low pressure-high temperature (LP/HT) conditions and at least two phases of folding and overthrusting. The Almanzora Unit shows a comparable tectono-metamorphic evolution post D_x+1. However, the P/T conditions prior to D_x+1 indicate a higher crustal position with respect to the Mulhacen Complex during the collisional event.     

Evaluation and validation of landslide-susceptibility maps obtained by a GIS matrix method: examples from the Betic Cordillera (southern Spain)

This work presents the results of applying the matrix method in a Geographic Information System (GIS) to the drawing of maps of susceptibility to slope movements in different sectors of the Betic Cordillera (southern Spain). In addition, the susceptibility models built by the matrix method were compared with a multivariate statistical method, and the first method gave the best results. The susceptibility maps drawn by the GIS matrix method were validated by calculating the coefficients of association with the degree of fit between recent slope movements registered in 1997 and the different levels of susceptibility of previously drawn maps (1995–1996) in different representative zones of the Betic Cordillera (southern Spain). The first sector studied showed excellent degrees of fit, with an error of less than 10% for all the slope failures and 3% when considering only failures of natural origin. In the second sector, the relative errors were less than 5%. In the third sector, the error hardly exceeded 6%. The results are discussed in the different zones and for each type of slope movement. In any case, these results evidence the predictive capacity of susceptibility maps drawn in GIS by the matrix method, for a great number of slope movements.     

羌塘盆地中侏罗统砂糖状白云岩流体包裹体碳—氧同位素分析及白云岩成因机制讨论

羌塘盆地隆鄂尼—昂达尔错古油藏带中侏罗统布曲组砂糖状白云岩储集层成因一直备受关注和争议。白云岩成因及其储层预测对于碳酸盐岩油气藏勘探具有重要意义,但是关于羌塘盆地布曲组白云岩的成因并没有一个相对统一的认识,争议核心聚焦在白云岩化流体性质。笔者等试图在包裹体测温和盐度分析的基础上,利用同位素分馏方程系统研究白云岩包裹体碳—氧同位素,探讨羌塘盆地侏罗系砂糖状白云岩白云岩化流体特征。研究表明白云岩白云石包裹体和灰岩方解石包裹体均一温度分布范围皆为50~220℃,但白云石的包裹体温度峰值分布区间明显要高于方解石的峰值温度,多数样品的温度集中在150℃到220℃区间;另外,与同层灰岩相比,白云岩具有明显的重碳同位素异常富集特征,该特征是高温流体交代石灰岩或者说是水岩反应的标志;此外,通过碳—氧同位素分馏方程计算出白云岩包裹体流体碳、氧同位素分别为-1. 30‰～1. 53‰和5. 81‰～12. 50‰,具有高盐度的卤水特征。综合包裹体温度、盐度,以及包裹体碳、氧同位素特征,本文认为羌塘盆地布曲组砂糖状白云岩是热液交代白云岩化产物。     

Diagenesis, palaeoclimate and tectono-sedimentary influences on clay mineralogy and stable isotopes from Upper Cretaceous marine successions of the Basque-Cantabrian Basin (N Spain)

Clay mineralogy and whole-rock stable isotopes (δ¹⁸O and δ¹³C) of Upper Cretaceous marly sediments on the Basque-Cantabrian Basin have been integrated to determine the main effects of diagenesis, palaeoclimate and tectono-sedimentary factors in sections belonging to deep- (Barrika) and platform-marine (Isla de Castro, Villamartín and Olazagutía) settings.The mean values for the clay assemblages and δ¹⁸O exhibit notable differences among the sections, partially explainable by the influence of diagenesis. The Barrika sediments, with more diagenetically advanced illite-smectite (I-S) mixed-layer (R1, 70% illite), authigenic chlorite, and low δ¹⁸O (−4.05‰ PDB), experienced higher diagenetic grade than Isla de Castro and Olazagutía, which have R0 I-S (20% illite) and heavier δ¹⁸O. Villamartín was also affected by higher diagenesis than Isla de Castro and Olazagutía, given the occurrence of R1 I-S (60% illite) and low δ¹⁸O (−4.11‰ PDB). However, the absence of other clays in Villamartín (e.g. authigenic chlorite) is indicative of less diagenetic grade than Barrika. These results show the useful integration of clay mineralogy and stable isotopes to detect different diagenetic grades in distinct marine successions of the same basin.Despite being influenced by diagenesis, the clay mineralogy partially preserves its inherited signature. This allows detection of major contents of I-S and mica, and minor kaolinite, interpreted as indicative of warm palaeoclimatic conditions. High kaolinite content in Villamartín and absence of kaolinite in Isla de Castro, though, are considered to be a product of neither diagenesis nor palaeoclimatic influences. Instead, tectono-sedimentary causes, related to unsuitable conditions for clay formation and transport from the local source areas, contributed to original clay differences. The inferred effects of diagenesis, palaeoclimate and tectono-sedimentary factors make this work important to show the potentially great variety of controls on the clay mineralogy of marine sections, which are often uncritically treated in studies concerning the Late Cretaceous.     

花岗岩型热液铀矿床C、O同位素研究---以甘肃省龙首山芨岭矿区为例

龙首山地区是西北重要的花岗岩型热液铀矿产区之一,区内控矿条件复杂。研究选取甘肃省龙首山芨岭矿区内的矿床和部分矿点的热液碳酸盐样品并测定其C、O同位素组成：δ13C VPDB的值在-1.50‰～-6.33‰之间,δ18OSMOW值为-2.577～5.051‰之间。进一步研究结果表明,成矿流体中矿化剂ΣCO2主要来源于与区域深大断裂有关的幔源脱气作用,同时伴有海相碳酸盐来源;成矿同时期伴随的强烈流体脱气(CO2)作用对矿质沉淀至关重要。成矿热液的水源主要为岩浆热液与大气降水混合特征,但以大气降水形成为主。     

中国陆相侏罗系—白垩系界线及其国际地层对比——以冀北—辽西地区侏罗系—白垩系年代地层为例

冀北—辽西地区陆相侏罗系—白垩系发育,各类生物化石丰富,并夹有火山岩,是利用岩石地层、生物地层、同位素测年和磁性年代地层综合研究侏罗系\\白垩系界线的理想地区。冀北滦平盆地侏罗系\\白垩系界线附近的地层为大北沟组和大店子组,辽西义县—北票地区侏罗系\\白垩系界线附近的地层为土城子组和义县组。大店子组含有孢粉Cicatricosisporites Luanpingspora Jugella 组合;介形类Yanshanina Cypridea Rhinocypris组合,Cypridea Yanshanina Timiriasevia组合,Cypridea sulcata亚组合和叶肢介Eosestheria Abrestheria组合等各类化石,这些生物组合与国内、外的对比,尤其是孢粉和介形类与英、法、德、俄和加拿大等地相关地层同类化石组合的对比,其时代为早白垩世早期（Berriasian）。辽宁西部义县组下部的孢粉、介形类和叶肢介与国内、外的对比,也得出与大店子组的时代大致相同的结论。大北沟组含孢粉Poceites Podocarpidites Schizaeoisporites组合,介形类Luanpingella Torinina Eoparacypris组合以及叶肢介Nestoria Keratestheria组合等,这些生物组合与国内、外同类生物组合的对比,得出的时代结论是晚侏罗世晚期（Tithonian）。土城子组含有孢粉、介形类及叶肢介等6大门类化石,根据已有的研究成果,得出的时代结论是晚侏罗世。因此,侏罗系\\白垩系的界线划在大北沟组与大店子组之间。生物地层的国际对比表明：此界线与国际侏罗系\\白垩系界线,即Tithonian\\Berriasian界线是一致的。根据冀北—辽西地区一系列同位素测年数据推断,侏罗系\\白垩系界线年龄应接近1307Ma 。     

Carbon-isotope records of the Early Jurassic (Toarcian) oceanic anoxic event from the Valdorbia (Umbria–Marche Apennines) and Monte Mangart (Julian Alps) sections: palaeoceanographic and stratigraphic implications

The Toarcian oceanic anoxic event ( ca 183 Ma) coincides with a global perturbation marked by enhanced organic carbon burial and a general decrease in calcium carbonate production, probably triggered by changes in the composition of marine plankton and elevated carbon dioxide levels in the atmosphere. This study is based on high-resolution sampling of two stratigraphic successions, located in Valdorbia (Umbria–Marche Apennines) and Monte Mangart (Julian Alps), Italy, which represent expressions of the Toarcian oceanic anoxic event in deep-water pelagic sediments. These successions are characterized by the occurrence of black shales showing relatively low total organic carbon concentrations (compared with coeval strata in Northern Europe), generally < 2%, and low hydrogen indices. On this basis, they are similar to other Toarcian black shales described from the Tethyan region. The positive and negative carbon-isotope records from the two localities permit a high-resolution correlation such that ammonite biostratigraphy information from Valdorbia can be transferred to those parts of the Monte Mangart section that lack these fossils. Spectral analyses of δ¹³C_org values and of CaCO₃ percentages from the sedimentary records of both the Valdorbia and Monte Mangart sections reveal a strong cyclic pattern, best interpreted as an eccentricity signal which hence implies a duration of ca 500 kyr for the negative carbon-isotope excursion. Based on the carbon-isotope curves obtained, the high-resolution correlation between the Italian successions and a section in Yorkshire (Northern Europe) confirms the supposition that the apparent mismatch between the dating of the Toarcian oceanic anoxic event in the Boreal and Tethyan realms is an artefact of biostratigraphy.     

Carbon and oxygen isotopes suggesting deep-water basin deposition associated with hydrothermal events （Shangsi Section,Northwest Sichuan Basin-South China）

Carbon and oxygen isotope records for Shangsi Section in Northwest Sichuan Basin, South China can help investigating depositional environments and processes, including the burial rate and possible contribution of hydrothermal events. Samples from the lower Chihsian Formation show δ13CPDB and δ18OPDB values close to those of typical marine limestone. However, the overlying Permian middle-upper Chihsian, Wujiaping, and Maokou Formation samples reveal negative δ18OSMOW values and strong positive δ13CPDB values. These indicate high biological productivity and rapid burial of organic carbon. Samples from the Dalong Formation present both negative δ13CPDB and negative δ18OPDB values, which are quite different from the underlying Permian strata. These abnormal carbon and oxygen isotope characteristics in the Dalong Formation may suggest that hydrothermal processes contributed to deposition.     

湘西黔东地区铅锌矿床C、O同位素地球化学特征及其对成矿过程的指示

近年来湘西黔东地区铅锌矿产勘查成果显著,已发现矿床(点)200余处,铅锌矿主要产于寒武系—奥陶系碳酸盐岩地层中。通过对该地区典型铅锌矿床碳酸盐围岩和成矿期方解石的C、O同位素组成分析,结果表明:碳酸盐围岩的δ13CPDB值(-1.16‰~1.70‰,均值0.51‰)和δ18OSMOW值(18.56‰~22.42‰,均值21.04‰)变化范围较小,组成相对均一,在δ13CPDB-δ18OSMOW图上投影点位于海相碳酸盐岩区;而成矿期方解石的δ13CPDB值(-5.80‰~0.42‰,均值-1.18‰)比围岩略低,δ18OSMOW值(12.96‰~23.05‰,均值18.36‰)有明显的下降,在δ13CPDB-δ18OSMOW图上投影点主要位于上地幔区和海相碳酸盐岩之间。根据C、O同位素组成特征并结合前人研究成果,认为成矿流体中的C主要来源于碳酸盐围岩,S来源于地层中的膏盐层,Pb、Zn主要来源于下寒武统牛蹄塘组地层,成矿流体是一种高盐度的低温热卤水,它与碳酸盐围岩的水-岩反应和降温的耦合作用是该地区成矿期方解石和矿石矿物沉淀的主要机制。     

Carbon and oxygen isotopic composition and foraminifers of condensed basal Zechstein (Upper Permian) strata in western Poland: environmental and stratigraphic implications

The basinal facies of the Lopingian Zechstein Limestone in SW Poland consists of thin (often less than 1 m thick) limestones and/or dolomites, often containing the Kupferschiefer (few tens of centimetres thick) at their base, and local thick (up to 90 m) reefal carbonates. The δ¹³C curve of these basal Zechstein deposits strongly suggests that even when the Kupferschiefer is lacking, the thin (condensed) sequences record the entire interval of the Zechstein prior to the onset of evaporite deposition, in contrast to the thick reef sequences which lack the characteristic δ¹³C curve for the lowermost part of the Zechstein. The calcite samples show considerable ranges of δ¹⁸O values. If the maximum δ¹⁸O values are considered to be the closest to the pristine original ones and if δ¹⁸O_water value = 0 is assumed, then the calculated range of palaeotemperatures for the Kupferschiefer and Zechstein Limestone calcite ranges from 19 to 34 °C. The faunal restriction, common dwarf foraminifers and the predominance of lagenids in the foraminiferal assemblage indicate continual dysaerobic conditions and possibly elevated salinity of seawater during deposition of thin basinal Zechstein Limestone deposits. The mixing of shallow and deeper waters in the stratified Zechstein Basin caused by upwelling could result in prolific carbonate precipitation in reefs located at the slope of the marginal carbonate platform of the Zechstein Limestone and in isolated reefs related to palaeohighs within the basin; however, there is no isotopic record of eventual upwelling. Copyright © 2014 John Wiley & Sons, Ltd.     

Reef development on a deepening platform: two Early Cretaceous coralgal patch reefs (Catí, Llàcova Formation, eastern Spain) compared

Two coralgal patch reefs of the Hauterivian Llàcova Formation (Maestrat Basin, eastern Spain), exposed at two consecutive stratigraphic levels within a single section, have been studied to document taxonomic implications of a changing environment. These two reefal palaeocommunities differ substantially in coral taxonomic composition, microbialite formation pattern and in abundance and composition of encrusters and bioeroders. Of a total of 14 coral species, just one (Stylina parvistella) occurs in both reefs, yet is abundant in the (lower) reef A and rare, occurring near the reef base, in the reef B assemblage. Reef A is dominated by a phototrophic fauna and coral species with small corallites and imperforate septa (a stylinid-thamnasteriid-heterocoeniid-actinastreid association), along with an encruster association dominated by Bacinella and Lithocodium. Reef B is characterised by a balanced phototrophic-heterotrophic fauna that gradually passes into a heterotrophic-dominated assemblage. During this latest growth stage, microsolenid corals dominated the assemblage. The encruster fauna is characterised by sponges, polychaetes and bryozoans. Moderate deepening during a transgressive systems tract (TST) depositional sequence and elevated nutrient supply are interpreted to represent the driving environmental parameters that caused faunal compositions to differ between these two reefal palaeocommunities. Nine coral taxa, previously known only from younger (Barremian–Cenomanian) strata, have been identified, namely Dimorphocoenia? rudis, Eocomoseris raueni, Eocomoseris sp., Holocoenia jaccardi, Latusastrea irregularis, Mesomorpha sp., Microsolena kugleri, Polyphylloseris mammillata and Polyphylloseris sp. This observation emphasises the importance of the Hauterivian Stage as a period of evolutionary transition in Late Jurassic–Cretaceous coral faunas.     

Geochemical,and stable and radiogenic isotope records in Devonian and Early Carboniferous carbonates from Valle de Tena,central Pyrenees (Spain): evidence for their diagenetic environments

Mineralogical, textural and geochemical investigations were made to determine the post-depositional evolution of Devonian and Early Carboniferous carbonates from Valle de Tena. The carbonate association is made up of low-Mg calcite, which occurs as micrite, spar cements, neomorphic patches and spar filling veinlets. Non-stoichiometric dolomite and ankerite occur as cements (dolomite also as replacements) in the Middle Devonian, post-dating calcite types. All these phases pre-date tectonic stylolites, indicating compaction after stabilization of the carbonate minerals. Strontium concentrations indicate that Early Devonian and Early Carboniferous micrites initially precipitated as aragonite; Middle and Late Devonian micrites precipitated as high-Mg calcites. Both precursors were diagenetically stabilized to low-Mg calcites through interaction with meteoric waters in phreatic environments. Trace elements in dolomite and ankerite indicate precipitation from Sr-enriched meteoric water. All studied carbonates, except Middle Devonian limestones, precipitated in reducing environments, which favoured incorporation of Fe and Mn. Late calcite generations precipitated from more saline waters than micrites. Light ¹⁸O values in micrites suggest alteration mainly in meteoric-phreatic environments. The dolomites and ankerites precipitated from more ¹⁸O-depleted fluids than the calcites, suggesting a greater contribution from meteoric waters. Variations in ¹³C of micrites represent primary secular trends, according to published ¹³C variations. The ¹³C oscillations within each succession probably relate to sea-level oscillations. Strontium isotopes also point to a meteoric origin of diagenetic fluids. Model calculations suggest that O and Sr isotopes equilibrated between calcites and fluid at relatively low water/rock ratios, whereas C isotopic signatures are inherited from limestones.     

Stable oxygen isotope and pollen records from eastern Scotland and a consideration of Late-glacial and early Holocene climate change for Europe

The presence of marl deposits belonging to the Lateglacial period in a former lake basin at Lundin Tower in Fife, Scotland has allowed palaeoenvironmental investigations by means of carbonate δ¹³C and δ¹⁸O, and organic matter δ¹³C, in addition to palynology. The variations that emerge reveal strong similarities between the pollen and isotope records and these are interpreted as reflecting climatic shifts. The classic Late-glacial pattern of Oldest Dryas–Bølling–Older Dryas–Allerød–Younger Dryas may be evident and other climatic oscillations are shown to have occurred not only during the Allerød but also in the Preboreal. The problem of the time discordance between isotopic change and pollen representation is addressed through explanations involving lags in plant colonization. A comparison of the δ¹⁸O records from 43 sites across Europe reveals two different regional patterns, which raises fundamental questions over the nature of Late-glacial palaeoclimates.     

Paleomagnetic study of the Messejana Plasencia dyke (Portugal and Spain): A lower Jurassic paleopole for the Iberian plate

The only Iberian lower Jurassic paleomagnetic pole come from the “Central Atlantic Magmatic Province”-related Messejana Plasencia dyke, but the age and origin of its remanence have been a matter of discussion. With the aim of solving this uncertainty, and to go further into a better understanding of its emplacement and other possible tectonic features, a systematic paleomagnetic investigation of 40 sites (625 specimens) distributed all along the 530 km of the Messejana Plasencia dyke has been carried out. Rock magnetic experiments indicate PSD low Ti-titanomagnetite and magnetite as the minerals carrying the NRM. The samples were mostly thermally demagnetized. Most sites exhibit a characteristic remanent component of normal polarity with the exception of two sites, where samples with reversed polarities have been observed. The paleomagnetic pole derived from a total of 35 valid sites is representative of the whole structure of the dyke, and statistically well defined, with values of PLa = 70.4°N, PLo = 237.6°E, K = 47.9 and A₉₅ = 3.5°. Paleomagnetic data indicates that: (i) there is no evidence of a Cretaceous remagnetization in the dyke, as it was suggested; (ii) most of the dyke had a brief emplacement time; furthermore, two dyke intrusion events separated in time from it by at least 10,000 y have been detected; (iii) the high grouping of the VGPs directions suggests no important tectonic perturbations of the whole structure of the dyke since its intrusion time; (iv) the pole derived from this study is a good quality lower Jurassic paleopole for the Iberian plate; and (v) the Messejana Plasencia dyke paleopole for the Iberian plate is also in agreement with quality-selected European and North American lower Jurassic paleopoles and the magnetic anomalies data sets that are available for rotate them to Iberia.     

Jurassic Black Shales Facies from Qiangtang Basin (Northern Tibet):Rare Earth and Trace Elements for Paleoceanographic Implications

The Biluo Co and Amdo 114 station, northern Tibet, cropping out the Early Toarcian and Middle-Late Tithonian (Jurassic) organic-rich black shales, have been a focus to petroleum geologists in discussing their oil-producing potential. This paper first reports the trace elements and rare earth elements to discuss the paleoenvironments, redox conditions and sedimentary mechanisms of those black shales. Both sections exhibit variation in trace element abundances with concentrations <0.1 ppm to 760 ppm, mostly enriched in V, Cr, Ni, Cu, Zn, Mo, Ba and U. Element ratios of Ni/Co, V/Cr, U/Th and V/(V+Ni) plus U were used to identify redox conditions. The shale-normalized rare earth element (REE) patterns are characterized by the flat-shale type with instable Ce anomalies and very weekly positive Eu anomalies. Positive Ceanom values are significant with values varying between –0.064 and 0.029 in Biluo Co, which may be interpreted as release of REE and input of riverine terrestrial matter with rich Ce (resulting in pH change) during the anoxic conditions. In the middle parts of Amdo 114 station, distinct negative Ceanom values are observed (?0.238 to ?0.111) and associated surface water warming were interpreted as being related to a major sea level rise. In contrast, the formation of the black shales in the lower and upper part of the studied succession took place during a cooler (Ceanom values >–0.10), lower surface water productivity, and lower sea-level stage. Thus, we emphasize the role of different factors that control the formation of local and regional black shales. The most important factors are sea-level fluctuations and increasing productivity.     

用Mo-TOC相关性估算海相泥质烃源岩原始有机碳的一种新方法——以藏南白垩系海相泥岩、页岩为例

本文引入一种原始有机碳恢复的新方法,即利用Mo-TOC相关性来估算海相泥质烃源岩原始有机碳。并以藏南地区白垩纪海相泥岩、页岩为例,估算其原始有机碳含量及有机碳损失率。该方法可能在我国高成熟度-过成熟烃源岩的评价和油气资源量预测中发挥重要的作用。     

Origin of high-An plagioclase in the early Permian (~280 Ma) Xiaohaizi wehrlite,Northwest China: insights from melt inclusions in clinopyroxene macrocrysts and zircon oxygen isotopes

ABSTRACT

The Xiaohaizi wehrlite intrusion in the early Permian Tarim Large Igneous Province, Northwest China, is characterized by unusual high-An (up to 86) plagioclases. It has been suggested that H₂O may have exerted a major control on their formation, but this interpretation requires further direct evidence. Moreover, it remains unclear where the water came from. In order to unravel these questions, we present electron microprobe analyses of minerals and melt inclusions in clinopyroxene macrocrysts in the dikes crosscutting the Xiaohaizi wehrlite intrusion and in situ oxygen isotope data of zircons from the Xiaohaizi wehrlite. The homogenized melt inclusions have restricted SiO₂ (45.5–48.7 wt.%) and Na₂O + K₂O (2.4–3.8 wt.%) contents, displaying sub-alkaline affinity. This is inconsistent with the alkaline characteristic of the parental magma of the clinopyroxenes, suggesting significant modification of melt inclusions by contamination of the host clinopyroxene due to overheating. Nevertheless, the Ca/Na ratios (2.9–4.7) of melt inclusions are the upper limit of the parental magma of the clinopyroxenes due to high CaO (21.5–23.0 wt.%) and very low Na₂O (0.22–0.34 wt.%) contents in the host clinopyroxenes. Thermodynamic calculation suggests that under fixed P (2.7 kbar) and T (1000°C), and assumed H₂O (~1.5 wt.%) conditions, the Ca/Na ratio of the parental magma cannot generate high-An plagioclase in the wehrlite. The results confirm that H₂O exerts a major control. Zircon δ¹⁸O (VSMOW) values (2.99–3.71‰) are significantly lower than that of mantle-derived zircon (5.3 ± 0.6‰). Such low zircon δ¹⁸O values may be due to incorporation of large amounts of low-δ¹⁸O, hydrothermally altered oceanic crust. However, geochemical and Sr-Nd-Pb isotopic data do not support recycled oceanic crust in the mantle source of the Xiaohaizi intrusion. Alternatively this can be explained by incorporation of meteoritic water in the magma chamber. This will increase the H₂O content of the liquid that finally crystallize high-An plagioclases.     

Constraining the age of the last marine sediments in the late Cretaceous of central south Pyrenees (NE Spain): Insights from larger benthic foraminifera and strontium isotope stratigraphy

The uppermost Cretaceous (upper Campanian–Maastrichtian) marine deposits of the central south Pyrenees host a rich larger benthic foraminiferal fauna and several rudist-rich levels. These marine deposits are directly overlain by the continental facies of the Arén and Tremp Formations, which are famous for their fossil dinosaur remains. Larger benthic foraminiferal distribution documents an important faunal turnover in all the carbonate platform environments within the photic zone, from open marine to littoral areas. Biostratigraphy indicates that this turnover occurred close to the Campanian-Maastrichtian boundary. This is also confirmed by strontium isotope stratigraphy which indicates an earliest Maastrichtian age for the appearance of the larger benthic foraminiferal assemblage constituted by Lepidorbitoides socialis, Clypeorbis mammillata, Wannierina cataluniensis, Orbitoides gruenbachensis, Siderolites aff. calcitrapoides, Fascispira colomi, Omphalocyclus macroporus and Laffiteina mengaudi. In particular, a numerical age of 71 Ma is obtained for the Hippurites radiosus level, just a few meters below the first continental deposits of the Arén sensu stricto Formation. The youngest marine sediments of the central south Pyrenees are early Maastrichtian in age. This is also an important constraint for the age of the end-Cretaceous dinosaur fossil localities of the Tremp basin.