An Ordovician age for the Muggort's Bay Lower Palaeozoic inlier,County Waterford,Ireland—the southernmost exposure of the Irish Caledonides

The most southerly exposed Lower Palaeozoic strata in Ireland occur on the southwest coast of County Waterford along a 2.5 km long coastal section at Muggort's Bay where they are surrounded by Devonian rocks. Five formations can be distinguished which, in ascending order, are: the Ballycurreen, Carrickbrean, Rathnameenagh, Moanbrack and Killinoorin formations. The total thickness of the succession is over 1800 m. No macrofossils are present, but the lithologies are largely fine‐grained turbidites and subordinate volcanic rocks which closely resemble the Ribband Group seen elsewhere in southeast Ireland and have previously therefore been classified with it. Palynological analysis was undertaken on 25 samples collected from Muggort's Bay, of which eight were productive. Diagnostic microfossils, comprising acritarchs, chitinozoans and scolecodonts, indicate an Early to Middle Ordovician age for both the Rathnameenagh and the Moanbrack formations. These ages confirm that the strata are part of the Ribband Group which elsewhere has been biostratigraphically dated as ranging from Mid‐Cambrian to Mid‐Ordovician. Reworked mid‐Middle Cambrian acritarchs occur in the Moanbrack Formation and reworked late Middle to early Late Cambrian acritarchs in the Rathnameenagh Formation. Despite generally poor preservation of the organic matter, some 20 acritarch species have been distinguished. Among these, three species belong to the herein revised genus Retisphaeridium for which an emended diagnosis is proposed together with two new combinations, Retisphaeridium capsulatum (Jankauskas, 1976 ) Vanguestaine nov. comb. and Retisphaeridium pusillum (Moczydlowska, 1998 ) Vanguestaine nov. comb. Copyright © 2005 John Wiley & Sons, Ltd.     

Cambro‐Ordovician trace fossils from the SW‐Norwegian Caledonides

A diverse trace fossil association is described for the first time from low‐grade metamorphic rocks of the SW‐Norwegian Caledonides. The investigated cliff sections with autochthonous to parautochthonous metasediments comprise a coarsening‐ and thickening‐upward succession interpreted as prograding delta deposits. Sedimentary features indicate a tide‐influenced environment. Twenty‐one ichnospecies have been identified and assigned to the Cruziana and Skolithos ichnofacies, including the oldest record of Beaconites capronus and Macaronichnus segregatis. Cruziana ichnostratigraphy (sensu lato), previously rarely used in other palaeocontinents than Gondwana, allows an age determination for these metasediments of Middle Cambrian to Lower Ordovician as indicated by the presence of Cruziana barbata, C. furcifera, C. rugosa, C. semiplicata, Didymaulichnus rouaulti and Rusophycus ramellensis. Baltica was geographically the most isolated from the other three large continents (Gondwana, Laurentia and Siberia) during Cambro‐Ordovician time, and provinciality of faunal assemblages (e.g. brachiopods, conodonts) has been proved and is also supposed for trilobites by some authors. However, although the Cruziana ichnospecies result from a high specialization of their tracemakers, and therefore only a small group of trilobite species is eligible for its origin, the ichnospecies reported from Baltica occur also on other palaeocontinents and do not support the assumption of trilobite provincialism. Copyright © 2004 John Wiley & Sons, Ltd.     

Evidence for microbial activity in British and Irish Ordovician pillow lavas

Pyrite is consistently found in modern seafloor vesicular basalts and has a sulphur isotopic composition consistent with microbial activity. We present S isotope data from pyrite in Ordovician pillow lavas at localities across the British Isles, which yield a range of δ³⁴S compositions consistent with two components of sulphur: groundmass pyrite (~0 ± 4‰) and ³²S‐enriched pyrite in the vesicles (−8‰ to −27‰). The latter are recorded from vesicular lavas in four different terranes, representing different settings at the margins of the Iapetus Ocean. Whereas a component of magmatic sulphate is recognized in the groundmass values, the isotopically light data in the vesicles are consistent with microbial reduction of seawater sulphate in sub‐seafloor lavas. This is consistent with modern examples and indicates considerable longevity for this sub‐seafloor microbial habitat. Copyright © 2014 John Wiley & Sons, Ltd.     

Exhumation of the Dora Maira ultrahigh‐pressure unit by buoyant uprise within a low‐viscosity mantle oblique‐slip shear zone

The Brossasco‐Isasca subunit (BIU) of the Dora Maira massif is currently the only known continental crustal ultrahigh‐pressure (UHP) unit in the Western Alps. The peak pressure/temperature conditions are 3.5–4.5 GPa/~730 °C; exhumation from ~3.5 GPa to ~1 GPa occurred within 2.2 ± 1.8 Ma, but the exhumation mechanism is incompletely understood. We present a conceptual model for the buoyancy‐driven exhumation of the BIU inside a low‐viscosity, dense mantle shear zone weakened by increased strain rates due to simultaneous strike‐slip and subduction (oblique‐slip) of the European plate. Two‐dimensional thermo‐mechanical models simulate such a buoyant uprise of an ellipse inside an inclined layer. Simulations (i) show the feasibility of the conceptual model, (ii) fit the pressure/temperature/time record and (iii) constrain effective viscosities. The model is compatible with the (i) small volume of continental crustal UHP rock in the Western Alps, (ii) minor erosion during exhumation and (iii) strike‐slip deformation during the exhumation period.     

Rapid tectonic exhumation, detachment faulting and orogenic collapse in the Caledonides of western Ireland

Collision of the oceanic Lough Nafooey Island Arc with the passive margin of Laurentia after 480 Ma in western Ireland resulted in the deformation, magmatism and metamorphism of the Grampian Orogeny, analogous to the modern Taiwan and Miocene New Guinea Orogens. After 470 Ma, the metamorphosed Laurentian margin sediments (Dalradian Supergroup) now exposed in Connemara and North Mayo were cooled rapidly (>35 °C/m.y.) and exhumed to the surface. We propose that this exhumation occurred mainly as a result of an oceanward collapse of the colliding arc southwards, probably aided by subduction rollback, into the new trench formed after subduction polarity reversal following collision. The Achill Beg Fault, in particular, along the southern edge of the North Mayo Dalradian Terrane, separates very low-grade sedimentary rocks of the South Mayo Trough (Lough Nafooey forearc) and accreted sedimentary rocks of the Clew Bay Complex from high-grade Dalradian meta-sedimentary rocks, suggesting that this was a major detachment structure. In northern Connemara, the unconformity between the Dalradian and the Silurian cover probably represents an eroded major detachment surface, with the Renvyle–Bofin Slide as a related but subordinate structure. Blocks of sheared mafic and ultramafic rocks in the Dalradian immediately below this unconformity surface probably represent arc lower crustal and mantle rocks or fragments of a high level ophiolite sheet entrained along the detachment during exhumation.Orogenic collapse was accompanied in the South Mayo Trough by coarse clastic sedimentation derived mostly from the exhuming Dalradian to the north and, to a lesser extent, from the Lough Nafooey Arc to the south. Sediment flow in the South Mayo Trough was dominantly axial, deepening toward the west. Volcanism associated with orogenic collapse (Rosroe and Mweelrea Formations) is variably enriched in high field strength elements, suggesting a heterogeneous enriched mantle wedge under the new post-collisional continental arc.     

青海拉脊山东段白家藏侵入岩锆石U-Pb年代学、地球化学特征及其地质意义

白家藏侵入岩位于青海省民和县,大地构造位置上处于拉脊山蛇绿混杂岩带东段。通过岩石学、同位素年代学和岩石地球化学方法,对白家藏侵入岩进行了研究,以确定其侵位时代并探讨大地构造环境。结果表明,白家藏侵入岩主要由闪长岩和石英闪长岩组成,分别在闪长岩和石英闪长岩中获得锆石U-Pb年龄为（472.5±1.9）Ma和（467.3±2.5）Ma,二者在误差范围内一致,据此判断白家藏侵入岩的侵位年龄约470 Ma,为中奥陶世。地球化学特征显示：岩体w（SiO₂）为55.67%~59.04%,Na₂O/K₂O值为3.35~6.14,且w（Na₂O）高于w（K₂O）,显示富钠、贫钾特征;A/CNK值主体介于0.76~1.01之间,属于准铝质钙碱性系列岩石;稀土配分曲线呈轻稀土元素相对弱富集（（La/Yb）_N=2.51~4.57）,轻、重稀土元素内部分馏较弱的微右倾型曲线;岩石明显富集大离子亲石元素Rb、Ba和活泼的不相容元素Th、U,相对亏损高场强元素Nb、Ta、P、Ti等;环境判别显示具岛弧花岗岩特征。以上特征表明白家藏侵入岩为拉脊山洋俯冲阶段的产物。     

Late Cretaceous Adakitic Granites of the Southeastern Tibetan Plateau: Garnet Fractional Crystallization of Arc‐Like Magmas at the Thickened Neo‐Tethyan Continental Margin

The tectonic setting of Cretaceous granitoids in the southeastern Tibet Plateau, east of the Eastern Himalaya Syntax, is debated. Exploration and mining of the Laba Mo–Cu porphyry-type deposit in the area has revealed Late Cretaceous granites. New and previously published zircon U–Pb dating indicate that the Laba granite crystallized at 89–85 Ma. Bulk-rock geochemistry, Sr–Nd isotopic data and in situ zircon Hf isotopic data indicate that the granite is adakitic and was formed by partial melting of thickened lower crust. The Ca, Fe, and Al contents decrease with increasing SiO2 content.These and other geochemical characteristics indicate that fractional crystallization of garnet under high-pressure conditions resulted in the adakitic nature of the Laba granite. Cretaceous granitoids are widespread throughout the Tibetan Plateau including its southeastern area, forming an intact curved belt along the southern margin of Eurasia. This belt is curved due to indenting by the Indian continent during Cenozoic, but strikes parallel to both the Indus–Yarlung suture zone and the Main Frontal Thrust belt. It is therefore likely that Cretaceous granitoids in both the Gangdese and southeastern Tibetan Plateau areas resulted from subduction of Neo-Tethyan lithosphere.     

Geochemical correlation of Ordovician flow tuffs in North Wales

Ordovician rhyolitic tuffs in North Wales are correlated on the basis of their whole-rock trace element composition. Multivariate statistics verify that major ignimbrite sheets are chemically unique, with Zr, Y and Nb being the most useful elements to characterize individual deposits. Fractionation processes during transport and emplacement of the pyroclastic flows results in little lateral variation in the whole-rock geochemistry of deposits; different diagenetic histories in subaerial and subaqueous environments did not mask recognition of primary ignimbrite units. A partially welded vitric ash flow tuff is correlated with the Pitts Head Tuff ash flow sheet, and a tuff horizon previously assumed to be reworked Pitts Head Tuff is shown to be chemically most similar to the fourth member of the Capel Curig Volcanic Formation. Validity of these correlations is upheld by biostratigraphic and sedimentological evidence. The new correlations necessitate a revision of the stratigraphy in North Wales and indicate a significant lapse of time (perhaps one million years) between emplacement of the Pitts Head Tuff and eruption of the Lower Rhyolitic Tuff of the overlying Snowdon Volcanic Group.     

A revision of the Ordovician stratigraphy for the western Ireland Caledonides and implications for tectonic models

The western Ireland Ordovician stratigraphy has been previously used to constrain the timing of docking of an island arc and its fore‐arc basin with the margin of Laurentia for the British and Irish Caledonides. New field relationships and age data indicate that one of the key formations, the Rosroe Formation (459.2 ± 0.8 and 465.1 ± 2.1 Ma), and its supposed lateral equivalent, the Maumtrasna Formation are younger than previously interpreted. New age data for a tuff band in the Maumtrasna Formation (468.9 ± 1.3 Ma) also support previous studies showing it can be correlated to the adjacent Mweelrea Formation. The new field evidence, age data and geochemistry contradict some previous studies and show that the Maumtrasna, Rosroe and Derrylea formations can no longer be considered lateral equivalents. Based on the new stratigraphy a revised tectonic model is required with sedimentation in this part of the Caledonides taking place in a fore‐arc basin outboard of a continental arc and the oceanic arc was an along‐strike equivalent of this arc situated in an embayment of the Laurentian margin. Copyright © 2010 John Wiley & Sons, Ltd.     

海南岛北西部邦溪地区奥陶纪火山-碎屑沉积岩岩石学、矿物学和地球化学:源区及构造环境暗示

海南岛奥陶纪火山-碎屑沉积岩矿物、地球化学成分与源区岩性质和沉积构造环境密切相关.岩相学观察和矿物化学分析表明,所研究的岩石主要碎屑矿物由石英、绿泥石(Si:5.8～6.2 a.p.f.u.、Mg/(Mg Fe):～0.45)和自色云母(Si:6.2～6.8 a.p.f.u.、Al:4.5～5.7 a.p.f.u.)组成,含少量的长石(主要为钾长石)、黑云母(Mg/(Mg Fe)=0.43、TiO2=0.01%)和磷灰石等矿物.地球化学特征上,这些岩石普遍具有高SiO2含量(Al2O3/SiO2=0.07～0.19)、相对高的K2O/Na2O比值(1.25～14.71)和高的FeOtotal MgO含量(普遍大于5%,最高达11.5%),但微量元素(含REE)含量普遍低于PAAS(NASC),且REE分布模式显示LREE富集((La/Yb)N=6.1～12.5)、Eu负异常或弱负异常(δEu=0.57～0.86).高的前交代CIA(～84)和PIA(～85)指数、A-CN-K分布模式以及可变的Th/U(2.9～25)比值还说明源区已经历强烈的化学和机械风化作用.低的Ce/Pb比值(2.1～2.8)则反映海南岛早古生代地壳已经历过Pb的富集事件.结合矿物化学成分和区域地质对比,研究区奥陶纪火山-碎屑沉积岩源区主要由变质的岩浆弧花岗闪长岩和弧长英质火山岩组成,少量的铁镁质成分不能排除,因而暗示一个从活动大陆边缘到被动大陆边缘的过渡性沉积构造环境.同时,推测海南岛在早古生代和晚古生代-早中生代可能分别存在一次俯冲增生-碰撞造山事件;海南岛(可能包括华夏地块)应于晚奥陶世后才脱离东冈瓦纳大陆的澳大利亚边缘.     

Fault slip analysis of Quaternary faults in southeastern Korea

The Quaternary stress field has been reconstructed for southeast Korea using sets of fault data. The subhorizontal direction of the maximum principal stress (σ₁) trended ENE and the direction of the minimum principal stress (σ₃) was nearly vertical. The stress ratio (Φ = (σ₂ − σ₃) / (σ₁ − σ₃)) value was 0.65. Two possible interpretations for the stress field can be made in the framework of eastern Asian tectonics; (1) The σ_Hmax trajectory for southeast Korea fits well with the fan-shaped radial pattern of maximum principal stress induced by the India–Eurasia collision. Thus, we suggest that the main source for this recent stress field in southeast Korea is related to the remote India–Eurasia continental collision. (2) The stress field in Korea shows a pattern similar to that in southwestern Japan. The origin for the E–W trending σ_Hmax in Japan is known to be related to the mantle upwelling in the East China Sea. Thus, it is possible that Quaternary stress field in Korea has evolved synchronously with that in Japan. We suggest further studies (GPS and in situ stress measurement) to test these hypotheses.     

Dolomitization of the Waulsortian Limestone (Lower Carboniferous) in the Irish Midlands

The Waulsortian Limestone (Lower Carboniferous) of the southern Irish Midlands is dolomitized pervasively over a much larger region than previous studies have documented. This study indicates a complex, multistage, multiple fluid history for regional dolomitization. Partially and completely dolomitized sections of Waulsortian Limestones are characterized by finely crystalline (0·01–0·3 mm) planar dolomite. Planar replacive dolomite is commonly followed by coarse (≥0·5 mm) nonplanar replacive dolomite, and pervasive void‐filling saddle dolomite cement is frequently associated with Zn–Pb mineralization. Planar dolomite has average δ¹⁸O and δ¹³C values (‰ PDB) of –4·8 and 3·9 respectively. These are lower oxygen and slightly higher carbon isotope values than averages for marine limestones in the Waulsortian (δ¹⁸O=–2·2, δ¹³C=3·7). Mean C and O isotope values of planar replacive dolomite are also distinct from those of nonplanar and saddle dolomite cement (–7·0 and 3·3; –7·4 and 2·4 respectively). Fluid inclusions indicate a complex history involving at least three chemically and thermally distinct fluids during dolomite cementation. The petrography and geochemistry of planar dolomites are consistent with an early diagenetic origin, possibly in equilibrium with modified Carboniferous sea water. Where the Waulsortian was exposed to hydrothermal fluids (70–280 °C), planar dolomite underwent a neomorphic recrystallization to a coarser crystalline, planar and nonplanar dolomite characterized by lower δ¹⁸O values. Void‐filling dolomite cement is isotopically similar to nonplanar, replacive dolomite and reflects a similar origin from hydrothermal fluids. This history of multiple stages of dolomitization is significantly more complex than earlier models proposed for the Irish Midlands and provides a framework upon which to test competing models of regional vs. localized fluid flow.     

Tephra‐linked peat humification records from Irish ombrotrophic bogs question nature of solar forcing at 850 cal. yr BC

This paper investigates evidence for palaeoclimatic changes during the period ca. 1500–500 cal. yr BC through peat humification studies on seven Irish ombrotrophic bogs. The sites are well‐correlated by the identification of three mid‐first millennium BC tephras, which enable the humification records at specific points in time to be directly compared. Phases of temporarily increased wetness are suggested at ca. 1300–1250 cal. yr BC , ca. 1150–1050 cal. yr BC , ca. 940 cal. yr BC and ca. 740 cal. yr BC . The last of these is confirmed to be synchronous at five sites, suggesting external forcing on a regional scale. The timing of this wet‐shift is constrained by two closely dated tephras and is demonstrated to be distinct from the widely reported changes to cooler/wetter conditions associated with a solar minimum at 850–760 cal. yr BC , at which time the Irish sites appear instead to experience drier conditions. The results suggest the possibility of either non‐uniform responses to solar forcing in northwest Europe at this time, or the existence of unrelated climate events in the early first millennium BC . The findings caution against the correlation of loosely dated palaeoclimate data if the effects of forcing mechanisms are to be understood. Copyright © 2006 John Wiley & Sons, Ltd.     

Reactivated strike–slip faults: examples from north Cornwall, UK

Several strike–slip faults at Crackington Haven, UK show evidence of right-lateral movement with tip cracks and dilatational jogs, which have been reactivated by left-lateral strike–slip movement. Evidence for reactivation includes two slickenside striae on a single fault surface, two groups of tip cracks with different orientations and very low displacement gradients or negative (left-lateral) displacements at fault tips.

Evidence for the relative age of the two strike–slip movements is (1) the first formed tip cracks associated with right-lateral slip are deformed, whereas the tip cracks formed during left-lateral slip show no deformation; (2) some of the tip cracks associated with right-lateral movement show left-lateral reactivation; and (3) left-lateral displacement is commonly recorded at the tips of dominantly right-lateral faults.

The orientation of the tip cracks to the main fault is 30–70° clockwise for right-lateral slip, and 20–40° counter-clockwise for left-lateral slip. The structure formed by this process of strike–slip reactivation is termed a “tree structure” because it is similar to a tree with branches. The angular difference between these two groups of tip cracks could be interpreted as due to different stress distribution (e.g., transtensional/transpressional, near-field or far-field stress), different fracture modes or fractures utilizing pre-existing planes of weakness.

Most of the d–x profiles have similar patterns, which show low or negative displacement at the segment fault tips. Although the d–x profiles are complicated by fault segments and reactivation, they provide clear evidence for reactivation. Profiles that experienced two opposite slip movements show various shapes depending on the amount of displacement and the slip sequence. For a larger slip followed by a smaller slip with opposite sense, the profile would be expected to record very low or reverse displacement at fault tips due to late-stage tip propagation. Whereas for a smaller slip followed by larger slip with opposite sense, the d–x profile would be flatter with no reverse displacement at the tips. Reactivation also decreases the ratio of d_max/L since for an original right-lateral fault, left lateral reactivation will reduce the net displacement (d_max) along a fault and increase the fault length (L).

Finally we compare Crackington Haven faults with these in the Atacama system of northern Chile. The Salar Grande Fault (SGF) formed as a left-lateral fault with large displacement in its central region. Later right-lateral reactivation is preserved at the fault tips and at the smaller sub-parallel Cerro Chuculay Fault. These faults resemble those seen at Crackington Haven.     

The stratigraphy and sedimentology of the Ordovician Partry Group,southeastern Murrisk,Ireland

The uppermost part of the Ordovician succession in southeastern Murrisk, western Ireland, consists of coarse-grained sedimentary rocks and tuffs, the Partry Group, hitherto subdivided into the Mweelrea Formation, unconformably overlain by the Maumtrasna Formation. The age of the lower part of the succession is late Llanvirn whilst that of the upper part is unknown. Evidence is presented to show that the two formations are lateral equivalents. Consequently the Mweelrea Formation is redefined and the Maumtrasna Formation becomes redundant. The revision of the stratigraphy enables a coherent sedimentological model for the group to be proposed. The sediments of the Mweelrea Formation were deposited on alluvial fans and distally-equivalent alluvial plains and delta fans. The direction of sediment transport was towards the north and northwest.     

An outline tephrochronology for the Holocene of the north of Ireland

Geochemically typed thin layers of Icelandic Holocene tephras form a tephrochronology for the north of Ireland. Tephrochronology construction is based on geochemical linkage with dated historic Icelandic eruptions and high-precision multisample radiocarbon dating. Comparison with geochemically typed Holocene layers at sites throughout Scotland and northern England shows that some layers are widespread throughout much of the northern British Isles. Other layers of known historic date have so far been detected only in Ireland.     

Preservation of subduction‐related prograde deformation in lawsonite pseudomorph‐bearing rocks

Lawsonite pseudomorphs are used to identify and distinguish the kinematic records of subduction and exhumation in blueschist‐facies rocks from Syros (Cyclades; Greece). Lawsonite is a hydrous mineral that crystallizes at high‐pressure and low‐temperature conditions. During decompression, lawsonite is typically pseudomorphed by an aggregate dominated by epidote and paragonite. Such aggregates are easily deformable and if deformation occurs after the lawsonite breakdown, the pseudomorphs are difficult to distinguish from the matrix. The preservation of the lawsonite crystal shape, despite complete retrogression, indicates therefore that the host blueschist rock has not been affected by penetrative deformation during exhumation, thus providing indication of strain‐free conditions. Therefore, tracking the lawsonite growth and destabilization along the P–T path followed by the rocks during a subduction/exhumation cycle provides information about the subduction/exhumation‐related deformation. Using microstructural observations and P–T pseudosections calculated with thermocalc , it is inferred that top‐to‐the‐south sense of shear preserved in lawsonite pseudomorph‐bearing blueschists on Syros occurred during the prograde metamorphic path within the lawsonite stability field, and is therefore associated with subduction. On the contrary, the deformation with a top‐to‐the‐north sense of shear is observed in surrounding rocks, where lawsonite pseudomorphs are deformed or apparently lacking. This deformation occurred after the lawsonite breakdown during exhumation. At the regional scale, exhumation‐related deformation is heterogeneous, allowing the preservation of lawsonite pseudomorphs in significant volumes of blueschists of the central and southern Cyclades. It is argued that such successive shearing deformation events with opposite senses more likely correspond to an exhumation process driven by slab rollback, in which subduction and exhumation are not synchronous.