Controls on Methane Occurrences in Shallow Aquifers Overlying the Haynesville Shale Gas Field,East Texas

Understanding the source of dissolved methane in drinking‐water aquifers is critical for assessing potential contributions from hydraulic fracturing in shale plays. Shallow groundwater in the Texas portion of the Haynesville Shale area (13,000 km²) was sampled (70 samples) for methane and other dissolved light alkanes. Most samples were derived from the fresh water bearing Wilcox formations and show little methane except in a localized cluster of 12 water wells (17% of total) in a approximately 30 × 30 km² area in Southern Panola County with dissolved methane concentrations less than 10 mg/L. This zone of elevated methane is spatially associated with the termination of an active fault system affecting the entire sedimentary section, including the Haynesville Shale at a depth more than 3.5 km, and with shallow lignite seams of Lower Wilcox age at a depth of 100 to 230 m. The lignite spatial extension overlaps with the cluster. Gas wetness and methane isotope compositions suggest a mixed microbial and thermogenic origin with contribution from lignite beds and from deep thermogenic reservoirs that produce condensate in most of the cluster area. The pathway for methane from the lignite and deeper reservoirs is then provided by the fault system.     

Effect of a Freshwater Layer Overlying Salt Water on the Regime of Replacement in Confined Coastal Aquifers

A mathematical model of fresh groundwater flow from a semi-infinite confined aquifer into a sea (pool, trench, and the like) filled with salt water and having a freshwater layer above its horizon. To study this problem a mixed boundary-value problem of the theory of analytical functions is formulated and solved with the use of the Polubarinova-Kochina method. The obtained exact analytical relationships and numerical calculations are used to perform a detailed hydrodynamic analysis of the effect of the freshwater layer and other physical parameters of the model on the character and the extent of displacement.     

Influence of Hydraulic Fracturing on Overlying Aquifers in the Presence of Leaky Abandoned Wells

The association between hydrocarbon‐rich reservoirs and organic‐rich source rocks means unconventional oil and gas plays usually occur in mature sedimentary basins—where large‐scale conventional development has already taken place. Abandoned wells in proximity to hydraulic fracturing could be affected by increased fluid pressures and corresponding newly generated fractures that directly connect (frac hit) to an abandoned well or to existing fractures intersecting an abandoned well. If contaminants migrate to a pathway hydraulically connected to an abandoned well, upward leakage may occur. Potential effects of hydraulic fracturing on upward flow through a particular type of leaky abandoned well—abandoned oil and gas wells converted into water wells were investigated using numerical modeling. Several factors that affect flow to leaky wells were considered including proximity of a leaky well to hydraulic fracturing, flowback, production, and leaky well abandonment methods. The numerical model used historical records and available industry data for the Eagle Ford Shale play in south Texas. Numerical simulations indicate that upward contaminant migration could occur through leaky converted wells if certain spatial and hydraulic conditions exist. Upward flow through leaky converted wells increased with proximity to hydraulic fracturing, but decreased when flowback and production occurred. Volumetric flow rates ranged between 0 and 0.086 m³/d for hydraulic‐fracturing scenarios. Potential groundwater impacts should be paired with plausible transport mechanisms, and upward flow through leaky abandoned wells could be unrelated to hydraulic fracturing. The results also underscore the need to evaluate historical activities.     

Numerical modeling of a long-term in situ chemical osmosis experiment in the Pierre Shale,South Dakota

We have numerically modeled evolving fluid pressures and concentrations from a nine-year in situ osmosis experiment in the Pierre Shale, South Dakota. These data were obtained and recently interpreted by one of us (C.E.N.) as indicating a potentially significant role for chemical osmosis in media like the Pierre Shale. That analysis considered only the final pressure differentials among boreholes that were assumed to represent osmotic equilibrium. For this study, the system evolution was modeled using a recently developed transient model for membrane transport. The model simulates hydraulically and chemically driven fluid and solute transport. The results yield an estimate of the thickness of the water film between the clay platelets b of 40 Å, which corresponds to an osmotic efficiency σ of 0.21 for the ambient pore water salinity of 3.5 g/l TDS. These values largely confirm the results of the earlier equilibrium analysis. However, the new model analysis provides additional constraints suggesting that intrinsic permeability k = 1.4 × 10⁻¹⁹ m², specific storage S_s = 1.7 × 10⁻⁵ m⁻¹, and diffusion coefficient D* = 6 × 10⁻¹¹ m²/s. The k value is larger than certain independent estimates which range from 10⁻²¹ to 10⁻²⁰; it may indicate opening of microcracks during the experiments. The fact that the complex transient pressure and concentration behavior for the individual wells could be reproduced quite accurately, and the inferred parameter values appear to be realistic for the Pierre Shale, suggests that the new model is a useful tool for modeling transient coupled flows in groundwater systems.     

Methane in the hyporheic zone of a small lowland stream (Sitka, Czech Republic)

Methane concentrations and selected chemical parameters in interstitial water were examined along subsurface flowpath in two subsystems (hyporheic and parafluvial sediments) in the Sitka stream, Czech Republic. Interstitial methane concentrations exhibited a distinct spatial pattern. In the hyporheic downwelling zone where the sediments are relatively well oxygenated due to high hydrologic exchange with the surface water, low interstitial methane concentrations, averaging 9.3 μg CH₄/l, were found. In contrast, upwelling sediments and parafluvial sediments (active channel sediments lateral to the wetted channel) had significantly higher methane concentrations (p < 0.05, and p < 0.01, respectively), averaging 43.2 μg CH₄/l and 160.5 μg CH₄/l, respectively. Dissolved oxygen was the highest where surface water entered hyporheic/parafluvial sediments and decreased with water residence time in the sediments (p < 0.01). Nitrate concentrations decreased along the flowpath and were significantly lower at downstream end of the riffle (p < 0.001). Sulfate concentrations also show a slight decline with the water residence time, but differences were not significant. Effect of both nitrate and sulfate on methanogenesis is also discussed. The interstitial methane concentration significantly increased with surface water temperature (p < 0.001) and was negatively correlated with redox potential (p < 0.01) and dissolved oxygen (p < 0.05).     

云南建水跃进水库宏观异常研究

2001年8月初,云南省建水县跃进水库出现特大宏观异常——激烈的翻花冒泡现象,历时50多天。事后研究结果表明：该异常为区域断裂活动的表现,标志该区地应力增强,并非地震短临前兆。     

Anisotropy of magnetic susceptibility in welded tuffs: application to a welded-tuff dyke in the tertiary Trans-Pecos Texas volcanic province,USA

Consideration of published anisotropy of magnetic susceptibility (AMS) studies on welded ignimbrites suggests that AMS fabrics are controlled by groundmass microlites distributed within the existing tuff fabric, the sum result of directional fabrics imposed by primary flow lineation, welding, and (if relevant) rheomorphism. AMS is a more sensitive indicator of fabric elements within welded tuffs than conventional methods, and usually yields primary flow azimuth estimates. Detailed study of a single densely welded tuff sample demonstrates that the overall AMS fabric is insensitive to the relative abundances of fiamme, matrix and lithics within individual drilled cores. AMS determinations on a welded-tuff dyke occurring in a choked vent in the Trans-Pecos Texas volcanic field reveals a consistent fabric with a prolate element imbricated with respect to one wall of the dyke, while total magnetic susceptibility and density exhibit axially symmetric variations across the dyke width. The dyke is interpreted to have formed as a result of agglutination of the erupting mixture on a portion of the conduit wall as it failed and slid into the conduit, followed by residual squeezing between the failed block and in situ wallrock. Irrespective of the precise mechanism, widespread occurrence of both welded-tuff dykes and point-welded, aggregate pumices in pyroclastic deposits may imply that lining of conduit walls by agglutionation during explosive volcanic eruptions is a common process.     

江苏宝应4.9级地震序列双差定位处理

运用双差定位方法,对2012年7月江苏省宝应县4.9级地震序列重新精定位.精确定位结果与原始定位结果比较发现,精定位后震中位置更加集中,呈条带状分布,与现场烈度保持一定的相似性,震源深度集中于10 km与14 km附近两个区间,相比原始定位结果更加收敛.     

山东莒县井远大震异常的初步研究

本文通过对山东莒县井水位、水温资料的分析,认为莒县井水位、水温的异常典型模式为突降,异常多为远场大震的临震异常;远场大震的发生,是对莒县井孔区域应力的卸载。目前该区域的应力状态为拉张,对莒县井孔附近区域近期震情起到缓解作用。     

Simulating and mapping the risk of surge floods in multiple typhoon scenarios: a case study of Yuhuan County,Zhejiang Province,China

We propose a scenario-based method for simulating and mapping the risk of surge floods for use by local authorities concerned with public safety and urban planning in coastal areas. Focusing on the triad of hazard, vulnerability and adaptation capability, we estimate the comprehensive risk and display its spatial distribution using the raster calculation tool in ArcGIS. The detailed methodology is introduced via a case study of Yuhuan, an island county in Zhejiang Province, China, which is frequently affected by typhoon storm surges. First, we designed 24 typhoon scenarios and modeled the flood process in each scenario using the hydrodynamic module of MIKE 21. Second, flood depth and area were used for hazard assessment; an authorized indicator system of land use categories and a survey of emergency shelters were used for vulnerability and adaptation capability assessment, respectively; and a quantified model was used for assessment of the comprehensive risk. Lastly, we used the GIS raster calculation tool for mapping the risk of storm surges in multiple typhoon scenarios. Our principal findings are as follows: (1) Seawalls are more likely to be overtopped or destroyed by more severe storm surges with increasing typhoon intensity. (2) Most of the residential areas with inadequate emergency shelters are highly vulnerable to flood events. (3) As projected in the risk mapping, if an exceptional typhoon with a central pressure of 915 or 925 hPa made a landfall in Yuhuan, a wide range of areas would be flooded and at high risk. (4) Determining optimal strategies based on identification of risk-inducing factors is the most effective way of promoting safe and sustainable development in coastal cities.     

Public awareness and attitudes towards naval sonar mitigation for cetacean conservation: a preliminary case study in Fairfax County, Virginia. (the DC Metro area)

The potential impacts of naval sonar on cetaceans has led to a series of court cases and statements of concern by international organizations. However, there has been no research conducted on attitudes of the general public with respect to this issue. To investigate this, a preliminary public survey was conducted in Fairfax, Virginia (the Washington, DC Metro region). The majority of the public sampled believed that naval sonar impacted marine mammals (51.3%), that the US Navy should not be exempt from environmental regulations in time of peace (75.2%), and that sonar use should be moderated if it impacts cetaceans (75.8%). Individuals who were conservative, Republican, and have served in the military were more likely to believe the Navy should be exempt from marine mammal protection regulations. In addition, expert interviews were conducted to gain opinions on the potential ramifications of the recent US Supreme Court case on naval sonar mitigation.     

Electrokinetic phenomena associated with a water injection experiment at the Nojima fault on Awaji Island, Japan

Abstract Self-potential variations were measured to estimate the magnitude of electrokinetic and hydrological parameters (zeta potential and permeability) of the Nojima Fault zone in Awaji, Japan. The study observed self-potential variations that seemed to be associated with water flow from the injection well to the fracture zone, which were induced by turning the injection on and off. Amplitudes of the variations were a few to 0.03 V across 320–450 m dipoles. These variations can be explained well with an electrokinetic model. The quantity k/ζ (permeability/zeta potential) is in the range 1.6 × 10⁻¹³− 5.4 × 10⁻¹³ m²/V. Permeability of the Nojima fault zone can be estimated as approximately 10⁻¹⁶–10⁻¹⁵ m² on the assumption that the zeta potential is in the range –0.01 to –0.001 V.     

Hydrothermal sediments associated with a relict back-arc spreading center in the Shikoku Basin, recovered from the Nankai accretionary prism, Japan

The hemipelagic mudrocks of the Nankai accretionary prism, Japan, contain hydrothermal deposits associated with a relict spreading center in the Shikoku Basin. Initial work on core samples from Ocean Drilling Program site 808 found several samples with elevated concentrations of calcium, magnesium, iron and manganese, at depths of between 1060 and 1111 m below sea floor. However, the origin of these sediments was uncertain, due to a lack of data. There was no recorded evidence of whether these elevated concentrations were present throughout this interval of core, or if they were present as discrete layers with the background hemipelagic mudrocks in between. In the present study the core was resampled, and the sediments with anomalous chemical compositions were found to be present in discrete layers. This fact, along with a detailed interpretation of their geochemistry, has allowed them to be identified as hydrothermal sediments, associated with the relict spreading center in the Shikoku Basin. The lower (older) two layers display a chemical composition typical of umbers, while the upper (younger) two layers are metalliferous mudrocks typical of deposits found further from the spreading center.     

2003年12月1日新疆昭苏6.1级地震序列特征分析

通过分析昭苏6．1级地震序列特征、震源与介质破裂特性、震源环境与历史地震活动类比及区域地震和前兆资料的异常变化等，对该震前的区域地震活动背景、震后的震情趋势等有了较为细致的了解和判定。主要结果有：①在2003年新疆境内中强地震成组活动的背景下，于现代地震活动很弱的昭苏盆地内发生了6．1级地震；②6．1级地震为主一余型地震序列，震后序列衰减正常；③主震震源机制解结果与现代区域构造应力场特征吻合，表明构造活动具有明显的继承性，并对地震活动有着控制作用；④震源区域构造应力释放充分，区域应力场处于相对稳定的调整状态。综合各类分析结果后认为，震区发生更大地震的可能性很小。     

The response of the high-latitude ionosphere to the solar-wind pressure jump with a southward IMF on January 10, 1997

The well-studied event of January 10, 1997, was used to study the mechanism responsible for the response of the auroral ionosphere to the solar-wind dynamic pressure jump given a southward interplanetary magnetic field. All solar-wind parameters of this event were constant except for the jump in plasma density (duration 22 min). Immediately after arrival and during the pressure jump, the inner boundary of the auroral oval moved poleward, whereas the position of the outer boundary was stable. The amplification of the magnetopause current caused by an increase in the solar-wind plasma density was calculated. We think that the amplified magnetopause current is closed by the polarization current at the front of the disturbed region in the magnetosphere, thus forming the “transient ring current” that exists during the pressure jump. We determined the northward magnetic field of this “temporary ring current,” the order of magnitude of which coincided with that of the field responsible for the observed poleward shift of the high-latitude boundary of the auroral oval.     

太湖流域上游土地利用变化机制的实证分析--以浙江省安吉县为例

近10年来,太湖流域上游地区经济发展逐步趋于活跃,受此影响,区域人口-资源、环境-发展(PRED)出现了新的特点与趋势。基于上游地区土地利用/覆被变化对流域整体水环境与生态安全格局所具有的重要意义,本文选择安吉县作为典型案例,分析其区域土地利用的基本特征,土地利用变化与景观格局动态的过程,以及驱动因素与机制,由此揭示山区土地利用/覆被变化的一般性规律,为太湖流域上游地区经济发展与土地利用、环境保护相互协调,提供决策借鉴与依据。     

Hydrodynamic conditions associated with the formation,maintenance and dissipation of a phytoplankton thin layer in a coastal upwelling system

During May–June 2005, a 17-d cruise was carried out in Ría de Pontevedra (Galician Rías Baixas) to study the physical–biological interactions that may lead to subsurface aggregations of phytoplankton organisms in thin layers (TLs). Physical processes governed the initiation and development, maintenance, and decline of a diatom (toxin producing Pseudo-nitzschia spp. and Chaetoceros socialis) TL during an upwelling relaxation-upwelling–downwelling sequence. Differences in shear profiles appeared to lead to the formation of a TL during upwelling events. These results reveal that the coupling between maximum values of shear and buoyancy frequency can shape a subsurface chlorophyll maximum (SCM) into a TL. The effect of shear upon phytoplankton patches, which has been predicted on the basis of theoretical studies, has been corroborated in this study in which the vertical distribution of an observed TL was controlled by physical processes.     

Swelling of a lava plug associated with a Vulcanian eruption at Sakurajima Volcano,Japan, as revealed by infrasound record: case study of the eruption on January 2, 2007

In order to clarify the time relation of the expansion of a gas pocket and failure of its overlying plug of lava during Vulcanian eruptions, infrasound records and video images of the Vulcanian eruption that occurred at Sakurajima volcano on January 2, 2007 were analyzed with respect to their origin times. Weak (≤3 Pa) and slowly increasing air pressure preceded the impulsive compression phase by 0.25–0.32 s, and a longer-period rarefaction phase of infrasound waves was recognized at all microphone stations. The velocity of the compression phase was assumed to be supersonic (ca. 400 m/s) up to 850 m above the crater bottom from other recent explosions. On the other hand, the propagation velocity of the preceding weak signal was regarded to be similar to the air sound velocity because the lack of impulsiveness is unlikely to be related to the main compression phase. Therefore, the estimated origin time of the main compression phase was delayed by 0.5–0.7 s from the preceding phase. The origin time of the preceding phase coincided with the onset of the isotropic expansion process of the pressurized gas pocket, which was obtained by the waveform inversion of the explosion earthquake. In contrast, the origin time of the main impulsive phase coincided with the time when the expansion rate reached its peak. This observation suggests that the volumetric increase of the gas pocket caused swelling of the surface of the crater bottom and its subsequent failure. When the expansion velocity exceeded a threshold level, the main impulsive compression phase radiated with a high velocity by the sudden releases of the pressurized gases. The volumetric change at the source was estimated to be 280–560 m³ from the preceding phase of the infrasound. This volume change indicates that the vertical displacement of the swelling ground was on the order of 1.0 m, assuming the radius of the lava plug was ca. 10 m.     

利用宁夏大峰矿特大爆破资料研究地震波的衰减特性

应用萨道夫斯基经验公式,研究2007年12月20日宁夏大峰矿特大爆破S波最大振幅的衰减特性,结果表明。银川盆地衰减比周边地区严重,大体可以看出银川盆地的东部边界和南部边界。在爆破点东73km和南122～151km．该结果和地质上给出的银川盆地的边界基本吻合。