The bimodal rift-related Juscelândia volcanosedimentary sequence in central Brazil: Mesoproterozoic extension and Neoproterozoic metamorphism

The Barro Alto Complex and Juscelândia volcanosedimentary sequence are exposed in the central part of the Neoproterozoic Brasília belt of central Brazil. The former is a large (approximately 150 km long), boomerang-shaped, mafic-ultramafic, layered complex formed by two different intrusions metamorphosed under granulite facies. These rocks are tectonically overlain by rocks of the Juscelândia volcanosedimentary sequence, represented mainly by biotite-gneiss and amphibolite, or amphibolite facies metamorphic equivalents of rhyolite and basalt, respectively. New SIMS U–Pb zircon data and Sm–Nd isochron data presented herein help clarify the igneous and metamorphic evolution of the Juscelândia volcanosedimentary sequence, as well as its relationship with the Barro Alto Complex. Zircon grains from two biotite gneisses were analyzed by SIMS (SHRIMP) and indicate Mesoproterozoic dates, approximately 1.28 Ga, interpreted as the time of bimodal volcanism in a tectonic setting transitional between a continental rift and an ocean basin. Metamorphism is constrained by Sm–Nd garnet-whole-rock isochrons for garnet amphibolite and pelitic schists of the Juscelândia sequence, as well as for clinopyroxene-garnet amphibolite and garnet granulite of the Barro Alto Complex, which give ages between 0.74 and 0.76 Ga, in agreement with SIMS dates for metamorphic zircon rims. These new data are significant, because they establish that a single metamorphic event affected both the Barro Alto Complex and the Juscelândia sequence. Based on these new data, we present a modified tectonic model for the Brasília belt.     

Response of zircon U−Pb isotopes and whole-rock geochemistry to CO2 fluid-induced granulite-facies metamorphism,Kabbaldurga, Karnataka,South India

The arrested, prograde amphibolite- to granulite-facies transition at Kabbaldurga, south India, overprints Archacan amphibolite-facies nebulitic gneisses and the late Archaean Closepet granite. Previous studies have shown that this facies transition was controlled by a channelled influx of a dehydrating fluid, assumed to be CO₂, at 750°C and 5.5 kbar confining pressure. The effect of this type of prograde transition on zircon U–Pb isotopic systematics and whole-rock geochemistry has been studied using 1 kg amphibolite-facies, transitional and granulite-facies domains from a single block of gneiss. The zircon populations from all three domains have essentially similar morphology and U–Pb systematics. This similarity shows that at the conditions under which the prograde granulite-facies transition took place via fluid influx, the zircon U–Pb systematics were not disturbed by the process. Using the pooled data from all three domains, it is concluded that the protolith of the gneiss formed at 2965±4 Ma (2), and that zircons also grew during an anatectic event common to all domains at 2528±5 Ma. The granulite-facies metamorphism has not been dated directly due to the lack of response to the zircon U–Pb isotopic systematies to it. However, field and petrographic criteria dictate that its maximum age is 2528±5 Ma, the age of the anatectic event common to each domain in the gneiss block, which was overprinted during the granulite-facies event. For most major and trace elements, consistent enrichment or depletion trends associated with the transition to granulite facies cannot be identified with confidence. However, the granulite-facies portion is LREE (light-rare-earth-element)-enriched and H (heavy) REE-depleted compared with the amphibolite-facies domain, and the transitional domain is at intermediate values. The isotopic and geochemical evidence presented supports the conclusion that the granulite-facies charnockitic rocks at Kabbaldurga were not formed by removal of an anatectic melt, but that they formed later by simple metamorphic overprint of amphibolite-facies rocks.     

Pre-Variscan geological events in the Austrian part of the Bohemian Massif deduced from U–Pb zircon ages

In an attempt to elucidate the pre-Variscan evolution history of the various geological units in the Austrian part of the Bohemian Massif, we have analysed zircons from 12 rocks (mainly orthogneisses) by means of SHRIMP, conventional multi-grain and single-grain U–Pb isotope-dilution/mass-spectrometry. Two of the orthogneisses studied represent Cadomian metagranitoids that formed at ca. 610 Ma (Spitz gneiss) and ca. 580 Ma (Bittesch gneiss). A metagranite from the Thaya batholith also gave a Cadomian zircon age (567±5 Ma). Traces of Neoproterozoic zircon growth were also identified in several other samples, underlining the great importance of the Cadomian orogeny for the evolution of crust in the southern Bohemian Massif. However, important magmatic events also occurred in the Early Palaeozoic. A sample of the Gföhl gneiss was recognised as a 488±6 Ma-old granite. A tonalite gneiss from the realm of the South Bohemian batholith was dated at 456±3 Ma, and zircon cores in a Moldanubian metagranitic granulite gave similar ages of 440–450 Ma. This Ordovician phase of magmatism in the Moldanubian unit is tentatively interpreted as related to the rifting and drift of South Armorica from the African Gondwana margin. The oldest inherited zircons, in a migmatite from the South Bohemian batholith, yielded an age of ca. 2.6 Ga, and many zircon cores in both Moravian and Moldanubian meta-granitoid rocks gave ages around 2.0 Ga. However, rocks from the Moldanubian unit show a striking lack of zircon ages between 1.8 and 1.0 Ga, reflecting an ancestry from Armorica and the North African part of Gondwana, respectively, whereas the Moravian Bittesch gneiss contains many inherited zircons with Mesoproterozoic and Early Palaeoproterozoic ages of ca. 1.2, 1.5 and 1.65–1.8 Ga, indicating a derivation from the South American part of Gondwana.     

Stabilization and reactivation of cratonic lithosphere from the lower crustal record in the western Canadian shield

New U–Pb geochronology for an extensive exposure of high-pressure granulites in the East Lake Athabasca region of the western Canadian shield is consistent with a history characterized by 2.55 Ga stabilization of cratonic lithosphere, 650 million years of lower crustal residence and cratonic stability, and 1.9 Ga reactivation of the craton during lithospheric attenuation and asthenospheric upwelling. High precision single-grain and fragment zircon data define distinctive discordia arrays between 2.55 and 1.9 Ga. U–Pb ion microprobe spot analyses yield a similar range of U–Pb dates with no obvious correlation between date and cathodoluminescence zonation. We attribute the complex U–Pb zircon systematics to growth of the primary populations during a 2.55 Ga high-pressure granulite facies event (~1.3 GPa, 850°C) recorded by the dominant mineral assemblage of the mafic granulite gneisses, with subsequent zircon recrystallization and minor secondary zircon growth during a second high-pressure granulite facies event (1.0 GPa, ~800°C) at 1.9 Ga. The occurrence of two discrete granulite facies metamorphic events in the lower crust, separated by an interval of 650 million years that included isobaric cooling for at least some of this time, suggests that the rocks resided at lower crustal depths until 1.9 Ga. We infer that this phase of lower crustal residence and little tectonic activity is coincident with an extended period of cratonic stability. Detailed structural and thermochronological datasets indicate that multistage unroofing of the lower crustal rocks occurred in the following 200 million years. Extended lower crustal residence would logically be the history inferred for lower crust in most cratonic regions, but the unusual aspect of the history in the East Lake Athabasca region is the subsequent lithospheric reactivation that initiated transport of the lower crust to the surface. We suggest that a weakened strength profile related to the 1.9 Ga heating left the lithosphere susceptible to far-field tectonic stresses from bounding orogens that drove the lower crustal exhumation. An ultimate return to cratonic stability is responsible for the preservation of this extensive lower crustal exposure since 1.7 Ga.     

Xes-Xen thermochronology of the Rayner metamorphic complex,Enderby Land (East Antarctica,Molodezhnaya Station Area)

The Xe_s-Xe_n dating of zircons from rocks of the Rayner Complex of the Enderby Land at the Molodezhnaya Station area (coast of the Alasheyev Bight) yielded age estimates of 550 ± 50 and 1040 ± 30 Ma. The metamorphic rocks of the Rayner Complex record two main events: first, the crystallization of the magmatic protoliths of charnockitic and enderbitic gneisses and, second, superimposed structural and metamorphic alterations under conditions transitional from the amphibolite to granulite facies (metamorphism manifested regionally in the rocks of the Rayner Complex). The most reliable Xe_s-Xe_n age estimates for magmatic zircons from the charnockitic and enderbitic gneisses correspond to the Grenville stage of the development of the Rayner Complex (～1.0 Ga). The Xe isotopic systematics of metamorphic zircons reflect a pan-African stage in the evolution of the Rayner Complex (600–550 Ma). Pan-African events are reflected in the U-Xe isotope system in two cases: if metamorphic zircons crystallized at the same time (which probably resulted in the formation of a plateau in the Xe_s-Xe_n age spectrum) and if the initial isotopic systems were disturbed (which resulted in a decrease in apparent age toward low-temperature gas fractions). It is important that secondary alterations and a decrease in apparent ages to 600–550 Ma affected only those components (i.e., caused xenon release only from those traps) that were unstable under the maximum metamorphic temperatures and yielded T _cl values lower than 750°C (conditions transitional from the amphibolite to granulite facies). At a higher xenon retention, “primary” isotopic systems are preserved. Consequently, the age of metamorphism transitional between the amphibolite and granulite facies can be estimated at 600–550 Ma on the basis of Xe_s-Xe_n dating. In general, the results of our study indicate that the age of regional metamorphism of the Rayner complex at the Molodezhnaya area is approximately 600–550 Ma rather than ～1.0 Ga, as was previously supposed.     

Metamorphism of the Koraput Alkaline Complex, Eastern Ghats Province, India—Evidence for reworking of a granulite terrane

An assemblage of predominantly metasedimentary rocks in the Eastern Ghats Province, India, underwent granulite facies metamorphism and deformation in early Neoproterozoic times, and was subsequently intruded by the Koraput alkaline complex. The intrusion was earlier believed to be syn- to late tectonic. The gabbroic core of the complex hosts nepheline-bearing syenitic dykes and veins. Following emplacement, magmatic amphibole within the syenites, and early orthopyroxene in feldspathic gneisses within the country rocks were retrogressed to biotite during pervasive solid-state deformation. Subsequent prograde metamorphism resulted in the formation of anhydrous assemblages at the expense of relict magmatic amphibole within the syenites, and metamorphic biotite in both the complex and the country rocks. Reactions reconstructed from textural observations indicate breakdown of biotite and amphibole to garnet + clinopyroxene ± orthopyroxene-bearing assemblages. Schreinemakers’ analysis on the relevant mineral associations suggests that heating was followed by loading of the region. This indicates thermal rejuvenation of the complex and the host granulites during an intracrustal orogeny that post-dates emplacement and cooling of the pluton. Available ages suggest that this event occurred in the mid-Neoproterozoic, and is probably unrelated to the amalgamation of the granulite belt with the Archaean Bastar/Dharwar craton.     

Geology of the High Grade Proterozoic Terrains of Sri Lanka, and the Assembly of Gondwana: an Update on Recent Developments

Nd model ages determined for the high-grade rocks of Sri Lanka delineate three crustal units, viz., the Highland Complex (HC), the Wanni Complex WC), and the Vijayan Complex (VC). The distribution of these three units differs considerably from the three geological divisions demarcated previously on the basis of geological mapping. The centrally located HC comprises mainly granulite grade charnockitic rocks, and metasediments characterized by older Nd model ages (2.0–3.4 Ga). The Highland sedimentary pile was thickened by intermittent granitoid intrusions, most of which are now charnockitic gneiss, and granulites, and basaltic sills, and dikes. All these metaigneous rocks now occur as conformable bands or layers due to intense polyphase deformation. The HC is bounded on the east by the amphibolite grade VC, composed mainly of granitic gneisses, basic gneisses, and migmatites, and they have ‘younger’ Nd model ages (1.1–1.8 Ga). The isotopic, and geochemical characteristics identify the precursors to the Vijayan rocks as I-type calc-alkaline granitoids originated at an ‘arc’-related tectonic environment. Thus, the earlier interpretation that the Vijayan rocks represent reworked HC was rejected. The granulite inliers within the VC, earlier considered as “resisters” to re-working, are now shown as overthrust klippen or rotated rafts of the HC. The WC, demarcated on the basis of Nd model ages (1.1–1.8 Ga) similar to those of the VC, lies west of the HC. It consists mainly of granitic gneisses, charnockitic gneisses, and migmatites, and the metamorphic grade ranges from amphibolite to granulite.Comprehensive geothermobarometric surveys constrain the P-T evolution of the three crustal units, and indicate that both the HC, and WC underwent near isobaric cooling, followed by a decompression with decreasing temperature. Extensive isotopic studies (U-Pb, Pb-Pb, Sm-Nd, Rb-Sr) have established a new geochronological framework for these high-grade rocks of Sri Lanka. The new framework has bracketed the age of high grade metamorphism in the three crustal units at 550–600 Ma.The recent advances in knowledge of the geology of Sri Lanka favour a strong geological correlation of the HC, and the VC of Sri Lanka, respectively, with the Lutzöw-Holm Complex, and the Yatmato-Belgica Complex in the East Antarctica. The geology of the WC suggests a possible correlation with Madagascar, and East Africa. The amalgamation of the three crustal units of Sri Lanka, is apparently related to the two distinct orogenic events that resulted in the assembly of the Gondwana supercontinent.     

Geologic correlation between the Neoproterozoic Sergipano belt (NE Brazil) and the Yaoundé belt (Cameroon, Africa)

The Yaoundé belt (Cameroon) and the Sergipano belt (NE Brazil) belonged to a major and continuous Neoproterozoic orogen at the northern margin of the ancient Congo-São Francisco craton. The Yaoundé belt comprises schists, quartzites, gneisses and migmatitic gneisses grouped into three domains; the low-grade Mbalmayo Group in south and the medium- to high-grade Yaoundé and Bafia Group in north. The Sergipano belt is divided into six domains, the three southernmost of which are mostly made up of clastic and chemical metasedimentary rocks whereas the others are more diverse with a migmatite–gneiss complex, and two metavolcanicplutonic complexes. In general, the two belts show structural vergence and decrease of metamorphic grade towards the craton; three main deformation phases are recognized in the Sergipano belt in contrast with two described in the Yaoundé belt. The minimum age of Pan-African-Brasiliano collision in the Sergipano belt is constrained at 628 ± 12 Ma on syn-collision granites, whereas in the Yaoundé belt collision took place between 620 and 610 Ma, i.e. the age of granulite facies metamorphism. Sm–Nd isotope geochemistry and U–Pb age dating indicate that most clastic metasedimentary rocks in both belts were derived from sources to the north and, to a lesser degree, from the cratons to the south.     

The Kabul Block (Afghanistan), a segment of the Columbia Supercontinent,with a Neoproterozoic metamorphic overprint

We report field relationships, petrography and isotopic ages from two superposed basement units of the Kabul Block, the so called Lower Sherdarwaza and Upper Welayati formations. The Sherdarwaza Formation is represented mostly by migmatites and gneisses that are derived from pelitic and psammitic lithologies with lenses and layers of mafic and carbonate rocks. Several bodies of orthogneisses are also exposed in the Sherdarwaza Formation. The Upper Welayati Formation is characterized by micaschist, quartzite and amphibolites. SHRIMP U–Pb data on zircon from the orthogneiss in the Sherdarwaza Formation indicates a Neoarchean age of ca 2.5–2.8 Ga for their magmatic crystallization. The rocks exhibit granulite facies conditions of 5–7 kbar and 800 °C that are documented by the presence of orthopyroxene and Ti-rich biotite in the orthogneiss and by olivine and phlogopite in some calc-silicate rocks at contact with marble. A Paleoproterozoic age of ca. 1.85–1.80 Ga for this metamorphism was obtained using U-Pb SHRIMP dating on zircon and U-Th dating on monazite. Mineral textural relations also show a younger amphibolite facies metamorphism that is documented in both the Sherdarwaza and Welayati formations. This metamorphism occurred at relatively higher pressure conditions of up to 9 kbar at ca. 650 °C, compared to the granulite facies event. A Neoproterozoic age of ca 0.85–0.9 Ga, for this metamorphism is confirmed by Ar-Ar data on biotite and white mica as well as by U-Th data on monazite. By combining the presented results on the metamorphic petrology, geochronology and geochemistry, we conclude that: (1) The Kabul basement is a fragment of an Archean block (craton); (2) the ca. 1.85–1.8 and 0.9–0.85 Ga metamorphism marks an important orogenic events for the basement rocks of the Kabul Block which was stabilized during the early Precambrian; (3) the two metamorphic ages correlate well with global-scale orogenies related to the assembly of the Paleoproterozoic Columbia and Neoproterozoic Rodinia supercontinents; (4) based on metamorphic characteristics and ages, the Kabul basement rocks show an affinity to the Neoarchean rocks of the Tarim and/or South China cratons.     

Monazite geochronology and geochemistry of meta-sediments in the Narryer Gneiss Complex, Western Australia: constraints on the tectonothermal history and provenance

Mt. Narryer and Jack Hills meta-sedimentary rocks in the Narryer Gneiss Complex of the Yilgarn Craton, Western Australia are of particular importance because they yield Hadean detrital zircons. To better understand the tectonothermal history and provenance of these ancient sediments, we have integrated backscattered scanning electron images, in situ U–Pb isotopic and geochemical data for monazites from the meta-sediments. The data indicate multiple periods of metamorphic monazite growth in the Mt. Narryer meta-sediments during tectonothermal events, including metamorphism at ~3.3–3.2 and 2.7–2.6 Ga. These results set a new minimum age of 3.2 Ga for deposition of the Mt. Narryer sediments, previously constrained between 3.28 and ~2.7 Ga. Despite the significant metamorphic monazite growth, a relatively high proportion of detrital monazite survives in a Fe- and Mn-rich sample. This is likely because the high Fe and Mn bulk composition resulted in the efficient shielding of early formed monazite by garnet. In the Jack Hills meta-sediments, metamorphic monazite growth was minor, suggesting the absence of high-grade metamorphism in the sequence. The detrital monazites provide evidence for the derivation of Mt. Narryer sediments from ca. 3.6 and 3.3 Ga granites, likely corresponding to Meeberrie and Dugel granitic gneisses in the Narryer Gneiss Complex. No monazites older than 3.65 Ga have been identified, implying either that the source rocks of >3.65 Ga detrital zircons in the sediments contained little monazite, or that >3.65 Ga detrital minerals had experienced significant metamorphic events or prolonged sedimentary recycling, resulting in the complete dissolution or recrystallization of monazite.     

SHRIMP U–Pb zircon dating of the Neoproterozoic Penglai Group and Archean gneisses from the Jiaobei Terrane, North China, and their tectonic implications

Archean basement gneisses and supracrustal rocks, together with Neoproterozoic (Sinian) metasedimentary rocks (the Penglai Group) occur in the Jiaobei Terrane at the southeastern margin of the North China Craton. SHRIMP U–Pb zircon dating of an Archean TTG gneiss gave an age of 2541 ± 5 Ma, whereas metasedimentary rocks from the Neoproterozoic Penglai Group yielded a range in zircon ages from 2.9 to 1.8 Ga. The zircons can be broadly divided into three age populations, at: 2.0–1.8 Ga, 2.45–2.1 Ga and >2.5 Ga. Detrital zircon grains with ages >2.6 Ga are few in number and there are none with ages <1.8 Ga. These results indicate that most of the detrital material comes from a Paleoproterozoic source, most likely from the Jianshan and Fenzishan groups, with some material coming from Archean gneisses in the Jiaobei Terrane. An age of 1866 ± 4 Ma for amphibolite-facies hornblende–plagioclase gneiss, forming part of a supracrustal sequence within the Archean TTG gneiss, indicates Late Paleoproterozoic metamorphism. Both the Archean gneiss complex and Penglai metasedimentary rocks resemble previously described components of the Jiao-Liao-Ji orogenic belt and suggest that the Jiaobei Terrane has a North China Craton affinity; they also suggest that the time of collision along the Jiao-Liao-Ji Belt was at 1865 Ma.     

990 and 1100 Ma Grenvillian tectonothermal events in the northern Oaxacan Complex, southern Mexico: roots of an orogen

Inliers of 1.0–1.3 Ga rocks occur throughout Mexico and form the basement of the Oaxaquia microcontinent. In the northern part of the largest inlier in southern Mexico, rocks of the Oaxacan Complex consist of the following structural sequence of units (from bottom to top), which protolith ages are: (1) Huitzo unit: a 1012±12 Ma anorthosite–mangerite–charnockite–granite (AMCG) suite; (2) El Catrı́n unit: ≥1350 Ma orthogneiss migmatized at 1106±6 Ma; and (3) El Marquez unit: ≥1140 Ma para- and orthogneisses. These rocks were affected by two major tectonothermal events that are dated using U–Pb isotopic analyses of zircon: (a) the 1106±6 Ma Olmecan event produced a migmatitic or metamorphic differentiation banding folded by isoclinal folds; and (b) the 1004–978±3 Ma Zapotecan event produced at least two sets of structures: (Z1) recumbent, isoclinal, Class 1C/3 folds with gently NW-plunging fold axes that are parallel to mineral and stretched quartz lineations under granulite facies metamorphism; and (Z2) tight, upright, subhorizontal WNW- to NNE-trending folds accompanied by development of brown hornblende at upper amphibolite facies metamorphic conditions. Cooling through 500 °C at 977±12 Ma is documented by ⁴⁰Ar/³⁹Ar analyses of hornblende. Fold mechanisms operating in the northern Oaxacan Complex under Zapotecan granulite facies metamorphism include flexural and tangential–longitudinal strain accompanied by intense flattening and stretching parallel to the fold axes. Subsequent Phanerozoic deformation includes thrusting and upright folding under lower-grade metamorphic conditions. The Zapotecan event is widespread throughout Oaxaquia, and took crustal rocks to a depth of 25–30 km by orogenic crustal thickening, and is here designated as Zapotecan Orogeny. Modern analogues for Zapotecan granulite facies metamorphism and deformation occur in middle to lower crustal portion of subduction and collisional orogens. Contemporaneous tectonothermal events took place throughout Oaxaquia, and in various parts of the Genvillian orogen in Laurentia and Amazonia.     

Neoarchaean high-grade metamorphism in the Central Zone of the Limpopo Belt (South Africa): Combined petrological and geochronological evidence from the Bulai pluton

The Bulai pluton represents a calc-alkaline magmatic complex of variable deformed charnockites, enderbites and granites, and contains xenoliths of highly deformed metamorphic country rocks. Petrological investigations show that these xenoliths underwent a high-grade metamorphic overprint at peak P–T conditions of 830–860 °C/8–9 kbar followed by a pressure–temperature decrease to 750 °C/5–6 kbar. This P–T path is inferred from the application of P–T pseudosections to six rock samples of distinct bulk composition: three metapelitic garnet–biotite–sillimanite–cordierite–plagioclase–(K-feldspar)–quartz gneisses, two charnoenderbitic garnet–orthopyroxene–biotite–K-feldspar–plagioclase–quartz gneisses and an enderbitic orthopyroxene–biotite–plagioclase–quartz gneiss. The petrological data show that the metapelitic and charnoenderbitic gneisses underwent uplift, cooling and deformation before they were intruded by the Bulai Granite. This relationship is supported by geochronological results obtained by in situ LA-ICP-MS age dating. U–Pb analyses of monazite enclosed in garnet of a charnoenderbite gneiss provide evidence for a high-grade structural-metamorphic–magmatic event at 2644 ± 8 Ma. This age is significantly older than an U–Pb zircon crystallisation age of 2612 ± 7 Ma previously obtained from the surrounding, late-tectonic Bulai Granite. The new dataset indicates that parts of the Limpopo's Central Zone were affected by a Neoarchaean high-grade metamorphic overprint, which was caused by magmatic heat transfer into the lower crust in a ‘dynamic regional contact metamorphic milieu’, which perhaps took place in a magmatic arc setting.     

Geochronological, isotopic, and geochemical data from Permo-Triassic granitic gneisses and granitoids of the Colombian Central Andes

New U–Pb SHRIMP ages in zircon, Ar–Ar ages in micas and amphiboles, Nd–Sr isotopes, and major and REE geochemical analyses in granitic gneisses and granitic stocks of the Central Cordillera of Colombia indicate the presence of a collisional orogeny in Permo-Triassic times in the Northern Andes related to the construction of the Pangea supercontinent. The collision is recorded by metamorphic U–Pb SHRIMP ages in inherited zircons around 280 Ma and magmatic U–Pb SHRIMP ages in neoformed zircons around 250 Ma within syntectonic crustal granitic gneisses. Magmatic U–Pb SHRIMP and Ar–Ar Triassic ages around 228 Ma in granitic stocks indicate the presence of late tectonic magmatism related to orogenic collapse and the beginning of the breakup of the supercontinent. During this period, the Central Cordillera of Colombia would have been located between the southern United States and northern Venezuela, in the leading edge of the Gondwana supercontinent.     

U–Pb and Hf-isotope analysis of zircons in mafic xenoliths from Fuxian kimberlites: evolution of the lower crust beneath the North China craton

Mafic xenoliths from the Paleozoic Fuxian kimberlites in the North China craton include garnet granulite, and minor pyroxene amphibolite, metagabbro, anorthosite and pyroxenite. The formation conditions of the amphibolites are estimated at 745–820 °C and 7.6–8.8 Kb (25–30 km); the granulites probably are derived from greater depths in the lower crust. LAM-ICPMS U–Pb dating of zircons from four granulites reveals multiple age populations, recording episodes of magmatic intrusion and metamorphic recrystallisation. Concordant ages and upper intercept ages, interpreted as minimum estimates for the time of magmatic crystallisation, range from 2,620 to 2,430 Ma in three granulites, two amphibolites and two metagabbros. Lower intercept ages, represented by near-concordant zircons, are interpreted as reflecting metamorphic recrystallisation, and range from 1,927 to 1,852 Ma. One granulite contains two metamorphic zircon populations, dated at 1,927±55 Ma and 600–700 Ma. Separated minerals from one granulite and one amphibolite yield Sm–Nd isochron ages of 1,619±48 Ma (¹⁴³Nd/¹⁴⁴Nd)i=0.51078), and 1,716±120 Ma (¹⁴³Nd/¹⁴⁴Nd)i=0.51006), respectively. These ages are interpreted as recording cooling following metamorphic resetting; model ages for both samples are in the range 2.40–2.66 Ga. LAM-MC-ICPMS analyses of zircon show a range in ¹⁷⁶Hf/¹⁷⁷Hf from 0.28116 to 0.28214, corresponding to a range of _Hf from –34 to +12. The relationships between ²⁰⁷Pb/²⁰⁶Pb age and _Hf show that: (1) the granulites, amphibolites and metagabbro were derived from a depleted mantle source at 2.6–2.75 Ga; (2) zircons in most samples underwent recrystallisation and Pb loss for 100–200 Ma after magmatic crystallisation, consistent with a residence in the lower crust; (3) metamorphic zircons in several samples represent new zircon growth, incorporating Hf liberated from breakdown of silicates with high Lu/Hf; (4) in other samples metamorphic and magmatic zircons have identical ¹⁷⁶Hf/¹⁷⁷Hf, and the younger ages reflect complete resetting of U–Pb systems in older zircons. The Fuxian mafic xenoliths are interpreted as the products of basaltic underplating, derived from a depleted mantle source in Neoarchean time, an important period of continental growth in the North China craton. Paleoproterozoic metamorphic ages indicate an important tectonic thermal event in the lower crust at 1.8–1.9 Ga, corresponding to the timing of collision between the Eastern and Western Blocks that led to the final assembly of the North China craton. The growth of metamorphic zircon at 600–700 Ma may record an asthenospheric upwelling in Neoproterozoic time, related to uplift and a regional disconformity in the North China craton.     

Composition and age of metaorthopyroxenite xenoliths and host enderbite gneisses in the Pobuzhie granulite complex,Ukrainian Shield

The SIMS U-Pb isotopic age of zircons from enderbite gneisses and their metaorthopyroxenite xenoliths in the Pobuzhie granulite complex, Ukrainian Shield (48°13′57.3″ N and 29°59′21.5″ E, WGS84 system), was determined. The chemical compositions of these rocks and composing minerals were studied. Enderbite gneisses contain quartz, antiperthite plagioclase, K-feldspar, clinoenstatite, diopside, amphibole, and a small amount of biotite; accessory minerals are ilmenite and apatite. The age of zircon from enderbite gneiss is estimated at about 3.15 Ga. Metaorthopyroxenites are composed of orthopyroxene, clinopyroxene, phlogopite (up to 6% TiO₂), and plagioclase. The age of magmatic zircons from metaorthopyroxenite determined by the upper intercept of the discordia with the concordia is 3485 ± 33 Ma (MSVD = 1.6), and the age of metamorphic zircons is 2742 ± 22 Ma (MSVD = 0.22). Hence, the enderbite gneisses studied pertain to a young group of enderbites in the Pobuzhie granulite complex, while the age of metaorthopyroxenites from xenoliths in these rocks is similar to that of ancient Pobuzhie enderbites and pyroxenites of the Novopavlovsk complex in the Azov Region.     

Deciphering polymetamorphic episodes in high-grade metamorphic orogens: Constraints from PbSL, Sm/Nd and Lu/Hf garnet dating of low- to high-grade metasedimentary rocks from the Kaoko belt (Namibia)

Three dating techniques for metamorphic minerals using the Sm–Nd, Lu–Hf and Pb isotope systems are combined and interpreted in context with detailed petrologic data from crustal segments in NW Namibia. The combination of isochron ages using these different approaches is a valuable tool to testify for the validity of metamorphic mineral dating. Here, PbSL, Lu–Hf and Sm–Nd garnet ages obtained on low- to medium-grade metasedimentary rocks from the Central Kaoko Zone of the Neoproterozoic Kaoko belt (NW Namibia) indicate that these samples were metamorphosed at around 550–560 Ma. On the other hand, granulite facies metasedimentary rocks from the Western Kaoko Zone underwent two phases of high-grade metamorphism, one at ca. 660–625 Ma and another at ca. 550 Ma providing substantial evidence that the 660–625 Ma-event was indeed a major tectonothermal episode in the Kaoko belt. Our age data suggest that interpreting metamorphic ages by applying a single dating method only is not reliable enough when studying complex metamorphic systems. However, a combination of all three dating techniques used here provides a reliable basis for geochronological age interpretation.     

豫西秦岭杂岩变质带的分布及主期变质时代的限定

豫西秦岭杂岩中变质分级可呈与造山带大致平行的带状分布,从两侧向中心变质级别升高,尤其南侧分带明显:由南向北,依次为黑云母带-石榴子石带-蓝晶石带-夕线石带,直至斜方辉石带,而不是整体上经历了麻粒岩相变质作用。局部发生的麻粒岩相变质未见明显向角闪岩相变质转化的退变结构。通过几种岩石的锆石LA-MC-ICPMS测年研究,多数样品中的锆石经受了后期强烈的改造,同位素体系或多或少被重置。尽管如此,侵位花岗岩和伟晶岩年龄限定了主期变质作用的时代应老于484±3Ma,并可能与早期的榴辉岩相变质作用在演化上有联系。主期变质(不包括榴辉岩相变质)性质与经典的巴罗式变质带可以对比;此外,研究区未经历明显的地壳增厚,与高喜马拉雅结晶岩系类似,秦岭杂岩可能经历了中、下地壳物质沿隧道流上升过程。     

Polymetamorphism in the mainland Lewisian complex,NW Scotland – phase equilibria and geochronological constraints from the Cnoc an t’Sidhean suite

The metamorphic evolution of rocks cropping out near Stoer, within the Assynt terrane of the central region of the mainland Lewisian complex of NW Scotland, is investigated using phase equilibria modelling in the NCKFMASHTO and MnNCKFMASHTO model systems. The focus is on the Cnoc an t’Sidhean suite, garnet‐bearing biotite‐rich rocks (brown gneiss) with rare layers of white mica gneiss, which have been interpreted as sedimentary in origin. The results show that these rocks are polymetamorphic and experienced granulite facies peak metamorphism (Badcallian) followed by retrograde fluid‐driven metamorphism (Inverian) under amphibolite facies conditions. The brown gneisses are inferred to have contained an essentially anhydrous granulite facies peak metamorphic assemblage of garnet, quartz, plagioclase and ilmenite (±rutile, K‐feldspar and pyroxene) with biotite, hornblende, muscovite, chlorite and/or epidote as hydrous retrograde minerals. P–T constraints imposed by phase equilibria modelling imply conditions of 13–16 kbar at >900 °C for the Badcallian granulite facies metamorphic peak, consistent with the field evidence for partial melting in most lithologies. The white mica gneiss comprises a muscovite‐dominated matrix containing porphyroblasts of staurolite, corundum, kyanite and rare garnet. Previous studies have suggested that staurolite, corundum, kyanite and muscovite all grew at the granulite facies peak, with partial melting and melt loss producing a highly aluminous residue. However, at the inferred peak P–T conditions, staurolite and muscovite are not predicted to be stable, suggesting they are retrograde phases that grew during amphibolite facies retrograde metamorphism. The large proportion of mica suggests extensive H₂O‐rich fluid‐influx, consistent with the retrograde growth of hornblende, biotite, epidote and chlorite in the brown gneisses. P–T conditions of 5.0–6.5 kbar at 520–550 °C are derived for the Inverian event. In situ dating of zircon from samples of the white mica gneiss yield apparent ages that are difficult to interpret. However, the data are permissive of granulite facies (Badcallian) metamorphism having occurred at c. 2.7–2.8 Ga with subsequent fluid driven (Inverian) retrogression at c. 2.5–2.6 Ga, consistent with previous interpretations.     

Trace element geochemistry and tectonic characterization of the granulite facies rocks from Southwest Obudu Plateau,southeastern Nigeria

The trace elements characteristics of the migmatitic gneisses (biotite-garnetand hornblende-biotite), granulite facies rocks (charnockitic gneisses) and meta-peridotite in the area of Southwest Obudu Plateau indicate that the area exhibits a high degree of geochemical variability. Compatible trace elements (Ni and Cr) are comparatively high in the granulite facies rocks and meta-peridotite. Ni ranges from 28×10-6 to 266×10-6 whilst Cr ranges from 62×10-6 to 481×10-6 for the granulite facies rocks (charnocki...