海南抱板金矿铅同位素化探评价

通过对海南抱板金矿几个切穿矿脉剖面的矿石和围岩的铅同位素组成分析。发现铅同位素组成与矿的产出具有相关关系。铅同位素的异常可能反映了成矿物质来源深度的差异，据此可进行铅同位素化探评价，提出了“正异常以深部找矿为主。负异常注意扩大横向找矿”的原则，土外山地区是地表的浅层金矿化，而二甲，北牛为深源金矿化，在土外山地区深部应可能找到对应于二甲，北牛的深源金矿化层。     

Pb同位素剖面化探法在甘肃玛曲地区大水金矿深部找矿中的应用

攻深找盲是大水金矿矿山勘查的主要任务。根据Pb同位素示踪的有关理论和隐伏矿预测的方法,以甘肃玛曲大水金矿区为例,利用Pb同位素剖面化探法在大水金矿典型剖面70、72勘探线采集Pb同位素样品78个,进行成矿截止深度预测。取本区域的成矿V2截止值在22.4～234.36之间,70、72勘探线在3450m标高左右V2值分别为49.11、64.83,预测70～72勘探线深部及以西成矿截止深度在3000～3100m之间,还有400～500m的勘查空间,找矿潜力大,是今后矿区勘查的重点地段。     

Isotope Geochemistry of Gold Ore Deposits in the Gezhen Shear Zone, Qiongxi, Hainan Island

Gold deposits hosted in the Gezhen shear zone at Qingxi, Hainan Island occur in the Preeambrian metamorphic rock series and are regionally developed in the N-E direction along the tectonic zone. From northeast to southwest are distributed the Tuwaishan-Baoban gold mining district, the Erjia gold mining district and the Bumo gold mining district, making up the most industrially important gold metallogenesis zone on the Hainan Island. Isotope geochemical studies of the typical gold deposits in this metallogenesis zone indicate that their ore-forming materials stemmed largely from the Baoban Group migmatite series, though the involvement of some plutonic materials could not be ruled out. The ore fluids are the mixture of migrnatitized hydrothermal solutions and meteoric waters in addition to the involvement of local magmatic hydrothermal solutions. The superimposition of plutonie materials and magmatic hydrothermal solutions is controlled by the deformation environment of the shear zone and later magrnatic activities. Obvious variations are noticed in isotopic composition in the region studied, probably related to tectonic deformation, metamorphism and other evolutionary characteristics. This study is of great significance in understanding the relationship between the shear zone and gold metallogenesis,the rules of gold metallogenesis and gold ore prognosis.     

化探在河北王林口金矿区的应用效果

通过对1：20万水系沉积物测量异常的分析研究，As64号异常有进一步工作价值，用1：5万水系沉积物、1：1万土壤和1：5000岩石测量进行查证，在石英正长班岩体内圈定了矿化带，通过钻探、槽探和坑探揭露，发现含金矿体9条。     

Fluid Inclusion Studies of Gold Deposits in the Gezhen Shear Zone,Hainan Province,China

The Tuwaishan, Baoban, Erjia, Bumo and other gold deposits in western Hainan occur in Precambrian metamorphic clastic rocks and are structurally controlled by the Gezhen shear zone. Fluid inclusion studies have been carried out of the gold deposits mentioned above. The homogenization temperatures of the whole fluid inclusion population range from 140°C to 370°C, indicating that gold was precipitated mainly at 240–250°C. The salinities are within the range of 2.0–9.2 wt% NaCl equiv. and the pressure of formation of the deposits was estimated at about 270×10⁵−500×10⁵Pa, corresponding to a depth of about 1.1–2.0 km under lithostatic confinement. Chemical studies show that the ore fluid is of the Na⁺(K⁺)-Ca²⁺-Cl⁻(F⁻) type. Theδ ¹⁸O andδD values of the fluid vary from −2.7‰- +4.4‰ and −50‰–−87‰ Evidence developed from fluid inclusions and geological setting indicates that the ore fluid was a mixture of magmatic and meteoric-hydrothermal waters. Changes in chemical composition andδ ¹⁸O andδD of fluid inclusions from one ore field to another seem to be related with regional tectonism, metamorphism and magmatism.     

云南元阳大坪金矿铅同位素化探评价

通过对云南元阳大坪金矿某切穿矿脉剖面、不同海拔高程矿脉的矿石和围岩的铅同位素组成分析，采用铅同位素系统剖面化探方法对大坪金矿进行了化探评价和隐伏矿的预测分析，指出大坪金矿已进入主矿体的中心部位，深部隐伏矿潜力不大，找矿战略应以扩大横向为主。金矿化与闪长岩铅同位素组成的一致性，表明金矿化受闪长岩的控制。     

海南抱板金矿田流体包裹体地球化学研究

对海南抱板金矿田的外山，抱板和二甲等三个金矿进行的液体包裹体研究表明成矿流体为低盐度（０．１－６ｗｔ％ＮａＣｌ），中低温（２００－２４０℃）热液，处于中低压力（６０－１６０ＭＰａ）下，其ＣＯ２含量较低，探针质谱分析表明流体包裹体中存在Ｈ２Ｓ，结合ＳＯ＾２－４的存在，金在热液中可能是以硫氢络合物的形式迁移的。     

湘东北正冲金矿床成矿物质来源的S-Pb同位素示踪

长沙-平江(长-平)成矿带位于江南造山带中段,金资源储量达250余吨。该区金矿床是典型的沉积变质岩容矿的热液脉状金矿床,构造控矿特征清晰,然而巨量金来源与矿床成因尚不明确。正冲金矿床主体赋存于新元古代变质沉积岩中,矿区内同时发育少量花岗岩体,是识别不同地质体对成矿贡献的理想选择。因此,本文选取正冲金矿床,在野外宏观地质工作基础上,系统开展了成矿阶段划分与载金硫化物同位素地球化学测试等工作。正冲金矿床严格受控于NNE-NE向的长-平断裂及其次级断裂系统,矿体呈脉状,走向NW或NNE,蚀变分带不明显。正冲金矿床矿物组合简单:早阶段发育有乳白色贫矿石英与白云母;成矿主阶段为石英细脉与自然金黄铁矿毒砂-多金属硫化物-少量绿泥石;成矿晚阶段发育有石英-方解石脉。其中,黄铁矿与毒砂是矿床内自然金与不可见金重要的载体。为弱化毒砂和黄铁矿裂隙中细粒多金属硫化物对同位素地球化学结果的干扰,本次研究挑选自形、未变形的毒砂、黄铁矿颗粒测试研究。实验结果表明载金毒砂铅同位素组成~(208)Pb/~(204)Pb、~(207)Pb/~(204)Pb与~(206)Pb/~(204)Pb分别为37.867～38.285、15.555～15.663与17.743-18.073,略高于黄铁矿铅同位素组成37.774～38.268、15.547～15.660与17.670～18.021;毒砂δ~(34)S变化幅度较小(-4.7‰～-0.9‰,均值为-3.0%),略高于黄铁矿δ~(34)S值(-9.1‰～-1.1‰,均值为-4.4‰),成矿流体氧逸度约为10~(-30.7)。正冲金矿床硫、铅同位素组成与赋矿围岩、区域内岩体和斑岩型矿床同位素特征具有较大差异,说明区内岩体与赋矿地层并不是正冲金矿床成矿物质的主要来源。金矿床成矿物质具有深源特征,可能来源于比冷家溪群地层变质程度更高、沉积位置更深的变质沉积岩。结合区域地质背景、金矿床地质-地球化学特征与成矿年代学资料,推断正冲金矿床为造山型金矿床。     

海南抱伦金矿床成矿时代研究

抱伦金矿床是海南省新近发现的大型金矿床之一，属于发育于下志留统陀烈组浅变质岩系中受断裂构造裂隙控制的岩浆热液型金矿床。成矿流体包裹体特征和氢氧同位素研究表明，成矿流体以岩浆水为主，有部分变质水的参与，大气降水影响比较小；成矿元素地球化学背景、硫同位素、稀土元素和初始锶比值等反映成矿物质来源虽然以变质岩为主，但有部分来源于岩浆岩；成矿物质和成矿流体来源反映出成矿作用与岩浆活动的密切关系。由热液蚀变矿物Rb-Sr等时线年龄234Ma和K－Ar年龄213Ma可知，金矿化年龄为210－230Ma，所以，抱化金矿床的成矿时代为印支期。这一结果与粤西－海南成矿带的成矿时代特征及特提斯构造演化特点相吻合。     

山东龙口大磨曲家金矿床地质特征及地球化学勘查模型

山东龙口市大磨曲家金矿区位于沂沭断裂带东侧,招平成矿带北端。矿床矿化类型为含金蚀变岩型,矿床经历了热液和表生 2 个成矿期及 5 个成矿阶段,围岩蚀变主要为硅化、绢云母化、钾化等。通过对 302 号脉坑道及钻孔岩心原生岩石地球化学特征研究,提出矿体前缘指示元素组合为 Hg-- As--Sb,近矿或矿体指示元素组合为 Au--Ag--Cu--Pb--Zn,矿体尾晕指示元素组合为 Bi--Co--Ni; 据此,建立了地球化学勘查模型。     

半干旱—干旱地区以钙积层为采样介质的隐伏金矿地球化学勘查

在隐伏金矿的地球化学勘查中,常用的采样介质包括岩石、水系沉积物、土壤、植物和地气等.近几十年,澳大利亚在半干旱—干旱地区以钙积层作为隐伏金矿床地球化学勘查的采样介质,并取得了成功.本文对以钙积层作为隐伏金矿地球化学勘查采样介质的理论和勘查进展进行总结,其勘查理论基础是土壤剖面中金-钙高度相关性,其成因机理较合理地解释为...     

Assessment of geochemical anomalies for gold exploration using lead isotopes in west Hainan, China

Lead isotopic ratios and Pb contents have been measured along typical profiles across orebodies of the Baoban and Tuwaishan gold deposits on Hainan Island, China. These deposits are hosted by the middle to upper Proterozoic Baoban Group, which is composed of migmatite and extends for about 51 km on the hanging-wall side of the Gezhen Fault. The deposits have a common initial Pb isotopic ratio of ²⁰⁶Pb/²⁰⁴Pb = 18.683, but show distinctive variations within each deposit.The Pb isotopic ratios are more homogeneous in the orebodies and altered auriferous rocks than in the migmatite wall rocks. The richest orebody in the study area is known as the V1 orebody of the Baoban deposit; it has the lowest and most homogeneous ²⁰⁶Pb/²⁰⁴Pb ratio. This feature suggests that in this migmatitic area, it is possible to distinguish ores from barren wall rocks, and rich ore shoots from non-commercial mineralization, by their distinctive Pb isotopic ratios.A lower initial Pb isotopic ratio (²⁰⁶Pb/²⁰⁴Pb= 18.538) was measured in two other deposits, Beiniu and Erjia, which occur in the same migmatite and are controlled by the same fault as the Baoban and Tuwaishan deposits. Therefore, two metallogenic phases may have taken place, one at 85 Ma and the other at 170 Ma; these ages can be calculated using the Pb growth model of Cumming and Richards.The feasibility of evaluating geochemical anomalies through their Pb isotopic signatures was investigated by comparing the Pb isotopic ratios of B horizon soils from significant and non-significant anomalies with those obtained from the ores and alteration zone rocks. The results show that the Pb isotopic ratios in significant anomalies are consistent with those of the ores, whereas the signatures of non-significant anomalies are heterogeneous and rather different from those of the ores.Six unexplored anomalies have been evaluated using this criteria; five of them were found to be non-significant. One anomaly, however, presents the same signature as the Beiniu deposit, suggesting that it may be related to undiscovered ore close to the Gezhen Fault. Plans have been made to drill this target.     

GEOCHEMICAL KINETIC SIMULATION ON WALL—ROCK ALTERATION ZONING IN THE BAOBAN GOLD FIELD，SOUTH CHINA

The Baoban gold field,located in the area of Hainan Island ,South China ,bears three gold de-posits :Tuwaishan ,Baoban ,and Erjia ,which belong to the wall-rock alteration type.In terms of the petrography data,four alteration zones can be recognized from the ore-vein outwards(1)the silicification zone;(2)the sericitization zone;(3)the chloritization zone;and (4)the calcitization zone.The geochemical kinetic simulation was carried out on sericitization and chloritization .Results of the study showed that the formation of the alteration zones is connected with the properties of hydrothermal fluids:the initial concentration of Al (O H)3,the diffusion coefficient and the velocity of fluid flow.The alteration zones in this field are the result of multiple interaction between hydrothermal fluids and wall rocks.     

湘西南金矿床地球化学特征及其成因

对湘西南金矿床的研究表明,五强溪组为金的主要矿源层,其形成的大地构造 活动大陆边缘;金矿床中Ｐｂ、Ｓ、Ｓｒ的同位素特征反映它们均来自赋矿围岩;成矿流体的和Ｈ、Ｏ同位素特征指示其主要来自大气降水;成矿流体显法出低温,低盐度、呈中性－弱碱性的特征;成矿时代为加里东期,而 传统认识中的武陵,雪峰期;矿床成因为大气降水热液改造成因。     

Isotope Geochemistry of the Dongchuan Copper Deposit,Yunnan,SW China： Stratigraphic Chronology and Application of Lead Isotopes in Geochemical Exploration

In this paper the Pb-Pb isochron method was used to determine the isotopic ages of the Luoxue Formation dolomites (1716 ±56 Ma), the Heishan Formation carbonaceous slates ( 1607 ±128 Ma) of the middle sub-group of the Kunyang Group and the Dayingpan Formation carbonaceous slates (1258 ±70Ma) of the upper sub-group of the Kunyang Group. The age of the middle sub-group of the Kunyang Group is about 1800 – 1600 Ma, belonging to the Late Paleo-Proterozoic, and that of the Dayingpan Formation in the upper sub-group of the Kunyang Group is about 1200 – 1300 Ma, belonging to the Middle Proterozoic. In addition, the Pb isotope chemical exploration techniques were used to study systematically the Pb isotopic compositions of rocks and ores across the No. 14 vein in the middle segment of the No. 1 pit of the Tangdan copper deposit and the result showed that the Pb isotope V₁ values are negatively correlated with the copper contents. It is the first trial to use the systematic section method to conduct Pb isotope chemical exploration. This research project was financially supported jointly by the National Natural Science Foundation of China (Grant Nos. 49702022, 40073001) and the State 973 Program (No.G1999043215).     

江西金矿地球化学勘查模式

论述江西省内有代表性意义的金山式剪切带型、氵吴村式微细粒型、银峰尖式火山岩型三大类型金矿床地球化学勘查模式,指导该区找矿.     

地球物理探测方法在吉林江源地区小石人金矿勘查中的应用

在小石人金矿勘查中,视电阻率法、激发极化法、高精度磁测法和伽马能谱法均为有效的地球物理探测方法。以视电阻率信息为主要标志,可以建立高阻、高极化、低磁、低K、低总计数率的地球物理模型,且该模型在空间上与硅化蚀变带相对应。在植被覆盖的条件下,该模型在此类金矿勘查中起到先导作用,可用于推断硅化蚀变带的规模和指导勘探工程的布设。     

东坪式金矿床铅同位素组成特征及其化探评价

东坪式金矿床产于华北克拉通化缘深大断裂－－尚义－赤城断裂的南侧,海西期水泉沟正长岩杂岩体内外接触带。矿体具有明显的分层笥,自上而下矿石类型由石英脉型向钾、硅化蚀变岩型过渡。矿床形成于燕山早期,成矿物质主要来源于正长岩杂岩体。矿石铅同位素组成与正长岩杂岩体相似,在＾２０７Ｐｂ／＾２０６Ｐｂ－＾２０８Ｐｂ／＾２０６Ｐｂ图解上,矿石、正长岩、矿石中的钾长石脉石及太古宇桑干群变质岩呈线性分布,矿石与正长岩     

安徽省东至县查册桥金矿地质特征及硫铅同位素示踪

东至县查册桥金矿位于扬子陆块北缘,矿床规模达中型。为了解成矿物质来源,对查册桥金矿矿石进行了硫、铅同位素分析。结果显示:δ(34S)变化范围为1.8×10~(-3)～18.1×10~(-3),平均值为11.09×10~(-3),较集中分布在10×10~(-3)～15×10~(-3)之间,分布宽泛;矿石硫化物矿物206 Pb/204 Pb值介于17.954～19.748之间,207 Pb/204 Pb值介于15.608～15.786之间,208 Pb/204 Pb值介于38.107～39.411之间,它们的μ值9.43～9.77;ω值32.63～38.83;w(Th)/w(U)值介于3.31～3.93,Δβ值18.45～30.06;Δγ值22.96～57.97。硫、铅同位素特征表明查册桥金矿床成矿物质主要来源于上地壳,其形成与陆内造山作用和岩浆作用密切相关。     

海南西南部抱伦金矿床流体包裹体及稳定同位素特征

抱伦金矿床的石英和方解石中的包裹体以气液包裹体为主,石英中舍大量CO2包裹体。成矿流体属Na（K）-Cl型。气相成分CH4、C2H6、H2S、O2、N2和心的含量反映属弱还原环境。液相成分中阴、阳离子分别以Cl^-、Na^＋为主,舍少量CO4^2-、F^-,Mg^2＋和Ca^2＋。Au在成矿流体中以AuCl2^-和Au（HS）2^-络合物的形式迁移。均一温度主要为160-350℃,属中温范畴。流体水的δ^18O和δD值分别为-3．4‰-＋9．8‰和-61‰-30‰,其来源主要为岩浆水与大气降水。石英的δ^18O值（＋10．4‰-＋15．5‰）与华南陆壳型花岗岩成因的钨、锡、稀有、稀土金属矿床一致。CO2和黄铁矿的C、S同位素反映C和S以花岗岩浆来源为主,少量来自志留系或更老的地层。综合分析认为矿床成因与印支期花岗质岩浆活动有关。