Reply to Molina-Garza et al. (2019) “Discussion of: Ortega-Flores et al. (2018) provenance analysis of Oligocene sandstone from the Cerro Pelón area,southern Gulf of Mexico”

ABSTRACT

The origin of the Oligocene turbidites from the Cerro Pelón area in south Gulf Mexico proposed by Ortega-Flores et al. (2018) is in disagree with the interpretations made by Molina-Garza et al. (2019), which main criticism is based on U-Pb ages of detrital zircons from the matrix of a conglomerate unit, which they refer to as ‘Nanchital Conglomerate’, as well as on the presence of limestone, gabbros, and mafic protolith-derived clasts. Molina-Garza et al. (2019) basically interpret the Nanchital Conglomerate as Miocene in age, which was sourced mainly from metamorphic complexes including their sedimentary covers located to the west and south of the Cerro Pelón area. For some reason, Molina-Garza et al. (2019) suppose that the Nanchital Conglomerate should have the same provenance sources that the Oligocene turbidites from Cerro Pelón area, reported by Ortega-Flores et al. (2018). Based on the foregoing, we strongly disagree with Molina-Garza et al. (2019) considering that, from the beginning, they intend to compare two units of different age. Additionally, the scarce data reported from both the matrix and the clasts of the Nanchital Conglomerate are not determinant for interpreting the provenance of this conglomeratic unit and subsequently, to consider the same rock sources from the Oligocene through Miocene time.     

GGR Critical Review of Analytical Developments in 2006–2007

In 2005 the Geostandards and Geoanalytical Research editorial team, in the true spirit of scientific endeavour, embarked on an experiment of our own. We decided to trial a new kind of review, somewhat different from those more typically observed in journals, and one that would provide readers with a summary of analytical developments across a broad range of topics appropriate to the Earth sciences. The first contribution of this kind appeared in 2005, and reported on developments in 2003 (Hergt et al. 2005). The second, this time a biennial review, was published in 2006 and reported on highlights of the 2004 and 2005 literature (Hergt et al. 2006). Based on reprint requests, positive remarks at conferences and strong citations we consider the experiment a resounding success and proudly present here the third in this series. This comprises six individual review sections that cover the main analytical technologies and topical application fields in geoanalysis and geochemistry, including geological and environmental reference materials, ICP‐thermal and secondary ionisation‐mass spectrometry, as well as neutron activation analysis, X‐ray fluorescence and atomic absorption spectrometry.     

Appraisal of soft computing techniques in prediction of total bed material load in tropical rivers

This paper evaluates the performance of three soft computing techniques, namely Gene-Expression Programming (GEP) (Zakaria et al 2010), Feed Forward Neural Networks (FFNN) (Ab Ghani et al 2011), and Adaptive Neuro-Fuzzy Inference System (ANFIS) in the prediction of total bed material load for three Malaysian rivers namely Kurau, Langat and Muda. The results of present study are very promising: FFNN (R ² = 0.958, RMSE = 0.0698), ANFIS (R ² = 0.648, RMSE = 6.654), and GEP (R ² = 0.97, RMSE = 0.057), which support the use of these intelligent techniques in the prediction of sediment loads in tropical rivers.     

Flood estimation in Mahanadi river system,India using partial duration series

Flood frequency analysis is a pre-requisite for setting up and safeguarding of many hydraulic structures, such as dams, barrages, check-dams, culverts and urban drainage systems. In the flood frequency analysis, partial duration series (PDS) may be considered when dealing with values exceeding certain limits causing floods. In fact, the PDS is capable of getting more information about extreme events than the annual maximum series (AMS). Additionally, an assumption that, the magnitude of the extreme events of a PDS is best described by a generalized Pareto (GP) distribution. The present work investigates the at-site flood frequency analysis to find the average number of peaks (λ) for modelling the PDS on the basis of the PDS/GP assumption and variability in the GP parameters coupled with the quantile estimation with an increase in the value of average number of peaks (λ) each year in the Mahanadi river system, Odisha, India. Also, to verify the PDS/GP assumption we tested seven different frequency distributions (Exponential, Gumbel, logistics, generalized extreme value (GEV), Lognormal (LN), generalized logistics (GL) and Pearson Type 3). Extensive daily discharge data collected from 23 gauging sites were used for the analysis. The results indicate precision and stability of GP distribution parameters for λ?=?4 for almost all the discharge sites. The peak flood estimated for various return periods in the Mahanadi river system using GP distribution is endowed with high correlation statistics for this λ value.     

Prospection géoélectrique pour l'étude de l'aquifère thermal des calcaires récifaux, Hmeïma–Boujabeur (Centre ouest de la Tunisie)

The Hmeïma–Boujabeur zone is considered as an important geothermal province for Tunisia. The reef limestone, characterized by intense fracturation and important karstification, confers them the property to be a regional thermal aquifer. A geophysical study based on two complementary geoelectrical methods, the Electrical Sounding (ES) and Magneto-Telluric Sounding (MTS), turned out to be very efficient to provide a complete electrical image of the underground until about 1-km depth. The synthetic approach integrating all data allowed us to delimit the favourable area for thermal water exploitation. To cite this article: M. Gouasmia et al., C. R. Geoscience 338 (2006).     

Évaluation de la qualité de l'eau par application de la méthode géoélectrique : exemple de la plaine d'El Mida–Gabes nord (Sud tunisien)

The Mida plain, which is part of the North Gabès region (southern Tunisia), is characterized by the deep sandy units of the ‘Continental intercalaire’ (CI) or the limestone of the Lower Senonian. A geophysical survey, by electrical sounding (ES), was undertaken in the studied region to better characterize the deep geological structure of this plain and therefore its aquifer resources potential. The analysis of the results shows that the prospected zone is characterized by the succession of several levels with contrasted resistivities, which are often affected by faults. Among these observed geoelectrical levels, the highly conductor one could host a saline aquifer. Another geoelectrical level corresponding to the resistant bedrock detected at Oudhref horst can contain better-quality water than that of the aquifer detected in the El Mida Graben. In this work, we tried to explain the origin of the salinity of this aquifer. Thus, we hypothesise about a contamination from Jebel Zemlet El Beida through a border fault and another one from the Sebkhet El Hamma. To cite this article: A. Mhamdi et al., C. R. Geoscience 338 (2006).     

Large European earthquakes of the 20th century

The magnitudes of the largest events in the European area have not exceeded M = 8 (shallow shocks) and m = 7.8 (intermediate depth shocks), respectively during the 20th century. Their geographical and depth distributions are discussed. The magnitude frequency relationships and the Gumbel III model define the statistical expectancy of the extreme events within the whole area. The strain release has a relatively constant trend between 1901–1975.     

LATE QUATERNARY DETRITAL CARBONATE (DC-) LAYERS IN BAFFIN BAY MARINE SEDIMENTS (67°–74°N): CORRELATION WITH HEINRICH EVENTS IN THE NORTH ATLANTIC?

Episodes of glaciation in the region north of Baffin Bay resulted in the erosion of Paleozoic carbonate outcrops in NW Greenland and the Canadian High Arctic. These events are recognized in the marine sediments of Baffin Bay (BB) as a series of detrital carbonate-rich (DC-) layers. BBDC-layers thin southward within Baffin Bay; thus, the contribution of Baffin Bay ice-rafted carbonate-rich sediments to the North Atlantic is probably slight, especially compared with sediment output from Hudson Strait during Heinrich events. We reexamine (cf. Aksu, 1981) a series of nine piston cores from the axis of Baffin Bay and across the Davis Strait sill and provide a suite of 21 AMS ¹⁴C dates on foramininfera which bracket the ages of several DC-layers. The onset of the last DC event is dated in six cores and has an age of ca. 12.4 ka. In northern and central Baffin Bay a thick DC-layer occurs at around 4 m in the cores and is dated >40 ka. There were three to six DC intervening events. The youngest BBDC event (possibly a double event) lags Heinrich event 1 (H-1) off Hudson Strait, dated at 14.5 ka, but it is coeval with the pronounced warming seen in GISP2 records from the Greenland Ice Sheet during interstadial #1. We hypothesize that BBDC episodes are coeval with major interstadial δ¹⁸O peaks from GISP2 and other Greenland ice core records and are caused by or associated with the advection of Atlantic Water into Baffin Bay (cf. Hiscott et al., 1989) and the subsequent rapid retreat of ice streams in the northern approaches to Baffin Bay.     

Discussion of ‘Coarse‐sand beach ridges at Cowley Beach,north‐eastern Australia: Their formative processes and potential as records of tropical cyclone history’ by Tamura et al. (2018), Sedimentology, 65, 721–744

The processes resulting in the formation of a coarse‐grained sand beach ridge plain at Cowley Beach, north‐east Australia have been questioned by Tamura et al. (2018). These authors now acknowledge the conclusions by Nott et al. (2009) and Nott (2014) that the dominant depositional mechanisms here are waves and inundations generated during tropical cyclones. The Tamura et al. (2018) new ground penetrating radar data highlights that scarping of incipient ridges is a common feature and occurs regularly under non‐storm conditions. The upper sedimentary units deposited during storms are not scarped and demonstrate the high preservation potential and usefulness of these deposits for reconstructing long‐term records of tropical cyclones. Tamura et al. (2018) question the robustness of the methodology used by Nott & Hayne (2001), Nott (2003) and Nott et al. (2009) in estimating the magnitude of the storms responsible for these sedimentary deposits. These supposed issues though have been dealt with in detail in a series of publications over the past nearly two decades. The shortcomings of the Tamura et al. (2018) criticisms are explained in detail here.     

Natural concentrations of lead in ancient Arctic and Antarctic ice

Concentrations of Pb and K were determined in a series of veneer layers chiseled in sequence from the outside toward the center of each of the five 1500–5500yr old ice core sections that had been drilled in Greenland and Antarctic ice. They were analogs of very old ice samples analyzed earlier by Herronet al. (1977) and Craginet al. (1975), who reported high concentrations of Pb in them. Lead contamination, existing at exterior concentrations of about 10⁶ ng/kg ice, had intruded to the centers of the cores, establishing interior values of at least 1.4 ng/kg ice in three electromechanically drilled Camp Century core sections taken from fluid filled drill holes. Corresponding Pb concentration changes were 3 × 10⁴ ng/kg ice to 1.2 ng/kg ice in two thermally drilled New Byrd Station core sections taken from non-fluid filled drill holes. Contamination made the lowest center concentrations serve only as upper limits to the original concentrations of Pb in the ice.Potassium concentrations decreased from exterior values of about 5 × 10⁵ ng/kg ice to an interior value of 2 × 10³ ng/kg ice in the Camp Century core sections and from 8 × 10⁴ ng/kg ice to 9 × 10² ng/kg ice in New Byrd Station core sections. Potassium contamination effects were not large within the central portions of the cores.These data verify earlier findings by Murozumiet al. (1969) and extend to a broader geographical significance the general validity of their observation of a ~ 300-fold increase of Pb concentrations in the Greenland ice sheet during the past 3000 yr. Our findings refute claims by Herronet al. (1977) and Craguinet al. (1975) that 100-fold excesses of natural Pb exist in 800 yr old Greenland ice above levels contributed by silicate dusts. Our new data also show that average Pb concentrations of 26 ng Pb/kg ice, claimed by Boutron and Lorius (1979) to be natural and present for 60 yr in snow strata in Antarctica, did not exist in old Antarctic ice, and that Pb concentrations have increased at least 10-fold in that ice during the past century.Virtually all of the present day ~300-fold excess of Pb above natural levels in Greenland ice can be shown to be caused by industrial Pb emissions to the atmosphere on the basis of the following factors: (1) the historic increase of Pb in snow strata coincides with the historic increase of industrial Pb production and atmospheric emissions (2) mass inventories of industrial emissions can account for the excess Pb in polar snow (3) new quantitative measurements of Pb emissions from volcanic plumes by Buat-Menard and Arnold (1978), Pattersonet al. (1981), and Buat-Menardet al. (1981), and from sea spray by Ng and Patterson (1981) and Settle and Patterson (1981). show that these natural sources cannot account for 99% of the excess Pb above contributions by silicate dusts observed today in the atmosphere; and (4) the historic increase of Pb in snow strata is paralleled by analogous increases of excess Pb shown by isotopic tracers to be industrial in water-laid sediments in a remote continental region (Shirahataet al., 1980). It is now known, however, that snows display about a 10-fold greater excess of industrial Pb above crustal silicate concentrations than exists in the air above the snows.     

Reply to the Discussion by John Nott on ‘Coarse‐sand beach ridges at Cowley Beach,north‐eastern Australia: Their formative processes and potential as records of tropical cyclone history’ by Tamura et al. (2018), Sedimentology,65, 721–744

Tamura et al. (2018) refined our understanding of formative processes that have resulted in a series of coarse‐sand beach ridges at Cowley Beach in north‐eastern Australia. Nott (2018) claimed that there are several shortcomings in the findings Tamura et al. (2018) presented. However, his criticism mostly derived from his misunderstanding of the data and discussion presented in Tamura et al. (2018), which thus should be clarified here. This reply also reiterates how his method for estimating the magnitude of past tropical cyclones from beach ridges is inconsistent with our observations of beach morphology and beach‐ridge formative processes.     

Reply to discussion of Jamaican cenozoic ichnology: review and prospectus: (v. 50, p. 364–382)

Mitchell and Ramsook comment on the lithostratigraphic assignment of Jamaican Cenozoic ichnofossils discussed in Donovan et al. They argue that the Paleogene Richmond Formation should be subdivided to produce a ‘Moore Town formation’ in eastern Jamaica, but the latter remains undefined as a lithostratigraphic unit and no new lithostratigraphic evidence is produced to support their supposition. Further, their use of a flawed table of trace fossil distributions does not support their thesis. The distribution of trace fossils in the White Limestone Group presented by Donovan et al. follows the lithostratigraphic scheme that was current at the time that the research was originally undertaken in the early 2000s. Yet, whatever lithostratigraphic scheme is utilised for the island, it is apparent that the more accurate data is provided by the biostratigraphy of the larger benthic foraminifers. Copyright © 2015 John Wiley & Sons, Ltd.     

On breaks of the Indian monsoon

For over a century, the term break has been used for spells in which the rainfall over the Indian monsoon zone is interrupted. The phenomenon of ’break monsoon’ is of great interest because long intense breaks are often associated with poor monsoon seasons. Such breaks have distinct circulation characteristics (heat trough type circulation) and have a large impact on rainfed agriculture. Although interruption of the monsoon rainfall is considered to be the most important feature of the break monsoon, traditionally breaks have been identified on the basis of the surface pressure and wind patterns over the Indian region. We have defined breaks (and active spells) on the basis of rainfall over the monsoon zone. The rainfall criteria are chosen so as to ensure a large overlap with the traditional breaks documented by Ramamurthy (1969) and Deet al (1998). We have identified these rainbreaks for 1901-89. We have also identified active spells on the basis of rainfall over the Indian monsoon zone. We have shown that the all-India summer monsoon rainfall is significantly negatively correlated with the number of rainbreak days (correlation coefficient -0.56) and significantly positively correlated with the number of active days (correlation coefficient 0.47). Thus the interannual variation of the all-India summer monsoon rainfall is shown to be related to the number of days of rainbreaks and active spells identified here. There have been several studies of breaks (and also active spells in several cases) identified on the basis of different criteria over regions differing in spatial scales (e.g., Websteret al 1998; Krishnanet al it 2000; Goswami and Mohan 2000; and Annamalai and Slingo 2001). We find that there is considerable overlap between the rainbreaks we have identified and breaks based on the traditional definition. There is some overlap with the breaks identified by Krishnanet al (2000) but little overlap with breaks identified by Websteret al (1998). Further, there are three or four active-break cycles in a season according to Websteret al (1998) which implies a time scale of about 40 days for which Goswami and Mohan (2000), and Annamalai and Slingo (2001) have studied breaks and active minus break fluctuations. On the other hand, neither the traditional breaks (Ramamurthy 1969; and Deet al 1998) nor the rainbreaks occur every year. This suggests that the `breaks’ in these studies are weak spells of the intraseasonal variation of the monsoon, which occur every year. We have derived the OLR and circulation patterns associated with rainbreaks and active spells and compared them with the patterns associated with breaks/active minus break spells from these studies. Inspite of differences in the patterns over the Indian region, there is one feature which is seen in the OLR anomaly patterns of breaks identified on the basis of different criteria as well as the rainbreaks identified in this paper viz., a quadrapole over the Asia-west Pacific region arising from anomalies opposite (same) in sign to those over the Indian region occurring over the equatorial Indian Ocean and northern tropical (equatorial) parts of the west Pacific. Thus it appears that this quadrapole is a basic feature of weak spells of the intraseasonal variation over the Asia-west Pacific region. Since the rainbreaks are intense weak spells, this basic feature is also seen in the composite patterns of these breaks. We find that rainbreaks (active spells) are also associated with negative     

Geoelectrical investigations by means of resistivity methods in karst areas in Romania

The applicability of resistivity methods to ground water investigations is well recognized. As water-saturated rock formations have a lower electrical resistivity than dry ones, an electrical resistivity survey should result in low resistivity anomalies. Normally, such anomalies are interpreted to indicate areas of potentially significant ground water flows. In karst areas, however, interpretation may not be as straightforward: for example, large electrically conductive domains can represent water bearing zones, whose fluid-permeability may be poor; alternatively, fast flow conduits, which may be unsaturated, occur as slender objects, and not as clear anomalous features. In order to deal with such extreme heterogeneities, resistivity investigations require some specific adjustments. One example is the so-called “mise à la masse” method. In Romania, it was used to trace the cold karst water inflows that detrimentally affected the commercial exploitation of a thermal spring, Hercules at Baile Herculane. Conventional geoelectrical approaches––such as using resistivity highs to detect air-filled cave passages, are proved to be less efficient in the considered karst investigations.     

Tellurium: Should it be isotopically anomalous in the Allende meteorite?

Isotopically anomalous Te is a by-product of the nuclear processes in zones of supernovae that have been proposed as sources for isotopically anomalous Xe. The calculated composition of the anomalous Te is roughly consistent with the disputed measurements made by Balladet al. (1979) and Oliveret al. (1979) of samples of the Allende meteorite with the exception that the large ¹²³Te overabundance reported by Oliveret al. (1979) is not predicted by the theory.     

Significance of Dar-Zarrouk parameters in the exploration of quality affected coastal aquifer systems

The interpreted Earth subsurface resistivity layer parameters of 55 vertical geoelectrical soundings are analyzed over a fan shaped area of 1,700 km² from Pipli-Astrang-Bhramgiri, Orissa, India. In this study, Dar-Zarrouk (D-Z) parameters, namely the longitudinal conductance (S), transverse resistance (T) and longitudinal resistivity (R _s ) are analyzed and we encountered the resistivity regime of the clay layers, saline and fresh water bearing formations. The significance of these parameters in establishing an easily decipherable vision about the occurrence and distribution of fresh and saline water aquifers, while dealing with complicated situations of intermixing of the resistivity ranges of saline and fresh water aquifers has been illustrated. The results show that the Dar-Zarrouk (D-Z) parameters provide a useful and confident solution in delineating the saline and fresh water aquifers. The behavior of the D-Z parameters S, T and R _s , and its patterns in space over large areas with respect to the occurrence of saline water and fresh water aquifer systems in the deltaic coastal aquifer system has been demonstrated.     

Comparison of aquifer vulnerability assessment techniques. Application to the Néblon river basin (Belgium)

Five different methods for assessing intrinsic aquifer vulnerability were tested in a case study and their results compared. The test area was a slightly karstified district in the Condroz region of Belgium. The basin covers about 65 km² and the karst aquifer provides a water-supply of about 28,000 m³d^-1. The methods tested were: EPIK (Doerfliger et al. 1999), DRASTIC (Aller et al. 1987), 'German method' (von Hoyer and Söfner 1998), GOD (Foster 1987) and ISIS (Civita and De Regibus 1995). The results are compared and critically examined. From the analysis, it seems that reducing the number of parameters is unsatisfactory, due to the variety of geological conditions. The various methods produce very different results at any given site. As only physically-based methods can be checked for their reliability, it is clear that future vulnerability mapping techniques must incorporate such methods.     

A reexamination of cellulose carbon-bound hydrogen δD measurements and some factors affecting plant-water D/H relationships

The method of Epstein et al. (1976) for analysis of D/H ratios of cellulose carbon-bound hydrogen has been modified. This modified “renitration” method yields δD values which are in agreement with those obtained by the sodium chlorite delignification method. Comparison of results obtained by the renitration method with the published results of Epstein et al. (1976) indicate some differences in the δD values of individual samples. However, the overall plant-water δD relationship determined by Epstein et al., is not greatly changed upon redetermination by the renitration method. Additional data from a variety of plants representing a wide geographical range reveal that relative humidity is an important variable in determining the δD value of cellulose C-H hydrogen on this inter-regional scale. The role of relative humidity can be reasonably explained by a leaf water model that assumes an isotopic steady-state during transpiration. These results reaffirm the conclusion of Epstein et al., that the δD variations of the source water are the dominant control of the δD variations of cellulose C-H hydrogen from naturally grown plants. Thus, there is an expectation that these cellulose δD variations can have climate significance.     

Temporal and spatial variations in the magnitude of completeness for homogenized moment magnitude catalogue for northeast India

Northeast India region is one of the most seismically active areas in the world. Events data for the period 1897–2010, used in this study has been largely compiled from global ISC, NEIC and GCMT databases. Historical seismicity catalogue of Gupta et al (1986) and some events data from the bulletins of India Meteorological Department are also used. Orthogonal regression relations for conversion of body and surface wave magnitudes to M _w,HRVD based on events data for the period 1978–2006 have been derived. An Orthogonal Standard Regression (OSR) relationship has also been obtained for scaling of intensity estimates to M _w,NEIC using 126 global intensity events with intensity VI or greater during the period 1975–2010.