内蒙古乌拉山地区变质作用的P—T条件和P—T—t轨迹

研究区主要由麻粒岩相变质的孔兹岩系组成，经历了初期、主期、峰期和晚期四个变质阶段。采用多种矿物对地质温压计方法估算，各变质阶段的温压条件分别为６５０－７００℃，０．５ＧＰａ；６７０－８３７℃，０．５３－０．７４ＧＰａ；６８７－９１１℃，０．３４－０５７ＧＰａ；６５０℃，０．３５ＧＰａ。温压条件的变化反映了变质作用 的动态力学过程，表现为顺时的Ｐ－Ｔｔ轨变。具有典型大造山带环境的变质演化特点和动力学     

阜平地区麻粒岩的P－T路径研究

阜平麻粒岩分布于阜平大柳树和坊里一带的原阜平超群下亚群索家庄组花岗质片麻岩中，以不同规模的透镜体、似层状体产出、麻粒岩主要由石榴石、单斜辉石、斜方辉石、角闪石和斜长石等矿物组成，含有少量的石英。根据岩石的矿物组合和结构特征可将其变质作用演化分为四个阶段：①石榴石中的角门石、斜长石、单斜辉石等变质矿物包体代表峰前阶段；②粗粒平衡共生的角闪石、单斜辉石、石榴石、斜长石±紫苏辉石±石英等代表了峰期变质阶段；③石榴石变斑晶后生合晶反应边中外侧细粒斜方辉石、斜长石和石英集合体代表了峰后变质阶段；④后生合晶反应边中内侧角门石、斜长石等，代表了晚期退化变质阶段。这四个变质阶段演化的Ｐ－Ｔ条件依次为：峰前阶段６３６℃、０．８２４ＧＰａ，峰期阶段７５１～８３３℃、０．８５４～１．０８５ＧＰａ，峰后阶段６７０～７４０℃、０．５５～０．７０ＧＰａ，退化变质阶段６６５℃、０．７２７ＧＰａ，构成了一条顺时针的Ｐ－Ｔ路径，反映了该变质区从早期褶皱增厚到晚期构造抬升的地质动力学过程。     

川西丹巴穹状变质体的P－T－t－d演化

在扬子地台西缘松潘－甘孜复合造山带东部的丹巴地区，发育一系列穹状变质体。据近年的研究，这些变质体至少经历了四期变形及相伴随的三期变质作用。利用变质反应、角闪石和二云母的矿物化学，矿物地质温压计及相关的同位素年龄资料，建立了丹巴变质体演化的Ｐ－Ｔ－ｔ－ｄ轨迹。此轨迹呈顺时针形式，反映了变质分带属于叠加复合型，黑云母带－蓝晶石带属于中压型。矽线石带则属低压高温型，即变质作用曾经历了增温增压，增温降压和恒压降温三个演化阶段，表明变质体具陆－陆碰撞的地壳加厚和随后花岗岩浆活化上侵的回返上隆的演化特点，这和区域大地构造背景相吻合。     

大别山榴辉岩（牌楼）P－T－t轨迹

本文重点研究了大别山潜山，牌楼地区榴辉岩Ｐ－Ｔ－ｔ轨迹，探讨了大别山地区榴辉岩成因，认为榴辉岩原岩主要是碱性玄武岩，少部分洋脊拉斑玄武岩岩浆早期结晶分异堆晶岩及部分钙质沉积岩。它们在华北与杨子板块碰撞时（２６０±３０Ｍａ），地壳向下俯冲到４０－６０ｋｍ处，温度５５０°－８３０°Ｃ，压力１．１－２．１ＧＰａ的条件下形成的。在构造抬升过程中，榴辉岩产生了角闪岩相、绿片岩相退变质作用，角闪岩相温压条件：４６０°－５７０℃，０．４－０．７ＧＰａ。流体包裹体研究表明：流体包体成分主要为ＮａＣｌ－Ｈ＿２Ｏ，Ｈ＿２Ｏ，ＮａＣｌ－ＣＯ＿２－Ｈ＿２Ｏ体系，变质作用过程从早至晚由氧化向还原环境转化。熔融包体的发现表明：榴辉岩形成具有局部深熔作用。从榴辉岩产状、岩石化学、地球化学特征表明本地区榴辉岩不是一种成因，同时具有Ｂ类、Ｃ类榴辉岩特征。     

四川会理小青山铜（金）矿区变质岩特征及变质作用P—T—D轨迹

经剖面测制及岩相学研究,确定小青山组主要由石榴石绢云母千枚岩、绢云母千枚岩及碳质板岩组成,而前人所提出的硬绿泥石千枚岩实际上是退变的石榴石绢云母千枚岩。镜下观察及成分研究证明石榴石具有两期生长的特点,其内核的Ｓｐｅ分子和Ａｌｍ分子分别为２９．２２％～３３．５５％和４３．２８％～４８．８６％,而边缘的Ｓｐｅ和Ａｌｍ分别为８．６５％～１７．０８％和６０．５５％～７０．０６％。依照结构特征划分出了２个阶段的白色云母。不同阶段白色云母的化学成分有一定差异。用同样的方法识别出了３个阶段的绿泥石,不同阶段绿泥石的成分也有一定差异。通过变质岩结构特征及矿物生长关系将变质作用划分为３个阶段（Ｍ１、Ｍ２、Ｍ３）。利用矿物温压计估算出了这３个阶段的Ｔ、Ｐ条件,Ｍ１：５００～５５０℃,０．６～０．７５ＧＰａ;Ｍ２：４００～４３０℃,０．３～０．５ＧＰａ;Ｍ３：２８０℃,＜０．３ＧＰａ。将变质变形研究相结合,建立了变质作用的Ｐ－Ｔ－Ｄ轨迹。小青山组变质Ｔ、Ｐ条件的确定,排除了其中赋存的小青山Ｃｕ（Ａｕ）矿床属沉积变质成因的可能。初步认为该Ｃｕ（Ａｕ）矿床为深源流体交代成因。     

东秦岭松树沟高压变质基性岩石及基退变质作用的PTt演化轨迹

在北秦岭商南松树沟出露的高压变质基性岩石，包括高压基性麻粒岩和石榴单斜辉石岩，遭受了从中压麻粒岩相、高角闪岩相到绿帘角闪岩相的连续的退变质作用的改造。这些岩石形成的温度为８２６℃－８８７℃，压力约为１．４０－１．５８ＧＰａ，其不同退变质阶段的温压条件依次分别是７６５℃－８２５℃和约１．０３－１．１４ＧＰａ、６５０℃－７５０℃和约０．９ＧＰａ以及４００℃－５００℃和约０．５－０．６ＧＰａ。它们共同构     

华中高压－超高压变质富铝岩石的温压条件研究及其地质意义

华中高压－超高压变质富铝岩石为陆壳岩石经变质而成，其典型的岩石类型为蓝晶石黄玉石英岩。矿物温压计估算其ｐ－Ｔ条件为Ｔ＝７００℃，ｐ＝１．２ＧＰａ；高温高压实验结果表明，蓝晶石＋黄玉组合在Ｔ＝１０００～１２００℃，Ｐ＝３．１～３．７７ＧＰａ范围内可以稳定存在，是高压－超高压变质作用产物。在蓝晶石石英岩中发现柯石英及柯石英假象，区域上其它岩石组合也有高压－超高压变质作用的证据。变质富铝岩石为榴辉岩相变质作用产物，从而证明陆壳岩石可以经历＞２．０ＧＰａ的变质压力条件。     

山东胶南隆起长英质岩石超高压高压岩石特征及其P—T演化

胶南隆起含榴辉石高压变质带为大别超高压带的东延部分，超高压变质作用的主要矿物共生组合为Ｇｒｔ＋Ｋｙ＋Ｒｕｔ＋Ｊｄ＋Ｑ；Ｓｐ＋Ｚｏ＋Ａｂ±Ｇｒｔ±Ｏｍｐ；变质作用的温压条件为Ｔ＝６００～７００℃，Ｐ＝２．３～２．６ＧＰａ。超高压岩石及高压岩石均经历了两期退变质作用，且具有相似的顺时钟Ｐ－Ｔ演化轨迹。     

东秦岭松树沟高压变质基性岩石及其退变质作用的PTt演化轨迹

在北秦岭商南松树沟出露的高压变质基性岩石，包括高压基性麻粒岩和石榴单斜辉石岩，遭受了从中压麻粒岩相、高角闪岩相到绿帘角闪岩相的连续的退变质作用的改造。这些岩石形成的温度为８２６℃～８８７℃，压力约为１．４０～１．５８ＧＰａ，其不同退变质阶段的温压条件依次分别是７６５℃～８２５℃和约１．０３～１．１４ＧＰａ、６５０℃～７５０℃和约０．９ＧＰａ以及４００℃～５００℃和约０．５～０．６ＧＰａ。它们共同构成一个早期近等温降压（ＩＴＤ）和晚期降温降压的顺时针ＰＴｔ演化轨迹。结合高压岩石９８３±１４０Ｍａ的退变质年龄和松树沟残存的蛇绿岩片考虑，这些高压岩石的形成和抬升与秦岭造山带中、晚元古宙时期洋壳的俯冲、消减和陆块碰撞伴随的快速构造上升作用有关。     

胶东早元古代荆山群富铝片麻岩中矿物共生的P—T—X关系及其演化

根据显微构造和矿物微区化学成分的详细研究,确定了胶东早元古代荆山群富铝片麻岩中存在平衡组合Ｇｒｔ－Ｃｒｄ－Ｂｔ－Ｓｉｌ－Ｋｆｓ－Ｐｌ－Ｑｔｚ,反映变质峰期Ｇｒｔ＋Ｓｉｌ＋Ｑｔｚ→Ｃｒｄ,Ｂｔ＋Ｓｉｌ＋Ｑｔｚ→Ｇｒｔ＋Ｃｒｄ＋Ｋｆｓ＋Ｈ２Ｏ和Ｐｌ（Ａｎ）→Ｇｒｔ（Ｇｒｓ）＋Ｓｉｌ＋Ｑｔｚ①等转换反应和Ｆｅ－Ｍｇ交换反应均基本保持平衡状态。实验资料和地质温压计估算确定其峰期Ｐ－Ｔ－Ｘ关系：Ｐ为０．６０～０．７０ＧＰａ,Ｔ为７００℃～７５０℃,ＸＧｒｔＭｇ为０．２１～０．２６,ＸＣｒｔＣａ为０．０４４～０．０５３,ＸＣｒｄＭｇ为０．６５～０．７２,ＸＢｔＭｇ为０．５０～０．５７,ＸＰｌＡｎ为０．２８５～０．３８８。但Ｇｒｔ、Ｂｔ和Ｐｌ又都有明显的微区成分变化,反映峰期后降温过程各种交换反应的效应,其封闭温度在５００℃～６００℃之间,压力为０．４０～０．５０ＧＰａ。研究确立逆时针的ＰＴｔ轨迹,其样式反映早元古代陆缘壳内拗陷带的闭合过程。     

Ostwald ripening of garnet in high P/T metamorphic rocks

This paper presents a theoretical formulation of Ostwald ripening of garnet and discusses the importance of the process during high pressure and low temperature (high P/T) metamorphism. The growth rate of garnet due to Ostwald ripening is formulated for the system consisting of minerals and an intergranular medium. Crystal size distribution (CSD) of garnets are examined and compared with the theoretical distribution for Ostwald ripening. Two types of CSDs are recognized. One is consistent with the theoretical prediction of size distribution while the other is wider than the theoretical distribution. The former CSD applies to samples in which garnets show homogeneous spatial distributions. The latter CSD applies to samples in which garnets show heterogeneous spatial distributions such as in clusters or layers. These relations suggest that the heterogeneity of spatial distributions results in a heterogeneity of concentration of garnet, causing the wide distributions. The mean diameter (dg) has a large variation in samples having narrow distributions. Ostwald ripening explains well the similar patterns of CSD in these samples with different dg because of a scaling law. Compositional profiles of garnets with different size are consistent with Ostwald ripening rather than nucleation and growth kinetics. This suggests that the CSDs result from Ostwald ripening. Magnitude of heating rate will determine which mechanism controls CSD. Nucleation and growth kinetics are dominant when heating rate is large. On the other hand, Ostwald ripening is dominant when heating rate is small. CSDs of garnets in high P/T metamorphic rocks are consistent with the latter case.     

Heterogeneous growth of cordierite in low P/T Tsukuba metamorphic rocks from central Japan

This paper examines the spatial statistics of matrix minerals and complex patterned cordierite porphyroblasts in the low‐pressure, high‐temperature (low P/T) Tsukuba metamorphic rocks from central Japan, using a density correlation function. The cordierite‐producing reaction is sillimanite + biotite + quartz = K‐feldspar + cordierite + water. The density correlation function shows that quartz is distributed randomly. However, the density correlation functions of biotite, plagioclase and K‐feldspar show that their spatial distributions are clearly affected by the formation of cordierite porphyroblasts. These observations suggest that cordierite growth occurred through a selective growth mechanism: quartz adjacent to cordierite has a tendency to prevent the growth of cordierite, whereas other matrix minerals adjacent to cordierite have a tendency to enhance the growth of cordierite. The density correlation functions of complex patterned cordierite porphyroblasts show power‐law behaviour. A selective growth mechanism alone cannot explain the origin of the power‐law behaviour. Comparison of the morphology and fractal dimension of cordierite with two‐dimensional sections from a three‐dimensional diffusion‐limited aggregation (DLA) suggests that the formation of cordierite porphyroblasts can be modelled as a DLA process. DLA is the simple statistical model for the universal fractal pattern developed in a macroscopic diffusion field. Diffusion‐controlled growth interacting with a random field is essential to the formation of a DLA‐like pattern. The selective growth mechanism will provide a random noise for the growth of cordierite due to random distribution of quartz. Therefore, a selective growth mechanism coupled with diffusion‐controlled growth is proposed to explain the power‐law behaviour of the density correlation function of complex patterned cordierite. The results in this paper suggest that not only the growth kinetics but also the spatial distribution of matrix minerals affect the progress of the metamorphic reaction and pattern formation of metamorphic rocks.     

An experimental investigation of Na incorporation in cordierite in low P/high T metapelites

Mineralogy and Petrology - The aim of this experimental study was to investigate the incorporation of Na in cordierite in metapelites as a function of temperature and pressure using natural...     

meso-四-(4-甲氧苯基)卟啉与铅的显色反应及其双波长和导数光谱行为研究

本文研究了meso-四-(4-甲氧苯基)卟啉与铅的高灵敏显色反应及双波长和导数光谱行为。当有Tween-80存在时,在强碱性介质中,于沸水浴上加热32min,显色反应能定量进行。该体系的表现摩尔吸光系数(ε_(466.5))为1.77×10~5,双波长的ε_(466.5/422)为3.16×10~5,四阶导数光谱的有效摩尔响应值为2.67×10~6。此显色体系用于合成样品中痕量Pb的测定,回收率在96.8～98.2％之间。     

The graphite-COH fluid equilibrium in P,T, f_{O_2 } space

The oxygen fugacity ( ) of a C-O-H fluid in equilibrium with graphite has been determined in the range 10–30 kbar by equilibrating solid -buffer assemblages in graphite capsules containing C-O-H fluid. By using different buffers (Fe_xO-Fe₃O₄, Ni-NiO, Co-CoO, Mo-MoO₂), the of the graphite-saturated fluid is bracketed within a narrow range. This technique produces a calibration for the imposed on a sample contained within a graphite capsule. To achieve a thermodynamically-invariant system at fixed P and T, the was imposed on the system with an external buffer and the double-capsule technique. The experiments were performed in solid-media, high pressure apparatus with 19 mm tale-pyrex assemblies. A series of experiments at 10, 15, 20, 25, and 30 kbar, 800–1600° C, with imposed by the Fe₂O₃-Fe₃O₄-H₂O equilibrium were conducted. The experimental results have been fitted to the following equation:

Characterization of Iron Grains near the P/T Boundary in the Meishan Section of China

The Meishan section of China has been confirmed as the ＂Global Stratotype Section and Point＂ of the P/T boundary. In the section, the authors found several types of iron grains, including pyrite, pure iron grains and goethite. From the research of macro minerals, it is easy to find that the grains rich in iron appear from the bottom of the event layer of the section. In other words, it is probably residue of the geochemical catastrophe of that time. Therefore, it is important to trace the source of these iron grains and their relationships, which probably provides evidence for volcanic eruption or impact-volcanoes and has directive significance to the crisis during the P/T transitional period. Through the study of the characterization and relationships of these iron grains, the authors make a preliminary discussion on the P/T mass extinction.     

P,T paths of natural eclogites during metamorphism — a record of subduction

The distribution of iron and magnesium between coexisting garnet and clinopyroxene is expressed by the distribution coefficient K_D^ga-cpx. This coefficient has been experimentally determined as a function of temperature and pressure, and is used to determine the temperature of equilibration of natural eclogites.

The presence of relict zoning in both garnet and clinopyroxene in low to medium temperature eclogites permits evaluation of the P,T path followed by these rocks during prograde metamorphism.

The average P,T path for eclogites of blueschist terranes (type C eclogites) is suggested to be 40°C/Kb during prograde metamorphism. The Tasmanian eclogite (type B) records crystallization along a different P,T path (lower pressure at given temperature) from those of the type C eclogites. Eclogites from the migmatite-gneiss terrances of Poland and Norway do not preserve evidence of prograde metamorphism in mineral zoning but indicate higher temperatures at the metamorphic maximum; pressures were similar to those attained by type C eclogites.     

Breakdown of hydrous ringwoodite to pyroxene and spinelloid at high P and T and oxidizing conditions

To get deeper insight into the phase relations in the end-member system Fe₂SiO₄ and in the system (Fe, Mg)₂SiO₄ experiments were performed in a multi-anvil apparatus at 7 and 13 GPa and 1,000–1,200°C as a function of oxygen fugacity. The oxygen fugacity was varied using the solid oxygen buffer systems Fe/FeO, quartz–fayalite–magnetite, MtW and Ni/NiO. The run products were characterized by electron microprobe, Raman- and FTIR-spectroscopy, X-ray powder diffraction and transmission electron microscopy. At fO₂ corresponding to Ni/NiO Fe-ringwoodite transforms to ferrosilite and spinelloid according to the reaction: 9 Fe₂SiO₄ + O₂ = 6 FeSiO₃ + 5 Fe_2.40Si_0.60O₄. Refinement of site occupancies in combination with stoichiometric Fe³⁺ calculations show that 32% of the total Fe is incorporated as Fe³⁺ according to From the Rietveld refinement we identified spl as spinelloid III (isostructural with wadsleyite) and/or spinelloid V. As we used water in excess in the experiments the run products were also analyzed for structural water incorporation. Adding Mg to the system increases the stability field of ringwoodite to higher oxygen fugacity and the spinel structure seems to accept higher Fe³⁺ but also water concentrations that may be linked. At oxygen fugacity corresponding to MtW conditions similar phase relations in respect to the breakdown reaction in the Fe-end-member system were observed but with a strong fractionation of Fe into spl and Mg into coexisting cpx. Thus, through this strong fractionation it is possible to stabilize very Fe-rich wadsleyite with considerable Fe³⁺ concentrations even at an intermediate Fe–Mg bulk composition: assuming constant K _D independent on composition and a bulk composition of x _Fe = 0.44 this fractionation would stabilize spl with x _Fe = 0.72. Thus, spl could be a potential Fe³⁺ bearing phase at P–T conditions of the transition zone but because of the oxidizing conditions and the Fe-rich bulk composition needed one would expect it more in subduction zone environments than in the transition zone in senso stricto.

P - V - T equation of state of stishovite to the mantle transition zone conditions

In-situ synchrotron X-ray diffraction experiments were conducted using the SPEED-1500 multi-anvil press of SPring-8 on stishovite SiO₂ and pressure-volume-temperature data were collected at up to 22.5 GPa and 1,073 K, which corresponds to the pressure conditions of the base of the mantle transition zone. The analysis of room-temperature data yielded V₀=46.56(1) ų, K_{T 0}=296(5) GPa and K _T =4.2(4), and these properties were consistent with the subsequent thermal equation of state (EOS) analyses. A fit of the present data to high-temperature Birch-Murnaghan EOS yielded (K_T /T) _P =–0.046(5) GPa K^–1 and = a + bT with values of a =1.26(11)×10^–5 K^–1 and b =1.29(17)×10^–8 K^–2. A fit to the thermal pressure EOS gives ₀=1.62(9)×10^–5 K^–1, ( K _T / T) _V =–0.027(4) GPa K^–1 and (²P /T ²) _V =27(5)×10^–7 GPa K^–2. The lattice dynamical approach by Mie-Grüneisen-Debye EOS yielded ₀=1.33(6), q =6.1(8) and ₀=1160(120) K. The strong volume dependence of the thermal pressure of stishovite was revealed by the analysis of present data, which was not detectable by the previous high-temperature data at lower pressures, and this yields ( K _T / T) _V 0 and q 1. The analyses for the fictive volume for a and c axes show that relative stiffness of c axis to a axis is similar both on compression and thermal expansion. Present EOS enables the accurate estimate of density of SiO₂ in the deep mantle conditions.