A Methodology for Clustering Lakes in Alberta on the basis of Water Quality Parameters

In this study, a methodology for clustering 18 lakes in Alberta, Canada using the data of 19 water quality parameters for a period of 11 years (1988–2002) is presented. The methods consist of (i) principal component analysis (PCA) to determine the dominant water quality parameters, (ii) cluster analysis techniques to develop the characteristics of the clusters, and (iii) pattern‐match lakes to determine the appropriate cluster for each of the lakes. The PCA revealed that three principal components (PCs) were able to explain ～88% of the variability and the dominant water quality parameters were total dissolved solids, total phosphorus, and chlorophyll‐a. We obtained five clusters for the period 1994–1997 by using the dominant parameters with water quality deteriorating as the cluster number increased from 1 to 5. Upon matching cluster patterns with the entire dataset, it was observed that some of the lakes belonged to the same cluster all the time (e.g., cluster 1 for lakes Elkwater, Gregg, and Jarvis; cluster 3 for Sturgeon; cluster 4 for Moonshine; and cluster 5 for Saskatoon), while others changed with time. This methodology could be applied in other regions of the world to identify the most suitable source waters and prioritize their management. It could be helpful to analyze the natural controlling processes, pollution types, impact of seasonal changes and overall quality of source waters. This methodology could be used for monitoring water bodies in a cost effective and efficient way by sampling only less number of dominant parameters instead of using a large set of parameters.     

Type-specific and indicator taxa of phytoplankton as a quality criterion for assessing the ecological status of Finnish boreal lakes

Key issues in the implementation of the Water Framework Directive are classification of lakes using biological quality parameters and type-specific reference conditions. This work is one of three studies considering different metrics of phytoplankton in the classification of ecological status. Phytoplankton was studied in a total of 55 Finnish boreal lakes, including 32 reference lakes. We tested the suitability of taxonomic composition and abundance of phytoplankton groups for biological classification. We also preliminarily determined the type-specific taxa for the studied lakes. The type-specific taxa for reference conditions are coincidently the indicator species/taxa for high ecological status. Interestingly, some taxa type-specific for impacted oligo-humic lakes proved to be the type-specific taxa for humic reference lakes. The pressure of human impact was observed not only as increase of biomass but also as changes in the species composition. The phytoplankton composition indicated the ecological status of impacted lakes moderately well. There was some variation in the indications given by different algal groups, probably due to the preliminary class boundaries used. However, the preliminary combination of indicative parameters to estimate the ecological status of the studied impacted lakes was in general in accordance with earlier classification of water quality in Finnish lakes.     

Pesticides Removal by Filtration over Cactus Pear Leaves: A Cheap and Natural Method for Small‐Scale Water Purification in Semi‐Arid Regions

This study aims to examine the efficiency of Opuntia ficus‐indica for removing organochlorine pesticides from surface waters. Adsorption properties such as size, dose, and time of O. ficus‐indica for aldrin, dieldrin, and dichlorodiphenyltrichloroethane (DDT) were studied through stirring and column methods. Because of their high affinity and swelling characteristics, dried O. ficus‐indica was studied in stirring while fresh unpeeled O. ficus‐indica was applied in both stirring and column experiments and proved to be well‐suited to column application. Before removing pesticides, the column was flashed with distilled water eliminate the turbidity and smell from fresh unpeeled cactus. The removal of pesticides increased with an increasing adsorbent dose and decreased with adsorbent particle sizes. The optimum adsorbent dose is 10 g for dried and 15 g for fresh unpeeled O. ficus‐indica. The experimental results show that O. ficus‐indica possesses strong adsorption ability for aldrin, dieldrin, and DDT, and the adsorption isotherm data obeyed the Freundlich model. The results of our small‐scale experiments suggest a strong potential to develop local small‐scale water treatment units that can be used at the level of individual households or local communities, using a widely available adsorbent.     

A Basic Water Quality Model for the River Neckar: Part 2 – model‐based analysis of the oxygen budget and scenarios

In this paper the Basic Water Quality Model (BWQM) for the central part of River Neckar is used to analyse the oxygen budget and to assess the potentials of various measures to prevent or mitigate critical dissolved oxygen (DO) declines. It is shown that the oxygen budget is mainly governed by phytoplankton dynamics. The excessive growth of algae and the sudden break down of the resulting algal blooms may cause episodic DO depressions. Therefore, to stabilise the oxygen budget in a sustainable way, eutrophication has to be controlled within the central part of River Neckar and the upstream regions. The only feasible way to reach this goal appears to be a further drastic reduction of phosphorus emissions. In addition, it is indispensable to hold the very high standards of biochemical oxygen demand and ammonium retention at the wastewater treatment plants. A worse performance of the treatment plants would dramatically aggravate critical DO declines which may be caused by algae dynamics. As long as the oxygen budget is not completely stabilised, weir and turbine aeration can be used to mitigate DO depressions. It could be shown that the potentials of these measures suffice to keep DO at a tolerable level. However, due to the long travel times in River Neckar, it is important to start aeration up to several days before the DO minimum is reached.     

Effects of Watershed Land Use and Lake Morphometry on the Trophic State of Chinese Lakes: Implications for Eutrophication Control

Water quality in lakes is influenced by a large number of watershed and lake characteristics. In this study, we examined the relative effects of watershed land use and lake morphology on the trophic state of 19 lakes in the Yunnan plateau and lower Yangtze floodplain, the two most eutrophic regions in China. Trophic state parameters consisted of total nitrogen, total phosphorus, chemical oxygen demand, chlorophyll‐a, Secchi depth, and trophic state index, while lake morphometric variables included area, maximum depth, mean depth, water residence time (WRT), volume, and length to width ratio. Percentages of forest, grassland, cropland, unused land, built‐up land, and water body in each lake's watershed were extracted from a land use map interpreted from Landsat TM images. A t‐test indicated that lower Yangtze floodplain lakes were shallower and had higher percentages of cropland and built‐up land in watersheds than Yunnan plateau lakes. Pearson's correlation analysis indicated that both watershed land use and lake morphometric variables were significantly related to most of the trophic state parameters. However, stepwise regression analyses demonstrated that the trophic state of the lower Yangtze floodplain lakes was mainly controlled by the percentages of cropland and built‐up land in watersheds, while that of Yunnan plateau lakes was mostly determined by the lake depth and WRT. These results suggest that the relative effects of watershed land use and lake morphology on lake trophic state are dependent on the lake's location. This study can provide some useful information in watershed land use management for controlling eutrophication in Chinese lakes.     

A Simplified Analytical Procedure for the Determination of Organically Bound Halogens in Salt‐containing Water Samples

A method was developed for the determination of organic halogens in water samples with the aim of minimizing matrix effects and simplifying the sample preparation technique commonly used. The method is based on the adsorption of organic halogens in modified hydrophilic divinylbenzene polymer columns and their elution with methanol. The adsorbent used enables rapid adsorption and desorption due to comparatively high operating flow rates and minimized solvent amounts. Furthermore, no additional reconcentration steps are needed. The methanol extract obtained is combusted with a standard EOX (extractable organic halogen) analyzer and the concentration of organically bound halogens is determined by microcoulometric analysis. The matrix effects are considerably reduced compared to the standard procedure (EN 1485) commonly used. A detection limit of 13 μg/L was established.     

A method for the direct estimation of floor acceleration spectra for elastic and inelastic MDOF structures

This paper deals with floor acceleration spectra, which are used for the seismic design and assessment of acceleration‐sensitive equipment installed in buildings. In design codes and in practice, not enough attention has been paid to the seismic resistance of such equipment. An ‘accurate’ determination of floor spectra requires a complex and quite demanding dynamic response history analysis. The purpose of the study presented in this paper is the development of a direct method for the determination of floor acceleration spectra, which enables their generation directly from the design spectrum of the structure, by taking into account the structure's dynamic properties. The method is also applicable to inelastic structures, which can greatly improve the economic aspects of equipment design. A parametric study of floor acceleration spectra for elastic and inelastic single‐degree‐of‐freedom (SDOF) and multiple‐degree‐of‐freedom structures was conducted by using (non)linear response history analysis. The equipment was modelled as an elastic single‐degree‐of‐freedom system. The proposed method was validated by comparing the results obtained with the more accurate results obtained in a parametric study. Due to its simplicity, the method is an appropriate tool for practice. In the case of inelastic structural behaviour, the method should be used in combination with the N2 method, or another appropriate method for simplified nonlinear structural analysis. Copyright © 2016 John Wiley & Sons, Ltd.     

A new laboratory technique for determining the compressional wave properties of marine sediments at sonic frequencies and in situ pressures

We describe a new laboratory technique for measuring the compressional wave velocity and attenuation of jacketed samples of unconsolidated marine sediments within the acoustic (sonic) frequency range 1–10 kHz and at elevated differential (confining – pore) pressures up to 2.413 MPa (350 psi). The method is particularly well suited to attenuation studies because the large sample length (up to 0.6 m long, diameter 0.069 m) is equivalent to about one wavelength, thus giving representative bulk values for heterogeneous samples. Placing a sediment sample in a water‐filled, thick‐walled, stainless steel Pulse Tube causes the spectrum of a broadband acoustic pulse to be modified into a decaying series of maxima and minima, from which the Stoneley and compressional wave, velocity and attenuation of the sample can be determined. Experiments show that PVC and copper jackets have a negligible effect on the measured values of sediment velocity and attenuation, which are accurate to better than ± 1.5% for velocity and up to ± 5% for attenuation. Pulse Tube velocity and attenuation values for sand and silty‐clay samples agree well with published data for similar sediments, adjusted for pressure, temperature, salinity and frequency using standard equations. Attenuation in sand decreases with pressure to small values below Q^?1 = 0.01 (Q greater than 100) for differential pressures over 1.5 MPa, equivalent to sub‐seafloor depths of about 150 m. By contrast, attenuation in silty clay shows little pressure dependence and intermediate Q^?1 values between 0.0206–0.0235 (Q = 49–43). The attenuation results fill a notable gap in the grain size range of published data sets. Overall, we show that the Pulse Tube method gives reliable acoustic velocity and attenuation results for typical marine sediments.     

A comparison of gauge and radar precipitation data for simulating an extreme hydrological event in the Severn Uplands,UK

This paper provides a comparison of gauge and radar precipitation data sources during an extreme hydrological event. November–December 2006 was selected as a time period of intense rainfall and large river flows for the Severn Uplands, an upland catchment in the United Kingdom. A comparison between gauge and radar precipitation time‐series records for the event indicated discrepancies between data sources, particularly in areas of higher elevation. The HEC‐HMS rainfall‐runoff model was selected to assess the accuracy of the precipitation to simulate river flows for the extreme event. Gauge, radar and gauge‐corrected radar rainfall were used as model inputs. Universal cokriging was used to geostatistically interpolate gauge data with radar and elevation data as covariates. This interpolated layer was used to calculate the mean‐field bias and correct the radar composites. Results indicated that gauge‐ and gauge‐corrected radar‐driven models replicated flows adequately for the extreme event. Gauge‐corrected flow predictions produced an increase in flow prediction accuracy when compared with the raw radar, yet predictions were comparative in accuracy to those using the interpolated gauge network. Subsequent investigations suggested this was due to an adequate spatial and temporal resolution of the precipitation gauge network within the Severn Uplands. Results suggested that the six rain gauges could adequately represent precipitation variability of the Severn Uplands to predict flows at an approximately equal accuracy to that obtained by radar. Temporally, radar produced an increase in flow prediction accuracy in mountainous reaches once the gauge time step was in excessive of an hourly interval. Copyright © 2010 John Wiley & Sons, Ltd.     

A micromorphological record of contemporary and relict pedogenic processes in soils of the Indo‐Gangetic Plains: implications for mineral weathering,provenance and climatic changes

Micromorphology has important application in earth surface process and landform studies particularly in alluvial settings such as the Indo‐Gangetic Plains (IGP) with different geomorphic surfaces to identify climatic changes and neotectonic events and their influence on pedogenesis. The soils of the IGP extending from arid upland in the west to per humid deltaic plains in the east developed on five geomorphic surfaces namely QIG1 to QIG5 originating during the last 13.5 ka. Four soil‐geomorphic systems across the entire IGP are identified as: (i) the western Yamuna Plains/Uplands, (ii) the Yamuna‐Ganga Interfluve, (iii) the Ganga‐Ghaghara Interfluve, and (iv) the Deltaic Plains. Thin section analysis of the soils across the four soil‐geomorphic systems provides a record of provenance, mineral weathering, pedogenic processes and polygenesis in IGP. The soils over major parts of the IGP dominantly contain muscovite and quartz and small fraction of highly altered feldspar derived from the Himalayas. However, soils in the western and eastern parts of the IGP contain large volumes of fresh to weakly altered plagioclase and smectitic clay derived from the Indian craton. The soils in western Yamuna Plains/Uplands dominated by QIG2–QIG3 geomorphic surfaces and pedogenic carbonate developed in semi‐arid climate prior to 5 ka. However, soils of the central part of the IGP in the Yamuna‐Ganga Interfluve and Ganga‐Ghaghara Interfluve regions with dominance of QIG4–QIG5 surfaces are polygenetic due to climate change over the last 13.5 ka. The clay pedofeatures formed during earlier wet phase (13.5–11 ka) show degradation, loss of preferred orientation, speckled appearance in contrast with the later phase of wet climate (6.5–4 ka). The soils over the deltaic plains with dominance of vertic features along with clay pedofeatures suggest that illuviation of fine clay is an important pedogenic process even in soils with shrink‐swell characteristics. Copyright © 2015 John Wiley & Sons, Ltd.     

A Sensitive and Versatile Multiplex PCR System for the Rapid Detection of Enterotoxigenic (ETEC), Enterohaemorrhagic (EHEC) and Enteropathogenic (EPEC) Strains of Escherichia coli

Although Escherichia coli is widely distributed in the marine environment, only a small percentage are pathogenic to humans. Nonetheless, the widespread occurrence of waterborne infections of E. coli origin in humans has become one of the major health problems worldwide. To date, several types of enterovirulent E. coli have been recognized as the aetiologic agents of various gastrointestinal infections in humans. The most commonly encountered are those belonging to the enterotoxigenic (ETEC), enteroinvasive (EIEC), enterohaemorrhagic (EHEC) and enteropathogenic (EPEC) subtypes. In order to better determine the health risks that are associated with exposure to some of these specific subtypes, we have developed a very sensitive multiplex PCR system for the rapid detection and typing of ETEC, EHEC and possibly EPEC strains of E. coli in the aquatic environment. The target genes chosen for this investigation included: the PHO-A housekeeping gene (present in all E. coli); the LT1, LT2 and ST1 genes of ETEC; the VT1 and VT2 verotoxin, and EAE virulence genes of EHEC and EPEC, respectively. Six pairs of oligonucleotide primers were designed to simultaneously amplify internal fragments of these genes by multiplex PCR to generate PCR products that could be analysed and confirmed with relative ease by gel electrophoresis and HincII enzyme digestion. The results showed that the six sets of PCR primers were highly specific for their target genes and produced specific amplimers of the expected size from several control strains of E. coli – ATCC 35401 (LT1+/ST1+); SA53 (LT2+/VT2+); and O157 (VT1+/VT2+/EAE+). The detection sensitivity of the multiplex PCR system for the six target genes in an E. coli cell mixture was optimized and enhanced by preincubating serially diluted cells in Luria-Bertani broth for 6 h prior to PCR analysis. The results obtained indicated a detection sensitivity of 10° CFU (of each strain) per 100 μl reaction. Multiplex PCR analysis of seawater samples collected from four sewage-polluted sites in Hong Kong indicated the presence in all four samples of E. coli bacteria that were positive for LT1, ST1, VT1 and EAE virulence genes. Overall, the data indicated that the multiplex PCR system described in this study is a potentially very useful and powerful method for routine monitoring and risk assessment of water quality.     

The Calculation Method for the Volume of Landslides and Dammed Lake Sediments Triggered by a Strong Historical Earthquake in the Loess Plateau: A Case Study of Qiuzigou, Gansu Province, Northwest China

The quantitative calculation of the volume of large earthquake-triggered landslides and related dammed lake sediments is of great significance in the study of secondary disasters and focal parameters of strong historical earthquakes. In this study, the dammed lake induced by Qishan M7 earthquake (Lingtai County, Gansu Province, Northwest China) is selected as the research object. Based on the information collected from the 4 boreholes in the dammed lake area, we further take advantage of the low-level Unmanned Aerial Vehicle (UAV) photogrammetry and the morphology recovery method,to calculate the volume of the dammed lake and landslides, respectively. Finally, major conclusions are obtained as follows:① the AMS-¹⁴C age at the bottom of the Qiuzigou Dammed Lake sediments is 2 890±30 BP, which coincides with the 780 BC Qishan earthquake; furthermore, the Qiuzigou Landslides seem to have been triggered by the earthquake, forming an enclosed dammed lake deposition environment after the upstream sediments accumulate;② the Qiuzigou landslides are opposite-sliding landslides that have blocked the river valley; in detail, landslide volumes at the right and left banks are 235×10⁴ m³ and 229×10⁴ m³, respectively. The length of the dammed lake is 2.6 km, with a thickness of approximately 43 m near the landslides, and the total sedimentary volume is 573×10⁴ m³; ③the erosion rate of Qiuzigou Landslide Dammed Lake is 0.44 mm/a, the accumulation rate is 15.05 mm/a, and the soil erosion modulus is 593 t/(km²/a), characterized as slight erosion. Quantitative research on the formation of landslides and dammed lakes from strong historical earthquakes is vital for increasing our understanding of the vibrational characteristics and surface action processes of these types of earthquakes.     

Genetic algorithm for fitting a mixed Bingham distribution to 3D orientations: a tool for the statistical and paleostress analyses of fracture orientations

The clustering of fracture orientations is important for tectonic studies and for geotechnical engineering. In this study, a real‐coded genetic algorithm was adopted to fitting a mixed Bingham distribution to orientation data by maximizing the log‐likelihood function of the distribution. The maximization is a difficult problem, because the function has multimodality and singularity. It was found that the algorithm was effective for this problem. Given the orientations of dilational fractures, the present method determines not only the stress axes and stress ratio of each of the fracture groups but also the maximum non‐dimensionalized fluid pressure at the time of their formation. In addition, the software calculates the 95 % error ellipses of the concentration axes. The present method found that the orientations of ore veins of the Akenobe Mine, SW Japan, should be partitioned into three clusters. It is shown that two of the groups had distinctive Zn and Sn contents, and that the ore fluids had overpressures only slightly greater than the minimum principal stress at the time of the deposition of Zn‐ and Sn‐rich veins.