首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到12条相似文献,搜索用时 20 毫秒
1.
    
Aromatic sulfonates can be found in drinking water. Thus, they must have passed water treatment and survived ozonation. Degradation of aromatic sulfonates can be achieved by the UV/H2O2‐process. Since drinking water is often treated with chlorine as a disinfectant, the formation of disinfection by‐products has to be considered. Therefore, the production of AOX (on activated carbon adsorbable organic halogens) after chlorination of the sulfonates with and without preoxidation was investigated. Instead of the analysis of the individual degradation products, the determination of the sum parameter AOX was used as a fast screening method. The investigated sulfonates were: anthraquinone‐2‐sulfonate, naphthalene‐2‐sulfonate, 2‐aminonaphthalene‐1‐sulfonate, and 4,4′‐diaminostilbene‐2,2′‐disulfonate. All sulfonates containing amino groups showed high potentials of AOX formation. The preoxidation with ozone increased the potentials of AOX formation in general. Treating the sulfonates by using the UV/H2O2‐process, the formation potentials run to zero after going through a maximum value.  相似文献   

2.
    
The purpose of the study is to gain a better understanding about the formation of THM (trihalomethanes), HAA (haloacetic acids), and AOX (adsorbable organic halogen) in river water (river Ruhr, Essen) through a chlorination kinetics approach. The effect of chlorination time and preozonation on the formation of THM, HAA, and AOX substances was studied. Preozonation can reduce the chlorine demand and the precursors for AOX and THM. THM generation was reduced further, when the ozone dosage consumed increased from 3.5 to 12.5 mg in the 1.4 L reaction vessel. AOX and TCAA (trichloroacetic acid) concentrations also decreased dramatically when 3.5 mg of ozone had reacted with the river water, but a higher dose of ozone did not further reduce AOX and TCAA formations. Besides, the characteristics of organic matter in raw water, ozonated water, and preozonated/chlorinated water was investigated. The results suggest the formation of low‐molecular‐weight acids with low UV absorbance when high‐molecular refractive matter is oxidized.  相似文献   

3.
    
In military out of area missions of the Bundeswehr, it can be necessary to produce drinking water even from highly polluted surface waters containing a variety of organic, inorganic, and microbiological contaminants. Thus, mobile drinking water purification systems must be able to remove such contaminants as far as possible to meet the requirements of the German and European drinking water regulation/directive. Presently, two novel drinking water purification units applying membrane filtration undergo intensive long‐term trials carried out by the Bundeswehr. If these trials positively proof the functionality of these units and their ability to remove all possible contaminants they shall substitute so far available devices which use large amounts of chemicals and charcoal filtration for water purification.In the course of a research project, the functionality of the new devices and their efficacy to remove high amounts of algae, microbes, and organic and inorganic pollutants are additionally tested in “worst‐case” field studies. In September 2000, the first mobile drinking water purification unit was tested at the Teltowkanal in Berlin, Germany.This canal was chosen because it carries high burdens of municipal sewage effluents. The results from the fatigue test confirmed the ability of the water purification unit to reduce the concentrations of all contaminants meeting the maximum tolerance levels set by the German/European drinking water regulation.The pre‐filtration device was very effective in removing algae and solid particles to protect the membranes from clogging and to enable an almost maintenance‐free operation. Residues of pharmaceuticals and some other organic contaminants have almost totally been removed from the surface water where they were detected at individual concentrations up to the μg/L‐level.  相似文献   

4.
    
In Germany, the gasoline additive methyl tert‐butyl ether (MTBE) is almost constantly detected in measurable concentrations in surface waters and is not significantly removed during riverbank filtration. The removal of MTBE from water has been the focus of many studies that mostly were performed at high concentration levels and centred in understanding the mechanisms of elimination. In order to assess the performance of conventional and advanced water treatment technologies for MTBE removal in the low concentration range further studies were undertaken. Laboratory experiments included aeration, granulated activated carbon (GAC) adsorption, ozonation and advanced oxidation processes (AOP). The results show that the removal of MTBE by conventional technologies is not easily achieved. MTBE is only removed by aeration at high expense. Ozonation at neutral pH values did not prove to be effective in eliminating MTBE at all. The use of ozone/H2O2 (AOP) may lead to a partly elimination of MTBE. However, the ozone/H2O2 concentrations required for a complete removal of MTBE from natural waters is much higher than the ozone levels applied nowadays in waterworks. MTBE is only poorly adsorbed on activated carbon, thus GAC filtration is not efficient in eliminating MTBE. A comparison with real‐life data from German waterworks reveals that if MTBE is detected in the raw water it is most often found in the corresponding drinking water as well due to the poor removal efficiency of conventional treatment steps.  相似文献   

5.
    
The roles of oxygen and its activated species (superoxide radicals, hydrogen peroxide, hydroxyl radicals), as well as that of sulfur compounds, are considered in relation to biological quality and the self-cleaning capacity of freshwater aquatic systems. The effects on the aquatic redox-processes are discussed in terms of atmospheric fallout of sulfur compounds, bottom sediment composition, and input of wastewaters containing reducing substances. It is shown that the totality of anthropogenic influences, and/or unfavourable natural geochemical conditions, as well as climatic effects in a region can increase the significance of one-electron transfer processes in bio-geochemical cycles of oxygen, sulfur and manganese, compared with the significance of two-electron transfer processes. The resulting, reactive intermediate products of one-electron transfer processes are very important with respect to the composition and properties of aquatic systems. Examples are given of practical applications of wastewater treatment, using hydrogen peroxide and UV-irradiation, and of regulation of consumers’ activities which affect natural waters.  相似文献   

6.
    
The paper presented here describes experiments with a nanofiltration pilot plant treating spring water which contains high amounts of humic substances. With this process, water components such as humic substances, iron, manganese, and aluminum may be very well removed. However, the low pH value of the NF filtrate does not conform with the German standards. This is why the pH value will be increased in a second treatment step by limestone filtration. Prior to limestone filtration, CO2 dosage is required in order to make sure that the pH value stays below the upper limit of the German standards of 9.5. With this treatment, a drinking water results which meets the German standards and has good chemical properties with respect to corrosion. The operation of the nanofiltration pilot plant for the treatment of the very soft spring water did not require the continuous addition of chemicals in order to prevent scaling. Although the spring water entered the NF without chemical pretreatment, there was no decrease in filtrate capacity observed over a period of six months. This is in contrast to other investigations involving colour reduction from very hard surface waters. When treating very hard waters by nanofiltration, the addition of complexing agents or acid is required in order to prevent scaling of the membranes. Such intricate pretreatment procedures cause doubt of the application of nanofiltration for the treatment of hard waters in large plants. However, in the case presented here, the application of NF in combination with the hardening step is quite simple, so that the full-scale plant may be operated mainly automatically and will require only little maintenance.  相似文献   

7.
    
Formation of Brominated Disinfection By-products after Chlorination of Water from Lake Constance Depending on Treatment Steps and Bromide Concentration The formation of halogenated disinfection by-products (DNP) (trihalomethanes (THM), haloacetic acids (HES), haloacetonitriles (HAN), haloketones (HKE) and chloropicrin (TCNM)) was studied after chlorination (0.5 mg/L) of raw water and drinking water from Lake Constance. The objectives of this study were to investigate the effect of bromide ion on the distribution of DNP-species resulting from chlorination and to draw up a bromide mass-balance. The treatment of water from Lake Constance with ozone decreased the formation of DNP about 35% and of total organic halogens (AOX) about 45%. This decline in DNP-formation is mainly due to the formation of chloroform, dichloro- and trichloroacetic acid. Though there is only a small amount of bromide (6.2 μg/L) in water from Lake Constance, about 32% of THM, 16% of HES, and 30% of HAN contained bromine after chlorination of treated water. The addition of bromide ion (up to 1 mg/L) shifted the DNP-composition to more brominated species. The distribution of the DNP-species depends on the initial molar bromide-to-chlorine ratio. A mathematic model showed the same pattern of DNP-species depending on the initial molar bromide-to-chlorine ratio that was observed experimentally in microstrained raw water and drinking water from Lake Constance. After chlorination of microstrained raw water, 27% of the bromide were incorporated in known DNP, 34% in unknown substances, and about 39% of bromide were not converted to organic bromine. After chlorination of treated water, only 16% of the bromide were incorporated in unknown substances, whereas 34% were found in known DNP. About 50% were found as bromide again. After addition of bromide (up to 25 μg/L) to ozonated and treated water from Lake Constance, between 60 and 72% of the bromide that had reacted after chlorination were found in analyzed low-molecular DNP.  相似文献   

8.
    
It was previously observed that sodium dodecylbenzenesulfonate (SDBS) is degraded in the presence of chrysotile fibres. A higher catalytic efficiency was obtained than the reported values for TiO2 under the same conditions. Chrysotile, a clay mineral fibre of low cost and relatively abundant, probably acts as a catalyst through an Advanced Oxidative Process (AOP) involving free radical formation. In this work, experiments with non‐ionic – Triton X‐45 (octil‐phenoxy polyethoxy ethanol) – and cationic – Herquat 3500 (alkyl dimethyl benzyl ammonium chloride) – surfactants were carried out. Diluted aqueous solutions (50 ppm) of these surfactants were kept in contact with chrysotile (4.0 g) in the dark at room temperature. The aromatic ring disappearance was followed through the absorbance peaks at 224 nm (Triton X‐45) and 208 nm (Herquat 3500) in the UV spectra. After 4 h, reductions in the surfactant solution concentration of 65.0% and 35.0% were observed for the Triton X‐45 and the Herquat 3500 surfactants, respectively. In both cases, reactions carried out without aeration showed a lower reduction of the aromatic ring concentration (30.0% less) when compared to the values obtained for the systems with airflow. The system containing the non‐ionic surfactant seems to achieve equilibrium after 2 h, what is not observed for the cationic surfactant system.  相似文献   

9.
    
It is shown that in the direct photolysis of polychlorinated phenols (2,4,5-TCP, PCP) in aqueous solution, under the action of solar light or UV-radiation from artificial sources, polychlorinated dibenzodioxins (PCDD) and dibenzofurans (PCDF) are found among the products of transformation. A mechanism is suggested of formation of these toxic compounds via the intermediate formation of free radicals. In the oxidation of chlorophenols by singlet oxygen, free radicals are not formed. Addition of fulvic acids prevents formation of PCDD and PCDF in solar light, possibly as a result of trapping of intermediate radicals.  相似文献   

10.
The seasonal variations in the advection and mixing of water masses in the northern Benguela were studied in relation to the oxygen minimum zone over the Namibian shelf. The used data set consists of hydrographic and current measurements from an oceanographic mooring 20 nm off Walvis Bay, monthly CTD transects from the Namibian 23°S monitoring line and recent large-scale hydrographic surveys. The current time series showed an intermittent southward continuation of the Angola Current (AC) through the Angola–Benguela frontal zone (ABFZ) into the northern Benguela, commonly known as poleward undercurrent. In austral summer hypoxic, nutrient rich South Atlantic central water (SACW) from the Angola Gyre is transported into the northern Benguela, whereas during the winter season the oxygen rich Eastern SACW (ESACW) spreads northward. The water mass analysis reveals a mixing between both water masses in the northern Benguela between the ABFZ and the Lüderitz upwelling cell (27°S). The oxygen balance over the Namibian shelf depends to a high extent on the water mass composition of the upper central water layer, controlled by the large scale and local circulation. The deviation of the measured oxygen concentration from its mixing concentration, calculated with the source water mass properties, was used to quantify the oxygen consumption. A new local definition SACW was derived to exclude biogeochemical processes, taking place in the Angola Gyre. The oxygen deficit in the northern Benguela central water amounted to about 60–80 μmol l−1 at the shelf edge and increased up to 150 μmol l−1 on the shelf, due to local oxygen consumption. In the austral summer anoxic bottom waters are observed at the central Namibian shelf, which correlate to an SACW fraction >55%. Periods with high SACW fraction in the water mass composition were congruent with hydrogen sulphide events detected by remote sensing.  相似文献   

11.
    
A brief review of the literature on filtrate quality obtained in constant and variable declining rate operation systems is presented, with the general conclusion that both systems usually produce filtrate of similar quality, assuming the flow‐rate controllers in the constant flow rate system operate properly. A mathematical model of CR (constant rate) filters and VDR (variable declining rate) filters based on the model by Mackie and Zhao (1999) has been described and used to investigate filtrate quality under different operating conditions. A similar quality of filtrate was achieved in computations carried out for both modes of operation, while the total head loss was much lower in the VDR mode. For the same time of filter runs slightly better filtration quality resulted from CR operation, but for different filter runs resulting from the same head loss of flow just before a backwash, the VDR control system produced lower turbidity filtrate.  相似文献   

12.
    
Effective biodegradation of organic compounds is one of the major objectives while optimizing biological drinking water treatment processes. Enhancing the biological activated carbon (BAC) filter performance with nutrient addition was studied using chemically pre-treated and ozonated lake water. Three parallel pilot-scale biofilters were operated: one with phosphorus addition, one with a mixture of inorganic nutrients addition, and one as a reference. The addition of nutrients had no statistically significant influence on the natural organic matter (NOM) removal when monitored by total organic carbon (TOC), UV absorbance, and assimilable organic carbon (AOC). However, the addition of nutrients significantly increased the heterotrophic plate count (HPC) bacteria of the filter effluent, while the adenosine triphosphate (ATP) analysis of the attached bacteria did not show any increase in BAC filters. It seemed that in BAC filters the bacterial growth was limited by phosphorus, but the increased bacteria could not attach themselves during the relatively short acclimatization period.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号