基于孔隙结构的酸性火山岩储层流体识别方法研究

酸性火山岩由于成岩矿物类型多样,孔隙结构复杂,电阻率普遍较高,应用常规的中子-密度测井曲线交会和电阻率的高低已经不能判断储层流体性质.在天然气的测井响应特征分析基础上,应用三孔隙度组合、横纵波时差比值、核磁共振及综合参数识别流体性质.应用结果表明这些方法只能识别含气储层,对于气水同层的识别效果并不好.电阻率对储层流体性质变化反映灵敏,但是对于酸性火山岩储层并不如此.从储层微观孔隙结构入手,对火山岩储层电阻率影响因素进行研究,表明孔隙结构复杂是酸性火山岩电阻率普遍较高的原因之一,在此基础上,研制了基于孔隙结构的流体性质逐步判别法.应用本文的方法,对徐深气田49口井流体性质进行判断,经69个层试气验证,识别准确率达94.1％,提高了近15个百分点.     

岩石的临界孔隙度反演及横波预测(英文)

临界孔隙度模型是利用岩石的临界孔隙度来计算岩石骨架的弹性模量,岩石的临界孔隙度值受到很多因素的影响,而实际应用中通常无法获得准确的临界孔隙度值,只能选取经验临界孔隙度值,就会给岩石物理建模带来误差。本文提出了一种利用纵波速度反演岩石的临界孔隙度的方法,并且把它应用于横波预测中。实验室和测井数据应用结果表明本文提出的方法可以降低以往选取经验值带来的不确定性,并且能够为横波预测提供准确的临界孔隙度值,提高了横波预测的精度。     

基于碳酸盐岩孔隙结构预测孔隙度方法研究

许多研究都已经证实在碳酸盐岩储层中孔隙结构对声波速度影响很大,因此在孔隙度反演时必须考虑孔隙结构的影响.本文通过对Gassmann方程的合理简化并引入Eshelby-Walsh干燥岩石椭球包体近似公式,推导出包含岩石孔隙结构参数、饱和岩石压缩系数与岩石基质压缩系数三个参数的计算孔隙度的新公式,该式岩石基质压缩系数是通过Russell流体因子和Gassmann-Boit-Geer tsma方程计算式建立目标函数反演获得的,然后通过测井交汇图技术把岩石孔隙结构参数与岩石基质压缩系数优选转换成纵横波速度与密度关系式,进而导出具体地区考虑碳酸盐岩孔隙结构孔隙度具体计算公式,测井与地震资料应用表明,基于碳酸盐岩孔隙结构的孔隙度预测方法的精度高于常规方法.     

基于岩石导电效率理论建立碳酸盐岩储层饱和度的计算方法(英文)

由于孔隙型碳酸盐岩储层的复杂孔隙结构和强非均质性,岩石导电效率与含水孔隙度之间理想的线性关系相对复杂或并不存在,故前人基于岩石导电效率理论建立含水饱和度的计算公式并不完全适用于碳酸盐岩储层。基于岩石导电效率理论,推导了岩石导电效率的计算公式,阐明了岩石导电效率与含水孔隙度之间线性关系相对复杂或并不存在的根本原因,发现了岩石导电效率与电阻率之间的幂函数关系,分析了所建立含水饱和度计算公式误差的主控因素,得出了岩石导电效率的计算精度是该方法是否能推广应用的关键。与Archie公式相比,基于岩石导电效率理论建立的含水饱和度计算公式能更准确地计算研究靶区孔隙型碳酸盐岩储层的含水饱和度。在伊拉克某油田和印尼某气田3口井碳酸盐岩储层中的应用,表明当计算岩石导电效率的相对误差不大于0.1时,所计算储层含水饱和度的绝对误差不大于0.1,基本满足孔隙型碳酸盐岩储层精细评价的需求。     

碳酸盐岩储层常规测井评价方法

碳酸盐岩储层非均质性强、储集空间类型复杂多样,储层中流体性质的识别及有效厚度的划分比较困难,为了完成碳酸盐岩储层的常规测井评价,根据碳酸盐岩储层地质特征,将储层分为三种类型:1)裂缝+孔隙型储层,其孔隙度大于3.5%,其裂缝为规模较大的构造缝,其次是一些宏观裂缝,是碳酸盐岩储层中最好的储层;2)微裂缝+孔隙型储层,其孔隙度大于3.5%,其裂缝主要为储层微观孔、缝以及孔洞.3)裂缝层,其孔隙度小于3.5%,裂缝较发育,基质孔隙度和储层含油饱和度很小,接近于零,为裂缝层.基于以上三种类型的储层来建立测井地质评价模型,由于碳酸盐岩储层是典型的双重介质模型,分别建立两类孔隙空间的几何模型及流体模型,分别建立三种储层的空间几何模型和流体分布模型,每种模型又分为裂缝系统和岩块孔隙系统,在此基础上总结各种测井曲线的响应特征,分别给出储层参数计算的数理模型,基质岩块和裂缝孔隙度、渗透率和储层油气水饱和度,对裂缝的张开度也进行了定量计算,给出了储层流体性质及有效厚度的划分标准,最终完成碳酸盐岩的常规测井评价.     

裂缝性储层孔隙指数、饱和度及裂缝孔隙度计算研究

裂缝性储层的裂缝孔隙度、饱和度和孔隙指数等参数的计算一直是测井界亟待解决的难题,它直接关系到对裂缝性储层的发育程度、含油气性、储量规模等方面的评价,前人已在这些方面做了大量的研究工作,但仍需进一步提高和深化对裂缝性储层参数计算的认识.基于考虑裂缝倾角和裂缝曲折度问题的Aguilera孔隙指数计算模型,研究了裂缝性储层孔隙指数的变化规律,研究表明裂缝性地层的孔隙指数受裂缝倾角、岩石总孔隙度、裂缝孔隙度和裂缝曲折度影响大.单组系裂缝性储层饱和度的计算采用将复合系统的孔隙指数代入阿尔奇公式的方法来计算,计算结果与目前国内仍广泛使用的基于串、并联关系建立的双重孔隙饱和度模型计算结果存在较大差别.对比分析了利用成像测井和三种基于双侧向资料的裂缝孔隙度计算模型计算的裂缝孔隙度,表明不同裂缝孔隙度模型计算的裂缝孔隙度大小差别较大.基于双侧向的裂缝孔隙度计算模型只适用于特低孔或致密地层,在由非裂缝因素引起的电阻率降低段使用该模型计算裂缝孔隙度时会出现错误,引入校正系数可拓宽模型的使用范围.     

非均质碳酸盐岩储层岩石物理建模:孔隙度估算与烃类检测(英文)

在非均质天然气藏中,天然气一般呈细小"斑块状"分布于含水岩石骨架内。这种非均质性,即"斑块状饱和",会引起显著的地震波速度频散和能量衰减现象。为了建立地震响应和流体类型之间的联系,本文进行了碳酸盐岩岩石物理建模。首先利用CT扫描分析部分饱和岩石中的流体分布,然后预测不同频率下波响应与岩性、孔隙流体基本性质之间的定量关系,基于岩石薄片分析孔隙结构和地震反演数据制作岩石物理图板,并将这种方法应用于阿姆河右岸地区的灰岩气藏,基于叠后阻抗反演和叠前弹性参数反演,采用地震数据估算岩石孔隙度与含气饱和度,预测结果与多井试气结果吻合。     

根据波速—压力关系评价岩石岩性、物性的实验研究

本文在实验室里对老爷庙油田馆陶组（Ng）油气贮层砂岩岩芯的孔隙度φ、空气渗透率κ、骨架密度ρma、岩石密度ρb和不同有效覆盖压力△P下岩芯的声波时差△t,做了精确测量,用回归分析拟合了φ-K、φ-ρb、φ-△t和V-△p（△t-△p）的经验关系式;保持原始孔隙结构不变的前提下,在岩芯饱和各种矿化度的孔隙流体时测定了声波时差△t与孔隙度φ的关系.研究结果表明,当贮层的φ-K、φ-ρb和φ-△t相关时,可用声波时差△t或波速V解释贮层的岩性,并可反演求出贮层的φ、K和ρb;地层有效覆盖压力对贮层的孔隙度和波速具有明显的影响.根据V-△p曲线的变化规律,可以评价贮层的岩性和埋藏地质体的油、气储集能力.这些结果对油田地震勘探和石油测井资料的解释具有重要的参考价值,并为预测储油有利地区和评价贮层提供了一种新的途径.     

地震尺度下碳酸盐岩储层的岩石物理建模方法(英文)

碳酸盐岩油藏的强非均质性以及孔隙结构的复杂性,使得作为连接油藏参数与地震参数重要桥梁的岩石物理模型,以及作为油藏预测和定量表征最有效工具的流体替换成为岩石物理建模的难点与重点。在碳酸盐岩储层复杂孔隙结构与地震尺度下碳酸盐岩储层非均质性分析基础上,研究采用岩石网格化方法,将地震尺度下非均质碳酸盐岩储层岩石划分为具有独立岩石参数的均质岩石子体,根据岩石孔隙成因与结构特征采用不同岩石物理模型分步计算岩石子块干岩石弹性模量,并根据不同孔隙连通性进行流体替换,计算饱和不同流体岩石弹性模量。基于计算的岩石子块弹性模量,采用Hashin-Shtrikman-Walpole弹性边界计算理论方法实现地震尺度下碳酸盐岩储层弹性参数计算。通过对含有不同类型孔隙组合碳酸盐岩储层模型的弹性模量进行计算与分析,明确不同孔隙对岩石弹性参数的影响特征,模拟分析结果与实际资料认识一致。     

裂缝和孔洞型储层孔隙模型的理论进展

对有洞的和裂缝型储层的分析已经成为一个热点,因而孔隙模型的研究近年得到了很好的发展.目前已经用双孔隙和三孔隙模型研究这类储层的特性并寻找估计孔隙指数的方法,以便计算含水饱和度.用串联或并联电阻网络模拟储层表明：双孔隙模型适用于基质与非连通孔洞储层以及裂缝和（或）连通孔洞的储层.三孔隙模型更适用于由基质、裂缝和不连通孔洞组成储层的岩石物理评价,对于当前碳酸盐岩和火成岩以及变质岩储层评价具有明显的指导意义.     

长岭地区火山岩储层流体性质测井预测

火山岩储层非均质性强,其岩石的矿物成分复杂,裂缝、溶蚀孔的类型、组合分布有极强的各向异性,这给火山岩储层流体性质预测造成很大困难.本文通过运用偶极横波资料和三重孔隙解释模型对长岭地区火山岩储层流体性质进行了预测,并取得了较好的效果.说明可以应用这些方法对火山岩储层流体性质进行预测.     

Multi-stage volcanism in the Ulleung Back-arc Basin, East Sea (Sea of Japan)

Abstract Multichannel seismic reflection profiling in the Ulleung back-arc Basin reveals that the acoustic basement largely comprises volcanic materials. The volcanics are interlayered with sediment sequences, forming an anomalously thick layer. The volcanic activities resulted in a zonation of the acoustic basement, trending northeast-southwest. In the southeastern part, the acoustic basement is deep and obscure, whereas in the northwestern part it is shallow and forms mounds and seamounts. The volcanic activities were probably initiated in the Early Miocene ( ca 20Ma). The volcanism was time-transgressive northward, associated with the possible southward drift of the Japanese islands.     

基于岩心室应力应变和不确定度分析的致密储层氦孔隙度测量方法

致密油气层的物性(孔隙度和渗透率)较差.针对致密储层,目前常用的氦气法孔隙度测量方法存在两个不足:器壁压变性参数G定义不明确;膨胀前压力设置普遍偏小.本次基于氦气法孔隙度测量装置岩心室的应力应变力学分析和不确定度理论分析,开发了一种面向致密储层的氦孔隙度测量方法.本次提出的方法给出了器壁压变性参数G的解析式,并基于G的解析式推导出了新的孔隙度计算公式,将刻度系数减少到1个,简化了刻度过程.其次,基于不确定度理论得到的孔隙度测量不确定度表明:氦气法测量致密储层孔隙度的膨胀前压力大于2 MPa基本可以将孔隙度绝对误差控制在0.5%以内.与高压压汞法孔隙度测量结果对比发现,该方法测量孔隙度的相对偏差在14%以内,远低于常规氦气法测量孔隙度的相对偏差(50%).     

中低渗油藏剩余油饱和度监测技术系列优化与应用

套管井剩余油饱和度监测技术是研究剩余油分布最重要的测井方法.针对研究区块中-低孔隙度、中-低渗透率、高矿化度地层水的油藏特点与饱和度监测的现状,对比研究了现有监测技术与仪器装备的性能指标,同时考虑脉冲中子、非弹性散射与地层中元素的相互作用的特性,提出了适用于这种不同油藏地质特点的剩余油饱和度监测系列优化方案.针对某区块编制了整体监测方案,并且对监测资料进行精细处理与解释.多口井实施和应用表明,该方案与应用效果良好.     

Spatial variation of effective porosity and its implications for discharge in an upland headwater catchment in Scotland

Spatial and temporal measurements of shallow sub-surface soil physical properties were made within a 1 km² upland catchment. The surface soil layer of the catchment was organic rich (>70% organic matter) with a corresponding total porosity of 81%. Monthly point observations of volumetric water content (θ) were combined with point estimates of total porosity () and the porosity <50 μm (_residual), to define the ratio of water filled pore volume:pore volume in pores <50 μm (=θ/_residual). Values of θ/_residual were compared with discharge to test whether mass flow occurred when θ/_residual>1. A correlation between water content and discharge was found, with discharge increasing rapidly when θ/_residual approached unity. Similar relationships between water content and catchment discharge were identified for soil units adjacent to the stream when θ/_residual approached unity. These data suggest that soil pores >50 μm are of crucial importance in determining catchment discharge. Spatial and temporal variations in soil properties related to moisture content of the soil were also observed. Under dry conditions, a clear division based on aspect was noted, the west-facing side of the catchment being wettest. In wetter months, total porosity and soil water content were significantly affected by soil type and the spatial pattern of soil water content was more variable than in the dryer months. The physical quantification of soil properties in the shallow sub-surface layer proved important in explaining different initial changes in discharge from the catchment in response to a rainfall event.     

NMR Measurements in Carbonate Rocks: Problems and an Approach to a Solution

Carbonate rocks are well known for their complex petrophysical behavior where, in contrast to siliciclastic rocks, different parameters, including porosity and permeability, usually are not directly related. This behavior is the result of thorough reorganization of porosity during diagenesis, and it turns prediction of reservoir quality of carbonate rocks into a challenge. The study presented here deals with the problem of utilizing NMR techniques in prediction of petrophysical properties in carbonates.We employ a visual porosity classification as a priori knowledge for better interpreting NMR data for prediction purposes. This allows for choice of suitable T₂ cutoff values to differentiate movable from bound fluids adapted for the specific carbonate rock, thus resulting in better interpretation of NMR data. The approach of using a genetic pore type classification for adapting the conventional method for T₂ cutoff determination, which originally was developed for siliciclastic rocks, is promising. Similarly, for permeability determination on the basis of NMR measurements, the classification of carbonate rocks based on porosity types also shows potential. The approach implemented here has the promise to provide a basis of standardized interpretation of NMR data from carbonate rocks.Acknowledgment We are grateful to Baker Hughes INTEQ, Celle, for permission to publish the results of this work. This study was part of I.S.s Masters Thesis at Hannover University that was carried out in collaboration with Baker Hughes INTEQ, Celle, Germany. We appreciate comments of an anonymous referee and PAGEOPH editor Brian J. Mitchell.     

岩芯尺度的宽频介电常数频谱实验室测量设备的误差分析及其在物质测量中的应用(英文)

宽频介电常数频谱测井技术最近被引进石油工业.这种新技术区别于传统介电常数测井技术在于多频率频谱的测定和利用.高频谱端包含介质油水饱和度信息,而低频谱端对介质中孔隙结构和水的分布形态很敏感.这种新技术可以有效地被应用于比如超淡水介质或者超黏度重油等对于常规测井来说是很困难的测量环境,而且受介质水中的含盐度影响很小.随着井下测井仪器的投入使用,相应的实验室岩芯测定设备和方法就变得重要起来.因为实验室环境相对较为稳定和可控,实验室岩芯测量结果是对井下测量的很好地验证和校订.文献中记载了许多非破坏性的实验室介电常数的测量设备,然而这些设备的共同局限性是它们对岩芯尺寸和岩芯样本的要求和限制,一般要求粉末状岩芯或者一厘米左右的小柱状岩芯.在碳酸盐介质中,非均匀性和各项异性非常普遍,小的岩芯样本能否涵盖井下设备测量尺度(1.5英寸)的特性很值得商榷.本文中介绍了一种最新设计的实验室大直径宽频介电常数测量设备.这个设备可以直接测量石油工业传统的1.5英寸岩芯样本,测量是非毁坏性的,也就是测量后的岩芯样本可以直接用于其它实验室测量设备,比如电阻率测量或核磁共振测量等.大量重复性试验测得的介电常数色散频谱的精确度对于低损耗介质在2%以内而对于高损耗介质在对孔隙度和含盐度校正以后精确度在3%.文中详细介绍了测量设备所使用的反演程序的算法模型,以及反演误差的算法.反演最后的误差可以用来做数据质量的评定.该测量装置被用于许多物质的测定.测定物质的数据库中合成石英(fused quartz),Teflon,合成陶瓷以及单晶硅的介电常数值可以在文献中找到.该设备的测量结果与文献参考值相符合,说明了该设备测量结果的可靠性.该设备还测量了矿物晶体碳酸钙,晶体白云石以及晶体硬石膏的介电常数,这是常见的碳酸盐介质的主要成分.这些测量给出了碳酸盐介质的边界成分区域值作为参考.该设备测量的两个单晶硅柱状样本的介电常数频谱特性发现退火会改变晶体的结构提高强度,同时会改变介质介电常数的特性.同时矿物晶体碳酸钙测量值高于粉末状测量结果也说明晶体结构可能会导致介电常数测量的不同.该设备具有1.5英寸的大尺度,因此具有和井下设备相仿的测量范围,因而不受介质水平各项异性的影响.但另一方面,该设备仍可以研究垂直各项异性.垂直各项异性的主要原因可能是化学成分不同,孔隙结构不对称或者温度对水分布的影响等等.在对岩石地面露头采样的研究中,宽频介电常数频谱实验室设备检测出了岩芯垂直各项异性,通过对比核磁共振一维孔隙度剖面结构发现总孔隙度不均衡以及分布不对称为该各项异性的主要来源,并且被CT图像所证实.     

Mechanism for calcite dissolution and its contribution to development of reservoir porosity and permeability in the Kela 2 gas field,Tarim Basin,China

This study is undertaken to understand how calcite precipitation and dissolution contributes to depth-related changes in porosity and permeability of gas-bearing sandstone reservoirs in the Kela 2 gas field of the Tarim Basin, Northwestern China. Sandstone samples and pore water samples are col-lected from well KL201 in the Tarim Basin. Vertical profiles of porosity, permeability, pore water chem-istry, and the relative volume abundance of calcite/dolomite are constructed from 3600 to 4000 m below the ground surface within major oil and gas reservoir rocks. Porosity and permeability values are in-versely correlated with the calcite abundance, indicating that calcite dissolution and precipitation may be controlling porosity and permeability of the reservoir rocks. Pore water chemistry exhibits a sys-tematic variation from the Na2SO4 type at the shallow depth (3600-3630 m), to the NaHCO3 type at the intermediate depth (3630―3695 m),and to the CaCl2 type at the greater depth (3728―3938 m). The geochemical factors that control the calcite solubility include pH, temperature, pressure, Ca2 concen-tration, the total inorganic carbon concentration (ΣCO2), and the type of pore water. Thermodynamic phase equilibrium and mass conservation laws are applied to calculate the calcite saturation state as a function of a few key parameters. The model calculation illustrates that the calcite solubility is strongly dependent on the chemical composition of pore water, mainly the concentration difference between the total dissolved inorganic carbon and dissolved calcium concentration (i.e., [ΣCO2] -[Ca2 ]). In the Na2SO4 water at the shallow depth, this index is close to 0, pore water is near the calcite solubility. Calcite does not dissolve or precipitate in significant quantities. In the NaHCO3 water at the intermedi-ate depth, this index is greater than 0, and pore water is supersaturated with respect to calcite. Massive calcite precipitation was observed at this depth interval and this intensive cementation is responsible for decreased porosity and permeability. In the CaCl2 water at the greater depth, pore water is un-der-saturated with respect to calcite, resulting in dissolution of calcite cements, as consistent with microscopic dissolution features of the samples from this depth interval. Calcite dissolution results in formation of high secondary porosity and permeability, and is responsible for the superior quality of the reservoir rocks at this depth interval. These results illustrate the importance of pore water chemis-try in controlling carbonate precipitation/dissolution, which in turn controls porosity and permeability of oil and gas reservoir rocks in major sedimentary basins.