Energizing historical materialism: Fossil fuels, space and the capitalist mode of production

In this paper, I present a theoretical argument that fossil fuel represents a historically specific and internally necessary aspect of the capitalist mode of production. Despite sustained attention to distributional conflicts between international capital and energy rich nation-states, few historical-materialists have paid attention to the relations between fossil fuel and capital accumulation in industrial capitalist societies. In opposition to ecological economic notions of fixed thermodynamic “laws”, I first propose a dialectical conception of energy as embedded in dynamic social processes and power relations. Second, I review the historical importance of the energy shift from solar or biological sources of energy (muscles, wind, and water) to fossilized sources of energy (coal, oil, and gas). I then demonstrate how attention to fossil fuel energy forces a reexamination of the core insights of ecological Marxism and the political economy of nature. In the core argument of the paper, I reconsider the shift from biological to fossil energy as internal to the generalization and extension of capitalist social relations from two basic vantage points - (1) capitalist production based on wage labor; (2) the spatial conditions of capitalist circulation. I conclude by asking whether it is accurate to conceptualize capitalism as a “fossil fuel mode of production” and highlight the political urgency of a historical materialist perspective that takes seriously the importance of energy to the reproduction of capitalist social relations.     

Fossil fuel compounds from fly dust in recent organic matter of southern Poland peats

Several samples of peat from 6 bogs located in southern Poland were investigated for occurrence and distribution types of biomarkers present in their extractable organic matter fraction. It was found that there are inputs from two different sources of organic compounds differing in their characteristics and origin: (1) recent immature peat organic matter deposited in situ which is the source of all polar functionalized compounds, most of n-alkanes, and acyclic isoprenoids, and (2) mature fossil fuels, most probably bituminous coals from the Upper Silesia Coal Basin of vitrinite reflectance equivalent values of 0.9–1.1%. The latter compounds were most probably transported with fly ash to bogs from nearby settlements utilizing such fuel in domestic ovens. This group includes pentacyclic triterpenoids (hopanes and moretanes), minor amounts of n-alkanes, and numerous alkyl naphthalenes and alkyl phenanthrenes. All these compounds show distributions and values of geochemical ratios characteristic for mature organic matter confirming there ex situ origin.     

Role of environmental geology in US Department of Energy's advanced research and development programs to promote energy security in the United States

The purpose of this report is to describe the research programs and program activities of the US Department of Energy (DOE) that most directly relate to topics in the field of environmental geology. In this light, the mission of the DOE and the definition of environmental geology will be discussed. In a broad sense, environmental geology is that branch of earth science that emphasizes the entire spectrum of human interactions with the physical environment that include environmental health, mineral exploration and exploitation, waste management, energy use and conservation, global change, environmental law, natural and man-made hazard assessment, and land-use planning. A large number of research, development, and demonstration programs are under DOE's administration and guidance that directly or indirectly relate to topics in environmental geology. The primary mission of the DOE is to contribute to the welfare of the nation by providing the scientific foundation, technology, policy, and institutional leadership necessary to achieve efficiency in energy use, diversity in energy sources, a more productive and competitive economy, improved environmental quality, and a secure national defense. The research and development funding effort has most recently been redirected toward greater utilization of clean fossil fuels, especially natural gas, weatherization, renewable energy, energy efficiency, fusion energy, and high-energy physics. This paper will summarize the role that environmental geology has played and will continue to play in the execution of DOE's mission and the energy options that DOE has investigated closely. The specific options are those that center around energy choices, such as alternative-fueled transportation, building technologies, energy-efficient lighting, and clean energy.     

Geological setting and tectonic subdivision of the Neoproterozoic orogenic belt of Tuludimtu, western Ethiopia

The N–S trending Tuludimtu Belt in the extreme west of Ethiopia has been subdivided into five lithotectonic domains, from east to west, the Didesa, Kemashi, Dengi, Sirkole and Daka domains. The Kemashi, Dengi and Sirkole Domains, forming the core of the belt, contain volcano-sedimentary successions, whilst the Didesa and Daka Domains are gneiss terranes, interpreted to represent the eastern and western forelands of the Tuludimtu Belt. The Kemashi Domain, which consists of an ophiolitic sequence of ultramafic and mafic volcanic and plutonic rocks together with sedimentary rocks of oceanic affinity, is interpreted as oceanic crust and is considered to represent an arc-continent suture zone. The Dengi Domain, composed of mafic to felsic volcanic and plutonic rocks, and a sequence of volcanoclastic, volcanogenic, and carbonate sediments, is interpreted as a volcanic arc. The Sirkole Domain consists of alternating gneiss and volcano-sedimentary sequences, interpreted as an imbricated basement-cover thrust-nappe complex. All the domains are intruded by syn- and post-kinematic Neoproterozoic granitoids. Structural analysis within the Didesa and Daka Domains indicate the presence of pre-Pan African structures, upon which Neoproterozoic deformation has been superimposed. The gneissic rocks of these two domains are regarded as pre-Pan African continental fragments amalgamated to West Gondwana during Neoproterozoic collision events. Unconformably overlying all of the above are a series of tilted but internally undeformed conglomerate–sandstone–shale sequences, regarded as post-accretionary molasse-type deposits, formed during gravitational collapse of the Tuludimtu Belt. The Tuludimtu Belt is interpreted as a collision orogenic belt formed during the assembly of West Gondwana prior to final closure of the Mozambique Ocean.     

Progress of Tracing Fossil Fuel CO2 by Radiocarbon in Chinese Cities

The main cause of increase in atmospheric CO₂ concentration is the carbon emissions from fossil fuel combustions and so on. Cities are regarded as the hot spots of carbon emissions. On the basis of obtaining the levels and spatial-temporal variation characteristics of atmospheric fossil fuel CO₂ （CO_2ff）， we can provide scientific data for government policy-making and international negotiations on carbon reductions. In the recent ten years， some important progresses have been achieved in the study of tracing urban atmospheric CO_2ff using ¹⁴C by Chinese scientists. The variation characteristics of urban CO_2ff at different temporal and spatial scales were obtained through the analysis of ¹⁴C in air， tree ring and annual plant samples. Our results show that the northern cities are the key points to reduce carbon emissions， and that the CO_2ff emissions can be reduced simultaneously by controlling atmospheric pollutant emissions， indicating a synergistic emission reduction. It was found that CO_2ff in Xi'an was mainly from local coal-burning emissions with the use of improved WRF-CHEM model and δ¹³C. Finally， the yearly CO_2ff traced by tree-ring ¹⁴C in Xi'an showed similar trends and amplitudes with the statistical data of carbon emissions， which indicates that the ¹⁴C tracing method and statistical method can be mutually validated to ensure the reliability of the data. In order to promote the ¹⁴C trace study to serve the national carbon emission reduction task， we suggest that the urban atmospheric Δ¹⁴CO₂ observation network should be established as soon as possible， and that this study should be enhanced with more scientists involved in it and more financial resources to support it.     

Disposable Ordos: The making of an energy resource frontier in western China

China’s economic growth in recent decades has been accompanied by vigorous growth in energy production and consumption. This article analyzes geographical shifts in the production of energy resources using a relational frontier concept. The frontier concept is deployed to examine the forces driving energy resource production to territories in China’s west. Through an understanding of frontiers as peculiar places shaped by flows of capital and contingent socio-economic conditions, this study underscores the both the contributions of national-level energy policy and local political-economy in bringing about a pronounced shift in the distribution of energy resource supply whereby the country’s west is increasingly recast as a production zone for energy and the east as a consumption zone. A case study of coal production in Inner Mongolia Autonomous Region’s Ordos Municipality in the 2000s details the unfolding of frontier processes for this key energy resource.     

贵州毕节地区煤炭资源与经济发展思路

贵州省毕节地区紧紧抓住自身具有的资源优势,提出了建设“绿色、能源、畜牧、旅游四大区”的发展思路,其中“立足能源资源优势,建设能源大区”是该近期经济发展最具拉动效果的有力举措。因此,该区成为国家和省规划的电煤基地、化工用煤基地、优质无烟煤出口基地,经济得到了快速的增长。     

Upper Oligocene–Miocene clinoforms of the foreland Austral Basin of Tierra del Fuego, Argentina: Stratigraphy, depositional sequences and architecture of the foredeep deposits

The Upper Oligocene–Miocene deposits of the foreland Austral Basin of Tierra del Fuego represent the youngest foredeep fill, developed in front of the adjacent fold and thrust belt. They consist of superbly exposed, sub-horizontal clastic successions of more than 600 m of sedimentary thickness. The study of 11 sections by means of facies analysis and sequence stratigraphic criteria enabled the identification of five depositional sequences (SI–SV), bounded by unconformities (dI-dV) involving hiatuses of different magnitudes. The basal sequence (SI) includes two members: A, mudstone dominated, deposited by cohesive flows; and B, glauconite-rich, sandstone dominated, deposited by episodic turbidity currents. The remaining sequences (SII–SV) are composed of complex arrangements of fine conglomerates, coarse- to fine-grained sandstones, and mudstones that were deposited mainly by hyperpycnal flows. The basal unconformities of the SI to SIV involve minor hiatuses, while that of the SV is a major order unconformity. Two types of clinofom geometries are recognized in the foredeep sequences. Type a clinoforms present a wedge shaped geometry and characterize the foredeep infill during the compressional tectonic regime. Regarding this clinoform type, SI is situated closer to the orogen and shows variations in the bedding dip with development of internal unconformities. SII to SIV are situated towards the foreland and are characterized by subhorizontal conformable beds of large lateral extension. Type b clinoforms, with sigmoidal geometry, show a clear northeast progradation related to a progressive foredeep fill under tectonic quiescence. This clinoform type characterizes the deposits in SV. The recognition of hyperpycnites and different types of clinoform geometries in these sequences incorporates new concepts in reservoir prospects, which are critical for the evaluation of the petroleum system in the Austral Basin.     

Geology and mineral potential of Ethiopia: a note on geology and mineral map of Ethiopia

This work presents a geoscientific map and database for geology, mineral and energy resources of Ethiopia in a digital form at a scale of 1:2,000,000, compiled from several sources. The final result of the work has been recorded on CD-ROM in GIS format so that the map and the database could be available to users on a personal computer.Metallic resources (precious, rare, base and ferrous–ferroalloy metals) are widely related to the metamorphic meta-volcano-sedimentary belts and associated intrusives belonging to various terranes of the Arabian–Nubian Shield, accreted during the East and West Gondwana collision (Neoproterozoic, 900–500 Ma).Industrial minerals and rock resources occur in more diversified geological environments, including the Proterozoic basement rocks, the Late Paleozoic to Mesozoic sediments and recent (Cenozoic) volcanics and associated sediments.Energy resources (oil, coal, geothermal resources) are restricted to Phanerozoic basin sediments and Cenozoic volcanism and rifting areas.     

Signs of power: Fascist urban iconographies in Ethiopia (1930s–1940s)

The aim of the present paper is to compare two different patterns of urban iconographies in Ethiopia during 1930s: the one of the Amhara – the traditionally Ethiopian dominant ethnicgroup – and the one of the Italian fascism. The paper gives an historical account of the structure of the Amhara settlements, focusing on the ways the power of their politico-military chiefs, being they the Negus or the Ras, shaped the spatial order of these settlements. When the Italians conquered military Ethiopia in 1936, they started re-shaping this spatial order, erasing the signs of the previous power and imposing their new iconographic apparatus. This was mainly done through urban planning which was devised to `write' the Fascist concepts of progress, order, hierarchy, and racial segregation on the territory. Owing to the short duration of the occupation, the poor material conditions of the colony and the lack of financial resources, such town-planning projects turned out to be just a political rhetoric exercise.     

Biomolecular Preservation of Miocene Fossil Liquidambar from Tiantai, China and Clarkia, USA: Implications for Palaeoenvironmental Study

Biomolecular characteristics of fossil Liquidambar from the Miocene Shengxian Formation, Tiantai, Zhejiang province in eastern China and Miocene Clarkia sediment, Idaho, U.S.A., are obtained by means of Pyrolysis-Gas chromatography-Mass spectrometry analysis (Py-GC-MS). Their modern equivalent (Liquidambar formosana) collected from Nanjing, eastern China, is also analyzed for comparison. The total ion chromatograms (TIC) of modern L. formosana leaves shows abundant pyrolysates of lignin, polysaccharide, aliphatic acid, and amino acid. However, only one polysaccharide molecule, i.e., levoglucosan, is retained in fossil Liquidambar leaves from the two Miocene sites with the Tiantai specimen possessing higher intensity. As expected, some lignin pyrolysates including benzene, phenol, guaiacol, vinylphenol and their derivatives, are detected in Miocene Tiantai L. miosinica. However, the lignin components with large molecular weight other than benzene and phenol compounds, are absent in Miocene Clarkia L. pachyphyllum. Abundant pristene and homologous series of n-alk-1-ene/n-alkane pairs with a long retention time are shown in pyrograms of both Tiantai and Clarkia fossils. Based upon our Py-GC-MS data, the molecular preservation in these Liquidambar leaf samples can be ranked as the following (from high to low quality respectively): modern sample >Tiantai sample >Clarkia sample. Vinyl phenol, an important compound, is present in modern and Tiantai Liquidambar leaves, while absent in Clarkia sample, implying that vinyl phenol may be sourced from lignin for Liquidambar leaves. Our data support the hypothesis of in situ polymerization for the origin of long-chain homologous series of n-alk-1-ene/n-alkane pairs as leaf alteration products. Our data have implications of the impact of leaf degradation toward biases for palaeoenvironmental reconstruction using stable carbon isotope of fossil plants, and suggest the importance of evaluating molecular preservation of fossil leaf tissues prior to the application of carbon isotope compositions of fossil leaves.     

Unravelling provenance from Eocene–Oligocene sandstones of the Thrace Basin,North‐east Greece

New sandstone petrology and petrostratigraphy provide insights on Palaeogene (Middle Eocene to Oligocene) clastics of the Thrace Basin in Greece, which developed synchronously with post‐Cretaceous collision and subsequent Tertiary extension. Sandstone petrofacies are used as a tool to unravel complex geodynamic changes that occurred at the southern continental margin of the European plate, identifying detrital signals of the accretionary processes of the Rhodope orogen, as well as subsequent partitioning related to extension of the Rhodope area, followed by Oligocene to present Aegean extension and wide magmatic activity starting during the Early Oligocene. Sandstone detrital modes include three distinctive petrofacies: quartzolithic, quartzofeldspathic and feldspatholithic. Major contributions are from metamorphic basement units, represented mostly by low to medium‐grade lithic fragments for the quartzolithic petrofacies and high‐grade metamorphic rock fragments for the quartzofeldspathic petrofacies. Volcaniclastic sandstones were derived from different volcanic areas, with a composition varying from dominantly silicic to subordinate intermediate products (mainly rhyolitic glass, spherulites and felsitic lithics). Evolution of detrital modes documents contributions from three key source areas corresponding to the two main crystalline tectonic units: (i) the Variegated Complex (ultramafic complex), in the initial stage of accretion (quartzolithic petrofacies); (ii) the Gneiss–Migmatite Complex (quartzofeldspathic petrofacies); and (iii) the Circum‐Rhodope Belt. The volcaniclastic petrofacies is interbedded with quartzofeldspathic petrofacies, reflecting superposition of active volcanic activity on regional erosion. The three key petrofacies reflect complex provenance from different tectonic settings, from collisional orogenic terranes to local basement uplift and volcanic activity. The composition and stratigraphic relations of sandstones derived from erosion of the Rhodope orogenic belt and superposed magmatism after the extensional phase in northern Greece provide constraints for palaeogeographic and palaeotectonic models of the Eocene to Oligocene western portions of the Thrace Basin. Clastic detritus in the following sedimentary assemblages was derived mainly from provenance terranes of the Palaeozoic section within the strongly deformed Rhodope Massif of northern Greece and south‐east Bulgaria, from the epimetamorphic units of the Circum‐Rhodope Belt and from superposed Late Eocene to Early Oligocene magmatism related to orogenic collapse of the Rhodope orogen. The sedimentary provenance of the Rhodope Palaeogene sandstones documents the changing nature of this orogenic belt through time, and may contribute to a general understanding of similar geodynamic settings.     

Lithostratigraphy, basin development, base metal deposits, and regional correlations of the Neoproterozoic Nguba and Kundelungu rock successions, central African Copperbelt

The Neoproterozoic Katangan Supergroup comprises a thick sedimentary rock succession subdivided into the Roan, Nguba, and Kundelungu Groups, from bottom to top. Deposition of both Nguba and Kundelungu Groups began with diamictites, the Mwale/Grand Conglomérat and Kyandamu/Petit Conglomérat Formations, respectively, correlated with the 750 Ma Sturtian and (supposedly) 620 Ma Marinoan/Varanger glacial events. The Kaponda, Kakontwe, Kipushi and Lusele Formations are interpreted as cap-carbonates overlying the diamictites. Petrographical features of the Nguba and Kundelungu siliciclastic rocks indicate a proximal facies in the northern areas and a basin open to the south. The carbonate deposits increase southward in the Nguba basin. In the southern region, the Kyandamu Formation contains clasts from the underlying rocks, indicating an exhumation and erosion of these rocks to the south of the basin. It is inferred that this formation deposited in a foreland basin, dating the inversion from extensional to compressional tectonics, and the northward thrusting. Sampwe and Biano sedimentary rocks were deposited in the northernmost foreland basin at the end of the thrusting. The Zn–Pb–Cu and Cu–Ag–Au epigenetic, hypogene deposits occurring in Nguba carbonates and Kundelungu clastic rocks probably originate from hydrothermal resetting and remobilization of pre-existing stratiform base metal mineralisations in the Roan Group.     

Oligo-Miocene foraminiferal record (Miogypsinidae, Lepidocyclinidae and Nummulitidae) from the Western Taurides (SW Turkey): Biometry and implications for the regional geology

The marine Oligo-Miocene units of western Taurides, deposited under different tectonic regimes (in Bey Da?lar? platform in foreland and coeval sequences in hinterland), were studied to establish a high-resolution biostratigraphic framework. Biometric study of the full spectrum of larger foraminifera in a regional scale allowed us correlating them with the shallow benthic zonation (SBZ) system introduced by [Cahuzac, B., Poignant, A., 1997. Essai de biozonation de l’Oligo-Miocène dans les bassins européens à l’aide des grands foraminifères néritiques. Bulletin de la Société géologique de France 168, 155–169], and to determine the ages of these sites on zonal precision for the first time. In correlating these assemblages to standard shallow benthic zones, planktonic data were also used whenever possible. Taxa, classified under the genera Nummulites, Miogypsina, Miolepidocyclina, Nephrolepidina, Eulepidina, Heterostegina, Operculina and Cycloclypeus (?) and their assemblages, closely resemble to the fauna described from European basins. These groups characterize the SBZ 22B to 25 zones referring to a time interval from early Chattian to Burdigalian. However, a main gap in late Chattian (SBZ 23) and in early part of the Aquitanian (SBZ 24) is also recorded in the platform succession. In the meantime, rare Eulepidina in the Burdigalian levels suggest a clear Indo-Pacific influence. Based on the discovery of early Chattian (SBZ 22B) deposits (previously mapped under Eocene/Miocene units), the Oligo-Miocene stratigraphy of the Bey Da?lar? platform is also revised. A more precise chronology for regional Miocene transgression is presented based on the miogypsinid evolutionary scale.     

Ichnodiversity and ichnoabundance: Revealing depositional trends in a confined turbidite system

Ichnological studies are still in their infancy when it comes to the interpretation of deep‐marine deposits. The Eocene–Oligocene turbidite system of the Grès d'Annot Formation in south‐east France is well‐studied sedimentologically, but its trace‐fossil content is poorly known. Here, an integrated ichnological–sedimentological study is presented from the Annot sub‐basin for the first time, which demonstrates its value for interpreting proximal to distal and axial to marginal trends in confined turbidite systems. A comprehensive trace‐fossil data set was collected from seven outcrops situated in the southern part of the basin. These data are presented following a morphology‐based classification scheme to allow easy recognition and characterization of ichnotaxa. Ichnodiversity and the abundance of ichnotaxa are regarded as important parameters in such interpretations. Instead of simply counting ichnotaxa per outcrop or stratigraphic unit, an equation has been developed in which the ‘ichnoabundance’ (new term) of each counted ichnotaxon is calculated. An exponential growth factor is applied to the increase of the frequency of trace fossils, and is assumed in this equation to better reflect the population dynamics of benthic organisms. A comparison of the solution for pre‐turbidite and post‐turbidite trace‐fossil suites seems to be more suitable for revealing regional and stratigraphic trends compared with conventional approaches. Despite varying size and conditions of the studied outcrops, the results achieved from the Grès d'Annot Formation can help in the reconstruction of sedimentary processes acting in this confined turbidite basin.     

The record of tidal cycles in mixed silici–bioclastic deposits: examples from small Plio–Pleistocene peripheral basins of the microtidal Central Mediterranean Sea

The Pliocene–Pleistocene peripheral marine basins of the Mediterranean Sea in southern Italy, from Basilicata and western Calabria to northern and eastern Sicily, represent tectonically formed coastal embayments and narrow straits. Here, units of cross‐stratified, mixed silici–bioclastic sand, 25 to 80 m thick, record strong tidal currents. The Central Mediterranean Sea has had a microtidal range of ca 35 cm, and the local amplification of the tidal wave is attributed to tides enhanced in some of the bays and to the out‐of‐phase reversal of the tidal prism in narrow straits linking the Tyrrhenian and Ionian basins. The siliciclastic sediment was generated by local bedrock erosion, whereas the bioclastic sediment was derived from the contemporaneous, foramol‐type cool‐water carbonate factories. The cross‐strata sets represent small to medium‐sized (10 to 60 cm thick) two‐dimensional dunes with mainly unidirectional foreset dip directions. These tidalites differ from the classical tidal rhythmites deposited in mud‐bearing siliciclastic environments. Firstly, the foreset strata lack mud drapes and, instead, show segregation of siliciclastic and bioclastic sand into alternating strata. Secondly, the thickness variation of the successive silici–bioclastic strata couplets, measured over accretion intervals of 2 to 3 m and analysed statistically, reveal only the shortest‐term, diurnal and semi‐diurnal tidal cycles. Thirdly, the record of diurnal and semi‐diurnal tidal cycles is included within the pattern of neap‐spring cycles. Differences between these sediments and classical tidal rhythmites are attributed to the specific palaeogeographic setting of a microtidal sea, with the tidal currents locally enhanced in peripheral basins. It is suggested that this particular facies of mud‐free, silici–bioclastic arenite rhythmites in the stratigraphic record might indicate a specific type of depositional sub‐tidal environment of straits and embayments and the shortest‐term tidal cycles.     

Relict chromian spinels in Tulu Dimtu serpentinites and listvenite,Western Ethiopia: implications for the timing of listvenite formation

Serpentinites (massive and schistose) and listvenite occur as tectonic sheets and lenses within a calcareous metasedimentary mélange of the Tulu Dimtu, western Ethiopia. The massive serpentinite contains high-magnesian metamorphic olivine (forsterite [fo] ~96 mol%) and rare relict primary mantle olivine (Fo_90–93). Both massive and schistose serpentinites contain zoned chromian spinel; the cores with the ferritchromite rims preserve a pristine Cr/(Cr+Al) atomic ratio (Cr# = 0.79–0.87), suggesting a highly depleted residual mantle peridotite, likely formed in a suprasubduction zone setting. Listvenite associated with serpentinites of smaller ultramafic lenses also contain relict chromian spinel having identical Cr# to those observed in serpentinites. However, the relict chromian spinel in listvenite has significantly higher Mg/(Mg+Fe²⁺) atomic ratios. This suggests that a nearly complete metasomatic replacement of ultramafic rocks by magnesite, talc, and quartz to prevent Mg–Fe²⁺ redistribution between relict chromian spinel and the host, that is, listvenite formation, took place prior to re-equilibration between chromian spinel and the surrounding mafic minerals in serpentinites. Considering together with the regional geological context, low-temperature CO₂-rich hydrothermal fluids would have infiltrated into ultramafic rocks from host calcareous sedimentary rocks at a shallow level of accretionary prism before a continental collision to form the East African Orogen (EAO).     

Sedimentary rock-hosted Au deposits of the Dian–Qian–Gui area, Guizhou, and Yunnan Provinces, and Guangxi District, China

Sedimentary rock-hosted Au deposits in the Dian–Qian–Gui area in southwest China are hosted in Paleozoic and early Mesozoic sedimentary rocks along the southwest margin of the Yangtze (South China) Precambrian craton. Most deposits have characteristics similar to Carlin-type Au deposits and are spatially associated, on a regional scale, with deposits of coal, Sb, barite, As, Tl, and Hg. Sedimentary rock-hosted Au deposits are disseminated stratabound and(or) structurally controlled. The deposits have many similar characteristics, particularly mineralogy, geochemistry, host rock, and structural control. Most deposits are associated with structural domes, stratabound breccia bodies, unconformity surfaces or intense brittle–ductile deformation zones, such as the Youjiang fault system. Typical characteristics include impure carbonate rock or calcareous and carbonaceous host rock that contains disseminated pyrite, marcasite, and arsenopyrite—usually with μm-sized Au, commonly in As-rich rims of pyrite and in disseminations. Late realgar, orpiment, stibnite, and Hg minerals are spatially associated with earlier forming sulfide minerals. Minor base–metal sulfides, such as galena, sphalerite, chalcopyrite, and Pb–Sb–As–sulphosalts also are present. The rocks locally are silicified and altered to sericite–clay (illite). Rocks and(or) stream-sediment geochemical signatures typically include elevated concentrations of As, Sb, Hg, Tl, and Ba. A general lack of igneous rocks in the Dian–Qian–Gui area implies non-pluton-related, ore forming processes. Some deposits contain evidence that sources of the metal may have originated in carbonaceous parts of the sedimentary pile or other sedimentary or volcanic horizons. This genetic process may be associated with formation and mobilization of petroleum and Hg in the region and may also be related to As-, Au-, and Tl-bearing coal horizons. Many deposits also contain textures and features indicative of strong structural control by tectonic domes or shear zones and also suggest syndeformational ore deposition, possibly related to the Youjiang fault system. Several sedimentary rock-hosted Au deposits in the Dian–Qian–Gui area also are of the red earth-type and Au grades have been concentrated and enhanced during episodes of deep weathering.     

Geology and characterisation of the Pecket coal deposit, Magellan Region, Chile

The geology, petrography and chemical variation of the Pecket coal sequence, Magellan Region (52°57′S, 71°10′W), the only Chilean coal used for electricity generation on a large scale, has been studied in order to predict their combustion behaviour, especially in coal blends. The depositional environment of formation of the coal seams was a swamp rarely exposed to subaerial conditions and was associated with the development of the folded foreland of the Magellan basin during the Tertiary (Oligo–Miocene). The general tectonic regime of the collision of the Antarctic and South American plates is reflected by a system of joints with 40°N–50°W strike. The maceral composition of all six seams studied indicates high contents of vitrinite (>90%), minor content of liptinite (4.7%) and inertinite (<2%). Occurrence of tonstein horizons altered to kaolinite indicates a distal volcanism during peat accumulation. Coal rank varies between lignite and subbituminous (Ro=0.28–0.42%) with an average dry basis calorific value of 5450 kcal/kg, 17 wt.% moisture, 41 wt.% volatile matter, and sulphur content below 0.5 wt.%. The mineral matter (LTA) associated with the coal shows a dominance of kaolinite with quartz, smectite, and minor basanite. SiO₂/Al₂O₃ and Fe₂O₃/CaO ratios of the ashes diminish towards the lower seams. With respect to the utilisation of Pecket coals in combustion, base/acid ratios (B/A) and silica ratios (SR) indicate potential fouling for seams 1, 2, 5, and 6i, with high fouling indexes (Rf) for seams 2 and 5. Pecket coal is excellent for blend combustion due to its low sulphur content.