Geochemistry of Mercury Mineralization,Catian,West Hunan

The Tongfeng mercury zone is an important producer of mercury in China.The underlying Lower Cambrian black rock series is strongly depleted in mercury and is thought to be the major source bed for mercury mineralization .The Catian deposit ,as the representative of the zone, was formed at low temperature,which is characterized by a meteoric chlorine-rich and sulfur-poor ore-forming solution of high salinity.A geochemical genetic model of buried hydrothermal explosion is proposed.     

Early Ordovician Sea Level Changes in South China and Their Worldwide Correlation

INTRODUCTIONTheoaf~ansed~arewidelydistributedinSouthetna,fromtheYanalCratondPborminnorthtocontinentalmarginofsoutheastern~insouth.ThePreSentpaperdiscussesmainlytheEarlyOrdovidan(thehoeofHirmtodontussimplex~tothebaseofNemopagngraciliszone,Wangatal.,1992)sealeVelchangeSandtheirworldwidecorrelationbasedonasyntheticalstudyofseqUenCe,bioshatiglaphyandaretratigl'aphy.Thisapproachwillfillinthe~instudyoftheOrdovidanofChina,andimprovethesu~ionandCO~ionofbio--,litho--andcbronostheigraphy.Mea…     

The Early Evolution of the Acanthomorphic Acritarchs in China and Their Biostratigraphical Implication

On the basis of a study of the acanthomorphic acritarchs discovered in the Late Proterozoicto Early Cambrian Meishucunian Stage in different regions of China, especially in southernShaanxi and the Yangtze Platform, coupled with a study of the assemblages, morphological cor-relation, microstructure, and evolutional relations of the acanthorphic acritarchs, as well as awide correlation with those found in different regions of the world, the authors discuss the earlyevolutionary stages of the acanthomorphs, features of their assemblages in various stages, theirbiostratigraphical significance, and their evolutionary trend in China.     

Age,petrogenesis and metamorphism of the syn-collisional Prøven Igneous Complex,West Greenland

The Paleoproterozoic Prøven Igneous Complex (PIC) in West Greenland extends from ca. 72°15 to 73°10N, approximately 500 km north of the subduction-related intrusive complex in the core of the +1100 km wide, asymmetric collisional Nagssugtoqidian-Rinkian Orogen. A new U-Pb SHRIMP age for the PIC of 1869±9 Ma indicates that it intruded synchronously with the main collisional phase of the orogen into the passive margin side of the collision. Sm-Nd and Lu-Hf isotopic and A-type geochemical signatures are compatible with its derivation from melted Archean lower crustal material contaminated to varying degrees by pelitic sedimentary rocks of the Karrat Group. The timing, petrogenesis and position of the PIC within the orogen support a model of collisionally induced delamination of the mantle lithosphere following initial collision. Upwelling asthenospheric mantle replacing the partially or completely detached mantle lithosphere caused widespread partial melting of lower crust that resulted in the areally extensive (~ 250,000 km²) Cumberland-Prøven intrusive complexes of Baffin Island and West Greenland. Emplacement of the PIC at 1.87 Ga caused a high-temperature low- to medium-pressure metamorphic aureole that contrasts the regional, overprinting higher-pressure amphibolite facies metamorphism. The consequent high-temperature garnet-orthopyroxene-biotite-bearing assemblages occurring within the margin of the intrusion in the aureole are attributed to the intrusion event. Garnet-controlled Sm-Nd and Lu-Hf ages of 1.82–1.80 Ga require efficient diffusion of these elements during orogenic reheating at this time. This age range overlaps the post-collisional, north–south shortening in the Nagssugtoqidian Orogen to the south and serves to confirm the recently proposed genetic link between these two orogens. These new data infer that garnet-controlled isochrons based on the Lu-Hf and Sm-Nd systems cannot date high-grade events in slowly cooled or significantly reheated terrains in rocks possessing other phases that close at low temperatures.     

Geological and Geochemical Characteristics of Early Cretaceous Mafic Dikes in Northern Jiangxi Province, SE China and Their Geodynamic Implications

The development of Early Cretaceous mafic dikes in northern and southern Jiangxi allows an understanding of the geodynamic setting and characteristics of the mantle in southeast China in the Cretaceous. Geological and geochemical characteristics for the mafic dikes from the Wushan copper deposit and No. 640 uranium deposit are given in order to constrain the nature of source mantle, genesis and tectonic implications. According to the mineral composition,the mafic dikes in northern Jiangxi can be divided into spessartite and olive odinite types, which belong to slightly potassium-rich calc-alkaline lamprophyre characterized by enrichment in large ion lithophile elements (LILE) and light rare earth elements (LREE), large depletion in high strength field elements (HSFE) and with negative Nb, Ta and Ti anomalies, as well as 87Sr/86Sr ratios varying from 0.7055 to 0.7095 and 143Nd/r44Nd ratios varying from 0.5119 to 0.5122.All features indicate that the magma responsible for the mafic dikes was derived mainly from metasomatic lithosphere mantle related to dehydration and/or upper crust melting during subduction. Differences in geochemical characteristics between the mafic dikes in northern Jiangxi and the Dajishan area, southern Jiangxi were also studied and they are attributed to differences in regional lithospheric mantle components and/or magma emplacement depth. Combining geological and geochemical characteristics with regional geological history, we argue that southeast China was dominated by an extensional tectonic setting in the Early Cretaceous, and the nature of the mantle source area was related to enrichment induced by asthenosphere upwelling and infiltration of upper crust-derived fluids responding to Pacific Plate subduction.     

Ore-forming Conditions and Prospecting in the West Kunlun Area,Xinjiang, China

The West Kunlun ore-forming belt is located between the northwestern Qinghai-Tibet Plateau and southwestern Tarim Basin. It situated between the Paleo-Asian Tectonic Domain and Tethyan Tectonic Domain. It is an important component of the giant tectonic belt in central China (the Kunlun-Qilian-Qinling Tectonic Belt or the Central Orogenic Belt). Many known ore-forming belts such as the Kunlun-Qilian Qinling ore-forming zone, Sanjiang (or Three river) ore-forming zone, Central Asian ore-forming zone, etc. pass through the West Kunlun area. Three ore-forming zones and seven ore-forming subzones were classified, and eighteen mineralization areas were marked. It is indicated that the West Kunlun area is one of the most favorable region for finding out large and superlarge ore deposits.     

Abundances of F,Cl S and P in Volcanic Magmas and Their Evolution,Wudalianchi

F, Cl, S and P were determined, using electron microprobe, in magmatic inclusions trapped within minerals and glass mesostasis from Wudalianchi volcanic rocks. The initial volcanic magma from Wudalianchi corresponds to the basanitic magma crystallized near the surface ( pressure < 91 Mpa ). The potential H₂O content of this magma is in the range 2 — 4 wt. %. The initial composition of volcanic magmas varies regularly from early to late volcanic events. From the Middle Pleistocene to the recent eruptions (1719 – 1721 yr.), the basicity of volcanic magma tends to increase, as reflected by an increase in MgO and CaO contents and by a progressive decrease in SiO₂ and K₂O contents. Meanwhile. from early (Q₂ ) to late (Q₃) episodic eruptions of the Middle Pleistocene, the initial concentrations of chlorine in volcanic magmas range from 1430 – 1930 ppm to 1700 ppm and decrease to 700 — 970 ppm for the first episodic eruption during the Holocene (Q ₄ ¹ ). The chlorine concentrations of volcanic magmas of recent eruption (Q ₄ ² ) are increased again to 2600 – 2870 ppm. A parallel evolution trend for phosphorus and chlorine concentrations in magmas has been certified: 1500 – 5970 ppm (Q₂)→ 3500 – 4210 ppm (Q₃)→ 1100– 3500 ppm (Q ₄ ¹ )→ 6800– 7900 ppm (Q ₄ ² ). The fluorine contents of volcanic magmas, from early to late volcanic events, show the same trend: 770 – 2470 ppm → 200–700 ppm → 700 – 800 ppm. During the crystallization-evolution of volcanic magmas, fluorine and phosphorus tend to be enriched in residual magmas as a result of crystal-melt differentiation. for example. the fluorine contents reach 5000– 6800 ppm and the phosphorus contents, 2.93wt.% in residual magmas. An appreciable amount of chlorine may be lost from water rich volcanic magmas prior to eruption as a result of degassing. Apparently, water serves as a gas carrier for the chlorine. The chlorine contents of residual magmas may decrease to 100 – 300 ppm. The volcanic magmas from Wudalianchi are poor in sulfur, normally ranging from 200 to 400ppm. On account of the behavior of sulfur in magmas and the strontium and oxygen isotopic analyses ((⁸⁷Sr /⁸⁶Sr)_i=0.70503– 0.70589; δ¹⁸O = + 5.50 – + 6.89 ‰ ), it can be considered that the basanitic magmas in the Wudalianchi volcanic area came from the upper mantle and have not yet been contaminated probably by continental crust materials.     

Geochemical Characteristics,Petrogenesis of the Sanukitic Dikes in the Miaoergou Area of West Junggar,Xinjiang, NW China and Their Geological SignificanceEI北大核心CSCD

NS-trending dikes which contain dioritic enclaves widely occur in the Miaoergou pluton, West Junggar, Xinjiang. The dikes are composed of quartz diorite and quartz diorite porphyrite. LA-ICP-MS zircon U-Pb ages of the quartz diorite and diorite are 298.0±3.7 Ma and 299.4±2.5 Ma, respectively, corresponding to the end of the Late Carboniferous to beginning of the Early Permian. The dikes and enclaves have similar geochemical properties with island arc features. They are calc-alkaline, with moderate SiO2 (53.58% to 57.89%), high MgO (3.09% to 4.83%, Mg# values ranging from 44.69 to 54.12), TiO2 (1.17% to 1.66%), Cr (51.24×10-6 to 126.1×10-6), Ni (35.91×10-6 to 57.55×10-6) contents and K/Na ratios (0.35 to 0.70). Moreover, all samples are enriched in large-ion lithophile elements (LILEs: e.g. K, Rb, Ba and U) and light rare earth elements, but strongly depleted in high field strength elements (HFSEs: e.g. Nb, Ta and Ti), with insignificant Eu anomalies (δEu=0.67 to 1.08). In contrast, the dikes and enclaves in the Miaoergou pluton show geochemical signatures similar to those of the Cenozoic sanukitoids in Setouchi volcanic belt of SW Japan and the sanukitoids in the Hatu area, West Junggar. The source of the dikes might be the depleted mantle previously metasomatized by fluids released from subduction slabs. These sanukitic dikes may be generated by interaction of the mantle wedge with fluids derived from dehydration of the subducting oceanic slab, resulting in 2% to 5% partial melting of amphibole-spine peridotite. The identification of the sanukitic dikes in the Miaoergou pluton, together with previous studies, suggest that the southern West Junggar region was still dominated by subduction-related island arc setting at the beginning of the Early Permian, and multi-stage subduction-accretionary orogeny may account for the difference of subduction duration between the north and the south of West Junggar. © 2018, Science Press. All right reserved.     

Silurian Seismites in Hanxia, Yumen, North Qilian Mountains, and Their Tectonic Significance

The Caledonian erogenic belt of the North Qilian Mountains is an intensely active structure belt. In the process of the Late Caledonian syn-orogeny, the North Qilian-Hexi Corridor area was situated on the tectonic background of a syn-orogenic basin. In response to the orogenic process of the North Qilian Mountains, typical earthquake event deposits-seismites of the Silurian were widely distributed around Hanxia of Yumen City, the Liyuan River of Sunan County and Biandukou of Minle County. In the Hanxia area, where seismites are typically developed, clastic deposits of tidal-flat facies are the background deposits of the Hanxia Formation. The earthquake event deposits are characterized by sandy mudstone veins, synsedimentary microfractures, micro-corrugated laminations and earthquake breccias, which in turn constitute complex seismites, featuring seismic corrugation, shattering and liquefied sandy mudstone veins, auto-clastic breccias and intraclastic parabreccias. The seismites and tidal flat deposits f     

Volgian–Early Berriasian Marginal Filter in the West Siberian Marine Basin and Its Influence on Sediment Distribution

Lithology and Mineral Resources - The West Siberian marine basin of the Volgian–initial Berriasian ages is described. It is shown that a marginal filter (according to A.P. Lisitsyn)...     

Paleogeographic conditions in the West Siberian Basin during the Tithonian–Early Berriasian

Based on facies, structural, and general paleogeographic analyses, new models of the bottom topography and accumulation of the Tithonian–Early Berriasian Bazhenov Formation (West Siberian Basin) are proposed. According to these patterns, quite a low proportion of the terrigenous material in the high-carbon facies of the Bazhenov Formation can be explained by its accumulation in relatively deep troughs that frame the uplifted shallow-water central part of the West Siberian basin. In addition, the structure and dynamics of ocean currents are considered. During the Tithonian–Early Berriasian, these currents were related to the aeration stages of bottom waters enriched in hydrogen sulfide and carbon dioxide. As a result of the convection of the water mass suffocation periods occurred.     

In, Sn, Pb and Zn Contents and Their Relationships in Ore-forming Fluids from Some In-rich and In-poor Deposits in China

All the indium-rich deposits with indium contents in ores more than 100×10- 6 seems to be of cassiterite-sulfide deposits or Sn-bearing Pb-Zn deposits, e.g., in the Dachang Sn deposit in Guangxi, the Dulong Sn-Zn deposit in Yunnan, and the Meng'entaolegai Ag-Pb-Zn deposit in Inner Mongolia, the indium contents in ores range from 98×10-6 to 236×10-6 and show a good positive correlation with contents of zinc and tin, and their correlation coefficients are 0.8781 and 0.7430, respectively. The indium contents from such Sn-poor deposits as the Fozichong Pb-Zn deposit in Guangxi and the Huanren Pb-Zn deposit in Liaoning are generally lower than 10×10-6, i.e., whether tin is present or not in a deposit implies the enrichment extent of indium in ores. Whether the In enrichment itself in the ore -forming fluids or the ore-forming conditions has actually caused the enrichment/depletion of indium in the deposits? After studying the fluid inclusions in quartz crystallized at the main stage of mineralization of several In-rich and In-poor deposits in China, this paper analyzed the contents and studied the variation trend of In, Sn, Pb and Zn in the ore-forming fluids. The results show that the contents of lead and zinc in the ore-forming fluids of In-rich and -poor deposits are at the same level, and the lead contents range from 22×10-6 to 81×10-6 and zinc from 164×10-6 to 309×10-6, while the contents of indium and tin in the ore-forming fluids of In-rich deposits are far higher than those of In-poor deposits, with a difference of 1-2 orders of magnitude. Indium and tin contents in ore-forming fluid of In-rich deposits are 1.9×10-6-4.1×10-6 and 7×100-6-55×10-6, and there is a very good positive correlation between the two elements, with a correlation coefficient of 0.9552. Indium and tin contents in ore-forming fluid of In-poor deposits are 0.03×10-6-0.09×10-6 and 0.4×10-6--2.0×10-6, respectively, and there is no apparent correlation between them. This indicates, on one hand, that In-rich ore-forming fluids are the material basis for the formation of In-rich deposits, and, on the other hand, tin probably played a very important role in the transport and enrichment of indium.     

Timing and maximum flood level of the Early Holocene glacial lake Nedre Glomsjø outburst flood,Norway

This study discusses the timing and maximum flood level of the Nedre Glomsjø outburst flood, Norway, based on sediment records retrieved from 15 bog and lake basins located close to the purported maximum flooded level. The sediment records in 12 of the basins consist of a distinct light-coloured silty bed that is correlated to the outburst-flood-deposited ‘Romerike Silt Bed’ identified elsewhere in the region. The silt bed is recorded in basins up to a certain elevation and is absent above this level. The new maximum flood level inferred from the basin sediment records exceeds the established landform-induced palaeostage indicators by 5–10 m. The data indicate a higher maximum flood level and larger inundation area than previously suggested and highlight the importance of acquiring a wide range of geological data when reconstructing palaeofloods. Radiocarbon dates of terrestrial macrofossils found stratigraphically above and below the Romerike Silt Bed suggest that the glacial lake Nedre Glomsjø outburst flood occurred between 10.5 and 10.3 cal. ka BP. The new and well-constrained timing of the outburst flood is beneficial for reconstructing regional deglaciation and provides a precise age for the Romerike Silt Bed chronostratigraphical marker, which is of value for studies in SE Norway and adjacent regions.     

Presolar Grains and Their Isotopic Anomalies in Meteorites

Study on presolar grains including diamond,silicon carbide,graphite,silicon nitrite(Si3N4),coundum and spinel isolated from meteorites is summarized in this paper.Except for nanometer-sized diamond,the other grains are micrometers to submicrometers in size.The presolar grains survived mainly in the fine-grained matrix of primitive chondrites and were isolated by chemical treatments.Diamond contains Xe isotopes(Xe-HL),typically produced in p-and r-processes,probably formed in supernovae.Mainstream silicon carbides are enriched in ^29,30Si and ^13C,but depleted in ^15N.They also contain various s-process products,consistent with calculations of AGB stars.Other silicon carbides exhibit much larger isotopic anomalies and are classified as groups X,Y,Z and AB.Among them,group X of SiC is characterized by enrichment of ^28Si and daughter isotopes of various short-lived nuclides,suggesting an origin from supernovae.Graphite can be divided into four density fractions with distince isotopic compositions.They may form in AGB stars,novae and supernovae,respctively,Si3N4 is similar to X-SiC in isotopic composition.Corundum is classified as four groups based on theid oxygen isotopic compositions.AGB and red giang stare are possible sources for the oxide.More comprehensive study of presolar grains,especially discovery of the other types of oxides and silicates,isotopic analyses of individual submicrometer-sized grains and distribution of presolar grains among various chemical groups and petropaphic types of chondrites will provide new information on nucleosynthesis,stellar evolution and formation of the solar nebula.     

Characteristics of Overpressure Systems and Their Significance in Hydrocarbon Accumulation in the Yinggehai and Qiongdongnan Basins, China

Overpressure systems are widely developed in the central depression and paleo-uplift in the Yinggehai and Qiongdongnan basins. They can be divided into three types according to the origin of abnormally high formation pressure in the reservoirs, i.e. the autochthonous, vertically-transmitted and laterally-transmitted types. The autochthonous overpressure system results from rapid disequilibrium sediment loading and compaction. In the allochthonous overpressure system, the increase of fluid pressure in sandstone originates from the invasion of overpressured fluid flowing vertically or laterally through the conduit units. The autochthonous overpressure system occurs in the deep-lying strata of Neogene age in the central depression of the Yinggehai and Qiongdongnan basins. The vertically transmitted overpressure system is developed in the shallow strata of Late Miocene and Pliocene ages in the diapiric zone of the central Yinggehai basin, and the laterally transmitted overpressure system occurs in the Oligo     

Mercury in river sediments, floodplains and plants growing thereon in the drainage area of the Idrija mine, Slovenia

Half a millennium mercury production at Idrija is reflected in increased mercury contents in all environmental segments. The bulk of roasting residues from the middle of the 19th century to 1977 was discharged directly into the Idrijca River, and the material was carried at high waters to the Soca River and farther into the Adriatic Sea. It has been estimated that 45500 tons of mercury were emitted into the environment during the operating period of the mine, which ceased production in 1994. In the lower reaches of the Idrijca the riverine deposits with high mercury contents have been, and will be in the future a source of mercury polluted sediment. Stream sediments were monitored at the same locations along the Idrijca and Soca rivers （70 kin） every 5 years since 1991 （1991-2005）. Grain size distribution was determined by dry sieving and fractions for geochemical analysis were prepared （〈0.04 and 〈0.125 mm）. Soils on river terraces were sampled at 5 localities in the lower course of Idrijca. At two locations of the terrace profiles the samples of averaged meadow forage and plantain （Plantago lanceolata） were collected within a 50-meters radius. We found that there was no decrease in mercury concentration in active river sediments during the last 20 years. Upstream from the Idrija Town the mercury concentrations in active river sediments vary from 1 to 10 mg/kg （average 3.3 mg/kg）. From Idrija to Spodnja Idrija the mercury concentrations increase extremely and vary greatly （32-4,121 mg/kg, the average is 734 mg/kg）. From Spodnja ldrija to the Idrijca-Soca confluence is the average 218 mg/kg, and 57 mg/kg downstream in the Soca River sediments.     

Hg and As Minerals in Fluid Inclusions from the Williams Mine,Hemlo,and Their Genetic Implications

The Hemlo mineralization is enigmatic compared to general Archean lode gold deposits based on the fact that is characterized by an exotic mineralogy containing elements such as As,Hg,Sb,Ba,V and Mo.The genetic concepts range from syngenetc to epigenetic types of mineralization.This reconnaissance study was designed to examine the relationshp of Hg-As minerals with respect of fluid inclusions in the Williams mine(formerly known as the Page Williams mine)covering the A and C ore zones.     

Characteristics of Volcanic Rocks in the Shoshonite Province, Eastern China, and Their Metallogenesis

The shoshonite province in eastern China is characterized by extensive distribution (ca. 80000 km2) of Late Jurassic-Early Cretaceous (165-100 Ma) shoshonite series with subordinate high-K calc-alkali series. It was formed in a dominantly tensile stress field. In comparison with their analogues in island arcs and active continental margins in other countries, the volcanic rocks in the shoshonite province have their specific characteristics in petrology, mineralogy and geochemistry as well as related mineralization association, which are the comprehensive reflection of the special composition and structure of the mantle and crust of the province and the special Mesozoic regional tectonic setting.     

R／S Analyses of Some Geochemical Indexes for Tianshuihai Lake Core in West Kunlun Mountain and Their Environmental Implications

With the decrease of gloal temperature,glacial epoch came over the earth and global climate fluctuated over a great range since the beginning of Quatenary .Paleoclimotologists of various countries have focussed attention to the periodic characteristics and dynamics of climation flucturation in the past many years(Berger,1977;Imbrie and Hays,1984:ding zhongli et al.,1990;Yu zhiwei et al.,1992:Liu Youmei et al.,1996),Although some of the workers have paid their attention to the nonlinear characteristics of the global Quaternary environmental evolution(Nicolis and Nicolis,1984,Lu Houyuan et al.,1993)_,it is worth while to do this kind of work in some special areas in the world,for example the Qinghai-Tibet Plateau.Using R/S analysis,the authors calculated the Hurst indexes H of some geochemical proxies,including organic carbon,FeO,Fe2O3 and FeO/Fe2O3,from the Tianshuihai Lake core in West Kunlun Mountain of the Qinghai-Tibet Plateau,The proxies satisfy the Hurst law with Honrg.carbon=0.735,HFe2O3=0.757,HFeO=0.848and HFeO/Fe2O3=0./646,All the indexs are greater than 0.5,meaning that from 240 to 15ka B.P.,there were some long-run dependencies-persistence in the climatic and environmental evolution around the Tianshuihai Lake area.This is in accordance with the climate there from 240 to 15ka B.P.(Yu Suhua et al.,1996),The paleo-climate and paleo-environment evolution around the Tianshuihai Lake area is of persistence as well as of fluctuation and is a combination of these two components,There are some differences between the four Hurst indexes,Which Probably resulted from the differnet intensitites of Persistence of the four proxies,organic carbon.FeO,Fe2O3 and FeO/Fe2O3,or from the change of drainage system around the Tianshuihai Lake area from opemness to closeness(Li Bingyuan et al.,1991;Sun Honglie,1996:Shi Yafeng et al.1998_).The Qinghai-Tibet plateau was the starter and sensor of the climatic and environmental variation of the surrounding areas(Yao Tandong et al.,1991;Feng Song et al., 1998) and some other scientists even regarded it as the driver and amplifier of global climatic variations (Pan Baotian and Li Jijun,1996).The persistence in which the climate and environment around the Tianshuihai Lake area evolved from 240 to 15ka B.P.is probably a function of the continuous uplift of the palteau in the same period of time.