Magnesite-bearing stratificated levels and their lithological nature in the Riphean dolomite sequences of the southern Urals

Three stratificated levels of magnesite-bearing dolomites—Lower Riphean (Bakal-Satka-Suran), Middle Riphean (Avzyan), and Upper Riphean (Min’yar)—are recognized in the Riphean section of the Bashkir Anticlinorium of the southern Urals. Dolomites contain submicroscopic (～1 μm) magnesite dissemination (MgO/CaO > 0.714). The Lower and Middle Riphean magnesite-bearing dolomites host metasomatic magnesite stocks, lenses, pockets, and large stratiform lodes formed as products of hydrothermal activity. No metasomatic magnesite bodies are known in areas without indications of the hydrothermal reworking of magnesite-bearing dolomites. Magnesite deposits of the southern Urals are typical elisional-hydrothermal products related to sedimentation and lithogenesis of carbonate rocks in isochemical system of sedimentary basin. Juvenile components did not participate in the formation of magnesite deposits in the southern Urals.     

Noble metal specialization of Lower and Middle Riphean terrigenous rocks in the South Urals

Results of the study of noble metal specialization of Lower and Middle Riphean terrigenous rocks in the Bashkir Anticlinorium (South Urals) are reported. The study revealed their genetic differences in the relatively unaltered, i.e., “background” terrigenous rocks in type sections of the Burzyan and Yurmatau groups and in sedimentary rocks of the same stratigraphic levels from tectonic zones subjected to local dynamothermal metamorphism of the greenschist facies and intruded by mafic rocks. It has been established that Ru serves as a geochemical marker of the impact of magmatic processes on sedimentary rocks and the redistribution of noble metals during metamorphism and local metasomatism. A generalized model is proposed for the formation of noble metal geochemical specialization of Lower and Middle Riphean terrigenous rocks in the South Urals.     

Geochemical and Lu/Hf isotopic (LA–ICP–MS) systematics of detrital zircons from the Upper Ordovician sandstones of the Bashkir Uplift (Southern Urals)

Analyses of trace elements and Lu/Hf isotopes have been carried out in already U–Pb dated detrital zircons from the Upper Ordovician sandstones of the southern part of the Bashkir Uplift. The concentrations of trace elements in the zircons suggest that they were derived from rocks of intermediate (62%), basic (24%), and felsic (9%) compositions as well as alkaline rocks (2%). The Lu/Hf systematics of the zircons demonstrated a wide variation of both ε_Hf (from +9.5 to–8.7) and model ages of the parental rocks (1.60 Ga < T _DM ^C < 3.28 Ga). Comparison of the isotopic–geochemical characteristics of the detrital zircons from different levels of the Riphean–Paleozoic sequence of the Bashkir Uplift against those from the Early Cambrian Brusov Formation of the Mezen Basin and Early Neoproterozoic Dzhezhim sandstones of Timan Ridge suggests that at the end of the Late Precambrian near the Uralian margin of Baltica a large block of Late Mesoproterozoic–Early Neoproterozoic crust existed, comprising a significant proportion of melanocratic rocks.     

Crystalline basement and fold complex of the Volga-Ural, Pericaspian, and Fore-Caucasus petroliferous basins

3D models of apparent magnetization and density of rocks allow us to provide insights into the deep structure of the Volga-Ural, Pericaspian, and Fore-Caucasus petroliferous basins. In the Volga-Ural Basin, some Riphean rifts reveal close spatial relations to Paleoproterozoic linear zones, presumably of the rift nature as well. The structure of the Paleoproterozoic Toropets-Serdobsk Belt is interpreted in detail. Rocks with petrophysical properties inherent to basic volcanics are established in the pre-Paleozoic basement of the marginal zone of the Pericaspian Basin. These rocks locally spread beyond the boundary escarpment and may be regarded as a part of the Riphean plume-related basaltic province. It is shown that the Pericaspian Basin was formed on the place of a triple junction of Riphean rifts: the Sarpa and Central Pericaspian oceanic branches and the continental branch of the Pachelma Aulacogen. The drastically different petrophysical properties of the basement beneath Baltica and the Astrakhan Arch indicate that this arch is an element of the large terrane that was attached to Baltica in the Vendian. The suture along which the Astrachan Terrane is conjugated with the basement of the central and southern segments of the Karpinsky Ridge is traced beneath the Paleozoic complex. A system of northwest-verging thrust faults formed during the collision between Scythia and Eurasia is mapped in the basement of the junction zone between the Karpinsky Ridge and Scythian Platform (Terrane). According to geological data, this event took place in the Early Paleozoic.     

Polychronous zirconology of syenites from the Avashla intrusion in the Kurgass anticline (Southern Urals)

Zircons were separated from syenites of the Avashla intrusion in the Kurgass anticline of the Bashkir megaanticlinorium in the Southern Urals. The obtained samples were dated using the U–Pb procedure by means of a SHRIMP II ion microprobe. The integrated mineralogical, geochemical, and isotope studies of zircons resulted in primary data on the origin and current conditions of zircons in syenites of the Avashla intrusion. The relics of early zircon generations (1320–1340 Ma) allowed us to specify the geological position of syenites along with the stratigraphic location of the enclosing sedimentary rocks. The time of the transformation (metamorphism) of the zircons at the Middle–Upper Riphean boundary is represented by a dating of 1097±20 Ma, which is of importance for specifying the boundary age and for revealing a geological event that started a new development stage of the stratoregion in the Upper Riphean.     

First results of U–Pb dating of detrital zircons from the Upper Ordovician sandstones of the Bashkir uplift (Southern Urals)

The first results of U–Pb dating of detrital zircons from Upper Ordovician sandstones of the Bashkir uplift in the Southern Urals and U–Pb isotopic ages available for detrital zircons from six stratigraphic levels of the Riphean–Paleozoic section of this region are discussed. It is established that the long (approximately 1.5 Ga) depositional history of sedimentary sequences of the Bashkir uplift includes a peculiar period lasting from the Late Vendian to the Emsian Age of the Early Devonian (0.55–0.41 Ga). This period is characterized by the following features: (1) prevalence of material from eroded Mesoproterozoic and Early Neoproterozoic crystalline complexes among clastics with ages atypical of the Volga–Urals segment of the East European Platform basement; (2) similarity of age spectra obtained for detrital zircons from different rocks of the period: Upper Vendian–Lower Cambrian lithic sandstones and Middle Ordovician substantially quartzose sandstones.     

Contribution of Grenvillian events to the formation of most complete Riphean sedimentary successions in Northern Eurasia

The Grenvillian orogeny (～1250 to 980 Ma) was one of the most significant Riphean events. It determined the formation of many structures observable now in North and South America, northwestern Europe, South Africa, Western Australia, Antarctica, and other regions. Nevertheless, its reflections in the most complete and relatively well investigated Upper Precambrian sedimentary sections of northern Eurasia such as the Riphean stratotype (Bashkir meganticlinorium) and hypostratotype (Uchur-Maya region) still remain unknown. This is primarily true of the petrographic and chemical compositions of terrigenous rocks. This work is dedicated to the analysis of peculiar features in variations of the whole-rock chemical composition of sandstones and fine-grained clastic rocks (shales, mudstones, fine-grained clayey siltstones) that constitute Middle-Upper Riphean boundary layers of the Bashkir meganticlinorium, Kama-Belaya aulacogen, and Uchur-Maya region. The analysis reveals no tendency for the decrease in the degree of the chemical and, consequently, mineralogical maturity in the upward direction through the Middle-Upper Riphean sections in the above-mentioned regions. The whole-rock compositions of fine-grained clastic rocks associated with sandstones correspond mostly to that of “common” Upper Precambrian clayey rocks. The formation of practically the entire Yurmatinian-Karatavian succession in the Bashkir meganticlinorium proceeded under relatively stable T_DM and ?_Nd(T) values. The period of 1250 to 980 Ma in the central and eastern parts of the Siberian Platform was marked by repeated rifting episodes alternating with accumulation of mature platformal sediments, although repercussions of Grenvillian collisional processes are missing from this region as well. The performed analysis provides grounds for the conclusion that contribution of the Grenvillian events to the formation of most complete Riphean successions in northern Eurasia was insignificant.     

Geodynamics of the Riphean stage in the evolution of the northern passive margin of the East European Craton

The nearly parallel northwest-trending Onega-Kandalaksha, Kerets-Leshukonsky, and Barents paleorift zones located in the northeastern part of the East European Platform are interpreted as a common structural assemblage that was formed in the Middle-Late Riphean as a result of horizontal extension of the continental margin. Therefore, it is reasonable to combine these paleorift structural features into the common White Sea Rift System instead of subdividing them into two or more systems as done previously. The White Sea Rift System originated owing to the breakup of the ancient Paleopangea supercontinent 1300–1240 Ma ago. The latter event occurred as a result of the divergence of the Baltia and Laurentia continental plates that most probably was caused by mantle spreading within the hot equatorial belt of the Earth. The diffuse rifting of that time occurred in the form of near-parallel rifts developing progressively from the inner part of the continental plate toward its margin. A pericratonic sedimentary basin eventually formed at the passive margin of Baltia as a system of roughly parallel rift zones. The geologic and geophysical data show that the passive margin of the East European Platform formed in the Riphean, a phenomenon that corresponds with a model of large-scale extension of the lithosphere after the stage of early ocean-floor spreading. In the course of this process, the brittle upper crust was detached from the ductile lower crust. The geodynamic regime of the Riphean passive margin of the East European Platform probably was similar to the regime of the present-day Atlantic-type passive margins. The White Sea Rift System differs from the transverse Mid-Russian Paleorift System both in origin and age. The Mid-Russian Paleorift System is considered to have formed in the Late Riphean as a result of transtension along a mobile zone in the ancient basement. The lithosphere of northeastern Fennoscandia has experienced horizontal extension since the Middle Riphean, a phenomenon that is closely related to the evolution of the White Sea Rift System, i.e., to the formation of the passive margin of the Baltia continent.     

The first magnetostratigraphic data on the stratotype of the Lopata Formation,Northeastern Yenisei Ridge: Problems of its age and paleogeography of the Siberian Platform at the Proterozoic–Phanerozoic boundary

New paleomagnetic and magnetostratigraphic data are presented for the stratotype of the Upper Riphean Lopata Formation (Teya River, Yenisei Ridge). The paleomagnetic pole calculated is significantly distinct from the Phanerozoic and Riphean poles of the Siberian Platform and is similar to the Late Vendian–Early Cambrian poles of the Madagascar Group. The stratigraphic range studied is characterized by an anomalously high frequency of geomagnetic inversions (15 zones of magnetic polarity), which is comparable with the inversion frequency of the Late Vendian sections of Baltica. These data, along with previous paleontological findings, indicate an age of the Lopata Formation of 555–540 Ma.     

Riphean fine-grained aluminosilicate clastic rocks in the Southern Urals, Uchur-Maya area, and the Yenisei Kryazh: Principal litho-geochemical characteristics

Analysis of the litho-geochemistry of fine-grained terrigenous rocks (metapelites, shales, and mudstones) of sedimentary megasequences in the Southern Urals, Uchur-Maya area, and the Yenisei Kryazh indicates that Riphean sequences in these regions are dominated by chlorite-hydromica rocks, with montmorillonite and potassic feldspar possibly occurring only in some of the lithostratigraphic units. According to the values of their hydrolysate modulus, most clay rocks from the three Riphean metamorphosed sedimentary sequences are normal or supersialites, with hydrosialites and hydrolysates playing subordinate roles. The most lithochemicaly mature rocks are Riphean clays in the Yenisei Kryazh (Yenisei Range). The median value of their CIA is 72, whereas this index is 70 for fine-grained aluminosilicate rocks from the Uchur-Maya area and 66 for fine-grained terrigenous rocks of the Riphean stratotype. Hence, at ancient water provenance areas from which aluminosilicate clastic material was transported in sedimentation basins in the southwestern (in modern coordinates) periphery of the Siberian Platform, the climate throughout the whole Riphean was predominantly humid. At the same time, the climate at the eastern part of the East European Platform was semiarid-semihumid. The K₂O/Al₂O₃ ratio, which is employed as an indicator of the presence of petro-and lithogenic aluminosilicate clastic component in Riphean sedimentary megasequences, shows various tendencies. According to their Sc, Cr, Ni, Th, and La concentrations and the Th/Sc ratio, the overwhelming majority of Riphean shales and mudstones notably differ from the average Archean mudstone and approach the average values for post-Archean shales. This suggests that mafic Archean rock in the provenance areas did not play any significant role in the origin of Riphean sedimentary megasequences. The Co/Hf and Ce/Cr ratios of the terrigenous rocks of the three Riphean megaseqeunces and their (Gd/Yb) _N and Eu/Eu* ratios place these rocks among those containing little (if any) erosion products of primitive Archean rocks. According to various geochemical data, the source of the great majority of fine-grained aluminosilicate clastic rocks in Riphean sediment megasequences in our study areas should have been mature sialic (felsic), with much lower contents of mafic and intermediate rocks as a source of the clastic material. The REE patterns of the Riphean shales and metapelites in the Bashkir Meganticlinorium, Uchur-Maya area, and Yenisei Kryazh show some features that can be regarded as resulting from the presence of mafic material in the ancient provenance areas. This is most clearly seen in the sedimentary sequences of the Uchur-Maya area, where the decrease in the (La/Yb) _N ratio up the sequence of the fine-grained terrigenous rocks from 15–16.5 to 5.8–7.1 suggests that mantle mafic volcanics were brought to the upper crust in the earliest Late Riphean in relation to rifting. Analysis of the Sm-Nd systematics of the Riphean fine-grained rocks reveals the predominance of model age values in the range of 2.5–1.7 Ga, which can be interpreted as evidence that the rocks were formed of predominantly Early Proterozoic source material. At the same time, with regard for the significant role of recycling in the genesis of the upper continental crust, it seems to be quite possible that the ancient provenance areas contained Archean complexes strongly recycled in the Early Proterozoic and sediments formed of their material. An additional likely source of material in the Riphean was mafic rocks, whose variable contribution is reflected in a decrease in the model age values. Higher Th and U concentrations in the Riphean rocks of the Yenisei Kryazh compared to those in PAAS indicate that the sources of their material were notably more mature than the sources of fine-grained aluminosilicate clastic material for the sedimentary megaseqeunces in the Southern Urals and Uchur-Maya area.     

Lithochemical composition of sandstones of the Vendian Asha Group,South Urals

The mineralogical–petrographic and chemical study of sandstones of the Vendian Asha Group in the Bashkir anticlinorium, the western slope of the South Urals, showed that this large stratigraphic unit consists of sedimentary associations formed in different conditions: (1) Pre-Uryuk sediments (Tolparovo, Suirovo, and Bakeevo formations) accumulated during marine regression possibly in the course of significant glacioeustatic sea level fluctuations and formation of the foredeep of Timanides. (2) Sediments of the Uryuk Formation, including alluvial and several related sediments. Analysis of the Qm–F–Lt, Qt–F–L, and ln(Q/L + CE)–ln(Q/F) diagrams showed that they were derived from magmatic/plutonic rocks in the inner parts of the East European Craton. Based on the distribution of data points of psammites in the Qt/(F + R)–Qp/(F + R) diagram, they were accumulated in the semihumid/semiarid conditions. (3) Coastal, shallowmarine, and fluvial/proluvial (?) sediments of the Basa, Kukkarauk, and Zigan formations. They were formed by the erosion of provenances located supposedly east of the present-day Bashkir anticlinorium. The psammites of the Asha Group were analyzed using the sandstone formation model proposed models proposed in (Dickinson et al., 1985; Garzanti et al., 2007). The distribution of data points of psammites from three uppermost formations of the Asha Group in the Qm–F–Lt and Qt–F–L diagrams suggests that they were accumulated by the redeposition of erosion products of the so-called clastic wedges of recycled orogens (clasticwedge provenance) made up of the fluvial and turbidite complexes of the foreland, fore-arc, or residual oceanic basins.     

First results of U/Pb dating of detrital zircons from middle Riphean sandstones of the Zigalga Formation,South Urals

The results of U/Pb dating of detrital zircons from sandstones of the Zigalga Formation, which is the base level of the Middle Yurmatu Group of the Bashkir uplift, southwestern Urals, are presented. The U/Pb ages of detrital zircons from sandstones of the Lower, Middle, and Upper Riphean are compared.     

The Southern Urals Large Igneous Province with an age of approximately 1380 Ma: Precision U–Pb ID-TIMS constraints

The formation of the Large Igneous Province (LIP) approximately 1380 Ma old in the South Urals was related to the Mashak riftogenic event in the Bashkir meganticlinorium, which was synchronous with the emplacement of different magmatic bodies (the Berdyaush pluton of rapakivi granites and associated rocks, the Main dike of the Bakal ore field, and the Medvedev, Guben, and Kusa massifs, among others) localized among sedimentary deposits of the Burzyan and Yurmatin Groups representing Lower and Middle Riphean type units of northern Eurasia. The U–Pb ID-TIMS age of 1379.6 Ma (MSWD = 1.3) obtained with an accuracy of ±2.9 Ma (confidence interval 95%) combined with the available published U–Pb ID-TIMS data constrain the age and duration of the Early–Middle Riphean pulse in the LIP formation in the Southern Urals.     

Formation Conditions of Ferromagnesian Metasomatic Carbonates in the Lower Riphean Terrigenous–Carbonate Rocks of the Southern Urals

Lithology and Mineral Resources - Ferromagnesian carbonate metasomatites in limestones of the Lower Riphean Suran Formation in the Avzyan ore region (Bashkir meganticlinorium) are represented by...     

Dispersed Organic Matter in Riphean Carbonate–terrigenous Sediments of the Kuzha Complex (Bashkirian Uplift, Southern Urals)

Regularities of the localization of dispersed organic matter in rhythmitic and carbonate members of the upper sequence of the Biktimir Formation were revealed by studying sections of the Middle Riphean sediments within the eastern limb of the Yurmatau Anticlinorium. This work presents the quantitative estimation of C_org content in lithological rock types and morphostructural features of carbonaceous inclusions and sulfide mineralization. The sedimentogenic–biogenic nature of organic matter and indications of gold mineralization in the host sedimentary rocks were revealed.     

The Influence of the Ufimian Tectonic Concentric Structure on the Hydrocarbon Migration and Ore Genesis

The Ufimian tectonic concentric structure (UTC) is a regional structure with concentric and zonal structure of the internal gravity field. In the Neoproterozoic this structure was at higher hypsometric level relative to the Bashkir Meganticlinorium. The most significant uplift of this tectonic concentric structure happened at the beginning of the Karatau time (~825 Ma) and was accompanied by the formation of a ring fractured zone, favorable for hydrocarbon migration from the Lower Riphean black shales. Due to this, bitumens with higher Mo content in the Neoproterozoic and Paleozoic deposits are confined spatially to this zone. The bitumenosity of the Neoproterozoic deposits on the southern slope of the Ufimian tectonic concentric structure could have contributed to the formation of complex Cu–Ag–Mo–Re ores (copper sands) at the upper boundary of terrigenous red deposits of the Zilmerdak Formation. Positive structures identified in the Neoproterozoic deposits near the margin of the Ufimian tectonic concentric structure are considered to be promising for searching for hydrocarbon fields.     

The late Neoproterozoic Enganepe ophiolite, Polar Urals, Russia: An extension of the Cadomian arc?

The Enganepe ophiolite, Polar Urals was formed at 670 Ma and records a diverse geochemical association of tholeiite, arc-tholeiite, adakite, and OIB-like lithologies. This constrains the tectonic setting of the protolith of the ophiolite to an oceanic island-arc, with ridge-trench interaction most readily explaining the diverse compositions. The initiation of intra-ocean subduction and the development of the Enganepe island arc off the eastern margin of Baltica probably pre-dated the formation of the Enganepe ophiolite, i.e. prior to 670 Ma. The timing of island-arc magmatism is similar in age to that recorded off Avalon in the Cadomian arc. We propose that the active margin of Baltica in the Vendian is an extension of the Cadomian arc. This requires the northeast margin of Baltica (present-day coordinates) to have been in a southerly position in the Vendian, in agreement with proposed tectonic reconstructions. Consequently, the post-Rodinia continental amalgamation, Pannotia, had active ocean-continent convergence along its entire southerly (west Avalonia and Amazonian cratons) margin at the time of its break-up.     

Geochemical specialization of terrigenous deposits of the Bashkirian meganticlinorium

The materials on the geology and geochemical specialization of Riphean terrigenous rocks of the Bashkirian meganticlinorium, including carbonaceous shale and conglomerate, are reported. Conglomerate is characterized by a high concentration of Au and PGEs mostly related to intensely dislocated zones. It is concluded that potentially ore-bearing zones in terrigenous deposits of the Bashkirian meganticlinorium were formed as a result of multistage polygene processes controlled by the Riphean–Vendian geodynamic evolution of the region.     

Sedimentary complexes of the cover of the Dzabkhan continental block: Different sedimentary basins and source areas

The geochemical and Sm–Nd isotope characteristics of Late Precambrian and Early Cambrian sandstones previously related to the sedimentary cover of the Dzabkhan continental block are reported. It is established that the Riphean and Vendian sedimentary rocks of the Ul’zitgol’skaya and Tsaganolomskaya Formations were accumulated within the Dzabkhan continental block as a result of recycling of the terrigenous deposits formed at the expense of destruction of basement rocks and younger granite. The formation of terrigenous rocks of the Bayangol’skaya Formation after a gap in sedimentation occurred in the sedimentary basin, where only the Late Riphean formations of the juvenile crust, probably of the Dzabkhan–Mandal block were the sources, without the contribution of the ancient crustal material. The Tsaganolomskaya and Bayangol’skaya Formations were formed in different sedimentary basins and cannot be related to the same complex.     

Burial and thermal history of the West Bashkirian sedimentary basins

The GALO system is applied to the numerical reconstruction of burial and thermal histories of the West Bashkirian lithosphere from the Riphean to the present. An analysis of the variation in tectonic subsidence of the basin during its development is utilized to estimate approximately the mantle heat flow variations. Our variant of basin evolution suggests that after cooling in the Early Riphean, the rather weak thermal reactivations have not led to considerable heating of the lithosphere in the study region. Surface heat flow decreased from relatively high values in the Early Riphean (60–70 mW/m² in the eastern area and 40–50 mW/m² in the western part) to present-day values of 32–40 mW/m². In spite of the relatively low temperature regime of the basin as a whole, a syn-rifting deposition of more than 10 km of limestone, shale and sandstone in the Riphean resulted in rather high temperatures (180–190 °C) at the base of present-day sedimentary blanket in the eastern area. In agreement with the observed data, computed present-day heat flow through the sediment surface increases slightly from 32 to 34 mW/m² near the west boundary of the region to 42 mW/m² near the boundary of the Ural Foldbelt, whereas the heat flow through the basement surface decreases slightly from 28–32 to 24–26 mW/m² in the same direction. The mantle heat flow is only 11.3–12.7 mW/m², which is considerable lower than mean heat flow of the Russian Platform (16–18 mW/m²) and comparable with the low heat flow of Precambrian shields.