Geocheemical variations in a suite of granitoids and gabbros from Southland,New Zealand

The Longwoods Complex of Southland, New Zealand is part of an extensive terrane consisting of intrusives, volcanics, and sediments, which outcrops in the southern and north-western portions of the South Island. This terrane represents a volcanic arc which was active from Permian to Jurassic times (Grindley, 1958; Challis, 1968, 1969; Coombs et al., 1976). Between Pahia Point and Oraka Point on the southern coast of the South Island a section across the Longwoods Complex is well exposed and intrusives ranging in composition from ultrabasic cumulate rock, high-Al gabbro and gabbroic diorite to quartz diorite and granite outcrop. Two models have been considered for the origin of the rocks of the Pahia Point-Oraka Point section: (a) the rocks constitute one suite, the members of which are related by a crystal fractionation process; (b) the rocks constitute two suites which are not directly related. The ultrabasic rocks, and quartz diorites are complementary and are derived from a high-Al gabbro parent by crystal fractionation involving pyroxene, olivine, plagioclase and hornblende, but considerations of viscosity and the geochemistry of the granite preclude derivation of the high-Si rocks by continuation of the crystal fractionation model. Furthermore, the quartz-diorites are of two types: xenolith bearing foliated quartz-diorites and xenolith deficient unfoliated types. The latter rock type appears to group with the gabbros on variation diagrams and partitioning of Ti between mica and amphibole supports the view that two distinct suites of rocks are involved: (a) a suite derived by fractional crystallization from a high-Al gabbro parent and consisting of cumulate ultramafic rocks, high-Al gabbro, gabbroic diorite and quartz-diorite; (b) a suite of foliated quartz diorites, formed by partial melting of lower crustal igneous rocks. The xenoliths in the foliated quartz-diorites represent modified residue left after partial melting. Melt and residue have unmixed to varying degrees during diapiric rise and a range of compositions has resulted. The association of the two suites is tectonic. Gabbroic melts are generated in the lithosphere during plate subduction beneath a continental margin and rise of these melts into the lower continental crust results in partial melting and generation of quartz-diorite magmas.     

Geochemical comparison of woodlawn and mount painter acid volcanics,Southeastern Australia

Major‐ and trace‐element chemistry (including rare‐earth elements), total‐rock Rb‐Sr and U‐Pb and zircon U‐Pb data are used in an attempt to distinguish between two essentially coeval, felsic volcanic suites: the predominantly submarine Woodlawn suite which is associated with massive Cu‐Pb‐Zn sulphide mineralization and the terrestrial Mt Painter suite, with minor vein‐type mineralization. The Woodlawn samples are the unmineralized equivalents of the volcanics in the immediate ore environment.

Alteration perturbs some of the major‐ and trace‐element chemistry, particularly Ca and alkalis, thereby precluding their usefulness. REE patterns exhibit a significant light to heavy rare‐earth enrichment with an average La/Yb of 12 in the Mt Painter volcanics compared with 5.6 in the Woodlawn volcanics. Both suites have a marked negative Eu anomaly, with that of the Woodlawn samples more pronounced (‐45.5) than in the Mt Painter volcanics (‐29.2). A hydrothermally‐altered sample from Woodlawn has apparently lost about 50% of its light rare‐earth elements.

Initial ⁸⁷Sr/⁸⁶Sr ratios at about 0.711 are the same for rocks from both suites and differences in initial lead‐isotopic ratios appear negligible.

Zircons from both suites are a mixture of clear euhedral crystals and rounded discrete crystals or rounded cores overgrown by clear zircon. The U‐Pb data substantiate the morphological features in that the zircon suites both contain older inherited Pb but the Mt Painter zircons contain a greater proportion.

Cs concentrations and Cs/Rb and Ti/Zr ratios can be used to distinguish between the Woodlawn suite and the Mt Painter suite.     

Early Palaeozoic arc-related gabbro-diorite suite in East Junggar,southern Central Asian Orogenic Belt: petrogenesis and tectonic implications

ABSTRACT

The Armantai and Kalamaili oceans were both important branches of the Palaeo-Asian Ocean between the Altai microcontinent and the Junggar juvenile crust; however, their geological evolution is not completely clear. This paper reports detailed petrological, zircon geochronological, whole-rock elemental and Sr-Nd-Pb isotopic data for a newly discovered gabbro-diorite suite (Akputo pluton) in East Junggar to constrain this issue. Quartz diorite and hornblende gabbro yield intrusion ²⁰⁶Pb/²³⁸U ages of ca. 444–440 Ma, which indicates that mafic-intermediate magmatism occurred in the earliest Silurian. The gabbroic-dioritic rocks have tholeiite to calc-alkaline affinities and are characterised by moderately fractionated rare earth element patterns with flat heavy rare earth elements, enrichment in Rb, Ba, K, Sr, and depletion in Nb, Ta, Ti. Low initial Sr and Pb isotopic compositions and positive ε_Nd(t) indicate a derivation from the isotopically depleted mantle sources. The geochemical compositions and melting calculations suggest that the gabbro-diorite suite originated from partial melting of spinel-bearing mantle sources that had been metasomatised by subduction-derived fluids and sediments. The Akputo intrusions formed in an arc setting related to the southward subduction of the Armantai Ocean. Taking the regional angular unconformity between the Ordovician sediments and Silurian volcanics into account, we further suggest that the Early to Middle Silurian was a transition period of the closure of Armantai Ocean and the initial spreading of Kalamaili Ocean.     

Utilization of SPOT 5 data for mapping gold mineralized diorite–tonalite intrusion,Bulghah gold mine area,Saudi Arabia

The present study utilizes the processed SPOT 5 data to discriminate and to generate 1:10,000 geologic image map to delineate the mineralized diorite–tonalite intrusion around Bulghah gold mine area, Saudi Arabia. The rock units exposed in the area include gossan, marble, Hulayfah volcanics, diorite–tonalite, gneissose granite, and alkali granite. Gold mineralization at Bulghah mine is hosted mainly by Syn- to Late-tectonic diorite–tonalite intrusion aligned along N–S direction and is associated mainly with cataclastic zones and quartz veins. Gossans and jasparoidal gossans (Hulayfah group), recorded at the western side of Bulghah mine area as discontinuous small lenses, can be easily discriminated on 4/2 and 4/3 band ratio SPOT images by their white and black image signatures, respectively. Granitoids (gneissose granite and alkali granite) are easily discriminated in 3/2 ratio image, in which gneissose granite has gray image signature, whereas alkali granite has dark gray image signature. On the SPOT false color composite band ratios image (3/2 R, 4/2 G, and 4/3 B), gossan, marble, Hulayfah volcanics, diorite–tonalite, gneissose granite, and alkali granite have sky blue, blood red, bluish light brown, orange, brick red, and deep blue colors, respectively. Fusion of the false color composite SPOT ratios image (3/2 R, 4/2 G, and 4/3 B) with the high spatial resolution SPOT pan image is performed using IHS transformation method. The fused image is used to delineate the mineralized diorite–tonalite intrusion and to produce 1:10,000 geologic image map for Bulghah gold mine area. The present study reveals the usefulness of the processed SPOT 5 data for adding new extensions at the southern and northern boundaries of diorite–tonalite intrusion.     

The high-K diorites and associated rocks of the Yeoval diorite complex,N.S.W.

Field relationships, petrography and chemistry (including selected trace elements) of an occurrence of high-K diorite from Yeoval, N.S.W., Australia, are described. The Yeoval diorite complex is a calc-alkaline suite of rocks ranging from gabbros through diorites to granites with an association of fine-grained types. The dominant type of diorite is high in potassium (>2% K₂O) and their classification is based mainly on chemical data rather than conventional petrography. As such the high-K diorites may be correlated with the high-K andesites of orogenic regions. Comparisons with occurrences of high-K andesites are made. Data are presented to show that the gabbros and diorites are genetically related whereas no relation between the diorites and granites can be established.     

扬子板块北缘新元古代构造属性的岩浆事件制约

黄陵地区新元古代侵入杂岩可为研究扬子板块北缘新元古代构造演化过程及其深部动力学机制提供关键信息。依据岩石组合及分布特征,可将黄陵杂岩划分为黄陵庙岩套、三斗坪岩套、大老岭岩套和晓峰岩套四个单元。本文以黄陵杂岩的围岩崆岭杂岩中花岗片麻岩、黄陵庙黑云母花岗岩和三斗坪闪长岩为研究对象,在系统的野外地质和岩石学研究基础上,开展了LA-ICP-MS锆石U-Pb年代学分析。结果表明,崆岭杂岩花岗片麻岩原岩年龄为1978±13 Ma,且记录了2.5 Ga的构造-热事件。黄陵庙黑云母花岗岩和三斗坪闪长岩分别形成于815±9 Ma和813±6 Ma,与黄陵庙岩套和三斗坪岩套的侵位时限基本一致。综合分析本次研究结果与前人资料,认为黄陵杂岩主要形成于863～794 Ma,为新元古代早期岩浆活动的产物。通过综述区域地质和地球化学研究资料,认为黄陵杂岩形成于新元古代早期活动大陆边缘的构造环境,提出扬子板块北缘在新元古代早期经历了长期的俯冲-增生造山过程。     

Late Palaeoproterozoic post-collisional magmatism in the North China Craton: geochemistry,zircon U–Pb geochronology,and Hf isotope of the pyroxenite–gabbro–diorite suite from Xinghe,Inner Mongolia

The North China Craton (NCC) witnessed a prolonged subduction–accretion history from the early to late Palaeoproterozoic, culminating with final collision at ca. 1.85 Ga and assembling the continental blocks into the cratonic framework. Subsequently, widespread post-collisional magmatism occurred, particularly along the Trans-North China Orogen (TNCO) that sutures the Eastern and Western blocks of the NCC. Here we present petrological, geochemical, and zircon U–Pb geochronological and Lu–Hf data from a pyroxenite (websterite)–gabbro–diorite suite at Xinghe in Inner Mongolia along the northern segment of the TNCO. The internal structures and high Th/U values of the zircons from the gabbro–diorite suite suggest magmatic crystallization. LA-ICP-MS U–Pb age data on three gabbros and one diorite from the suite yield emplacement ages of 1786.1 ± 4.8, 1783 ± 15 ,1754 ± 16 and 1767 ± 13 Ma, respectively. The ε_Hf(t) shows mostly positive values (up to 5.8), with the lowest value at –4.2, suggesting that the magma was derived from dominantly juvenile sources. The generally low SiO₂ and high MgO values, and other trace element features of the Xinghe suite are consistent with fractionation from a mantle-derived magma with a broadly E-MORB affinity, with no significant crustal contamination. Recent studies clearly establish that the major magmatic pulse associated with rifting of the NCC within the Columbia supercontinent occurred in the late Mesoproterozoic at ca. 1.3–1.2 Ga associated with mantle plume activity. This, together with the lack of robust geochemical imprints of rift-related magmatism in the Xinghe suite, prompts us to suggest a tectonic model that envisages magma genesis associated with post-collisional extension during slab break-off, following the westward subduction of the Eastern Block and its collision with the Western Block. The resulting asthenospheric upwelling and heat input might have triggered the magma generation from a heterogeneous, subduction-modified sub-lithospheric mantle source for the Xinghe rocks, as well as for similar late Palaeoproterozoic suites in the TNCO.     

Geochemistry and origin of hornblende‐bearing xenoliths in the I‐type Petford Granite,North‐East Queensland

Hornblende‐bearing xenoliths in the I‐type Petford Granite, north‐east Queensland, show an abundance pattern suggesting redistribution in a convecting magma system and were probably carried up with the host magma. The Petford Granite and xenoliths are chemically cognate, but quartz monzodiorite‐granodiorite bodies (a potential source for the xenoliths) in the adjacent country rocks belong to an independent magma suite. The xenoliths are chemically similar to andesite lavas and dykes 90 km to the NW. They represent fragments of the parental andesite (diorite) of a calcalkaline suite, which fractionated to yield the Petford Granite. They are not source rocks for the granite melt, melt residua, or early cumulates. The fractionated granite melt broke through the earlier envelope of diorite and rose into the upper crust, carrying dioritic fragments with it. Interaction between magma and xenoliths was generally minimal.     

浙东南某些中生代侵入岩体的^40Ar—^39Ar年龄测定

采用~(40)Ar~(39)Ar定年技术测定了浙东南几个侵入于磨石山群中的燕山期中酸性岩侵入体的年龄。梁弄岩体的石英闪长岩和二长花岗岩的年龄为101Ma,龙王堂岩体的花岗岩和钾长花岗岩的年龄均为110Ma,山头郑石英闪长岩年龄为108Ma,洪公石英正长岩的年龄为124Ma。此年龄范围与早白垩世太平洋洋底快速扩张期相当。     

Geochemistry of Proterozoic volcanic and granitic rocks from the Gold Hill-Wheeler Peak area,northern New Mexico

Early Proterozoic supracrustal and plutonic rocks from the Gold Hill-Wheeler Peak area in northern New Mexico define three populations: amphibolite—diorite—tonalite, hornblendite—cumulus amphibolite and felsic volcanics and porphyries. Also present are mid-Proterozoic granites. Amphibolites are similar in Ti, Zr, Cr, Ni and REE contents to young calc-alkaline and arc basalts and diorites and tonalites are similar in composition to young andesites and to high-Al₂O₃ tonalites, respectively. Felsic volcanics resemble young felsic volcanics from mature arc systems in their immobile-element contents. Geochemical model studies suggest that the amphibolites, hornblendites, diorites and tonalites are related by progressive fractional crystallization of a hydrous parent tholeiite magma produced from partial melting of undepleted lherzolite. Amphibolites represent parent tholeiites modified by olivine removal. Hornblendite is an early solid residue comprised chiefly of hornblende, clinopyroxene, and olivine; diorite and cumulus amphibolite represent respectively residual solid (clinopyroxene, plagioclase, hornblende) and liquid, after 50% crystallization. Tonalite represents a residual liquid after 80% crystallization. Felsic volcanic rocks are produced by partial melting of a tonalite or diorite source with granulite-facies mineralogy in the lower crust. Granites have a similar origin to felsic volcanics although requiring an inhomogeneous source with the presence of residual hornblende or garnet.The calc-alkaline igneous rocks in the Gold Hill-Wheeler Peak area suggest the presence of an arc system in northern New Mexico during the Early Proterozoic. The fact that these rocks interfinger with and are overlain by mature clastic sediments favors a model in which a continental arc system is uplited, eroded and buried by cratonic sediments from the north.     

Geochronological and geochemical constraints on the genesis of the Tieshan complex in the Edong district,Eastern China with implications for Fe and Cu skarn mineralization

Fe and Cu skarn deposits constitute the most important skarn type worldwide, whereas the controlling factors that lead to the difference in metal associations remain not well known. The Fe- and Cu-hosting Tieshan complex in the Edong district provides a good opportunity for comparative study on the genetic differences between Fe and Cu skarn deposits. In this study, integrated studies of geochronology, geochemistry and Sr-Nd-Hf isotope compositions were conducted on the complex. LA-ICP-MS zircon U-Pb dating results show that the Tieshan complex was emplaced in the time interval of 135 ± 3 to 144 ± 1 Ma. Multiphase rocks from the complex can be broadly subdivided into two suites. The Fe-Cu-related suite, which consists of diopside diorite, quartz diorite, quartz diorite porphyrite and porphyritic granodiorite, possesses low SiO₂ (53.5–67.1 wt.%), K₂O (2.44–3.53 wt.%) and Rb (45−83 ppm) contents, but high Sr (1132−2684 ppm), Ba (1073−1656 ppm) contents and negligible Eu anomalies, with very high Sr/Y (>90) ratios, similar to typical high Ba-Sr granitoids. The rock suite has initial ⁸⁷Sr/⁸⁶Sr values of 0.70648 to 0.70737, ε_Nd(t) values of −12.3 to −8.2 and ε_Hf(t) values of −16 to −7, comparable to values of the Early Cretaceous mafic rocks in the Edong district and adjacent areas, indicating that it might be largely derived from an enriched lithospheric mantle source, along with minor involvement of lower-crustal components. By contrast, the Fe-related suite, which is composed of quartz diorite, quartz diorite porphyrite and granodiorite porphyry, is characterized by relatively high SiO₂ (63.0–71.0 wt.%) and K₂O contents (3.36–5.53 wt.%), and a wide range of Sr (158−1135 ppm), Ba (762−1366 ppm) contents and Sr/Y (11–99) ratios. In combination with the presence of abundant inherited zircon grains, the lower ε_Nd(t) (−12.4 to −9.3) and ε_Hf(t) (−25 to −15) values indicate a greater degree of lower-crustal contribution for the Fe-related suite. In addition, the calculated zircon Ce (Ce/Ce* and Ce⁴⁺/Ce³⁺) and Eu (Eu/Eu*) anomalies suggest that the Fe-Cu-related suite has much higher oxygen fugacity (fO₂) than the Fe-related suite. This study highlights fO₂ and fractionation degree of magma as useful indicators for differentiating Fe and Cu skarn mineralization.     

新疆昭苏卡拉盖雷铜钴金矿区岩石地球化学特征

卡拉盖雷铜钴金矿是那拉提构造带内发现的首例以Cu为主,伴生Mo,Co,Au,Pb,Zn的火山岩型热液矿床.矿区内出露的地层主要为石炭系下统大哈拉军山组火山岩地层,矿区岩浆岩主要有花岗闪长岩、闪长岩和辉绿岩脉.通过火山岩地层和侵入岩样品的地球化学分析,认为区内大哈拉军山组是一套由玄武岩、安山岩、英安岩、流纹岩组成的连续亚碱性的火山岩系列,且以钙碱性系列为主;矿区钾长花岗岩属于准铝质—过铝质岩类,碱性系列,花岗闪长岩和闪长岩属于准铝质—过铝质岩类,钙碱性—碱性系列,基性侵入岩属于弱碱性—碱性系列.稀土元素特征显示中酸性侵入岩可能属于地壳重熔型花岗岩;基性侵入岩与基性火山岩来源一致.     

Field and geochemical characteristics of the Coolac Ophiolite suite and its possible origin in a marginal sea

Geological and geochemical data from the Coolac Serpentinite Belt, North Mooney Complex and Honeysuckle Beds in southern New South Wales indicate that the association represents a partially dismembered ophiolite suite. All the ideal ophiolite units are present, although the sheeted dyke unit is apparently of limited extent. Major and trace element (including rare‐earth) results, relationships of mafic volcanics and dolerite to massive and layered gabbroic and ultramafic intrusives, the occurrence of tectonised harzburgite with podiform chromitite, and the nature of pyritic sulphide occurrences, are consistent with a marginal sea or back‐arc environment for the generation of the ophiolite suite.     

Interpretation of field relationships of Diorites and associated rocks with particular reference to northwest Guernsey,Channel Islands

In northwest Guernsey, excellently exposed sections of coast reveal a wide variety of diorites and associated rocks which are particulariy instructive in understanding field relationships in diorite complexes generally. In this area, three groups of rocks may be distinguished. A Diorite Group consists of even grained diorite, acicular diorite and appinite, believed to be related to each other by fractionation. This group was intruded by a Granodiorite Group which contains diorite xenoliths. In turn, both of these were intruded by an Inhomogeneous Suite of rocks varying from meladiorite through to tonalite. Field evidence and geochemistry show that this last, highly variable suite of rocks was formed by the unusual process of fractional crystallization coupled with disruption and partial redigestion of early solid fractionates by derivative liquids, leading to the marked inhomogeneity. Such a mechanism may be more generally applicable but clear evidence for it seems to be restricted to rocks of dioritic composition. The margins of the Inhomogeneous Suite usually consist of tonalite which has piped into the surrounding diorites of the Diorite Group, and the two rock groups are thought to have been at least partially liquid at the same time. The exact shape of pipes may prove to be a useful indicator of physicai conditions at the time of magma emplacement in this and other intimate associations of magmas of contrasted composition. Although the Diorite Group was emplaced first, dark (apparently chilled) margins sometimes occur in diorites of this Group where they are in contact with the later Inhomogeneous Suite. In such intimate associations as this, dark margins must be interpreted with extreme caution.     

An example of post-collisional appinitic magmatism with an arc-like signature: the Wadi Nasb mafic intrusion,north Arabian–Nubian Shield,south Sinai,Egypt

We present new data for the Neoproterozoic mafic intrusion exposed in Wadi Nasb, south Sinai, Egypt (northernmost Arabian–Nubian Shield; ANS). The Nasb mafic intrusion (NMI) intrudes metasediments, Rutig volcanics, and diorite/granodiorite, and is intruded in turn by younger monzogranite and quartz-monzonite. Available geochronological data for the country rocks of the NMI provide a tight constraint on its age, between 619 and 610 Ma, during the hiatus between the lower and upper Rutig volcanics. The NMI is neither deformed nor metamorphosed, indicating post-collisional emplacement, and uralitization by late-magmatic and sub-solidus alteration is restricted to the margins of the intrusion. A quantitative fractionation model indicates a fractionating assemblage of 61% primary amphibole, 10% clinopyroxene, 28% plagioclase, 1% biotite, 0.4% apatite, and 0.15% Fe-Ti oxide. Contrary to the recent studies, we find that the nearby diorite of Gebel Sheikh El-Arab is not co-genetic with the appinitic gabbro of the NMI. Although there are volcanic xenoliths in the NMI, we find no chemical evidence requiring contamination by continental crust. A subduction-related signature in a post-orogenic intrusion requires the inheritance of geochemical tendencies from a previous subduction phase. Given that the fine-grained gabbro of the NMI is consistent with a near-primary mantle melt, we attribute this inheritance to persistence and later melting of the slab-modified mantle domains, as opposed to partial melting and assimilation of the juvenile continental crust. The fine-grained gabbro composition indicates derivation at temperature and pressure conditions similar to the sources of mid-ocean ridge basalts: mantle potential temperature near 1350°C and extent of melting about 7%. Such temperatures, neither so high as to require a plume nor so low as to be consistent with small degrees of melting of a volatile-rich source, are most consistent with a lithospheric delamination scenario, allowing the upwelling of fertile, subduction-modified asthenosphere to depths ≤50 km.     

内蒙古西乌旗南部石炭纪石英闪长岩地球化学特征及其构造意义

内蒙古西乌旗地区位于贺根山蛇缘岩带和西拉木伦缝合带之间,区内岩浆岩分布广泛。本文对达其浑迪和金星石英闪长岩进行了锆石LAICPMS UPb定年,结果表明两个岩体分别形成于325±3Ma和322±3Ma。岩石学和地球化学分析结果显示岩石属于低钾拉斑系列和钙碱性系列,相对富集Rb、Ba、K等大离子亲石元素（LILE）,亏损Nb、Ta、Ti、P等高场强元素化学。地球化学成分表明岩体具有俯冲带成因的特征。通过区域对比分析,苏左旗和西乌旗地区均发育一套角闪闪长岩、石英闪长岩、英云闪长岩及花岗闪长岩组合,与岛弧和活动大陆边缘岩浆岩组合相似,共同构成早石炭世晚期到晚石炭世的岩浆弧,该岩浆弧的出现与古亚洲洋板片向北俯冲有关。     

Volcanic facies and mineral chemistry of Tertiary volcanics in the northern part of the Eastern Pontides,northeast Turkey: implications for pre-eruptive crystallization conditions and magma chamber processes

Tertiary volcanics in the northern zone of the Eastern Pontides are characterized by subaerial and shallow-subaqueous facieses, and are divided into three volcanic suites: Eocene aged (1) basalt-trachybasalt-basaltic trachyandesite (BTB) and (2) trachyte-trachyandesite (TT), and Miocene aged (3) basanite-tephrite (BT) suites. Clinopyroxene is a common phase in all three volcanic suites, and has different compositions with Mg# varying from 0.57 to 0.91 in BTB suite and 0.57–0.84 in TT suite to 0.65–0.90 in BT suite. Feldspars in all suites generally exhibit wide range of compositions from sanidine to albite or anorthite and have weak normal and reverse compositional zoning. Olivines in BTB and BT suites have Fo_60–92. Hornblendes in BTB, TT and BT suites are commonly magnesio-hastingsite and rare pargasite in composition (Mg#: 0.67–0.90). Brown mica is mainly phlogopite with Mg# ranging from 0.56 to 0.92 in the BTB suite, 0.59–0.84 in the TT suite, and 0.75–0.93 in the BT suite. Analcime is present only in the BT suite rocks. Fe–Ti oxides in all suites are mainly composed of magnetite and titanomagnetite. Textural petrographic and mineral chemical data suggest that magmas had undergone hydrous and anhydrous crystallizations in deep-, mid-, and shallow-crustal magma chambers. Clinopyroxene thermobarometric calculations show that Eocene magma chambers were characterized by temperature ranging from 1,100 to 1,244 °C and pressure ranging from 1.84 to 5.39 kbar. Similarly, the Miocene magma chambers were characterized by temperature ranging from 1,119 to 1,146 °C and pressure ranging from 4.23 to 4.93 kbar. Hornblende thermobarometry, oxygen fugacity, and hygrometer reveal that the crystallization temperature of Eocene volcanics range from 956 to 959 °C at pressure ranging from 6.49 to 6.52 kbar. Eocene volcanics were characterized by water content ranging from 7.83 to 8.57 wt.% and oxygen fugacity of 10^?9.36 to 10^?9.46 (ΔNNO+2). Miocene volcanics had crystallization temperature ranging from 970 to 978 °C at pressure ranging from 8.70 to 9.00 kbar with water content ranging from 8.04 to 8.64 wt.% and oxygen fugacity ranging from 10^?8.75 to 10^?8.87 (ΔNNO+2). Brown mica thermobarometric data show that Eocene volcanics were characterized by relatively high oxygen fugacity varying from 10^-10.32 to 10^-12.37 (HM) at temperature ranging from 858 to 953 °C and pressure ranging from 1.08 to 1.41 kbar. Miocene volcanics were crystallized at highly oxidized conditions, which are characterized by high oxygen fugacity of 10^?12.0 (HM) at temperature of 875 °C and pressure of 2.09 kbar. The wide range of obtained temperatures for clinopyroxenes of the suites denotes that the equilibration of clinopyroxene crystals initiates from depth until close to the surface before magma eruption. The compositional variations, resorbed core and reverse zoning patterns in clinopyroxene phenocrysts, as well as variable pressures of crystallization, further indicate that the magmas that formed the suites were polybaric in origins and were composite products of more than one petrogenetic stage. The observed range of phenocryst assemblage and different compositional trends possibly originated from fractionation of magmas with different initial water contents under variable pressures of crystallization. The repeated occurrence of magmas from different suites during a single period of activity suggests that the magmatic system consists of several conduit systems and that magma reservoirs are dispersed at different levels of crustal magma chambers.     

黄陵花岗岩基的成因

黄陵花岗岩基位于扬子地台北缘，它连同汉南和鲤鱼寨岩基一起构成扬子地台北缘的低钾花岗岩等，形成于晋宁晚期扬子地台北侧的“秦岭洋”壳向南俯冲导致的大陆边缘造山运动过程中。黄陵花岗岩基可解体为三斗坪、黄陵庙、大老岭、晓峰4个岩套和14个单元，侵位于832－750Ma之间。三斗坪和黄陵庙两个岩套主要由英云闪长岩、奥长花岗岩花岗闪地组成，是在近南北向区域挤压下于约16km深部塑性域定位的同构造花岗岩，前者主要依靠岩浆在构造弱面逐次强力楔入创造定位空间，后者主要在处于活动状态的韧性拉张剪切带内定位。钙碱性系列的大老岭和晓峰岩套则是在本区地壳迅速隆起过程中分别在5km和＜1．5km深度的脆性域定位的构造晚期花岗岩。根据岩石化学和同位素组成推断，三斗坪岩套的源岩主要是晚太古代大陆拉斑玄武岩，母岩浆相当于英安质，岩套内的成分变化主要受角闪石分离结晶作用控制；黄陵庙岩套除受分离结晶作用影响外，成分变化主要与英安质母岩浆和某种长英质岩浆的混合有关；大老岭岩套的源岩亦为早前寒武纪火山岩。     

The Archaean High-Mg Diorite Suite: Links to Tonalite-Trondhjemite-Granodiorite Magmatism and Implications for Early Archaean Crustal Growth

The 2·95 Ga Pilbara high-Mg diorite suite intrudes thecentral part of the Archaean granite–greenstone terrainof the Pilbara Craton, Western Australia, and shows many featurestypical of high-Mg diorite (sanukitoid) suites from other lateArchaean terrains. Such suites form a minor component of Archaeanfelsic crust. They are typically emplaced in late- to post-kinematicsettings, sometimes in association with felsic alkaline magmatism,and are either unaccompanied by, or post-date, tonalite–trondhjemite–granodiorite(TTG) magmatism, which comprises a much greater proportion ofArchaean felsic crust. The TTG series comprises sodic, Sr-richrocks with high La/Yb and Sr/Y ratios, thought to result frompartial melting of eclogite facies basaltic crust. High-Mg dioriteshares these characteristics but has significantly higher mg-number(     

Geology, Geochemistry and Tectonic Significance of Mafic-ultramafic Rocks of Mesoproterozoic Phulad Ophiolite Suite of South Delhi Fold Belt, NW Indian Shield

A thick sequence of mafic-ultramafic rocks, occurs along a major shear zone (Phulad lineament), running across the length of Aravalli Mountain Range for about 300 kms. It has been suggested, that this sequence may represent a fragment of ophiolite or a rift related metavolcanic suite made up of basalts and fractionated ultramafics. The geological and tectonic significance of the complex is assessed using field relationships, petrography and geochemistry. Structurally, the lowest part of the complex comprises a discontinuous band of plastically deformed harzburgite (mantle component) followed by layered cumulus gabbroic rocks (crustal component). A complex of non-cumulus rocks comprising hornblende schists, gabbros, sheeted dykes and pillowed basalts structurally overlies layered gabbros. Huge bodies of diorite intrude volcanics.

Geochemical classification suggests that all non-cumulus mafic rocks are sub-alkaline basalts except one variety of dykes which shows mildly alkaline character. The sub-alkaline rocks are tholeiite to calc-alkaline with boninite affinity. Tectono-magmatic variation diagrams and MORB normalised patterns suggest a fore arc tectonic regime for the eruption of these rocks.

The mafic rocks of Phulad Ophiolite Suite are zoned across the strike in terms of their distribution from west to east. The hornblende schists and basalts are exposed at the westernmost margin followed by gabbros and dykes. The alkaline dyke occurs at the easternmost part. The rocks of Phulad suite are juxtaposed with shallow water sediments in the east followed by platformal sediments and then continental slope sediments in the further east indicating gradual thickening of the crust from west to east and an eastward subduction. The geochemical interpretation presented in this study, together with discussion of lithological association is used to decipher the tectonic evolution of the Mesoproterozoics of NW Indian shield.