The content and stable isotopic composition of carbon in individual micrometeorites from Greenland and Antarctica

Abstract— The C contents and δ¹³C values of eleven individual micrometeorites have been determined using a combination of stepped combustion and static mass spectrometry. A new low-blank procedure, involving pretreatment of the samples with a solvent to remove surficial contaminants, has enabled samples of 6–84 μg to be analysed successfully. The eleven samples (seven separated from Greenland cryoconite and four from Antarctic ice) were each split prior to C determination and a fragment taken for study using analytical electron microscopy. In this way, the chemical compositions were obtained thereby allowing comparison with other investigations. As with previous studies of micrometeorites collected at the Earth's surface, the major difficulty with interpreting the results involves distinguishing indigenous components from terrestrial contaminants. Overall C contents were typically <0.2 wt%, although one of the Greenland samples contained 1.5 wt% C, considered to arise mainly from algal contamination. For the other samples, around 0.05–0.15 wt% of the total C in each micrometeorite was considered to be organic in nature with at least some of this (if not all) being terrestrial in origin; the remainder was probably indigenous, being analogous to the macromolecular organic material found in primitive carbonaceous chondrites. The generally low content of this indigenous organic material, compared to conventional meteorites, is presumably a reflection of C loss from the micrometeorites either during atmospheric heating, or subsequent weathering. For that C combusting between 500 and 600 °C, ten of the samples appeared to show a simple two-component system (i.e., a mixture of blank and an isotopically light component; δ¹³C > ?32%). It is possible that the light component is C_δ, a fine-grained form of presolar diamond which is known to be prevalent in primitive chondritic meteorites. If so, then it is present in the micrometeorites at concentrations of ～30–600 ppm (typically 200 ppm), which is a similar level to that in meteorites. An analysis of algae separated from Greenland cryoconite shows tentative evidence for the presence of extraterrestrial silicon carbide; however, further work will be needed to substantiate this     

A composite Fe,Ni‐FeS and enstatite‐forsterite‐diopside‐glass vitrophyre clast in the Larkman Nunatak 04316 aubrite: Origin by pyroclastic volcanism

Abstract– We studied the mineralogy, petrology, and bulk, trace element, oxygen, and noble gas isotopic compositions of a composite clast approximately 20 mm in diameter discovered in the Larkman Nunatak (LAR) 04316 aubrite regolith breccia. The clast consists of two lithologies: One is a quench‐textured intergrowth of troilite with spottily zoned metallic Fe,Ni which forms a dendritic or cellular structure. The approximately 30 μm spacings between the Fe,Ni arms yield an estimated cooling rate of this lithology of approximately 25–30 °C s^?1. The other is a quench‐textured enstatite‐forsterite‐diopside‐glass vitrophyre lithology. The composition of the clast suggests that it formed at an exceptionally high degree of partial melting, perhaps approaching complete melting, and that the melts from which the composite clast crystallized were quenched from a temperature of approximately 1380–1400 °C at a rate of approximately 25–30 °C s^?1. The association of the two lithologies in a composite clast allows, for the first time, an estimation of the cooling rate of a silicate vitrophyre in an aubrite of approximately 25–30 °C s^?1. While we cannot completely rule out an impact origin of the clast, we present what we consider is very strong evidence that this composite clast is one of the elusive pyroclasts produced during pyroclastic volcanism on the aubrite parent body ( Wilson and Keil 1991 ). We further suggest that this clast was not ejected into space but retained on the aubrite parent body by virtue of the relatively large size of the clast of approximately 20 mm. Our modeling, taking into account the size of the clast, suggests that the aubrite parent body must have been between approximately 40 and 100 km in diameter, and that the melt from which the clast crystallized must have contained an estimated maximum range of allowed volatile mass fractions between approximately 500 and approximately 4500 ppm.     

Measurement of the OH rotational temperature at Mawson,East Antarctica

Measurements of the hydroxyl rotational temperature for the (8, 3) Meinel band are reported for observations made at Mawson, East Antarctica (67° 36′ S, 62° 53′ E) over the austral winter of 1979. Mean values of the rotational temperature are given for 54 nights. The average value lies in the range 160–170 K. The measured temperatures appear lower than those that have been reported at similar latitudes in the Northern Hemisphere. A gradual decrease in the value of the temperature throughout the course of the evening is the only diurnal trend observed. There is little evidence for any impulsive heating associated with auroral activity.     

Noble gas compositions of Antarctic micrometeorites collected at the Dome Fuji Station in 1996 and 1997

Abstract— The noble gases He, Ne, Ar, Kr, and Xe were measured in 27 individual Antarctic micrometeorites (AMMs) in the size range 60 to 250 μm that were collected at the Dome Fuji Station. Eleven of the AMMs were collected in 1996 (F96 series) and 16 were collected in 1997 (F97 series). One of the F97 AMMs is a totally melted spherule, whereas all other particles are irregular in shape. Noble gases were extracted using a Nd‐YAG continuous wave laser with an output power of 2.5‐3.5 W for ?5 min. Most particles released measurable amounts of noble gases. ³He/⁴He ratios are determined for 26 AMMs ((0.85‐9.65) × 10^?4). Solar energetic particles (SEP) are the dominant source of helium in most AMMs rather than solar wind (SW) and cosmogenic He. Three samples had higher ³He/⁴He ratios compared to that of SW, showing the presence of spallogenic ³He. The Ne isotopic composition of most AMMs resembled that of SEP as in the case of helium. Spallogenic ²¹Ne was detected in three samples, two of which had extremely long cosmic‐ray exposure ages (> 100 Ma), calculated by assuming solar cosmic‐ray (SCR) + galactic cosmic‐ray (GCR) production. These two particles may have come to Earth directly from the Kuiper Belt. Most AMMs had negligible amounts of cosmogenic ²¹ Ne and exposure ages of <1 Ma. ⁴⁰Ar/³⁶Ar ratios for all particles (3.9–289) were lower than that of the terrestrial atmosphere (296), indicating an extraterrestrial origin of part of the Ar with a very low ⁴⁰Ar/³⁶Ar ratio plus some atmospheric contamination. Indeed, ⁴⁰Ar/³⁶Ar ratios for the AMMs are higher than SW, SEP, and Q‐Ar values, which is explained by the presence of atmospheric ⁴⁰Ar. The average ³⁸Ar/³⁶Ar ratio of 24 AMMs (0.194) is slightly higher than the value of atmospheric or Q‐Ar, suggesting the presence of SEP‐Ar which has a relatively high ³⁸Ar/³⁶Ar ratio. According to the elemental compositions of the heavy noble gases, Dome Fuji AMMs can be classified into three groups: chondritic (eight particles), air‐affected (nine particles), and solar‐affected (eight particles). The eight AMMs classified as chondritic preserve the heavy noble gas composition of primordial trapped component due to lack of atmospheric adsorption and solar implantation. The average of ¹²⁹Xe/¹³²Xe ratio for the 16 AMMs not affected by atmospheric contamination (1.05) corresponds to the values in matrices of carbonaceous chondrites (?1.04). One AMM, F96DK038, has high ¹²⁹Xe/¹³²Xe in excess of this ratio. Our results imply that most Dome Fuji AMMs originally had chondritic heavy noble gas compositions, and carbonaceous chondrite‐like objects are appropriate candidate sources for most AMMs.     

Post-entry and volcanic contaminant abundances of zinc,copper, selenium,germanium and gallium in stratospheric micrometeorites

Abstract— Some fraction of Zn, Cu, Se, Ga and Ge in chondritic interplanetary dust particles (IDPs) collected in the lower stratosphere between 1981 May and 1984 June has a volcanic origin. I present a method to evaluate the extent of this unavoidable type of stratospheric contamination for individual particles. The mass-normalised abundances for Cu and Ge as a function of mass-normalised stratospheric residence time show their time-integrated stratospheric aerosol abundances. The Zn, Se and Ga abundances show a subdivision into two groups that span approximately two-year periods following the eruptions of the Mount St. Helens (1980 May) and El Chichón (1982 April) volcanos. Elemental abundances in particles collected at the end of each two-year period indicate low, but not necessarily ambient, volcanic stratospheric abundances. Using this time-integrated baseline, I calculate the stratospheric contaminant fractions in nine IDPs and show that Zn, Se and Ga abundances in chondritic IDPs derive in part from stratospheric aerosol contaminants. Post-entry elemental abundances (i.e., the amount that survived atmospheric entry heating of the IDP) show enrichments relative to the CI abundances but in a smaller number of particles than previously suggested.     

The characteristics of Pc 3 and Pc 4 geomagnetic micropulsations recorded at Sanae,Antarctica

Digital dynamic spectra of micropulsations recorded at SANAE (L ～ 4) show that Pc 3 pulsations have frequencies which decrease throughout the day. Both the onset frequency and the rate of decrease of frequency depend on the level of magnetic activity during the previous night. The variation of Pc 3 amplitudes and frequencies is explained in terms of the position of the plasmapause and the associated Pc 3 resonance region in the plasmatrough.For Pc 4 pulsations a constant frequency is observed on most days and it is not possible to infer the presence of a Pc 4 resonance region.     

Accumulation of particulate organic carbon at the Eurasian continental margin during late Quaternary times: controlling mechanisms and paleoenvironmental significance

Data on the amount and composition of organic carbon were determined in sediment cores from the Kara and Laptev Sea continental margin, representing oxygen isotope stages 1–6. The characterization of organic matter is based on hydrogen index (HI) values, n-alkanes and maceral composition, indicating the predominance of terrigenous organic matter through space and time. The variations in the amount and composition of organic carbon are mainly influenced by changes in fluvial sediment supply, Atlantic water inflow, and continental ice sheets. During oxygen isotope stage (OIS) 6, high organic carbon contents in sediments from the Laptev Sea and western East Siberian Sea continental margin were probably caused by the increased glacial erosion and further transport in the eastward-flowing boundary current along the continental margin. During OIS 5 and early OIS 3, some increased amounts of marine organic matter were preserved in sediments east of the Lomonosov Ridge, suggesting an influence of nutrient-rich Pacific waters. During OIS 2, terrigenous organic carbon supply was increased along the Barents and western Kara Sea continental margin caused by extended continental ice sheets in the Barents Sea (Svalbard to Franz Josef Land) area and increased glacial erosion. Along the Laptev Sea continental margin, on the other hand, the supply of terrigenous (organic) matter was significantly reduced due to the lack of major ice sheets and reduced river discharge. Towards the Holocene, the amount of total organic carbon (TOC) increased along the Kara and Laptev Sea continental margin, reaching average values of up to 0.5 g C cm⁻² ky⁻¹. Between about 8 and 10 ka (9 and 11 Cal ka), i.e., during times when the inner shallow Kara and Laptev seas became largely flooded for the first time after the Last Glacial Maximum, maximum supply of terrigenous organic carbon occurred, which is related to an increase in coastal erosion and Siberian river discharge. During the last 8000 years, the increased amount of marine organic carbon preserved in the sediments from the Kara and Laptev Sea continental margin is interpreted as a result of the intensification of Atlantic water inflow along the Eurasian continental margin.     

Bulk mineralogical changes of hydrous micrometeorites during heating in the upper atmosphere at temperatures below 1000 °C

Abstract— Small particles 200 μm in diameter from the hydrous carbonaceous chondrites Orgueil CI, Murchison CM2, and Tagish Lake were experimentally heated for short durations at subsolidus temperatures under controlled ambient pressures in order to examine the bulk mineralogical changes of hydrous micrometeorites during atmospheric entry. The three primitive meteorites consist mainly of various phyllosilicates and carbonates that are subject to decomposition at low temperatures, and thus the brief heating up to 1000 °C drastically changed the mineralogy. Changes included shrinkage of interlayer spacing of saponite due to loss of molecular water at 400–600 °C, serpentine and saponite decomposition to amorphous phases at 600 and 700 °C, respectively, decomposition of Mg‐Fe carbonate at 600 °C, recrystallization of secondary olivine and Fe oxide or metal at 700–800 °C, and recrystallization of secondary low‐Ca pyroxene at 800 °C. The ambient atmospheric pressures controlled species of secondary Fe phase: taenite at pressures lower than 10^?2 torr, magnesiowüstite from 10^?3 to 10^?1 torr, and magnetite from 10^?2 to 1 torr. The abundance of secondary low‐Ca pyroxene increases in the order of Murchison, Orgueil, and Tagish Lake, and the order corresponds to saponite abundance in samples prior to heating. Mineralogy of the three unmelted micrometeorites F96CI024, kw740052, and kw740054 were investigated in detail in order to estimate heating conditions. The results showed that they might have come from different parental objects, carbonaterich Tagish Lake type, carbonate‐poor Tagish Lake or CI type, and CM type, respectively, and experienced different peak temperatures, 600, 700, and 800?900 °C, respectively, at 60–80 km altitude upon atmospheric entry.     

Evidence for paleolakes in Erythraea Fossa, Mars: Implications for an ancient hydrological cycle

There is now widespread agreement that the surface of Mars underwent some degree of fluvial modification, but there is not yet full understanding of its surface hydrological cycle and the nature of standing bodies of water, rivers, and precipitation that affected its surface. In this paper we explore Erythraea Fossa (31.5 W, 27.3 S), a graben adjacent to Holden crater, which exhibits strong evidence that it once housed a chain of three lakes, had overland water flow, and was subject to precipitation. The inlet valley, outlet valley, and fan morphologies in the paleolakes are used to qualitatively discern the hydrologic history of the paleolakes; based on topography constraints, the three basins combined once held 56 km³ of water. Depositional features within the basins that change with drainage area and nearby valleys that start near drainage divides indicate that the paleolakes may have been fed by precipitation driven runoff. This suggests the presence of an atmosphere, at least locally, that was capable of supporting a hydrological cycle.     

Millochau crater, Mars: Infilling and erosion of an ancient highland impact crater

The geology and stratigraphy of Millochau crater (21.4° S, 275° W), located in the highlands of Tyrrhena Terra, Mars, are documented through geomorphic analyses and geologic mapping. Crater size-frequency distributions and superposition relationships are used to constrain relative ages of geologic units and determine the timing and duration of the geologic processes that modified Millochau rim materials and emplaced deposits on Millochau's floor. Crater size-frequency distributions show a Middle Noachian age for rim materials and Middle Noachian to Early Hesperian ages for most of the interior deposits. Valley networks and gullies incised within Millochau's rim materials and interior wall, respectively, indicate fluvial activity was an important erosional process. Millochau contains an interior plateau, offset northeast of Millochau's center, which rises up to 400 m above the surrounding crater floor and slopes downward to the south and west. Layers exposed along the northern and eastern scarp boundaries of the plateau are tens to hundreds of meters thick and laterally continuous in MOC images. These layers suggest most materials within Millochau were emplaced by sedimentary processes (e.g., fluvial or eolian), with the potential for lacustrine deposition in shallow transient bodies of water and contributions of volcanic airfall. Mass wasting may have also contributed significant quantities of material to Millochau's interior, especially to the deposits surrounding the plateau. Superposition relationships combined with impact crater statistics indicate that most deposition and erosion of Millochau's interior deposits is ancient, which implies that fluvial activity in this part of Tyrrhena Terra is much older than in the eastern Hellas region. Eolian processes mobilized sediment to form complicated patterns of long- and short-wavelength dunes, whose emplacement is controlled by local topography. These deposits are some of the youngest within Millochau (Amazonian) and eolian modification may be ongoing.     

COCHISE: the first light of the Italian millimetre telescope at Concordia (Dome C, Antarctica)

COCHISE (Cosmological Observations at Concordia with High-sensitivity Instrument for Source Extraction) is a 2.6 m telescope located on the high Antarctic Plateau near the Italian–French Concordia Base. The telescope is mainly devoted to Cosmological observations, able to operate between 200 μm and 3 mm of wavelength. In this paper we describe the main characteristics of the instrument. We also report on the first light, obtained during summer 2010–2011: this result marks the beginning of millimetre astrophysical observations at Concordia. Responsivity, noise equivalent temperature and field of view of the instrument are reported. At present COCHISE is the largest telescope located at Concordia. Beside the scientific expectations, the use of this kind of instrument in the Antarctic environment poses technological aspects of relevant interest: thus COCHISE can be considered as a pathfinder for future Antarctic telescopes.     

VLF goniometer observations at Halley Bay,Antarctica—I. The equipment and the measurement of signal bearing

A transistorized wide-band (0.5–11 kHz) VLF goniometer has been developed for the study of whistlers and ELF/VLF emissions. It consists of two crossed vertical loops from which a single loop aerial, rotating about a vertical axis at a frequency of 25 sec^?1, is synthesized electronically. During periods of high whistler activity, when the same propagation paths may be identified in successive whistler groups, it is possible to determine the bearing of the exit point of such a magnetospheric path with an error, typically, of ± 10–20°.     

A whistler study of plasmapause motion in the vicinity of sanae,Antarctica

For 4 months of synoptic records whistlers have been analyzed in two groups, high latitude (HL) whistlers with f_n?8 kHz and low latitude (LL) whistlers with f_n?8 kHz. A decrease in percentage occurrence of HL whistlers with increasing K_p is interpreted as being due to equatorwards movement of the plasmapause in the vicinity of SANAE, Antarctica (L=4). The diurnal variation in HL and LL whistler occurrence reveals an average behaviour of the plasmapause, namely, an equatorwards movement beginning at around 2000 LT followed by a return movement from 0400 LT to 0800 LT.     

The Ricker Hills Tillite provides evidence of Oligocene warm-based glaciation in Victoria Land, Antarctica

The relationship between the Ricker Hills Tillite (RHT), which represents the northernmost outcrop of lithified continental glacial deposits in Victoria Land, is discussed with respect to the glacial landscape assemblage of the Ricker Hills, a nunatak at the internal border of the Transantarctic Mountains. A warm-based ice sheet deposited the tillite and induced syn- to post-depositional glacial deformation under wet conditions both of the tillite and of the bedrock. The thickness of the ice sheet on the nunatak is estimated to have been 600 m, at most. The area had been deeply eroded before deposition of the RHT as documented by the low elevation of tillite outcrops located in overdeepened depressions of the nunatak. Micropaleontological analysis evidences only the presence of Permian to Jurassic palynomorphs. X-ray diffraction and SEM–EDS analyses of clay minerals in the RHT indicate continental chemical weathering under wet conditions after the RHT deposition. As documented by clay mineral assemblage variation in CRP drillholes, the progressive cooling of the Antarctic continent allowed chemical weathering in “warm” conditions until the Late Oligocene period in southern Victoria Land, leading to a chronological constrain for RHT deposition. Conservatively estimating the sea level to have been between the tillite outcrops and the erosional trimline limiting horns in the Ricker Hills, at the time of RHT deposition, we suggest that the maximum uplift of the area would not have exceeded 900–1500 m since at least Late Oligocene.     

A nuclear microprobe study of the distribution and concentration of carbon and nitrogen in Murchison and Tagish Lake meteorites,Antarctic micrometeorites,and IDPs: Implications for astrobiology

Abstract— Using a nuclear microprobe, we measured the carbon and nitrogen concentrations and distributions in several interplanetary dust particles (IDPs) and Antarctic micrometeorites (MMs), and compared them to 2 carbonaceous chondrites: Tagish Lake and Murchison. We observed that IDPs are richest in both elements. All the MMs studied contain carbon, and all but the coarse‐grained and 1 melted MM contained nitrogen. We also observed a correlation in the distribution of carbon and nitrogen, suggesting that they may be held in an organic material. The implications for astrobiology of these results are discussed, as small extraterrestrial particles could have contributed to the origin of life on Earth by delivering important quantities of these 2 bio‐elements to the Earth's surface and their gas counterparts, CO₂ and N₂, to the early atmosphere.     

Formation of ω Centauri from an ancient nucleated dwarf galaxy in the young Galactic disc

We first present a self-consistent dynamical model in which ω Cen is formed from an ancient nucleated dwarf galaxy merging with the first generation of the Galactic thin disc in a retrograde manner with respect to the Galactic rotation. Our numerical simulations demonstrate that during merging between the Galaxy and the ω Cen host dwarf with   M _B≃−14 mag  and its nucleus mass of  10⁷ M⊙  , the outer stellar envelope of the dwarf is nearly completely stripped, whereas the central nucleus can survive from the tidal stripping because of its compactness. The developed naked nucleus has a very bound retrograde orbit around the young Galactic disc, as observed for ω Cen, with apocentre and pericentre distances of ∼8 and ∼1 kpc, respectively. The Galactic tidal force can induce radial inflow of gas to the centre of the dwarf and consequently triggers moderately strong nuclear starbursts in a repetitive manner. This result implies that efficient nuclear chemical enrichment resulting from the later starbursts can be closely associated with the origin of the observed relatively young and metal-rich stars in ω Cen. Dynamical heating by the ω Cen host can transform the young thin disc into the thick disc during merging.     

3He, 20,21,22Ne, 14C, 10Be, 26Al,and 36Cl in magnetic fractions of cosmic dust from Greenland and Antarctica

Abstract— We report on studies of the concentrations of cosmogenic nuclides in the magnetic fraction of cosmic dust particles recovered from the South Pole Water Well (SPWW) and from Greenland. Our results confirm that cosmic dust material from these locations contains measurable amounts of cosmogenic nuclides. The Antarctic particles (and possibly those from Greenland as well) also contain minor amounts of solar Ne. Concentrations of cosmogenic nuclides are consistent with irradiation of this material as small objects in space, with exposure ages similar to the expected Poynting‐Robertson (P‐R) lifetimes of 50–200 kyr for particles 25–100 μm in size.     

Observations and interpretations at Vredefort,Sudbury, and Chicxulub: Towards an empirical model of terrestrial impact basin formation

Abstract— The structural, topographic and other characteristics of the Vredefort, Sudbury, and Chicxulub impact structures are described. Assuming that the structures originally had the same morphology, the observations/interpretations for each structure are compared and extended to the other structures. This does not result in any major inconsistencies but requires that the observations be scaled spatially. In the case of Vredefort and Sudbury, this is accomplished by scaling the outer limit of particular shock metamorphic features. In the case of Chicxulub, scaling requires a reasoned assumption as to the formation mechanism of an interior peak ring. The observations/interpretations are then used to construct an integrated, empirical kinematic model for a terrestrial peak‐ring basin. The major attributes of the model include: a set of outward‐directed thrusts in the parautochthonous rocks of the outermost environs of the crater floor, some of which are pre‐existing structures that have been reactivated during transient cavity formation; inward‐directed motions along the same outermost structures and along a set of structures, at intermediate radial distances, during transient cavity collapse; structural uplift in the center followed by a final set of radially outward‐directed thrusts at the outer edges of the structural uplift, during uplift collapse. The rock displacements on the intermediate, inward and innermost, outward sets of structures are consistent with the assumption that a peak ring will result from the convergence of the collapse of the transient cavity rim area and the collapse of the structural uplift.