Silicon ion chemistry in the ionosphere

Loss processes which remove Si⁺ ions selectively relative to other meteor-derived atomic ions in the E- and D-regions of the ionosphere have been identified and measured in the laboratory. The major Si⁺ loss in the E-region is the reaction Si⁺ + H₂O → HSiO⁺ + H (1) with a rate constant 2.3 ± 0.9 × 10^?10 cm³s^?1 at 300 K. The corresponding reactions with Fe⁺, Mg⁺ and other metallic meteor ions are endothermic. Presumably (1) is followed by a fast dissociative-recombination with electrons to produce neutral SiO or Si. At lower altitudes Si⁺ ions associate in a three-body reaction with O₂ with a much larger rate constant than the corresponding associations of Fe⁺ and Mg⁺ with O₂.     

Transterminator ion flow in the Martian ionosphere

The upper ionospheres of Mars and Venus are permeated by the magnetic fields induced by the solar wind. It is a long-standing question whether these fields can put the dense ionospheric plasma into motion. If so, the transterminator flow of the upper ionosphere could explain a significant part of the ion escape from the planets atmospheres. But it has been technically very challenging to measure the ion flow at energies below 20 eV. The only such measurements have been made by the ORPA instrument of the Pioneer Venus Orbiter reporting speeds of 1-5 km/s for O⁺ ions at Venus above 300 km altitude at the terminator ( [Knudsen et al., 1980] and [Knudsen et al., 1982]). At Venus the transterminator flow is sufficient to sustain a permanent nightside ionosphere, at Mars a nightside ionosphere is observed only sporadically. We here report on new measurements of the transterminator ion flow at Mars by the ASPERA-3 experiment on board Mars Express with support from the MARSIS radar experiment for some orbits with fortunate observation geometry. We observe a transterminator flow of O⁺ and O₂⁺ ions with a super-sonic velocity of around 5 km/s and fluxes of 0.8×10⁹/cm² s. If we assume a symmetric flux around the terminator this corresponds to an ion flow of 3.1±0.5×10²⁵/s half of which is expected to escape from the planet. This escape flux is significantly higher than previously observed on the tailside of Mars. A possible mechanism to generate this flux can be the ionospheric pressure gradient between dayside and nightside or momentum transfer from the solar wind via the induced magnetic field since the flow velocity is in the Alfvénic regime. We discuss the implication of these new observations for ion escape and possible extensions of the analysis to dayside observations which may allow us to infer the flow structure imposed by the induced magnetic field.     

Theoretical ion densities in the lower ionosphere

We have solved the coupled momentum and continuity equations for NO⁺, O₂⁺, and O⁺ions in the E- and F-regions of the ionosphere. This theoretical model has enabled us to examine the relative importance of various processes that affect molecular ion densities. We find that transport processes are not important during the day; the molecular ions are in chemical equilibrium at all altitudes. At night, however, both diffusion and vertical drifts induced by winds or electric fields are important in determining molecular ion densities below about 200 km. Molecular ion densities are insensitive to the O⁺ density distribution and so are little affected by decay of the nocturnal F-region or by processes, such as a protonospheric flux, that retard this decay. The O⁺ density profile, on the other hand, is insensitive to molecular ion densities, although the O⁺ diffusion equation is formally coupled to molecular ion densities by the polarization electrostatic field. Nitric oxide plays an important role in determining the NO⁺ to O₂⁺ ratio in the E-region, particularly at night. Nocturnal sources of ionization are required to maintain the E-region through the night. Vertical velocities induced by expansion and contraction of the neutral atmosphere are too small to affect ion densities at any altitude.     

Helium ion outflow from the terrestrial ionosphere

Extensive calculations have been made of the behaviour of He⁺ for situations where ion outflow occurs from the topside ionosphere. For these circumstances, steady state solutions for the He⁺ continuity, momentum and energy equations have been obtained self-consistently, yielding density, velocity and temperature profiles of He⁺ from 200 to 2000 km altitude. To model the high latitude topside ionosphere, a range of background H⁺O⁺ ionospheres was considered with variations in the H⁺ outflow velocity, the presence of a perpendicular electric field and different peak O⁺ densities. In addition, the atmospheric density of neutral helium was chosen to model typical observed winter and summer densities. From our studies we have found that: (a) The outflowing He⁺ has density profiles of similar shape to those of H⁺, for basically different reasons; (b) The effect of the perpendicular electric field differs considerably for H⁺ and He⁺. This difference stems from the fact that an electric field acts to alter significantly the O⁺ density at high altitudes and this, in turn, changes the H⁺ escape flux through the O⁺+H charge exchange reaction. A similar situation does not occur for He⁺ and therefore the He⁺ escape flux exhibits a negligibly small change with electric field; (c) The fractional heating of He⁺ due to the He⁺O⁺ relative flow is not as effective in heating He⁺ as the H⁺O⁺ relative flow is in heating H⁺; (d) During magnetospheric disturbances when the N₂ density at the altitude of the He⁺ peak (600 km) can increase by a factor as large as 50, the He⁺ peak density decreases only by approximately a factor of 2; and (e) The He⁺ escape flux over the winter pole is approximately a factor of 20 greater than the He⁺ escape flux over the summer pole. Consequently, on high latitude closed field lines there could be an interhemispheric He⁺ flux from winter to summer.     

A model of the electron and ion temperatures in the ionosphere

A model (empirical) of the electron and ion temperatures (T_eT_i) is presented in the altitude interval 50–4000 km as a function of time (diurnal, annual), space (position, altitude) and solar flux (F_10.7). Using observations of six satellites (AE-C, AE-D, AE-E, ISIS-1, ISIS-2, OGO-6), five incoherent scatter stations (Arecibo, Chatanika, Jicamarca, Millstone Hill, St Santin) and rocket measurements, this model describes the global gross features of the ionosphere during quiet geophysical conditions (K_p⩽3). The numerical analysis is based on spectral decomposition; the horizontal structure is represented by spherical harmonies and Fourier series, and the vertical structure by spline functions. The electron temperature is, in general, very similar to the ion temperature below ∼90 km. Up to approx. 1500 km, the electron temperature is, on an average, distinctly higher than the ion temperature. Above ∼2000 km, however, the ion temperature is quickly catching up and attains somewhat below 4000 km the same magnitude as the electron temperature.     

Effect of diffusion-thermal processes on the high-latitude topside ionosphere

We have studied the extent to which diffusion-thermal heat flow affects H⁺ temperatures in the high-latitude topside ionosphere. Such a heat flow occurs whenever there are H⁺?O⁺ relative drifts. From our study we have found that at high-latitudes, where H⁺ flows up and out of the topside ionosphere, diffusion-thermal heat flow acts to reduce H⁺ temperatures by 500–600 K at altitudes above about 900 km.     

A fast computation of the diurnal secondary ion production in the ionosphere of Titan

We propose an analytic model that allows rapid computation of the secondary ion production due to electron impact from the primary photo-production in the ionosphere of Titan. The model parameters are given for each of the 5 major ion productions (N⁺₂, CH⁺₄, N⁺, CH⁺₃, N⁺⁺₂) as well as for the electron production.     

Influence of neutral transport on ion chemistry uncertainties in Titan ionosphere

Models of Titan ionospheric chemistry have shown that ion densities depend strongly on the neutral composition. The turbulent diffusion transport conditions, as modeled by eddy coefficients, can spectacularly affect the uncertainty on predicted neutral densities. In order to evaluate the error budget on ion densities predicted by photochemical models, we perform uncertainty propagation of neutral densities by Monte Carlo sampling and assess their sensitivity to two turbulent diffusion profiles, corresponding to the extreme profiles at high altitudes described in the literature. A strong sensitivity of the ion density uncertainties to transport is observed, generally more important than to ion–molecule reaction parameters themselves. This highlights the necessity to constrain eddy diffusion profiles for Titan ionosphere, which should progressively be done thanks to the present and future measurements of the orbiter Cassini.     

The role of relative ion flows on the thermal structure of the ionosphere

Calculations are presented which show that, contrary to previous suggestions, ion flow velocity differences do not have a significant effect on the thermal structure of the midlatitude topside ionosphere.     

Measurements of positive ion conversion and removal reactions relating to the Jovian ionosphere

Measured rates are presented for the reaction of He⁺ ions with H₂ (and D₂) molecules to form H⁺, H₂⁺, and HeH⁺ ions, as well as for the subsequent reactions of H⁺ and HeH⁺ ions with H₂ to form H₃⁺. The neutralization of H₃⁺ (and H₅⁺) ions by dissociative recombination with electrons is shown to be fast. The reaction He⁺ + H₂ is slow (k = 1.1 × 10^?13 cm³/sec at300°K) and produces principally H⁺ by the dissociative charge transfer branch. It is concluded that there may be a serious bottleneck in the conversion of two of the primary ions of the upper Jovian ionosphere, H⁺ and He⁺ (which recombine slowly), to the rapidly recombining H₃⁺ ion (α[H₃⁺]?3.4 × 10^?7 cm³/sec at 150°K).     

Thermal ion flows in the topside auroral ionosphere and the effects of low-altitude,transverse acceleration

Topside ionospheric profiles are used to study the upward field-aligned flow of thermal O⁺ at high latitudes. On the majority of the field lines outside the plasmasphere, the mean flux is approximately equal to the mean polar wind measured by spacecraft at greater altitudes. This is consistent with the theory of thermal light ion escape supported, via charge exchange, by upward O⁺ flow at lower heights. Events of larger O⁺ flow are detected at auroral latitudes and their occurrence is found to agree with that of transversely accelerated ions within the topside ionosphere and the magnetosphere. The effects of low altitude heating of O⁺ by oxygen cyclotron waves, driven by downward field-aligned currents, are considered as a possible common cause of these two types of event.     

Wave processes in the ionosphere over Europe that accompanied the solar eclipse of March 20, 2015

Ionospheric disturbances at an altitude of 300 km that accompanied the solar eclipse of March 20, 2015, have been analyzed based on the ionosondes located in Europe. It has been confirmed that the eclipse was accompanied by the generation of gravity waves in the neutral atmosphere and traveling ionospheric disturbances. The period of the latter was 30–100 min, and the amplitude of relative electron density disturbances was 4–19%. The disturbances continued for not less than 2 h. During the eclipse, the disturbance amplitude more frequently increased. It decreased in one case, since the wave process observed previously was suppressed by the process generated by the eclipse.     

Spectral studies of molecules of astrophysical interest

This paper has been devoted to a minimum amount of literature necessary for an understanding of the spectra of molecules, molecular ions, and radicals present in the cosmic objects such as Sun, comet, interstellar medium, Earth's atmospheres, long period variables, peculiar late-type stars, nebulae, and planetary atmospheres.Astrophysics and Space Science Review Article.     

A comparison study between the newly-born ion effect and the thermal effect on the whistlers in the ionosphere

We have considered an ionospheric plasma model that includes the thermal effect along with the newly born ionic effect and derived a group travel time for the low-frequency whistlers with a view to employing it as a diagnostic tool in the ionosphere. The mathematical development shows that the thermal effect contribution varies with ( _i – )_–7/2 whereas that of the newly born ionic effect varies with _i – )_–5/2. Both the effects are discussed separately. It is concluded that the effects are reasonably countable in the ionosphere. The investigations finally conclude that both the effects should be taken into the whistler waves, otherwise the method might cause a discrepancy in the results, which could affect their accuracy.     

Modification of the phase methods for investigation of non-stationary processes in the ionosphere,magnetosphere and interplanetary space

The method of elimination of the nonrelativistic Doppler effect, suggested in 1960 by Badessa et al. allows the possibility of eliminating the influence of the first derivative of electron content $\text{?N}\text{?t}$ along the signal path. This gives in principal the possibility of measuring the second derivative of N and therefore of studying rapid small amplitude processes in the medium. Other possible reasons for the influence of the medium on the phase and frequency of signal stabilized with high accuracy ($\text{Δω}\text{ω}\text{?10}{}^{\mathrm{?12}}$) are investigated. For example, the frequency shift appears due to the motion of the ionized medium. That allows under favourable conditions the study of large scale unbalanced electric fields in the ionosphere, magnetosphere and interplanetary space.     

Local plasma processes and enhanced electron densities in the lower ionosphere in magnetic cusp regions on Mars

Both the MARSIS ionospheric sounder and the charged particle instrument package ASPERA-3 are experiments on board the Mars Express spacecraft. Joint observations have shown that events of intense ionospheric electron density enhancements occur in the lower ionosphere of magnetic cusp regions, and that these enhancements are not associated with precipitation of charged particles above a few hundred electron volts (<300 eV). To account for the enhancement by particle precipitation, electron fluxes are required with mean energy between 1 and 10 keV. No ionizing radiation, neither energetic particles nor X-rays, could be identified, which could produce the observed density enhancement only in the spatially limited cusp regions. Actually, no increase in ionizing radiation, localized or not, was observed during these events. It is argued that the process causing the increase in density is controlled mainly by convection of ionosphere plasma driven by the interaction between the solar wind and crustal magnetic field lines leading to excitation of two-stream plasma waves in the cusp ionosphere. The result is to heat the plasma, reduce the electron–ion recombination coefficient and thereby increase the equilibrium electron density.     

Electron distribution function and ion concentrations in the earth's lower ionosphere from Boltzmann-Fokker-Planck theory

Using the Boltzmann-Fokker-Planck method and the local approximation we derive coupled non-linear equations for the electron and ion concentrations and the energy-dependent electron distribution function in the Earth's lower ionosphere. These equations are new and give the appropriate generalization of the standard electron-ion continuity equations in the local approximation when electron-neutral particle impact ionization is treated rigorously. We report stable, numerical solutions to these equations and compare our calculated electron concentration to the experimentally determined result for a rocket experiment where the electron concentration and solar EUV spectral flux were measured simultaneously.     

Mass spectrometer measurements of the positive ion composition in the D- and E-regions of the ionosphere

On 14 December 1971, during the maximum of the Geminid Meteor Shower, the positive ion composition was measured in the D- and E-regions above Sardinia. The payload was launched at 12:11 UT, and measurements were made between 68.5 and 152 km altitude. A magnetic sector type mass spectrometer with dual collector and a liquid helium cryopump was used. The instrument covered the mass range from 11 to 73 AMU and had a resolution at the 1 % level of M/ΔM = 60.In the E-region two distinct metal ion layers were observed, centred at 95 and 119 km, respectively. In the lower layer Fe⁺ and Mg⁺ were the most abundant metal ions, and in the upper layer Si⁺ was dominant. Si⁺ ions were conspicuously absent in the lower layer (Si⁺/Mg⁺ < 2 × 10⁻³). This particular behaviour of Si could be due to the inability of atomic oxygen to reduce SiO, whereas in the upper layer Si⁺ions might be formed directly by the charge rearrangement reaction SiO + O⁺ → Si⁺+ O₂. In addition, Na⁺, Al⁺, K⁺, Ca⁺, Ti⁺, Cr⁺, Ni⁺ and Co⁺ were also identified. The metal oxide ions AlO⁺ and SiO⁺ were detected, and probably also MgO⁺ and SiOH⁺. The concentrations of NO⁺ and O₂⁺ show a deep minimum at the maximum of the lower metal ion layer. A very high neutral metal density of 6 × 10⁷ cm⁻³ would be required to explain this feature as resulting from charge transfer reactions between the molecular and metal ions Such a high metal density is in contradiction to direct measurements and to cosmic dust influx rates. The isotopic ratios of Mg⁺, Si⁺, and of the major isotopes of Fe⁺ and Ni⁺ were measured, some of them with an accuracy of a few per cent (²⁵Mg⁺/²⁴Mg⁺ = 0.124 ± 0.006; ²⁶Mg⁺/²⁴Mg⁺ = 0.139 ± 0.008; ²⁹Si⁺/²⁸Si⁺ = 0.050 ± 0.004; ⁵⁴Fe⁺/⁵⁶Fe⁺ = 0.069 ± 0.005; ⁵⁷Fe⁺/⁵⁶Fe⁺ = 0.029 ± 0.004; ⁶⁰Ni⁺/⁵⁸Ni⁺ = 0.31 ± 0.12). The isotopic ratios agree within the experimental errors with the corresponding terrestrial ratios, thus giving evidence that these elements have the same isotopic composition in the Geminid meteors as in the Earth's crust, in chrondrites, and in lunar material.In the D-region the ions Na⁺H₂O, Na⁺(H₂O)₂, NaO⁺ and NaOH⁺ were tentatively identified. Below 95 km altitude the relative abundances of the ions 32⁺, 33⁺ and 34⁺ deviate from the values expected for molecular oxygen isotopes. Their abundances can not be explained by the presence of S-ions only, and we conclude that HO₂⁺ and H₂O₂⁺ are present.The ion density profiles of the major D-region constituents show some remarkable deviations from typical D-region conditions. These deviations are related to the winter anomaly in ionospheric absorption observed over Spain during the launch day, and our data represent the first ion composition measurements during such conditions. In particular, H⁺(H₂O)₂ is the major ion only up to 77 km, and at 80 km altitude the NO⁺ concentration exceeds the total water cluster ion density by almost two orders of magnitude. An increase of the mesospheric NO, O₃ and O concentrations as well as of the O/H₂O ratio could explain the observed ion profiles. The low NO⁺/O₂⁺ ratios of approximately unity measured in the E-region are in agreement with a strong downward transport of NO and/or O into the mesosphere during the launch day. A simple four-ion model was used to interpret our D-region data. The calculated neutral NO concentration increases from about 2 × 10⁷ cm⁻³ at 85 km to 5 × 10⁷ cm⁻³ at 80 km. In addition, evidence for an increased O₂⁺ production rate above 83 km was found, probably due to an enhanced O₃ concentration. We conclude that our data strongly support vertical transport of minor neutral consituents as cause of the winter anomaly.     

Temperature domains in the ionosphere

The non-linear stationary temperature waves (domains) is analysed. The exact analytical solutions of the non-linear equation of the heat conductivity determine the region of existence of such domains and the critical values of plasma parameters, correspond to the increase of the periodical temperature profiles in the plasma. A stationary source of heating (photo-electrons or electric fields) may stimulate the existence of domains, when the power of the source reaches a critical value. Conditions in the F-region of the ionosphere near the equator favour the increase of the domains.     

Spatial resonance in the ionosphere

When the phase velocity of an internal gravity wave equals the natural drift of an ionization irregularity, then a spatial resonance results. If the ionization irregularity has been produced by the gravity wave then it is possible to obtain simple quantitative relations to describe this effect. They indicate this spatial resonance will only occur when the horizontal electric field is westward (i.e. at night) and for tropospherically launched waves it will only affect the ionization at the valley of the equatorial electron density profile.