The Yudomian of Siberia,Vendian and Ediacaran systems of the International stratigraphic scale

In Russia, the terminal Neoproterozoic formally includes the Vendian of western part of the East European platform and the concurrent Yudoma Group of Siberia. As is shown in this work, the designated subdivisions correspond in the stratotypes only to the upper, Yudomian Series of the Vendian. In the Siberian platform, the Ust-Yudoma and Aim horizons of the Yudomian are tightly interrelated. The lower of them, bearing remains of Ediacaran Fauna, represents the Ediacarian Stage, whereas the upper one containing small-shelled fossils (SSF) corresponds to the Nemakit-Daldynian Stage divided into the trisulcatus and antiqua superregional zones. In more complete sections of the platform periphery, sediments of these subdivisions conformably rest on siliciclastic succession that should be ranked as basal subdivision of the Yudomian. The succession is concurrent to the Laplandian Stage of the East European platform. According to geochronological dates obtained recently, the Yudomian Series spans interval of 600–540 Ma. In the East European platform, the Upper Vendian (Yudomian) begins with the Laplandian basal tillites of synonymous stage. In the west of the platform, tillites are dated at 600 Ma like the Upper Vendian base in Siberia. The next Ediacarian Stage of the East European platform is stratigraphic equivalent of the Redkino Horizon, while summary range of the Kotlin and Rovno horizons is concurrent to that of the Nemakit-Daldynian Stage. The Vendian of Russia is conformably overlain by the Tommotian Stage of the Lower Cambrian. Intense pre-Vendian events constrained distribution areas of the Lower Vendian sediments in Russia. The Lower Vendian deposits of the East European platform are most representative and well studied in the central Urals, where they are attributed to the Serebryanka Group. In Siberia, separate subdivisions representing the Lower Vendian are the Maastakh Formation of the Olenek Uplift, two lower members of the Ushakovka Formation in the Baikal region, and the Taseeva Group of the Yenisei Range. Chronological interval of the Lower Vendian corresponds to 650–600 Ma. The Marinoan Glaciation dated in Australia at 650–635 Ma is concurrent to basal part of the pre-Yudomian interval of the Vendian in Russia, whereas the Laplandian Tillite and Gaskiers Glaciation (600–580 Ma) correspond to onset of the Yudomian Epoch. The new Ediacaran System (Knoll et al., 2004) legalized in the International Neoproterozoic scale is close in range to the entire Vendian (635–544 Ma), although without basal beds (Marinoan Tillite) it deprives the terminal Neoproterozoic of its original sense. Inferiority of the system consists also in its indivisibility into stages. Hence, it is clear that the Vendian System subdivided in detail in Russia should be retained in the rank of terminal system of the Precambrian, one of the basic in general scale of the Neoproterozoic.     

Secular variations of the upper crust composition: Implication of geochemical data on the Upper Precambrian shales from the Southern Urals western flank and Uchur-Maya region

In the mid-1980s, it was concluded based on geochemical study that Th, Sc, La concentrations and ratios Th/Sc, La/Sc and Eu/Eu* did not wary significantly in the post-Archean time. It was impossible to judge about compositional variations of upper crust during the Riphean and Vendian, because data of that time characterized a limited number of samples from the post-Archean basins of Australia, New Zealand, and Antarctic. Considered in this work are variations of Eu/Eu*, LREE/HREE, Th/Sc, and La/Sc ratios in Upper Precambrian fine-grained siliciclastic rock of the Southern Urals western flank (Bashkirian meganticlinorium) and Uchur-Maya region (Uchur-Maya plate and Yudoma-Maya belt). As is established, only the Eu anomaly in the studied siliciclastic rocks is practically identical to this parameter of the average post-Archean shale. Three other parameters plot on the Riphean-Vendian variation curves with positive and negative excursions of diverse magnitude, which do not coincide always in time. It is assumed that these excursions likely mark stages of local geodynamic activity, destruction of pre-Riphean cratons, and progressing recycling of sedimentary material during the Riphean.     

Vendian Volcanism,Weathering, and Phosphorus Cycle Variation in the East European Platform

Two geochemical types of volcanic ash are recognized in the Redkino Horizon of the East European Platform based on the systematics of trace elements. The first type developed in the northeastern area of the platform is characterized by Ni/Cr and Ce/Yb ratios typical of the silicic tephra of recent volcanic eruptions in the Kuril–Kamchatka and Aleutian island-arc systems. The respective ratios in ash of the second type are typical of volcanics from the lower Vendian Berestovets Formation. Depletion of the upper Vendian pelites of the East European Platform in Ca, Sr and P (relative to the PAAS) indicates the continental chemical weathering of provenance.     

The Baikalian and Vendian sequences in the Lower Angara area (southwestern Siberian Platform)

In the section of Agaleevskaya BH-4 drilled in the lower reaches of the Angara River, Vendian and Baikalian sediment sequences have been recognized within Neoproterozoic strata. The Vendian sequence is formed by terrigenous-carbonate deposits of the Tetere, Soba, and Katanga Formations of the Danilovo Horizon, referred to as the Upper Vendian Nemakit-Daldyn Stage, as well as by terrigenous deposits of the Taseeva Group. The Baikalian Horizon is composed of the Brus Formation, earlier recognized only on the Chadobets uplift, and is separated from the Vendian deposits by a stratigraphic gap. In the Brus Formation, a microfossil complex similar to earlier described biotas of the Siberian Baikalian strata was found. The underlying deposits of the Terina Formation contain microfossils lacking below the basement of the Lakhanda Horizon (Neoproterozoic).     

Geochemical Aspects of Hypogene Hydrothermal Alteration Zones in the Chol-qeshlaghi Area, NW Iran: Constrains on REEs

Chol-qeshlaghi altered area lies in the northwestern part of the post-collisional Urumieh-Dokhtar magmatic arc, NW Iran. Pervasive silicic, argillic, phyllic and propylitic altered zones appears to be intimately affiliated to the fluids derivative of upper Oligocene Khankandi granodiorite. This paper is dedicated to the identification of geochemical characteristics of hydrothermal alterations, focusing on the determination of the mass gains and losses of REEs, to gain significant insights regarding the chemical exchanges prevailed between the host rocks and hydrothermal fluids. The low pH and high activity of SO_4~(-2) ligands in silicic alteration fluids, resulting in depletion of entire REEs. Decreasing of LREEs appeared in argillic zone may attributed to reduce in adsorption ability of clay minerals in low pH; whereas HREEs enrichment in phyllic zone was inclined to put it down to the abundance of sericite(± Fe oxides). A significant reduction of Eu/Eu* ratio in silicic zone can be attributed to negligible sulfides and clay minerals as some effective agents in adsorption of released Eu~(+2). Factors such as changes in pH, the abundance of absorptive neomorph mineral phases, activity of ligands play an important role in controlling the distribution and concentration of REEs in Chol-qeshlaghi alteration system.     

Microfossils and biofacies of the Vendian fossil biota in the southern Siberian Platform

Based on the study of the litho- and biofacies of the Vendian Nepa Horizon in the central area of the Siberian Platform inland, a paleoecological model for the Vendian microbiota has been developed. The sedimentation environments of the Katanga saddle have been reconstructed, and three sedimentary systems have been recognized: (1) lower continental, formed by the deposits of proluvial fans and riverbeds of temporary streams; (2) middle transgressive, made up of littoral sand facies in the lower part and of fine-clastic shelf strata in the upper part; and (3) upper, of sea highstand, composed of alternating sand bank facies and fine-clastic lagoon deposits. Four biofacies have been recognized in the fine-terrigenous deposits of the Nepa Horizon: (1) Appendisphaera, represented by a Doushantuo-Pertatataka acanthomorph assemblage; (2) Transitional, with a great diversity of plankton and benthic (including complex) taxa; (3) Vanavarataenia, dominated by Vanavarataenia complex benthic algae; and (4) Oscillatoriopsis, represented by taxonomically poor biotas with morphologically simple (mainly prokaryotic) remains. These biofacies are confined to the following sedimentation environments: Appendisphaera is widespread in the distal open-sea areas; the Transitional biofacies is localized in the distal environments of the semi-isolated inner basin; Vanavarataenia occurs in the proximal areas; and Oscillatoriopsis is typical of the shallow-water environments, both extended (corresponding to the highstand period) and local.     

萤石：Eu2+的发光及微结构

萤石掺杂Eu在还原气氛下灼烧可制备出发蓝色荧光的萤石 :Eu2 +晶体 ,该体系的发光为5d→ 4f跃迁发射。在萤石 :Eu2 +体系中对称程度较高的 [0 11]方向发现Eu或F点缺陷 ,但其对发光体整体发光影响不大 ;对发光有重要作用的是对称性较低的 [ l12 ]、[0 13]方向的Eu2 +及F晶簇。Eu2 +晶簇与基体界面会产生定域能级     

Sorption Characteristics of Rare Earth Element Eu^3＋ onto Silica-Water Interfaces Studied by Fluorescence Spectroscopy

The sorption of Eu species onto nano-size silica-water interfaces was investigated using fluorescence spectroscopy for Ph ranges of 1-8.5 and an initial Eu concentration (Ceu) of 2×10-4 M. The sorption rate of Eu was initially low, but significantly increased at Ph>4. The sorption density of Eu species on a silica surface was ～1.58×10-7 mol/m2 when the dissolved Eu species were completely sorbed onto silica-water interfaces at Ph=～5.8. The sorbed Eu species at Ph<6 is aquo Eu3 , which is sorbed onto silica-water interfaces as an outer-sphere complex at Ph<5, but may be sorbed as an inner-sphere bidentate complex at 5相似文献   

New data on Maastrichtian-Paleocene foraminifers from the Sinegorsk Horizon of Southern Sakhalin

Data on planktonic foraminifers first found in the reference section of the Sinegorsk Horizon outcropping along the Naiba River are discussed. The lower part of this stratigraphic unit yields an assemblage of upper Maastrichtian low-latitude thermophilic species, while its upper layers contain upper Paleocene (Thanetian) taxa. Beds with different benthic foraminifers are also defined in the unit.     

Peculiarities of distribution of trace elements in the major ore types from the Mesozoic gold deposits of east Transbaikalia

It has been established that different ore types from the Mesozoic gold deposits of East Transbaikalia were formed from variously differentiated ore-bearing magmatic chambers at different depths of the upper continental crust. The magmatic chambers, which were sources of gold-quartz-arsenopyrite ores, were most differentiated (Eu/Eu* = 0.29–0.32; Rb/Sr = 0.98–1.40) and shallow-seated (Eu/Sm = 0.08–0.14) in contrast to less differentiated and deeper sources of the gold-quartz and gold-sulfide-quartz ores (Eu/Eu* = 0.53–0.72, Rb/Sr = 0.10–0.54, Eu/Sm = 0.11–0.19).     

湖北峡东地区灯影组石板滩段微化石

本文研究了发现于湖北峡东地区，震旦系灯影组石板滩段燧石夹层岩石薄片中的微古植物化石，包括１０属５种（其中１新属新种）和５个未定种，石板滩段黑色薄层灰岩以富含宏观藻类及碳质印膜和少量后生动物而闻名，我们在燧石夹层牟岩石薄片中，不仅发现上述宏观藻类，而且首次发现共生的微化石。及其他保存很好的微化石，这一发现进一步丰富 我国震旦纪的古生物资料，为地层对比提供了依据。     

The stratotype and facies of the glacial Lower Vendian Nichatka Formation,Chara River basin,Central Siberia

Sediments of the Nichatka Formation are facially studied and thoroughly described, the sections are correlated, and the subformations are recognized. The formation represents a key stratigraphic unit to reveal the origin of the Central Siberian glacial horizon and to correlate it with glacial horizons in other regions of the world, namely, with the Laplandian Horizon of the Lower Vendian, Nantou and Marino tillites, etc. The Nichatka Formation is correlated with the glacial Bolshoi Patom (Dzhemkukan) Formation of the Vendian reference section at the Ura Uplift. Unlike the latter, it is mainly composed of continental glacial deposits and is marked by a complex facies composition. The glacial origin of the Nichatka Formation is reliably determined on the basis of a set of diagnostic characters. This permits a more complete reconstruction of the Early Vendian depositional environments. In addition to typical basal tillites and marginal moraine deposits, the formation includes glaciolacustrine and fluvioglacial sediments along with aquatillites, allotillites, and the glacial fan, including subaqueous, deposits.     

Lanthanides and highly mobile elements in sedimentary and metasedimentary rocks as indicators of the tectonic activity in the platform basement: An example of the Voronezh Crystalline Massif

The Eu/Eu*, Eu/Sm, and Ce/La ratios can serve as indicators of zones permeable to ascending fluid fluxes that mark time spans when the kinematics of faults in the basement changed (extension and compression phases). The Eu/Eu* ratio is more informative, the variations in the Eu/Sm ratio are correlated with transgressions in the territory of the anteclise, and the variations in the Ce/La ratio could be caused by both metasomatic processes and low-temperature hydrothermal solutions. In the Voronezh anteclise, whose sedimentary cover is relatively thin and provides no evidence of catagenetic processes, high As concentrations and Eu/Eu* ratios of sedimentary rocks can be utilized as indicators of deep zones of fluid generation centres. Comparable average Eu/Eu*, Eu/Sm, and Ce/La ratios in Proterozoic sedimentary rocks in the platform cover and metasediments of Proterozoic banded iron formations (BIF) confirm that the tectonic environments in which sedimentary units of various age were accumulated were similar.     

Provenance composition and features of geological evolution of the Late Vendian foreland basin of the Timan orogen

The provenance composition and geological evolution of different segments in the distal zone of the Late Vendian foreland basin of the Timan orogen were deciphered on the basis of sequence stratigraphic reconstructions and precision geochemical data on the Upper Vendian fine-grained terrigenous rocks from the Southeast White Sea region, Vychegda, Verkhnekama, and Shkapovo-Shikhan basins, and the Kvarkush-Kamennogorsk and Bashkirian meganticlinoriums. The Upper Vendian of the Southeast White Sea region is subdivided into four sequences: Agma, Solza, Zimnie Gory, and Erga. The tracing of sequence boundaries and lateral facies associations from the Southeast White Sea Region to the South Urals made it possible to identify the main stages of the evolution of sedimentary filling of the foreland basin: (I) shallow water epiplatformal basin, (II) isolated basin, (III) lowstand system tract, and (IV) progradation of delta platforms. Position of data points of the Upper Vendian shales, silty mudstones, and mudstones plotted in the diagrams Th-La, Ni-Cr, Gd_N/Yb_N-Eu/Eu*, Sc-Th/Sc, La/Sm-Sc/Th, and Co/Hf-Ce/Cr, together with their REE systematics and data on Nd model ages indicates that the Proterozoic, including Neoproterozoic rocks of the Timan thrust-folded belt served as the main source for fine aluminosiliciclastic material in the distal zones of the Timan foreland basin. Obtained results are consistent with the concept that the Vendian stage of the evolution of the Eastern European platform is related to the intense input of allochthonous material in its peripheral area owing to the activation of orogenic processes in the adjacent mobile belts and allow us to significantly specify the paleogeographical reconstructions.     

Eu(Ⅲ)溶液对膨润土-砂混合物渗透性能影响研究

在高放废物处置库长期运营过程中包封容器将发生破坏,核素会向外界迁移,缓冲回填材料的水力传导系数是评价处置库工程屏障性能的重要指标。采用柔性壁渗透仪,研究2.0×10-5 mol/L的Eu(III)溶液作为渗入液时膨润土-砂混合物的渗透特性。结果表明,膨润土-砂混合物的水力传导系数K=(2.07⁵.23)×10-10 cm/s;在05.23)×10-10 cm/s;在0⁵0%掺砂率范围内,膨润土-砂混合物吸水膨胀过程中渗透性能随掺砂率增大时没有明显的变化,能够满足高放废物处置库缓冲回填材料低渗透性的要求。使用有效黏土密度的概念,得到膨润土-砂混合物的体积膨胀率随初始有效黏土密度的增大呈指数增大的趋势;混合物水力传导系数的对数值与有效黏土密度存在良好的线性衰减关系;与蒸馏水相比,渗入液(ECDD)为2.0×10-5 mol/L的Eu(III)溶液时,膨润土-砂混合物的水力传导系数较小,可能是由于渗入液黏滞性的影响。     

The radiolarian assemblages of the Bonarelli Horizon in the Umbria-Marche Apennines and Southern Alps, Italy

The Bonarelli Horizon is an important regional marker level in the Umbria-Marche Apennines. It is characterized by consisting of black bituminous shales that yield a distinctive radiolarian fauna. Black shales referable to the Bonarelli Horizon are also present in the Southern Alps. The horizon is of uniform lithology and contains radiolarian assemblages of late Cenomanian-early Turonian age throughout both the Umbria-Marche Apennines and Southern Alps. Several new radiolarian taxa have been recognised and described from the Bonarelli Horizon of both areas. Two new species are defined in this paper, namelySethocapsa bossoensisandXitus picenus.     

大同盆地高砷地下水稀土元素特征及其指示意义

对大同盆地典型高砷地下水开展了稀土元素地球化学研究.研究表明: 高砷地下水具有低∑REE含量及富集重稀土(HREEs)特征.地下水中低含量∑REE与含水层沉积物中Fe-Mn氧化物/氢氧化物对REEs的吸附有关.地下水中重稀土元素相对于轻稀土元素的富集可能是吸附作用和碳酸根离子同REEs发生络合作用的共同结果.采用平均大陆上地壳标准化的地下水稀土元素分布表现出显著的Ce及Eu正异常.地下水Ce/Ce*值及Eu含量与Fe+Mn具有显著相关性, 表明铁锰氧化物还原性溶解是控制Ce/Ce*值及Eu含量特征的主要因素.Ce/Ce*值及Eu含量与As浓度的关系表明, Ce异常及Eu含量特征能对地下水中As的富集进行有效指示.      

磷灰石Eu/Y-Ce:基于大数据的源区类型判别新图解SCIEI北大核心CSCD

磷灰石广泛分布于火成岩、沉积岩和变质岩中,是一种常见的、包含丰富微量元素的副矿物。磷灰石晶格可容纳丰富的微量元素,且因其形成的物理化学条件不同会表现出差异明显的微量元素特征。利用磷灰石微量元素特征可以追踪物质来源和演化。现在常用的方法是利用磷灰石的微量元素绘制二元判别图解,经典判别图解包括Sr-Y、Sr-Mn、Y-(Eu/Eu^(*))和(Ce/Yb)_(N)-REE图解。随着微区测试技术发展,磷灰石微量元素数据日渐丰富,同时由于磷灰石化学成分的复杂性,传统图解已逐渐无法有效利用这些数据所携带的信息,进而无法准确判别其生成环境。建立能准确判别磷灰石物源的新型判别图解故而迫切。近年来,磷灰石微量元素数据的大量积累,为运用以大数据为依托,准确判别磷灰石物源奠定了数据基础。本研究将大数据技术与地球化学数据相结合,共收集整理了1925个代表性磷灰石测试点的微量元素数据,对富碱性火成岩、超镁铁质岩石、镁铁质火成岩、长英质花岗岩、中-低级变质岩、高级变质岩六种类型中磷灰石微量元素数据进行穷举端元处理,共获得7140个磷灰石物源判别图解端元组合,在轮廓系数限定下,进一步有效筛选并提取出能判别磷灰石物源类型的最优图解端元。本文构建了Eu/Y-Ce磷灰石判别新图解,相较于之前的磷灰石判别图解,其涵盖了更全面的物源类型,可以更准确地判别源区类型。     

Characteristics of Rare Earth and Trace Element Patterns in Bedded Cherts from the Bottom of the Lower Cambrian in the Northern Tarim Basin, Northwest China and Their Genetic Significance

The sedimentary sequence of the Lower Cambrian is a key interval to reveal the early evolution history of the Earth and there occur widespread cherts worldwide. These cherts possibly carry important information to decipher the breakup process of the Rodinia Continent. Black rock series at the bottom of the Lower Cambrian in the Northern Tarim Basin, China, is composed of black shales interbedded with thin-bedded cherts. Ten chert samples were systematically collected from two outcrops at Xiaoerbulak and Sogatbulak, 8.8 and 7.5 m thick respectively. The cherts were crushed, and were analyzed for trace element and rare earth concentrations. Trace elements such as V, Cu, Zn, U, Pb, Ba, Cd, Ag, Mo,As and Sb are highly enriched, and others such as Rb, Zr, Cs, Hf, Ta, W, T1, Bi and Th are highly depleted in the cherts.These trace element patterns suggest that the cherts may be of deep crustal origin. The low ratios of Th/U and Rb/Sr further suggest that the cherts are of earth interior sources or received hydrothermal input during their deposition. Chondritenormalized Eu/Eu* value markedly decreases upward in the section from 5.54 at the lowermost to 0.73 at the top, and NASC-normalized Eu/Eu* value decreases from 8.05 to 1.03. The relatively high Eu/Eu* ratio for the cherts from the northern Tarim Basin is most likely due to a hydrothermal input (e.g., Eu/Eu*-10). The systematic decrease of Eu/Eu* ratio from the bottom to the top of the section reflects that the hydrothermal input is the largest in the lowermost portion of the section and gradually decreases upward. The chondrite-normalized Ce/Ce* ratio ranges from 0.42 to 0.83, with an average of 0.60. North American Shale Composite (NASC)-normalized Ce/Ce* ratio ranges from 0.42 to 0.79, with an average of 0.57. Negative Ce anomalies are distinct. EREEs in the cherts generally increase from 10.50 ppm at the bottom to 35.97 ppm at the top of the sampled section. NASC-normalized (La/Lu)N ratio decreases from 2.72 at the bottom to 0.67 at the top. NASC-normalized (La/Ce)N ratio increases from 1.36 at the bottom to 3.13 at the top. These REE patterns are very similar to those for the cherts deposited in the pelagic ocean-basin floor in the Franciscan Complex exposed at Marin Headlands, California (F-MH chert) (Murray et al., 1991). These geochemical signatures are inconsistent with our previous sedimentological data, which suggests a continental shelf setting. Based on multiple lines of evidence including high TOC content in the concomitant black shales, phosphorite at the bottom of black rock series, regional rise of sea level,and beginning of the southern Tianshan Ocean geotectonic cycle, the authors infer that the hydrothermal fluid was carried to the continental shelf by upwelling from a divergent pelagic ocean floor setting.     

Lithogeochemistry of the fine-grained siliciclastic rocks of the Vendian Serebryanka Group of the Central Urals

Sedimentation environments were reconstructed for the Early Vendian successions of the western slope of the Central Urals, which comprises one of the most complete sections of the terminal Precambrian system in northern Eurasia. It was shown that, despite the presence of several diamictite levels in the sections of the Serebryanka Group, mature and multiply recycled fine-grained siliciclastic materials (CIA = 65–77) were delivered into the sedimentation basin over the whole Early Vendian. Based on the lithochemical characteristics of shales, the climate of Serebryanka time can be estimated as semiarid-semihumid, similar to that dominating in Late Vendian paleocatchments. Based on relatively high Mo/Mn values (0.011–0.024), it was suggested that anoxic or similar conditions existed in the basin of Buton time, whereas other sedimentary complexes of the Serebryanka Group were formed in well aerated environments. The systematics of Sr, Ba, Zr, Cu, and V in fine-grained siliciclastic rocks and Sr isotopic data for carbonate rocks indicate that the sediments were accumulated in a fresh-water basin. The values of trace-element indicator ratios, e.g., Th/Sc, La/Sc, Th/Cr and others, in the shales of the Serebryanka Group and Nd model age estimates indicate that a variety of mainly Early Proterozoic complexes, ranging from granitoids to basic rocks, occurred in the Early Vendian paleocatchments. The basic rocks were eroded most extensively probably in the end of Serebryanka time. Based on the Ce/Ce* values of shales, it was concluded that submarine volcanism had no significant influence on sedimentation processes in the Early Vendian. An exception is Koiva and Kernos time, when hematite-bearing shales were accumulated in association with pillow basalts in some zones of the basin. The distribution of the compositions of shales from various formations of the Serebryanka Group in discrimination diagrams suggests that the Early Vendian sedimentary sequences were formed in passive geodynamic settings.