Particle sieving and sorting under simulated martian conditions

We report on sorting of small grained material under simulated martian conditions in order to better understand the nature of particle movement in the acquisition-to-analysis chain for future martian missions. We find that triboelectric charging when material is sieved is a major phenomenon that has to be understood and mitigation strategies explored in order to be able to successfully move particles under these types of conditions while minimizing cross sample talk. In different experimental set-ups, we have observed such phenomena as caking of the sieve, adhesion of particles to hardware, clodding of dry fines, and electrostatic repulsion. These phenomena occur when different experimental testing is performed with varied configurations and environmental conditions. Identifying these electrostatic effects can help us understand potential bias in the analytical instruments and to define the best operational protocols to collect samples on the surface of Mars. These experiments demonstrate the need for end-to-end system testing under the most realistic environmental conditions and platforms before mission configurations can be demonstrated before launch.     

The global martian volcanic evolutionary history

Viking mission image data revealed the total spatial extent of preserved volcanic surface on Mars. One of the dominating surface expressions is Olympus Mons and the surrounding volcanic province Tharsis. Earlier studies of the global volcanic sequence of events based on stratigraphic relationships and crater count statistics were limited to the image resolution of the Viking orbiter camera. Here, a global investigation based on high-resolution image data gathered by the High-Resolution Stereo Camera (HRSC) during the first years of Mars Express orbiting around Mars is presented. Additionally, Mars Orbiter Camera (MOC) and Thermal Emission Imaging System (THEMIS) images were used for more detailed and complementary information. The results reveal global volcanism during the Noachian period (>3.7 Ga) followed by more focused vent volcanism in three (Tharsis, Elysium, and Circum-Hellas) and later two (Tharsis and Elysium) volcanic provinces. Finally, the volcanic activity became localized to the Tharsis region (about 1.6 Ga ago), where volcanism was active until very recently (200-100 Ma). These age results were expected from radiometric dating of martian meteorites but now verified for extended geological units, mainly found in the Tharsis Montes surroundings, showing prolonged volcanism for more than 3.5 billions years. The volcanic activity on Mars appears episodic, but decaying in intensity and localizing in space. The spatial and temporal extent of martian volcanism based on crater count statistics now provides a much better database for modelling the thermodynamic evolution of Mars.     

Effects of soil heterogeneity on martian ground-ice stability and orbital estimates of ice table depth

Data from the Mars Odyssey Gamma-Ray Spectrometer (GRS) instrument suite and results from numerical simulations of subsurface ground-ice stability have been used to estimate the depth of martian ground-ice. Geographic correlation between these estimates is remarkable; the relative ice table depth distributions also agree well. However, GRS-based estimates of ice table depth are generally deeper than predictions based on ground-ice stability simulations. This discrepancy may be related to heterogeneities in the martian surface such as rocks, dust, and albedo variations. We develop a multi-dimensional numerical model of ground-ice stability in a heterogeneous martian subsurface and use it to place the first quantitative constraints on the response of the ice table to meter-scale heterogeneities. We find that heterogeneities produce significant undulations/topography in the ice table at horizontal length scales of a few meters. Decimeter scale rocks create localized areas of deep ice, producing a vertical depression of 10-60 cm in the ice table over a horizontal range of 1-2 rock radii. Decimeter scale dust lenses produce locally shallow ice; however the magnitude of the vertical deflection of the ice table is small (1-4 cm). The effects of decimeter scale albedo variations on the ice table are nearly negligible, although albedo very weakly enhances the effects of dark rocks and bright dust on the ice table. Additionally, we investigate the role played by rocks in estimates of ice table depth based on orbital data. Surface rocks can account for more than half of the discrepancy between ice table depths inferred from GRS data and those predicted by theoretical ice-stability simulations that utilize thermophysical observations. Our results have considerable relevance to the up-coming Mars Scout Mission, Phoenix, because they indicate that the uncertainty in the ice table depth of a given region is greater than differences between current depth estimates. Likewise, small-scale depth variability due to heterogeneities at the eventual landing site is potentially greater than differences between current depth estimates.     

Spectral reflectance properties of minerals exposed to simulated Mars surface conditions

A number of mineral species were exposed to martian surface conditions of atmospheric pressure and composition, temperature, and UV light regime, and their evolution was monitored using reflectance spectroscopy. The stabilities for different groups varied widely. Phyllosilicate spectra all showed measurable losses of interlayer H₂O, with some structural groups showing more rapid H₂O loss than others. Loss of OH from the phyllosilicates is not always accompanied by a change in metal-OH overtone absorption bands. OH-bearing sulfates, such as jarosite and alunite, show no measurable change in spectral properties, suggesting that they should be spectrally detectable on Mars on the basis of diagnostic absorption bands in the 0.4-2.5 μm region. Fe³⁺- and H₂O-bearing sulfates all showed changes in the appearance and/or reduction in depths of hydroxo-bridged Fe³⁺ absorption bands, particularly at 0.43 μm. The spectral changes were often accompanied by visible color changes, suggesting that subsurface sulfates exposed to the martian surface environment may undergo measurable changes in reflectance spectra and color over short periods of time (days to weeks). Organic-bearing geological materials showed no measurable change in CH related absorption bands, while carbonates and hydroxides also showed no systematic changes in spectral properties. The addition of ultraviolet irradiation did not seem to affect mineral stability or rate of spectral change, with one exception (hexahydrite). In some cases, spectral changes could be related to the formation of specific new phases. The data also suggest that hydrated minerals detected on Mars to date retain their diagnostic spectral properties that allow their unique identification.     

The role of aqueous alteration in the formation of martian soils

Martian equatorial dark regions are dominated by unweathered materials and it has often been assumed that they have not been significantly altered from their source lithology. The suite of minerals present is consistent with a basaltic composition and there has been no need to invoke additional processes to explain the origin of these compositions. We have begun to question this result based on detailed observations using a variety of datasets. Locally derived dark soils have a mineralogy distinct from that of adjacent rocky surfaces; most notably a lower olivine content. This pattern is common for many surfaces across the planet. Previous work using detailed measurements acquired within the Gusev Plains has shown that olivine dissolution via acidic weathering may explain chemical trends observed between rock rinds and interiors. Mineralogical trends obtained from rocks and soils within the Gusev Plains are more prominent than the elemental trends and support previous results that indicate that dissolution of olivine has occurred. However, clear differences are also present in elemental abundances that indicate a variety of inputs and processes are likely responsible for the formation of martian dark soils. Despite the potential complexity of source materials and processes, it appears that most martian dark regions have likely experienced aqueous alteration and chemical weathering appears to be closely linked to the mechanical breakdown of materials. Regardless of the responsible mechanism, there appears to be a general, though not perfect, correlation between elevated olivine abundance and high-thermal inertia surfaces on Mars.     

Methane adsorption on a martian soil analog: An abiogenic explanation for methane variability in the martian atmosphere

Recent observations suggest methane in the martian atmosphere is variable on short spatial and temporal scales. However, to explain the variability by loss reactions requires production rates much larger than expected. Here, we report results of laboratory studies of methane adsorption onto JSC-Mars-1, a martian soil simulant, and suggest that this process could explain the observations. Uptake coefficient (γ) values were measured as a function of temperature using a high-vacuum Knudsen cell able to simulate martian temperature and pressure conditions. Values of γ were measured from 115 to 135 K, and the data were extrapolated to higher temperatures with more relevance to Mars. Adsorptive uptake was found to increase at lower temperatures and larger methane partial pressures. Although only sub-monolayer methane surface coverage is likely to exist under martian conditions, a very large mineral surface area is available for adsorption as atmospheric methane can diffuse meters into the regolith. As a result, significant methane may be temporarily lost to the regolith on a seasonal time scale. As this weak adsorption is fully reversible, methane will be re-released into the atmosphere when surface and subsurface temperatures rise and so no net loss of methane occurs. Heterogeneous interaction of methane with martian soil grains is the only process proposed thus far which contains both rapid methane loss and rapid methane production mechanisms and is thus fully consistent with the reported variability of methane on Mars.     

The effects of the martian regolith on GCM water cycle simulations

This paper describes General Circulation Model (GCM) simulations of the martian water cycle focusing on the effects of an adsorbing regolith. We describe the 10-layer regolith model used in this study which has been adapted from the 1-D model developed by Zent, A.P., Haberle, R.M., Houben, H.C., Jakosky, B.M. [1993. A coupled subsurface-boundary layer model of water on Mars. J. Geophys. Res. 98 (E2), 3319-3337, February]. Even with a 30-min timestep and taking into account the effect of surface water ice, our fully implicit scheme compares well with the results obtained by Zent, A.P., Haberle, R.M., Houben, H.C., Jakosky, B.M. [1993. A coupled subsurface-boundary layer model of water on Mars. J. Geophys. Res. 98 (E2), 3319-3337, February]. This means, however, that the regolith is not able to reproduce the diurnal variations in column water vapour abundance of up to a factor of 2-3 as seen in some observations, with only about 10% of the atmospheric water vapour column exchanging with the subsurface on a daily basis. In 3-D simulations we find that the regolith adsorbs water preferentially in high latitudes. This is especially true in the northern hemisphere, where perennial subsurface water ice builds up poleward of 60° N at depths which are comparable to the Odyssey observations. Much less ice forms in the southern high latitudes, which suggests that the water ice currently present in the martian subsurface is not stable under present conditions and is slowly subliming and being deposited in the northern hemisphere. When initialising the model with an Odyssey-like subsurface water ice distribution the model is capable of forcing the simulated water cycle from an arbitrary state close to the Mars Global Surveyor Thermal Emission Spectrometer observations. Without the actions of the adsorbing regolith the equilibrated water cycle is found to be a factor of 2-4 too wet. The process by which this occurs is by adsorption of water during northern hemisphere summer in northern mid and high latitudes where it remains locked in until northern spring when the seasonal CO₂ ice cap retreats. At this time the water diffuses out of the regolith in response to increased temperature and is returned to the residual water ice cap by eddie transport.     

Catalogue of large alluvial fans in martian impact craters

We conducted a systematic, global survey using Thermal Emission Imaging System Infrared (THEMIS IR) coverage (∼100 m/pixel) to search for large alluvial fans in impact craters on Mars. Our survey has focused on large fans (apron areas greater than ∼40 km², usually located in craters greater than 20 km in diameter) due to the resolution of the THEMIS images and Mars Orbiter Laser Altimeter (MOLA) coverage. We find that the host craters are found to have a distinctive diameter range from 30-150 km. The fans generally cluster in three geographic areas—southern Margaritifer Terra, southwestern Terra Sabaea, and southwestern Tyrrhena Terra, however several outliers do exist. The alluvial fans do not form in a particular orientation along the crater rim nor are they associated with the location of current high rim topography. Fan area magnitude and variability increase with crater diameter while fan concavity magnitude and variability increase with decreasing crater diameter. Smaller fan aprons in general have higher, more variable concavity. The source of the water forming these fans is uncertain given the challenges of accommodating the global distribution pattern and formation patterns within the craters.     

Spectral reflectance properties of carbonates from terrestrial analogue environments: Implications for Mars

Spectroscopic analysis of carbonate-bearing samples from a variety of terrestrial environments provides important insights into spectroscopy-based investigations of Mars designed to detect the presence of carbonate minerals. In order to better address the spectral detectability of carbonates on Mars, we examined the spectral reflectance properties of carbonates and carbonate-bearing lithologies from a variety of terrestrial environments, including impact structures (Haughton, St. Martin, Eagle Butte), landslides (Frank), quarrying operations (Hecla), carbonates affected by weathering (Haughton, East German Creek), and sulfide-sulfate-carbonate assemblages (Central Manitoba). The goal is to identify processes and environments that can affect spectroscopy-based carbonate detection, for more detailed follow-on studies. Common carbonates appear to be stable, from a spectroscopic perspective, to various tectonic processes. Iron oxides/hydroxides do not appear to significantly affect spectral detectability of carbonates, as the spectrum-altering effects of these phases are largely restricted to the region below ∼1 μm, while useful carbonate absorption bands occur longward of ∼1.8 μm. Carbonate detection and characterization in the 0.35-2.5-μm region is largely restricted to a single absorption feature in the 2.3-μm region, which can be problematic for robust carbonate identification. While tectonic processes and iron oxide/hydroxide staining do not appear to significantly impair carbonate detection based on the 2.3-μm region absorption band, a number of other factors can affect carbonate detection. These include the fact that this absorption band is weak compared to many other minerals, a number of other minerals also exhibit absorption bands in this wavelength region (leading to possible misidentifications), and that even small abundances of minerals that absorb strongly in this region will reduce the strength of the carbonate absorption band. Identifying the nature of accessory minerals associated with carbonates can be used to constrain possible formation environments. Ongoing research at carbonate-bearing terrestrial analogue sites will continue to provide new insights into the occurrence and detection of carbonates on Mars.     

Spatial inhomogeneity of the martian subsurface water distribution: implication from a global water cycle model

In an effort to test and to understand the global hydrogen distribution in the shallow subsurface of Mars retrieved by the Mars Odyssey gamma-ray spectrometer, the present state and movement of water are investigated by a coupled global subsurface-atmosphere water cycle model. It was found that the observed global subsurface hydrogen distribution is largely consistent with the modeled global water cycle, so a large fraction of hydrogen is likely to exist as water, at low and mid latitudes in the form of adsorbed water. Under the present climate the water content in the shallow subsurface becomes higher in the northern hemisphere than in the southern hemisphere as a result of global water cycle, regardless of the initial water distribution in the soil or adsorptive capacity. The higher annual maximum soil temperature in the south, stronger net northward transport of atmospheric water vapor, and the emission of vapor from the northern residual polar cap in northern summer contribute to this hemispheric asymmetry. The generally higher adsorptive capacity of clay minerals in the northern plains may further increase this bias. The longitudinal inhomogeneity is caused by several factors, such as thermal inertia, adsorptive capacity, and atmospheric surface pressure. The water abundance is locally high in low thermal inertia regions (e.g., Arabia Terra) and at deep places where the surface pressure is high (e.g., Hellas); it is low in soil with a low adsorptive capacity (e.g., Tharsis) and high thermal inertia regions (e.g., Solis Planum). Most of the soil humidity near the surface at low and mid latitudes may originate from the atmosphere. The model implies that the upper soil layer should be largely ice-free because otherwise an excessive sublimation and vapor emission into the atmosphere in warm seasons would violate the observational constraints. Moreover, the more uniform latitudinal variation of the observed hydrogen abundance near the surface compared to that of deeper layers is indicative of the presence of adsorbed water instead of ground ice because the adsorbed water content does not as steeply depend on latitude as the ground ice stability. Concerning the regolith mineralogy, montmorillonite can much better account for the observed water cycle than palagonite. While the presence of permanent ground ice appears likely in the polar region below a thin layer, large seasonal cycle of phase change between pore ice and adsorbed water may be possible. Regolith adsorption/desorption is neither negligible nor crucial for the seasonal atmospheric water cycle, but the surface-atmosphere coupling is a major prerequisite for the long-term evolution of subsurface water distribution.     

Predicted and observed magnetic signatures of martian (de)magnetized impact craters

The current morphology of the martian lithospheric magnetic field results from magnetization and demagnetization processes, both of which shaped the planet. The largest martian impact craters, Hellas, Argyre, Isidis and Utopia, are not associated with intense magnetic fields at spacecraft altitude. This is usually interpreted as locally non- or de-magnetized areas, as large impactors may have reset the magnetization of the pre-impact material. We study the effects of impacts on the magnetic field. First, a careful analysis is performed to compute the impact demagnetization effects. We assume that the pre-impact lithosphere acquired its magnetization while cooling in the presence of a global, centered and mainly dipolar magnetic field, and that the subsequent demagnetization is restricted to the excavation area created by large craters, between 50- and 500-km diameter. Depth-to-diameter ratio of the transient craters is set to 0.1, consistent with observed telluric bodies. Associated magnetic field is computed between 100- and 500-km altitude. For a single-impact event, the maximum magnetic field anomaly associated with a crater located over the magnetic pole is maximum above the crater. A 200-km diameter crater presents a close-to-1-nT magnetic field anomaly at 400-km altitude, while a 100-km diameter crater has a similar signature at 200-km altitude. Second, we statistically study the 400-km altitude Mars Global Surveyor magnetic measurements modelled locally over the visible impact craters. This approach offers a local estimate of the confidence to which the magnetic field can be computed from real measurements. We conclude that currently craters down to a diameter of 200 km can be characterized. There is a slight anti-correlation of −0.23 between magnetic field intensity and impact crater diameters, although we show that this result may be fortuitous. A complete low-altitude magnetic field mapping is needed. New data will allow predicted weak anomalies above craters to be better characterized, and will bring new constraints on the timing of the martian dynamo and on Mars’ evolution.     

Survival of endospores of Bacillus subtilis on spacecraft surfaces under simulated martian environments: implications for the forward contamination of Mars

Experiments were conducted in a Mars simulation chamber (MSC) to characterize the survival of endospores of Bacillus subtilis under high UV irradiation and simulated martian conditions. The MSC was used to create Mars surface environments in which pressure (8.5 mb), temperature (-80, -40, -10, or +23 degrees C), gas composition (Earth-normal N2/O2 mix, pure N2, pure CO2, or a Mars gas mix), and UV-VIS-NIR fluence rates (200-1200 nm) were maintained within tight limits. The Mars gas mix was composed of CO2 (95.3%), N2 (2.7%), Ar (1.7%), O2 (0.2%), and water vapor (0.03%). Experiments were conducted to measure the effects of pressure, gas composition, and temperature alone or in combination with Mars-normal UV-VIS-NIR light environments. Endospores of B. subtilis, were deposited on aluminum coupons as monolayers in which the average density applied to coupons was 2.47 x 10(6) bacteria per sample. Populations of B. subtilis placed on aluminum coupons and subjected to an Earth-normal temperature (23 degrees C), pressure (1013 mb), and gas mix (normal N2/O2 ratio) but illuminated with a Mars-normal UV-VIS-NIR spectrum were reduced by over 99.9% after 30 sec exposure to Mars-normal UV fluence rates. However, it required at least 15 min of Mars-normal UV exposure to reduce bacterial populations on aluminum coupons to non-recoverable levels. These results were duplicated when bacteria were exposed to Mars-normal environments of temperature (-10 degrees C), pressure (8.5 mb), gas composition (pure CO2), and UV fluence rates. In other experiments, results indicated that the gas composition of the atmosphere and the temperature of the bacterial monolayers at the time of Mars UV exposure had no effects on the survival of bacterial endospores. But Mars-normal pressures (8.5 mb) were found to reduce survival by approximately 20-35% compared to Earth-normal pressures (1013 mb). The primary implications of these results are (a) that greater than 99.9% of bacterial populations on sun-exposed surfaces of spacecraft are likely to be inactivated within a few tens of seconds to a few minutes on the surface of Mars, and (b) that within a single Mars day under clear-sky conditions bacterial populations on sun-exposed surfaces of spacecraft will be sterilized. Furthermore, these results suggest that the high UV fluence rates on the martian surface can be an important resource in minimizing the forward contamination of Mars.     

A search for basaltic-to-intermediate glasses on Mars: Assessing martian crustal mineralogy

Multiple datasets have demonstrated that the crust of Mars is fundamentally basaltic. However, spectral libraries used to interrogate thermal infrared spectra of Martian dark regions through spectral deconvolution have heretofore lacked mafic glasses despite the importance of amorphous phases (or phases with amorphous-like spectral signatures) in Martian mineralogy. To establish the presence and importance of basaltic-to-intermediate glasses in Martian lithologies, we created five such glasses, obtained their thermal infrared spectra and included the spectra in a library used to deconvolve nine regional Thermal Emission Spectrometer spectra from Mars. We employed the nonnegative least squares (NNLS) deconvolution method, which yields deconvolved phase abundances and the uncertainties associated with those abundances. The basaltic-to-intermediate glasses do not appear in the deconvolution solutions, indicating they are not globally or regionally important phases. Because Martian igneous or impact processes are capable of basaltic-to-intermediate glass formation, the lack of such glasses in the deconvolved mineralogies suggests either the glasses did not form in detectable quantities or they (or their signatures) have been removed. The masking or replacement of basaltic-to-intermediate glasses through alteration is supported by the appearance in the deconvolution solutions of amorphous phases (e.g., silica-rich glasses, opal) or phases with amorphous-like spectral signatures (e.g., clays, zeolites) that commonly form through aqueous alteration of mafic glasses. The glasses may still be important to local-scale thermal infrared studies given the basaltic nature of Mars and the variety of local-scale lithologies detected by various missions. The regional mineralogies derived from the NNLS deconvolution analysis divide into five statistically separable groups, which provide insight into regional trends in mineralogy.     

The rayed crater Zunil and interpretations of small impact craters on Mars

A 10-km diameter crater named Zunil in the Cerberus Plains of Mars created ∼¹⁰⁷ secondary craters 10 to 200 m in diameter. Many of these secondary craters are concentrated in radial streaks that extend up to 1600 km from the primary crater, identical to lunar rays. Most of the larger Zunil secondaries are distinctive in both visible and thermal infrared imaging. MOC images of the secondary craters show sharp rims and bright ejecta and rays, but the craters are shallow and often noncircular, as expected for relatively low-velocity impacts. About 80% of the impact craters superimposed over the youngest surfaces in the Cerberus Plains, such as Athabasca Valles, have the distinctive characteristics of Zunil secondaries. We have not identified any other large (?10 km diameter) impact crater on Mars with such distinctive rays of young secondary craters, so the age of the crater may be less than a few Ma. Zunil formed in the apparently youngest (least cratered) large-scale lava plains on Mars, and may be an excellent example of how spallation of a competent surface layer can produce high-velocity ejecta (Melosh, 1984, Impact ejection, spallation, and the origin of meteorites, Icarus 59, 234-260). It could be the source crater for some of the basaltic shergottites, consistent with their crystallization and ejection ages, composition, and the fact that Zunil produced abundant high-velocity ejecta fragments. A 3D hydrodynamic simulation of the impact event produced 10¹⁰ rock fragments ?10 cm diameter, leading to up to 10⁹ secondary craters ?10 m diameter. Nearly all of the simulated secondary craters larger than 50 m are within 800 km of the impact site but the more abundant smaller (10-50 m) craters extend out to 3500 km. If Zunil is representative of large impact events on Mars, then secondaries should be more abundant than primaries at diameters a factor of ∼1000 smaller than that of the largest primary crater that contributed secondaries. As a result, most small craters on Mars could be secondaries. Depth/diameter ratios of 1300 small craters (10-500 m diameter) in Isidis Planitia and Gusev crater have a mean value of 0.08; the freshest of these craters give a ratio of 0.11, identical to that of fresh secondary craters on the Moon (Pike and Wilhelms, 1978, Secondary-impact craters on the Moon: topographic form and geologic process, Lunar Planet. Sci. IX, 907-909) and significantly less than the value of ∼0.2 or more expected for fresh primary craters of this size range. Several observations suggest that the production functions of Hartmann and Neukum (2001, Cratering chronology and the evolution of Mars, Space Sci. Rev. 96, 165-194) predict too many primary craters smaller than a few hundred meters in diameter. Fewer small, high-velocity impacts may explain why there appears to be little impact regolith over Amazonian terrains. Martian terrains dated by small craters could be older than reported in recent publications.     

Dating martian climate change

Geological evidence indicates that low-latitude polygonally-patterned grounds on Mars, generally thought to be the product of flood volcanism, are periglacial in nature and record a complex signal of changing climate. By studying the martian surface stratigraphically (in terms of the geometrical relations between surface landforms and the substrate) rather than genetically (by form analogy with Earth), we have identified dynamic surfaces across one-fifth of martian longitude. New stratigraphical observations in the Elysium-Amazonis plains have revealed a progressive surface polygonisation that is destructive of impact craters across the region. This activity is comparable to the climatically-driven degradation of periglacial landscapes on Earth, but because it affects impact craters—the martian chronometer—it can be dated. Here, we show that it is possible to directly date this activity based on the fraction of impact craters affected by polygon formation. Nearly 100% of craters (of all diameters) are superposed by polygonal sculpture: considering the few-100 Ma age of the substrate, this suggests that the process of polygon formation was active within the last few million years. Surface polygonisation in this region, often considered to be one of the signs of young, ‘plains-forming’ volcanism on Mars, is instead shown to postdate the majority of impact craters seen. We therefore conclude that it is post-depositional in origin and an artefact of thermal cycling of near-surface ground ice. Stratigraphically-controlled crater counts present the first way of dating climate change on a planet other than Earth: a record that may tell us something about climate change on our own planet. Parallel climate change on these two worlds—an ice age Mars coincident with Earth’s glacial Quaternary period—might suggest a coupled system linking both. We have previously been unable to generalise about the causes of long-term climate change based on a single terrestrial example—with the beginnings of a chronology for climate change on our nearest planetary neighbour, we can.     

Scattering matrices and expansion coefficients of martian analogue palagonite particles

We present measurements of ratios of elements of the scattering matrix of martian analogue palagonite particles for scattering angles ranging from 3° to 174° and a wavelength of 632.8 nm. To facilitate the use of these measurements in radiative transfer calculations we have devised a method that enables us to obtain, from these measurements, a normalized synthetic scattering matrix covering the complete scattering angle range from 0° to 180°. Our method is based on employing the coefficients of the expansions of scattering matrix elements into generalized spherical functions. The synthetic scattering matrix elements and/or the expansion coefficients obtained in this way, can be used to include multiple scattering by these irregularly shaped particles in (polarized) radiative transfer calculations, such as calculations of sunlight that is scattered in the dusty martian atmosphere.     

Evaluation of carbonate abundance in putative martian paleolake basins

Carbonate deposits have not been found so far on Mars, although there appears to have been sufficient water to have supported their formation. Many hypotheses have been proposed in order to explain this. In the present work we explore the possibility that the missed detection of carbonate deposits on the martian surface could be simply due to the fact that the concentration of carbonates, when mixed with other materials present in the sedimentary deposits, may be below the detection limit of the various instruments used so far in this search. In the present study we consider 21 putative paleolacustrine basins and use a sediment transport model to estimate the abundance of carbonates which could be present in the sediments deposited on the basin floor. In this way we find that for all the selected basins the estimated carbonate abundances are in general less than a few percent, and such values are below (or at best comparable to) the detection limits of the spectrometers flown around Mars during the recent space missions. Furthermore, applying the sediment transport model to the well studied Eberswalde crater, we conclude that the fluvio-lacustrine activity in this basin should have lasted for a period on the order of 10³–10⁴ years, in good agreement with previous work. Our results suggest that a hydrological cycle, able to move large volumes of water and to create relatively stable lakes, could have been active intermittently on Mars in the past, producing carbonate deposits that could escape detection by the instruments that have flown to date.     

Modeling sublimation of ice exposed by new impacts in the martian mid-latitudes

New impacts in the martian mid-latitudes have exposed near-surface ice. This ice is observed to slowly fade over timescales of months. In the present martian climate, exposed surface ice is unstable during summer months in the mid-latitudes and will sublimate. We model the sublimation of ice at five new impact sites and examine the implications of its persistence. Even with generally conservative assumptions, for most reasonable choices of parameters it is likely that over a millimeter of sublimation occurred in the period during which the ice was observed to fade. The persistence of visible ice through such sublimation suggests that the ice is relatively pure rather than pore-filling. Such ice could be analogous to the nearly pure ice observed by the Phoenix Lander in the “Dodo-Goldilocks” trench and suggests that the high ice contents reported by the Mars Odyssey Gamma Ray Spectrometer at high latitudes extend to the mid-latitudes. Our observations are consistent with a model of the martian ice table in which a layer with high volumetric ice content overlies pore-filling ice, although other structures are possible.     

Adsorptive fractionation of HDO on JSC MARS-1 during sublimation with implications for the regolith of Mars

A chamber was constructed to simulate the boundary between the ice table, regolith and atmosphere of Mars and to examine fractionation between H₂O and HDO during sublimation under realistic martian conditions of temperature and pressure. Thirteen experimental runs were conducted with regolith overlying the ice. The thickness and characteristic grain size of the regolith layer as well as the temperature of the underlying ice was varied. From these runs, values for the effective diffusivity, taking into account the effects of adsorption, of the regolith were derived. These effective diffusivities ranged from 1.8 × 10⁻⁴ m² s⁻¹ to 2.2 × 10⁻³ m² s⁻¹ for bare ice and from 2.4 × 10⁻¹¹ m² s⁻¹ to 2.0 × 10⁻⁹ m² s⁻¹ with an adsorptive layer present. From these, latent heats of adsorption of 8.6 ± 2.6 kJ mol⁻¹ and 9.3 ± 2.8 kJ mol⁻¹ were derived at ice-surface temperatures above 223 ± 8 K and 96 ± 28 kJ mol⁻¹ and 104 ± 31 kJ mol⁻¹ respectively for H₂O and HDO were derived at colder temperatures. For temperatures below 223 K, the effective diffusivity of HDO was found to be lower than the diffusivity of H₂O by 40% on average, suggesting that the regolith was adsorptively fractionating the sublimating gas with a fractionation factor of 1.96 ± 0.74. Applying these values to Mars predicts that adsorbed water on the regolith is enriched in HDO compared to the atmosphere, particularly where the regolith is colder. Based on current observations, the D/H ratio of the regolith may be as high as 21 ± 8 times VSMOW at 12°S and L_S = 357° if the regolith is hydrated primarily by the atmosphere, neglecting any hydration from subsurface ice.     

Impact demagnetization of the martian crust

The lack of magnetic anomalies within the giant martian impact basins, Hellas, Argyre, and Isidis suggests that the impacts demagnetized the crust. Our analysis of the magnetic anomaly intensity shows that the interior parts of the basins are completely demagnetized, while the outer parts and surroundings are partially demagnetized. We investigate the shock pressure and impact heating resulting from the impacts. The crust has been completely demagnetized within ∼0.8 basin radius by a combination of thermal and shock effects, and the surroundings have been partially demagnetized by shock to a distance of at least 1.4 radii. We also investigate magnetic signatures of intermediate-size craters. From the pressures generated by both the large and intermediate-sized impacts, we conclude that the remanent magnetization is carried at least in part by high coercivity rocks. Since the crust beneath the basins does not appear to have been remagnetized as it cooled following the impacts, we conclude that the martian core dynamo was inactive or very weak for at least 100 Myr following the Hellas impact.