Venus upper atmospheric CO, temperature, and winds across the afternoon/evening terminator from June 2007 JCMT sub-millimeter line observations

The Venus mesosphere constitutes a highly variable transition region between the zonal rotation of the lower atmosphere and the diurnal circulation of the upper atmosphere. It further serves as the primary photochemical region of the Venus atmosphere. We obtained James Clerk Maxwell Telescope (JCMT, Mauna Kea Hawaii) sub-millimeter line observations of mesospheric ¹²CO and ¹³CO during coordinated space (MESSENGER and Venus Express) and ground-based observations of Venus in June of 2007. Such CO spectra line measurements support temperature, CO mixing ratio, and wind retrievals over the 80-110 km altitude range, encompassing the upper mesosphere and lower thermosphere of Venus. Five-point beam integrations were obtained across the observed Venus disk, allowing distinction of afternoon (noon to 6 p.m.) versus evening (6 p.m. to midnight) local times and northern (0-60N) versus southern (0-60S) latitudes. Distinctive diurnal variations (noon to midnight) are retrieved for both temperatures above 95 km and CO mixing ratios above 85 km altitudes. Separate CO line maps obtained on (UT) June 2, 3, 6, and 11 indicate moderate daily variability in afternoon and evening CO mixing ratios (20-50%) and temperatures (5-10 K). Average Venus mesospheric temperatures over this period were 10 K warmer than returned from 1978 to 1979 Pioneer Venus or 2000-01 sub-millimeter measurements, without evidence for the very large temperature inversions indicated by Venus Express SPICAV measurements at 90-100 km altitudes (Bertaux, J.L., Vandaele, A.-C., Korablev, O., Villard, E., Fedorova, A., Fussen, D., Quémerais, E., Belyaev, D., Mahieux, A., Montmessin, F., Muller, C., Neefs, E., Nevejans, D., Wilquet, V., Dubois, J.P. Hauchecorne, A., Stepanov, A., Vinogradov, I., Rodin, A., Bertaux, J.-L., Nevejans, D., Korablev, O., Montmessin, F., Vandaele, A.-C., Fedorova, A., Cabane, M., Chassefière, E., Chaufray, J.Y., Dimarellis, E., Dubois, J.P., Hauchecorne, A., Leblanc, F., Lefèvre, F., Rannou, P., Quémerais, E., Villard, E., Fussen, D., Muller, C., Neefs, E., Van Ransbeeck, E., Wilquet, V., Rodin, A., Stepanov, A., Vinogradov, I., Zasova, L., Forget, F., Lebonnois, S., Titov, D., Rafkin, S., Durry, G., Gérard, J.C., Sandel, B., 2007. A warm layer in Venus’ cryosphere and high-altitude measurements of HF, HCl, H₂O and HDO. Nature 450, 646-649). Measured Doppler shifts associated with June 2 and 11 ¹²CO line center absorptions indicate nearly supersonic (200 m/s, Mach 1) afternoon-to-evening (retrograde) circulation; composed of additive subsolar-to-antisolar (SSAS) and zonal retrograde wind components, which are not separable due to the particular observational geometry.     

Mesospheric vertical thermal structure and winds on Venus from HHSMT CO spectral-line observations

We report vertical thermal structure and wind velocities in the Venusian mesosphere retrieved from carbon monoxide (¹²CO J=2-1 and ¹³CO J=2-1) spectral line observations obtained with the Heinrich Hertz Submillimeter Telescope (HHSMT). We observed the mesosphere of Venus from two days after the second Messenger flyby of Venus (on 5 June 2007 at 23:10 UTC) during five days. Day-to-day and day-to-night temperature variations and short-term fluctuations of the mesospheric zonal flow were evident in our data. The extensive layer of warm air detected recently by SPICAV at 90-100 km altitude is also detected in the temperature profiles reported here.These data were part of a coordinated ground-based Venus observational campaign in support of the ESA Venus Express mission. Furthermore, this study attempts to cross-calibrate space- and ground-based observations, to constrain radiative transfer and retrieval algorithms for planetary atmospheres, and to contribute to a more thorough understanding of the global patterns of circulation of the Venusian atmosphere.     

The thermosphere of Venus and its exploration by a Venus Express Accelerometer Experiment

The forthcoming observations by Venus Express provide an ideal opportunity to comprehensively study the atmosphere of Venus for the first time since Pioneer Venus (1978–1992), and for the first time ever in detail at polar latitudes. This article reviews some of our current knowledge from space and ground-based observations about the upper atmosphere of Venus, such as its thermal structure, the global distribution of gases and dynamics. We discuss the processes most likely responsible for phenomena such as the cold nightside cryosphere, the cloud top superrotation and waves, and highlight outstanding scientific challenges for Venus Express measurements. In particular, we describe an experiment to measure atmospheric drag using the on-board accelerometers.     

Venus Express—The first European mission to Venus

Venus Express is the first European mission to planet Venus. The mission aims at a comprehensive investigation of Venus atmosphere and plasma environment and will address some important aspects of the surface physics from orbit. In particular, Venus Express will focus on the structure, composition, and dynamics of the Venus atmosphere, escape processes and interaction of the atmosphere with the solar wind and so to provide answers to the many questions that still remain unanswered in these fields. Venus Express will enable a breakthrough in Venus science after a long period of silence since the period of intense exploration in the 1970s and the 1980s.The payload consists of seven instruments. Five of them were inherited from the Mars Express and Rosetta projects while two instruments were designed and built specifically for Venus Express. The suite of spectrometers and imaging instruments, together with the radio-science experiment, and the plasma package make up an optimised payload well capable of addressing the mission goals to sufficient depth. Several of the instruments will make specific use of the spectral windows at infrared wavelengths in order to study the atmosphere in three dimensions. The spacecraft is based on the Mars Express design with minor modifications mainly needed to cope with the thermal environment around Venus, and so a very cost-effective mission has been realised in an exceptionally short time.The spacecraft was launched on 9 November 2005 from Baikonur, Kazakhstan, by a Russian Soyuz-Fregat launcher and arrived at Venus on 11 April 2006. Venus Express will carry out observations of the planet from a highly elliptic polar orbit with a 24-h period. In 3 Earth years (4 Venus sidereal days) of operations, it will return about 2 Tbit of scientific data.Telecommunications with the Earth is performed by the new ESA ground station in Cebreros, Spain, while a nearly identical ground station in New Norcia, Australia, supports the radio-science investigations.     

Global mean cloud coverage on Venus in the near-infrared

We present a map of the global mean lower cloud coverage of Venus. This map is the average of 35 nights of 2.26 μm night side observations taken at NASA's Infrared Telescope Facility on Mauna Kea, over the years spanning 2001-2007. The atmosphere of Venus is a very dynamic system, and the lower clouds are constantly changing [Crisp, D., Allen, D.A., Grinspoon, D.H., Pollack, J.B., 1991a. The dark side of Venus: near-infrared images and spectra from the Anglo-Australian Observatory. Science, 253, 1263-1266]. By studying average cloud coverage, the daily variations are suppressed in order to see the underlying persistent cloud pattern. We find a relatively thick but highly variable equatorial band of clouds (±20° in latitude) and more quiescent mid-latitude clouds that are less opaque on average, with persistent cloudiness near the poles. We show that there is enough variation between our daily observations or between observations taken in different months that they cannot be considered individually representative of the global mean. We also compare the cloud coverage map to the topography of Venus and find no definitive correlations with high altitude features.     

Upstream proton cyclotron waves at Venus

Data from the magnetometer MAG aboard the Venus Express S/C are investigated for the occurrence of cyclotron wave phenomena upstream of the Venus bow shock. For an unmagnetized planet such as Venus and Mars the neutral exosphere extends into the on-flowing solar wind and pick-up processes can play an important role in the removal of particles from the atmosphere. At Mars upstream proton cyclotron waves were observed but at Venus they were not yet detected. From the MAG data of the first 4 months in orbit we report the occurrence of proton cyclotron waves well upstream from the planet, both outside and inside of the planetary foreshock region; pick-up protons generate specific cyclotron waves already far from the bow shock. This provides direct evidence that the solar wind is removing hydrogen from the Venus exosphere. Determining the role the solar wind plays in the escape of particles from the total planetary atmosphere is an important step towards understanding the evolution of the environmental conditions on Venus. The continual observations of the Venus Express mission will allow mapping the volume of escape more accurately, and determine better the present rate of hydrogen loss.     

Scattering particles in nightside limb observations of Venus’ upper atmosphere by Venus Express VIRTIS

Nightside infrared limb spectra of the Venus upper atmosphere, obtained by Venus Express VIRTIS, show strong scattering of thermal radiation. This scattering of upward-going radiation into the line-of-sight is dominant below 82.5 km even at a wavelength of 5 μm, which is indicative of relatively large particles. We show that 1 μm-sized sulfuric acid particles (also known as mode 2 particles) provide a good fit to the VIRTIS limb data at high altitudes. We retrieve vertical profiles of the mode 2 number density between 75 and 90 km at two latitude ranges: 20-30°N and 47-50°N. Between 20 and 30°N, scattering by mode 2 particles is the main source of radiance for altitudes between 80 and 85 km. Above altitudes of 85 km smaller particles can also be used to fit the spectra. Between 47 and 50°N mode 2 number densities are generally lower than between 20 and 30°N and the profiles show more variability. This is consistent with the 47-50° latitude region being at the boundary between the low latitudes and high latitudes, with the latter showing lower cloud tops and higher ultraviolet brightness (Titov, D.V., Taylor, F.W., Svedhem, H., Ignatiev, N.I., Markiewicz, W.J., Piccioni, G., Drossart, P. [2008]. Nature 456, 620-623).     

The legacy of Venus Express: highlights from the first European planetary mission to Venus

The ESA/Venus Express mission spent more than 8 years in orbit around Venus to extensively study its atmosphere, ionosphere and plasma environment and unveil new aspects of its surface. Extensive reviews of the work of Venus Express are underway, to cover in-depth studies of the new face of Venus revealed by Venus Express and ground-based concurrent observations. This paper intends to give a summarized and wide overview of some of the outstanding results in all the science areas studied by the mission. This paper will first review the main aspects of the mission and its instrumental payload. Then, a selection of results will be reviewed from the outermost layers interacting with the Solar wind, down to the surface of Venus. As Venus Express is already considered by space agencies as a pathfinder for the future of Venus exploration, perspectives for future missions will be given, which will have to study Venus not only from orbital view, but also down to the surface to solve the many remaining mysteries of the sister planet of the Earth.     

Observational definition of the Venus mesopause: vertical structure, diurnal variation, and temporal instability

Submillimeter line observations of CO in the Venus middle atmosphere (mesosphere) were observed with the James Clerk Maxwell Telescope (JCMT, Mauna Kea) about the May 2000, February 2002 superior and July 1999, March 2001 inferior conjunctions of Venus. Combined ¹²CO and ¹³CO isotope spectral line measurements at 345 and 330 gHz frequencies, respectively, provided enhanced sensitivity and vertical coverage for simultaneous retrievals of atmospheric temperatures and CO mixing ratios over the altitude region 75-105 km with vertical resolution 4-5 km. Supporting millimeter ¹²CO spectral line observations with the Kitt Peak 12-m telescope (Steward Observatories) provide enhanced temporal coverage and CO mixing sensitivity. Implementation of CO/temperature profile retrievals for the 2000, 2002 dayside (superior conjunction) and 1999, 2001 nightside (inferior conjunction) periods yields a first-time definition of the vertical structure and diurnal variation of a low-to-mid-latitude mesopause within the Venus atmosphere. At the times of these 1999-2002 observations, the Venus mesopause was located at a slightly lower level in the nightside (0.5 mbar, ∼87 km) versus the dayside (0.2 mbar, ∼91 km) atmosphere. Average diurnal variation of Venus mesospheric temperatures appears to be ≤ 5 K at and below the mesopause. Diurnal variation of Venus thermospheric temperatures increases abruptly just above the mesopause, reaching 50 K by the 0.01-mbar pressure level (∼102 km). Atmospheric temperatures above and below the Venus mesopause exhibited global-scale (≥4000 km horizontal) variations of large amplitude (7-15 K) on surprisingly short timescales (daily to monthly) during the 2001 nightside and 2002 dayside observing periods. Venus dayside mesospheric temperatures observed during the 2002 superior conjunction were also 10-15 K warmer than observed during the 2000 superior conjunction. A characteristic timescale for these global temperature variations is not defined, but their magnitude is comparable to previous determinations of secular variability in nightside mesospheric temperatures (Clancy and Muhleman, 1991).     

Thermal structure and CO distribution for the Venus mesosphere/lower thermosphere: 2001–2009 inferior conjunction sub-millimeter CO absorption line observations

Sub-millimeter ¹²CO (346 GHz) and ¹³CO (330 GHz) line absorptions, formed in the mesosphere and lower thermosphere of Venus (70–120 km), have been mapped across the nightside Venus disk during 2001–2009 inferior conjunctions, employing the James Clerk Maxwell Telescope (JCMT). Radiative transfer analysis of these thermal line absorptions supports temperature and CO mixing profile retrievals, as well as Doppler wind fields (described in the companion paper, Clancy et al., 2012). Temporal sampling over the hourly, daily, weekly and interannual timescales was obtained over 2001–2009. On timescales inferred as several weeks, we observe changes between very distinctive CO and temperature nightside distributions. Retrieved nightside CO, temperature distributions for January 2006 and August 2007 observations display strong local time, latitudinal gradients consistent with early morning (2–3 am), low-to-mid latitude (0–40NS) peaks of 100–200% in CO and 20–30 K in temperature. The temperature increases are most pronounced above 100 km altitudes, whereas CO variations extend from 105 km (top altitude of retrieval) down to below 80 km in the mesosphere. In contrast, the 2004 and 2009 periods of observation display modest temperature (5–10 K) and CO (30–60%) increases, that are centered on antisolar (midnight) local times and equatorial latitudes. Doppler wind derived global (zonal and should be SSAS) circulations from the same data do not exhibit variations correlated with these CO, temperature short-term variations. However, large-scale residual wind fields not fit by the zonal, SSAS circulations are observed in concert with the strong temperature, CO gradients observed in 2006 and 2007 (Clancy et al., 2010). These short term variations in nightside CO, temperature distributions may also be related to observed nightside variations in O₂ airglow (Hueso, H., Sánchez-Lavega, A., Piccioni, G., Drossart, P., Gérard, J.C., Khatuntsev, I., Zasova, L., Migliorini, A. [2008]. J. Geophys. Res. 113, E00B02. doi:10.1029/2008JE003081) and upper mesospheric SO and SO₂ layers (Sandor, B.J., Clancy, R.T., Moriarty-Schieven, G.H., Mills, F.P. [2010]. Icarus 208, 49–60).The retrieved temperature profiles also exhibit 20 K long-term (2001–2009) variations in nightside (whole disk) average mesospheric (80–95 km) temperatures, similar to 1982–1991 variations identified in previous millimeter CO line observations (Clancy et al., 1991). Global average diurnal variations in lower thermospheric temperatures and mesospheric CO abundances decreased by a factor-of-two between 2000–2002 versus 2007–2009 periods of combined dayside and nightside observations. The infrequency and still limited temporal extent of the observations make it difficult to assign specific timescales to such longer term variations, which may be associated with longer term variations observed for cloud top SO₂ (Esposito, L.W., Bertaux, J.-L., Krasnopolsky, V., Moroz, V.I., Zasova, L.V. [1997]. Chemistry of lower atmosphere and clouds. In: Bougher, S.W., Hunten, D.M., Phillips, R.J. (Eds.), VENUS II, 1362pp) and mesospheric water vapor (Sandor, B.J., Clancy, R.T. [2005]. Icarus 177, 129–143) abundances.     

A comparison of water vapor line parameters for modeling the Venus deep atmosphere

The discovery of the near infrared windows into the Venus deep atmosphere has enabled the use of remote sensing techniques to study the composition of the Venus atmosphere below the clouds. In particular, water vapor absorption lines can be observed in a number of the near-infrared windows allowing measurement of the H₂O abundance at several different levels in the lower atmosphere. Accurate determination of the abundance requires a good database of spectral line parameters for the H₂O absorption lines at the high temperatures (up to ∼700 K) encountered in the Venus deep atmosphere. This paper presents a comparison of a number of H₂O line lists that have been, or that could potentially be used, to analyze Venus deep atmosphere water abundances and shows that there are substantial discrepancies between them. For example, the early high-temperature list used by Meadows and Crisp [Meadows, V.S., Crisp, D., 1996. J. Geophys. Res. 101 (E2), 4595-4622] had large systematic errors in line intensities. When these are corrected for using the more recent high-temperature BT2 list of Barber et al. [Barber, R.J., Tennyson, J., Harris, G.J., Tolchenov, R.N., 2006. Mon. Not. R. Astron. Soc. 368, 1087-1094] their value of 45±10 ppm for the water vapor mixing ratio reduces to 27±6 ppm. The HITRAN and GEISA lists used for most other studies of Venus are deficient in “hot” lines that become important in the Venus deep atmosphere and also show evidence of systematic errors in line intensities, particularly for the 8000 to 9500 cm⁻¹ region that includes the 1.18 μm window. Water vapor mixing ratios derived from these lists may also be somewhat overestimated. The BT2 line list is recommended as being the most complete and accurate current representation of the H₂O spectrum at Venus temperatures.     

A layer of ozone detected in the nightside upper atmosphere of Venus

To date, ozone has only been identified in the atmospheres of Earth and Mars. This study reports the first detection of ozone in the atmosphere of Venus by the SPICAV ultraviolet instrument onboard the Venus Express spacecraft. Venusian ozone is characterized by a vertically confined and horizontally variable layer residing in the thermosphere at a mean altitude of 100 km, with local concentrations of the order of 10⁷–10⁸ molecules cm⁻³. The observed ozone concentrations are consistent with values expected for a chlorine-catalyzed destruction scheme, indicating that the key chemical reactions operating in Earth’s upper stratosphere may also operate on Venus.     

SWAS observations of water vapor in the Venus mesosphere

We present the first detections of the ground-state H₂¹⁶O (₁₁₀-₁₀₁) rotational transition (at 556.9 GHz) and the ¹³CO (5-4) rotational transition from the atmosphere of Venus, measured with the Submillimeter Wave Astronomy Satellite (SWAS). The observed spectral features of these submillimeter transitions originate primarily from the 70-100 km altitude range, within the Venus mesosphere. Observations were obtained in December 2002, and January, March, and July 2004, coarsely sampling one Venus diurnal period as seen from Earth. The measured water vapor absorption line depth shows large variability among the four observing periods, with strong detections of the line in December 2002 and July 2004, and no detections in January and March 2004. Retrieval of atmospheric parameters was performed using a multi-transition inversion algorithm, combining simultaneous retrievals of temperature, carbon monoxide, and water profiles under imposed constraints. Analysis of the SWAS spectra resulted in measurements or upper limits for the globally averaged mesospheric water vapor abundance for each of the four observation periods, finding variability over at least two orders of magnitude. The results are consistent with both temporal and diurnal variability, but with short-term fluctuations clearly dominating. These results are fully consistent with the long-term study of mesospheric water vapor from millimeter and submillimeter observations of HDO [Sandor, B.J., Clancy, R.T., 2005. Icarus 177, 129-143]. The December 2002 observations detected very rapid change in the mesospheric water abundance. Over five days, a deep water absorption feature consistent with a water vapor abundance of 4.5±1.5 parts per million suddenly gave way to a significantly shallower absorption, implying a decrease in the water vapor abundance by a factor of nearly 50 in less that 48 h. In 2004, similar changes in the water vapor abundance were measured between the March and July SWAS observing periods, but variability on time scales of less than a week was not detected. The mesospheric water vapor is expected to be in equilibrium with aerosol particles, primarily composed of concentrated sulfuric acid, in the upper haze layers of the Venus atmosphere. If true, moderate amplitude (10-15 K) variability in mesospheric temperature, previously noted in millimeter spectroscopy observations of Venus, can explain the rapid water vapor variability detected by SWAS.     

Hydroxyl airglow on Venus in comparison with Earth

Hydroxyl nightglow is intensively studied in the Earth atmosphere, due to its coupling to the ozone cycle. Recently, it was detected for the first time also in the Venus atmosphere, thanks to the VIRTIS-Venus Express observations. The main Δν=1, 2 emissions in the infrared spectral range, centred, respectively, at 2.81 and 1.46 μm (which correspond to the (1-0) and (2-0) transitions, respectively), were observed in limb geometry (Piccioni et al., 2008) with a mean emission rate of 880±90 and 100±40 kR (1R=10⁶ photon cm⁻² s⁻¹ (4πster)⁻¹), respectively, integrated along the line of sight. In this investigation, the Bates-Nicolet chemical reaction is reported to be the most probable mechanism for OH production on Venus, as in the case of Earth, but HO₂ and O may still be not negligible as mechanism of production for OH, differently than Earth. The nightglow emission from OH provides a method to quantify O₃, HO₂, H and O, and to infer the mechanism of transport of the key species involved in the production. Very recently, an ozone layer was detected in the upper atmosphere of Venus by the SPICAV (Spectroscopy for Investigation of Characteristics of the Atmosphere of Venus) instrument onboard Venus Express (Montmessin et al., 2009); this discovery enhances the importance of ozone to the OH production in the upper atmosphere of Venus through the Bates-Nicolet mechanism. On Venus, OH airglow is observed only in the night side and no evidence has been found whether a similar emission exists also in the day side. On Mars it is expected to exist both on the day and night sides of the planet, because of the presence of ozone, though OH airglow has not yet been detected.In this paper, we review and compare the OH nightglow on Venus and Earth. The case of Mars is also briefly discussed for the sake of completeness. Similarities from a chemical and a dynamical point of view are listed, though visible OH emissions on Earth and IR OH emissions on Venus are compared.     

Magnetic field investigation of the Venus plasma environment: Expected new results from Venus Express

The Venus Express mission is scheduled for launch in 2005. Among many other instruments, it carries a magnetometer to investigate the Venus plasma environment. Although Venus has no intrinsic magnetic moment, magnetic field measurements are essential in studying the solar wind interaction with Venus. Our current understanding of the solar wind interaction with Venus is mainly from the long lasting Pioneer Venus Orbiter (PVO) observations. In this paper, we briefly describe the magnetic field experiment of the Venus Express mission. We compare Venus Express mission with PVO mission with respect to the solar wind interaction with Venus. Then we discuss what we will achieve with the upcoming Venus Express mission.     

First observation of 628 CO2 isotopologue band at 3.3 μm in the atmosphere of Venus by solar occultation from Venus Express

The new ESA Venus Express orbiter is the first mission applying the probing technique of solar and stellar occultation to the atmosphere of Venus, with the SPICAV/SOIR instrument. SOIR is a new type of spectrometer used for solar occultations in the range 2.2-4.3 μm. Thanks to a high spectral resolving power R∼15,000-20,000 (unprecedented in planetary space exploration), a new gaseous absorption band was soon detected in the atmospheric transmission spectra around 2982 cm⁻¹, showing a structure resembling an unresolved Q branch and a number of isolated lines with a regular wave number pattern. This absorption could not be matched to any species contained in HITRAN or GEISA databases, but was found very similar to an absorption pattern observed by a US team in the spectrum of solar light reflected by the ground of Mars [Villanueva, G.L., Mumma, M.J., Novak, R.E., Hewagama, T., 2008. Icarus 195 (1), 34-44]. This team then suggested to us that the absorption was due to an uncatalogued transition of the ¹⁶O¹²C¹⁸O molecule. The possible existence of this band was soon confirmed from theoretical considerations by Perevalov and Tashkun. Some SOIR observations of the atmospheric transmission are presented around 2982 cm⁻¹, and rough calculations of line strengths of the Q branch are produced, based on the isotopic ratio measured earlier in the lower atmosphere of Venus. This discovery emphasizes the role of isotopologues of CO₂ (as well as H₂O and HDO) as important greenhouse gases in the atmosphere of Venus.     

Venus express: Highlights of the nominal mission

Venus Express is the first European (ESA) mission to the planet Venus. Its main science goal is to carry out a global survey of the atmosphere, the plasma environment, and the surface of Venus from orbit. The payload consists of seven experiments. It includes a powerful suite of remote sensing imagers and spectrometers, instruments for in-situ investigation of the circumplanetary plasma and magnetic field, and a radio science experiment. The spacecraft, based on the Mars Express bus modified for the conditions at Venus, provides a versatile platform for nadir and limb observations as well as solar, stellar, and radio occultations. In April 2006 Venus Express was inserted in an elliptical polar orbit around Venus, with a pericentre height of ～250 km and apocentre distance of ～66000 km and an orbital period of 24 hours. The nominal mission lasted from June 4, 2006 till October 2, 2007, which corresponds to about two Venus sidereal days. Here we present an overview of the main results of the nominal mission, based on a set of papers recently published in Nature, Icarus, Planetary and Space Science, and Geophysical Research Letters.     

Water vapor variations in the Venus mesosphere from microwave spectra

Mm-wave spectra of HDO in the Venus mesosphere (65-100 km) were obtained over the period March 1998 to June 2004. Each spectrum is a measurement of the hemispheric-average H₂O vapor mixing ratio in the Venus mesosphere. Observations were conducted for wide ranges of Venus solar elongations (46° W to 47° E), and fractional disk illuminations (f=0% to 99%), yielding water vapor abundances on 17 dates and over a full range of local solar time (LST) at the sub-Earth point on Venus. Our mesopheric H₂O values are more numerous and far more precise than the earliest mm-derived H₂O measurements [Encrenaz, Th., Lellouch, E., Paubert, G., Gulkis, S., 1991. First detection of HDO in the atmosphere of Venus at radio wavelengths: An estimate of the H₂O vertical distribution. Astron. Astrophys. 246, L63-L66; Encrenaz, Th., Lellouch, E., Cernicharo, J., Paubert, G., Gulkis, S., Spilker, T., 1995. The thermal profile and water abundance in the Venus mesosphere from H₂O and HDO millimeter observations. Icarus 117, 162-172], allowing an analysis of variability that was previously impossible. Measured 65-100 km H₂O ranged from 0.0±0.06 to 3.5±0.3 ppmv, with significantly different variability than found in previous infrared (lower altitude, cloudtop) studies. Strong global variability on a 1-2 month timescale is clear and unambiguous. A limited number of excellent s/n measurements tentatively indicate the 1-2 month variability manifests most rapidly as change in the lower mesosphere, and more slowly as change in the upper mesosphere. Neither long term (1998-2004) nor diurnal variability in 65-100 km H₂O is evident. While six-year and/or diurnal variabilities are not ruled out, they are weaker than the 1-2 month timescale variation. These conclusions are supported by initial (2004) sub-mm measurements.