Midinfrared spectra and optical constants of bulk hematite: Comparison with particulate hematite spectra

Hematite is an iron oxide that is very important for the study of climatic evolution of Mars. It can occur in three forms: nanophase (dark purple), fine-grained (red) and coarse-grained (gray).In a previous work, we studied the influence of particle size and shape on the infrared spectra (in the wavelength range 6.25-50 μm) of submicron red hematite particles and found that bulk optical constants did not fit the spectra of very fine particles with several classes of models.In the present paper, we derive bulk optical constants of a sample of the same parent material of hematite already used in a previous work in order to determine the particulate optical constants. As a first result we find that, also in this case, bulk and particulate optical constants are different from each other. Furthermore, we show that these bulk optical constants, although derived starting from the same parent material of hematite and used with a model adopting the laboratory measured grain size distribution of the sample, cannot be used to reproduce the spectra of submicron particles. Our results can help the scientific community to appropriately model the contribution of hematite submicron grains to the martian dust for a better understanding of the geologic evolution of the planet.     

The 506 nm absorption feature in pyroxene spectra: Nature and implications for spectroscopy-based studies of pyroxene-bearing targets

High-resolution (0.34 nm) reflectance spectra of a suite of terrestrial ortho- and clinopyroxenes were characterized in the 506-nm region. This region exhibits absorption bands attributed to spin-forbidden transitions in Fe²⁺ located in the M2, and possibly M1, crystallographic site(s). The most intense absorption bands (up to 3.8% deep in <45 μm fractions) are present in low Ca-content orthopyroxene spectra. This region exhibits two (spectral Group I) or more (spectral Group II) absorption bands in the 500-515 nm interval. Group I spectra are associated with the lowest Ca-content samples. For orthopyroxenes, the number of constituent absorption bands and band depths vary as a function of Ca content; increasing Ca content results the appearance of more than two absorption bands and a general reduction in band depths, offsetting an expected increase in band depth with increasing Fe²⁺ content; band depths may also be reduced due to the long wavelength wing of ultraviolet region Fe-O charge transfer absorptions. Band depths and shapes in this region are also a function of grain size, with the strongest bands appearing for larger grain sizes - in the 90-250 μm range. The number and position of constituent absorption bands can be used to constrain factors such as cooling rates, as expressed in the formation of Guinier-Preston zones versus coarser-grained augite exsolution lamellae. Band depths in the spectra of fine-grained (<45 μm) clinopyroxenes do not exceed 1% and are generally lowest for spectral type A clinopyroxenes, where most of the Fe²⁺ is present in the M1 crystallographic site. The appearance of the 506 nm band in the spectra of pyroxene-bearing asteroids can be used to constrain pyroxene composition and structure. The results of this study suggest that detailed analysis of absorption features in the 506 nm region is a powerful tool for determining the composition and structure of pyroxenes. The spectral resolution of the VIR-MS spectrometer aboard the Dawn spacecraft - which will examine Asteroid 4 Vesta, a body possessing surficial pyroxenes - will be sufficient to provide some constraints on pyroxene composition.     

A new systematic approach using the Modified Gaussian Model: Insight for the characterization of chemical composition of olivines, pyroxenes and olivine-pyroxene mixtures

An automatic procedure has been implemented on the original MGM approach (Sunshine et al., 1990) in order to deal with an a priori unknown mafic mineralogy observed in the visible-near infrared by reflectance spectroscopy in the case of laboratory or natural rock spectra. We consider all the mixture possibilities involving orthopyroxene, clinopyroxene and olivine, and use accordingly for each configuration different numbers of Gaussians, depending on the potential complexity of the mixture. A key issue is to initialize the MGM procedure with a proper setting for the Gaussians parameters. An automatic analysis of the shape of the spectrum is first performed. The continuum is handled with a second order polynomial adjusted on the local maxima along the spectrum and Gaussians parameters initial settings are made on the basis of laboratory results available in the literature in the case of simple mixtures of mafic minerals. The returned MGM solutions are then assessed on spectroscopic grounds and either validated or discarded, on the basis of a mineralogical sorting.The results presented in this paper are a first quantitative step to characterize both modal and chemical compositions of pyroxenes and olivines. A demonstration of the methodology on specific examples of binary and ternary olivine-pyroxenes mixtures has been made, which shows that the different non-linear effects which affect the Gaussian parameters (center and strength) can be successfully handled. Of note is the fact that the band center positions associated with the different mafic minerals are not set here in the inverse problem, and thus the MGM outputs are truly informative of the chemical composition of pyroxenes and olivines. With the consideration of some limits on the detection thresholds, these results are quite promising for increasing the operational use of the Modified Gaussian Model with large hyperspectral data sets in view of establishing detailed mineralogical mappings of magmatic units.     

Analysis of phyllosilicate deposits in the Nili Fossae region of Mars: Comparison of TES and OMEGA data

Diverse phyllosilicate deposits discovered previously in the Nili Fossae region with near infrared reflectance data are a window into the complex history of aqueous alteration on Mars. In this work, we used thermal infrared data from the Thermal Emission Spectrometer (TES) in combination with near infrared data from the Observatoire pour la Minéralogie, l’Eau, les Glaces, et l’Activité (OMEGA) to better constrain the mineralogy and geologic origin of these deposits. We developed a TES spectral index for identification of clay minerals, which correctly identifies the phyllosilicates in the Nili Fossae area and points to several other interesting deposits in the Syrtis Major region. However, detailed inspection of the TES spectral features of Nili Fossae phyllosilicates shows a feature at low wavenumbers (350-550 cm⁻¹) that is not an exact match to any specific Fe³⁺-, Al-, or Mg-rich phyllosilicate phase. Instead, the feature is more similar to basaltic glass and may indicate that the phyllosilicates in this region are: (1) rich in Fe²⁺ (based on similarity to trends seen in laboratory data of clay minerals), (2) poorly crystalline/extremely disordered, and/or (3) present within a matrix of actual basalt glass. This feature is similar to spectral features seen in altered rocks in the Columbia Hills region of Gusev Crater by previous authors. By calibrating measured spectral index values against mathematical spectral mixtures of typical martian dark surfaces and known abundances of alteration minerals, we are able to estimate an enrichment in abundance of alteration minerals in the altered surfaces. Many dark, Noachian deposits in the Nili Fossae area are enriched phyllosilicates by 20-30% (±10-15%) relative to dark, volcanic surfaces in the same region. The distribution and abundance of these phases indicates that alteration in the region was pervasive, but did not completely erase the original mineralogy of what was likely an Fe-rich basalt protolith. As a group, the Nili Fossae phyllosilicate deposits are fundamentally different from those found in the Mawrth Vallis region. Nili Fossae deposits have strong thermal infrared features related to admixed pyroxene, plagioclase, and occasionally olivine, whereas the Mawrth Vallis deposits contain no mafic minerals. Comparison of TES and OMEGA data also illustrates some more general differences between the datasets, including the impact of physical character of the martian surface on detectability of minerals in each spectral range.     

A multidisciplinary study of silica sinter deposits with applications to silica identification and detection of fossil life on Mars

Surface features observed on Mars and evidence from martian meteorites both suggest that hydrothermal systems have operated in the crust of the planet. Hydrothermal systems are a potential habitat for living organisms and identifying these on Mars is, therefore, important in the search for life beyond the Earth. One of the surface expressions of hydrothermal systems on Earth are silica sinters, deposited during the cooling of hydrothermal solutions. In this paper we present analyses of the mineralogy, textures, chemistry and organic chemistry of silica sinters from two very different geothermal provinces, Waiotapu, New Zealand and Haukadalur, Iceland, in order to determine common features by which silica sinters can be identified. Infrared reflectance spectroscopy was utilised in combination with textural studies to evaluate the mineralogy of sinter deposits in terms of the abundances of different polymorphs of SiO₂. Concentrations of organic molecules, principally lipids, within regions of the sinters in which there is textural evidence for micro-organisms were identified in the infrared spectral data and their presence was confirmed using gas chromatography mass spectroscopy. The results of this study indicate that reflectance spectra in the wavelength region from 2.5 to 14 μm, when calibrated against natural terrestrial analogues, can be used to identify silica sinters, as well as the possible presence of recent microbial communities on Mars.     

Quantitative compositional analysis of martian mafic regions using the MEx/OMEGA reflectance data 1. Methodology, uncertainties and examples of application

The Mars Express Observatoire pour la Minéralogie, l'Eau, les Glaces et l'Activité (OMEGA) collected an unprecedented visible and near-infrared hyperspectral dataset covering the low albedo regions of Mars. We investigate the ability to infer modal abundance of surfaces of these regions from a radiative transfer model developed by Shkuratov et al. [Shkuratov, Y., Starukhina, L., Hoffmann, H., Arnold, G., 1999. Icarus 137, 235-246] and adapted to basaltic surfaces by Poulet and Erard [Poulet F., Erard, S., 2004. J. Geophys. Res. 109 (E2), doi:10.1029/2003JE002179]. From OMEGA measurements of mafic surfaces, we develop several sensitivity tests to assess the extent to which the model can be applied to predict pyroxene composition (high-calcium phase and low-calcium phase), abundance of almost neutral components (plagioclase) in the near-infrared wavelength as well as grain sizes, by using a library of selected end-members. Results of the sensitivity tests indicate that the scattering model can estimate both abundances and grain sizes of major basaltic materials of low albedo regions within uncertainties (±5 to 15 vol%). The model is then applied to data from dissected cratered terrains located in Terra Meridiani. The derived grain size including uncertainties is in the 50-500 μm range. This is consistent with the thermal inertia and albedo of this region, which indicates a fine sand-sized surface with little dust. The abundances of plagioclase (43-57%) and pyroxenes (35-45±10%, including 11±5% of low-calcium phase) are in good agreement with previous basalt-like compositions of low albedo regions from thermal infrared spectral measurements. The method presented in this paper will provide a valuable tool for evaluating the modal mineralogy of other mafic regions of Mars observed in the near-infrared wavelength range.     

Assessing the limits of the Modified Gaussian Model for remote spectroscopic studies of pyroxenes on Mars

We investigate the ability to refine pyroxene composition and modal abundance from laboratory and remotely acquired spectra. Laboratory data including the martian meteorites, Shergotty, Zagami, MIL03346, and ALH84001 as well as additional pyroxene-rich spectra obtained from the OMEGA (Observatoire pour la Minéralogie, l'Eau, les Glaces, et l'Activité) spectrometer for Mars are characterized using the Modified Gaussian Model (MGM), a spectral deconvolution method developed by Sunshine et al. [Sunshine, J.M., Pieters, C.M., Pratt, S., 1990. J. Geophys. Res. 95, 6955-6966]. We develop two sensitivity tests to assess the extent to which the MGM can consistently predict (1) pyroxene composition and (2) modal abundance for a compositionally diverse suite of pyroxene spectra. Results of the sensitivity tests indicate that the MGM can be appropriately applied to remote spectroscopic measurements of extraterrestrial surfaces and can estimate pyroxene composition and relative abundance within a derived uncertainty. Deconvolved band positions for laboratory spectra of the meteorites Shergotty and Zagami are determined within ±17 nm while remotely acquired OMEGA spectra are defined within ±50 nm. These results suggest that absolute compositions can be uniquely derived from laboratory pyroxene-rich spectra and non-uniquely derived from the remote measurements of OMEGA at this time. While relative pyroxene chemistries are not assessed from OMEGA measurements at this time, relative pyroxene abundances are estimated using a normalized band strength ratio between the low-calcium (LCP) and high-calcium (HCP) endmember components and are constrained to ±10%. The fraction of LCP in a two-pyroxene mixture is the derived value from the normalized band strength ratio, LCP/(LCP + HCP). This calculation for relative abundance is robust in the presence of up to 10-15% olivine. Deconvolution results from the OMEGA spectra indicate that the ancient terrain in the Syrtis Major region is uniquely enriched in LCP (59±10% LCP) relative to HCP while the volcanics of Syrtis Major are uniquely enriched in HCP (39±10% LCP).     

Mineralogy of Asteroid 1459 Magnya and implications for its origin

Detailed near-infrared spectral observations of Asteroid 1459 Magnya reveal an asteroid that is primarily composed of pyroxene and plagioclase feldspar, confirming earlier suggestions that Magnya has a basaltic composition. The average Magnya spectrum for March 23, 2002 has a Band I center of 0.926 μm and a Band II center of 1.938 μm. Observations over  hours show little variation in band center positions. The feldspar-to-pyroxene ratio is ∼0.6 on Magnya's surface. Comparing Magnya with the spectral parameters from 4 Vesta shows discordant pyroxene chemistries; Magnya's pyroxenes contain ∼10 mol% less Fs than Vesta's pyroxenes. This suggests that Magnya originated from a parent body other than 4 Vesta and that its progenitor formed in a more chemically reduced region of the solar nebula within the asteroid belt.     

Fresnel modeling of hematite crystal surfaces and application to martian hematite spherules

The gray crystalline hematite at Meridiani Planum first discovered by the Mars Global Surveyor Thermal Emission Spectrometer (MGS-TES) instrument occurs as spherules that have been interpreted as concretions. Analysis of the TES and mini-TES spectra shows that no 390 cm⁻¹ feature is present in the characteristic martian hematite spectrum. Here, we incorporate the mid-IR optical constants of hematite into a simple Fresnel reflectance model to understand the effect of emission angle and crystal morphology on the presence or absence of the 390 cm⁻¹ feature in an IR hematite spectrum. Based on the results we offer two models for the internal structure of the martian hematite spherules.     

Stratigraphy in the Mawrth Vallis region through OMEGA, HRSC color imagery and DTM

The Mawrth Vallis region contains an extensive (at least 300 km × 400 km) and thick (?300 m), finely layered (at meter scale), clay-rich unit detected by OMEGA. We use OMEGA, HRSC DTMs derived from stereoscopic imagery, HRSC color imagery and high resolution imagery such as MOC, CTX and HiRISE to characterize the geometry and the composition of the clay-rich unit at the regional scale. Our results show that the clay-bearing unit can be divided into sub-units on the basis of differences in color and composition. In false-color visible imagery, alternating white/bluish and orange/red colored units correspond to a compositional succession of, respectively, Al- and Fe- or Mg-phyllosilicate rich material. Geological cross-sections are presented along the principal outcrops of the region in order to define the stratigraphy of these sub-units. This method shows that the dips of the sub-units are frequently close to the slopes of the present topography, except for scarps visible at the dichotomy boundary, inside impact craters walls, and outcrops inside Mawrth Vallis. In addition to the Al- and Fe- or Mg-phyllosilicate rich sub-units, an altered surface is identified as the lower basement unit. We propose two possible end-member scenarios to explain the derived stratigraphy: (1) alteration of volcaniclastic, aeolian or aqueous layered deposits of various compositions by groundwater, resulting in distinct altered rocks; or (2) Alteration coeval with the deposition of sediments under varying chemical conditions, in wet pedodiagenetic environment.     

Mineralogical constraints on the high-silica martian surface component observed by TES

The Thermal Emission Spectrometer (TES) has observed a high-silica material in the dark regions of Mars that is spectrally similar to obsidian glass and may have a volcanic origin. An alternate interpretation is that the spectrally amorphous material consists of clay minerals or some other secondary material, formed by chemical alteration of surface rocks. The regions where this material is observed (e.g., Acidalia Planitia) have relatively high spectral contrast, suggesting that the high-silica material exists as coarse particulates, indurated soils or cements, within rocks, or as indurated coatings on rock surfaces. The geologic interpretation of this spectral result has major implications for understanding magmatic evolution and weathering processes on Mars. One of the complications in interpreting spectral observations of glasses and clay minerals is that both are structurally and compositionally complex. In this study, we perform a detailed spectroscopic analysis of indurated smectite clay minerals and relate their thermal emission spectral features to structural and crystal chemical properties. We examine the spectral similarities and differences between smectite clay minerals and obsidian glass from a structural-chemical perspective, and make further mineralogical interpretations from previous TES results. The results suggest that neither smectite clays nor any clay mineral with similar structural and chemical properties can adequately explain TES observations of high-silica materials in some martian dark regions. If the spectrally amorphous materials observed by TES do represent an alteration product, then these materials are likely to be poorly crystalline aluminosilicates. While all clay minerals have Si/O ratios ?0.4, the position of the emissivity minimum at Mars suggests a Si/O ratio of 0.4-0.5. The spectral observation could be explained by the existence of a silica-rich alteration product, such as Al- or Fe-bearing opal, an intimate physical mixture of relatively pure silica and other aluminosilicates (such as clay minerals or clay precursors), or certain zeolites. The chemical alteration of basaltic rocks on Mars to phyllosilicate-poor, silica-rich alteration products provides a geologically reasonable and consistent explanation for the global TES surface mineralogical results.     

Mid-infrared reflectance spectra and optical constants of six iron oxide/oxyhydroxide phases

We have determined the real and imaginary indices of refraction (n and k) for six iron oxide/oxyhydroxide phases—magnetite, maghemite, goethite, lepidocrocite, akaganéite, and ferrihydrite. A single crystal of magnetite was used to derive bulk n and k values from 100-2000 cm⁻¹ (5-100 μm). Synthetic nanocrystalline samples of maghemite, goethite, lepidocrocite, akaganéite, and ferrihydrite were pressed into compact pellets used to determine bulk n and k values from 100-1200 cm⁻¹ (8.33-100 μm). All values of n and k (the optical constants) were determined from specular reflectance spectra acquired at 2 cm⁻¹ spectral sampling using classical Lorentz-Lorenz dispersion theory. In this paper, we present the optical constants of all six minerals and the oscillator parameters with which they were modeled. Use of these optical constants could aid in radiative transfer models of terrestrial dust as well as Mars, the Moon, and airless bodies in the Solar System.     

Radar measurements of Mercury’s north pole at 70 cm wavelength

We present radar imaging of Mercury using the Arecibo Observatory’s 70-cm wavelength radar system during the inferior conjunction of July 1999. At that time the sub-Earth latitude was ∼11°N and the highly reflective region at Mercury’s north pole that was first identified in radar images at the shorter wavelengths of 3.6 cm [Slade, M.A., Butler, B.J., Muhleman, D.O., 1992. Science 258, 635-640] and 13 cm [Harmon, J.K., Slade, M.A., 1992. Science 258, 640-643] was again clearly detected. The reflectivity averaged over a 75,000 km² region including the pole is similar to that measured at the other wavelengths over a comparable area, and the 70 cm circular polarization ratio of μ_C∼0.87 is possibly slightly lower. If this strong backscattering results from volume scattering in low absorption layers, the persistence of this effect over more than an order of magnitude change in wavelength scale has implications for the depth and thickness of the deposits responsible. The resolution of the radar maps at this wavelength is not sufficient to resolve individual craters, nor to discern features at other latitudes, but the planet’s total reflectivity is consistent with previous work and the scattering function suggests a surface roughness at this wavelength similar to the lunar highlands.     

Assessing spectral evidence of aqueous activity in two putative martian paleolakes

We evaluate the evidence for the presence of mineral spectral signatures indicative of the past presence of water at two putative paleolakes on Mars using observations by the Mars Reconnaissance Orbiter (MRO) Compact Reconnaissance Image Spectrometer for Mars (CRISM). CRISM spectra of both sites are consistent with laboratory spectra of Mg-rich phyllosilicates. Our analysis represents the first detailed evaluation of these locations. The spatial occurrence and association with topographic features within the craters is distinctly different for the two sites. The occurrence of these minerals supports the conclusion that water was once active in the areas sampled by these craters. The distribution of the phyllosilicates in Luqa does not provide distinctive evidence for the presence of a previous standing body of water and is consistent with either impact emplacement or post-impact alteration. For Cankuzo, the phyllosilicate distribution provides evidence of a layer in the crater wall indicative of aqueous activity, but does not require a paleolake.     

Thermal inertia of main belt asteroids smaller than 100 km from IRAS data

Recent works have shown that the thermal inertia of km-sized near-Earth asteroids (NEAs) is more than 2 orders of magnitude higher than that of main belt asteroids (MBAs) with sizes (diameters) between 200 and 1000 km. This confirms the idea that large MBAs, over hundreds millions of years, have developed a fine and thick thermally insulating regolith layer, responsible for the low values of their thermal inertia, whereas km-sized asteroids, having collisional lifetimes of only some millions years, have less regolith, and consequently a larger surface thermal inertia.Because it is believed that regolith on asteroids forms as a result of impact processes, a better knowledge of asteroid thermal inertia and its correlation with size, taxonomic type, and density can be used as an important constraint for modeling of impact processes on asteroids. However, our knowledge of asteroids’ thermal inertia values is still based on few data points with NEAs covering the size range 0.1-20 km and MBAs that .Here, we use IRAS infrared measurements to estimate the thermal inertia values of MBAs with diameters and known shapes and spin vector, filling an important size gap between the largest MBAs and the km-sized NEAs. An update to the inverse correlation between thermal inertia and diameter is presented. For some asteroids thermophysical modeling allowed us to discriminate between the two still possible spin vector solutions derived from optical lightcurve inversion. This is important for (720) Bohlinia: our preferred solution was predicted to be the correct one by Vokrouhlický et al. [2003. The vector alignments of asteroid spins by thermal torques. Nature 425, 147-151] just on theoretical grounds.     

Mid-infrared (5–100 μm) reflectance spectra and optical constants of ten phyllosilicate minerals

We have derived the real and imaginary indices of refraction for 10 phyllosilicate minerals—montmorillonite, beidellite, nontronite, hectorite, saponite, illite, illite–smectite (60/40 interlayered) kaolinite, halloysite, and serpentine—from 100–2000 cm⁻¹ (5–100 μm) at 2 cm⁻¹ spectral sampling using classical Lorentz–Lorenz dispersion theory. We present the real and imaginary indices and the oscillator parameters with which they were modeled. Use of these optical constants will aid in the modeling of thermal infrared spectra of planets, asteroids, interplanetary and interstellar dust, and protoplanetary disks around nearby stars.     

Estimating the water content of hydrated minerals using reflectance spectroscopy: I. Effects of darkening agents and low-albedo materials

The apparent strength of absorptions due to H₂O near 1.9 and 3 μm in reflectance spectra is strongly affected by sample albedo. This study uses experimental and analytical approaches to quantify the effects of albedo on estimating the water content of hydrated minerals using various band parameters. We compare spectral band parameters for a series of low-albedo physical and numerical mixtures to measured water contents. Physical experiments consist of montmorillonite, clinoptilolite, and palagonite mixed with lesser amounts of carbon black and ilmenite, whereas numerical mixtures are composed of these host minerals mixed with a material of constant, low albedo. We find the effective single-particle absorption-thickness parameter provides the best correlation to water content, independent of composition and albedo, when derived from continuum-removed single scattering albedo spectra. Uncertainties in estimated water content are on the order of ±1 wt% using this method. The normalized optical path length parameter provides the best correlation to water content when using reflectance spectra, yielding estimates within ±1.6 wt% H₂O. The accuracy of these models is related to the physical nature of the darkening material. Scattering and absorption efficiencies are easier to model for intimate mixtures containing relatively large, dark grains than mixtures dominated by coatings of a fine-grained, strongly absorbing material. This suggests the physical properties that give rise to the albedo of a material are an important factor for accurate estimates of absolute water content.     

Composition and thermal inertia of the Mawrth Vallis region of Mars from TES and THEMIS data

Clay mineral-bearing deposits previously discovered on Mars with near infrared (λ=0.3-5 μm) remote sensing data are of major significance for understanding the aqueous history, geological evolution, and past habitability of Mars. In this study, we analyzed the thermal infrared (λ=6-35 μm) surface properties of the most extensive phyllosilicate deposit on Mars: the Mawrth Vallis area. Clay mineral-bearing units, which in visible images appear to be relatively light-toned, layered bedrock, have thermal inertia values ranging from 150 to 460 J m⁻² K⁻¹ s^−1/2. This suggests the deposits are composed of a mixture of rock with sand and dust at 100-meter scales. Dark-toned materials that mantle the clay-bearing surfaces have thermal inertia values ranging from 150 to 800, indicating variable degrees of rockiness or induration of this younger sedimentary or pyroclastic unit. Thermal Emission Spectrometer (TES) spectra of the light-toned rocks were analyzed with a number of techniques, but none of the results shows a large phyllosilicate component as has been detected in the same surfaces with near-infrared data. Instead, TES spectra of light-toned surfaces are best modeled by a combination of plagioclase feldspar, high-silica materials (similar to impure opaline silica or felsic glass), and zeolites. We propose three hypotheses for why the clay minerals are not apparent in thermal infrared data, including effects due to surface roughness, sub-pixel mixing of multiple surface temperatures, and low absolute mineral abundances combined with differences in spatial sampling between instruments. Zeolites modeled in TES spectra could be a previously unrecognized component of the alteration assemblage in the phyllosilicate-bearing rocks of the Mawrth Vallis area. TES spectral index mapping suggests that (Fe/Mg)-clays detected with near infrared data correspond to trioctahedral (Fe²⁺) clay minerals rather than nontronite-like clays. The average mineralogy and geologic context of these complex, interbedded deposits suggests they are either aqueous sedimentary rocks, altered pyroclastic deposits, or a combination of both.     

Correlations between VIMS and RADAR data over the surface of Titan: Implications for Titan’s surface properties

We apply a multivariate statistical method to Titan data acquired by different instruments onboard the Cassini spacecraft. We have searched through Cassini/VIMS hyperspectral cubes, selecting those data with convenient viewing geometry and that overlap with Cassini/RADAR scatterometry footprints with a comparable spatial resolution. We look for correlations between the infrared and microwave ranges the two instruments cover. Where found, the normalized backscatter cross-section obtained from the scatterometer measurement, corrected for incidence angle, and the calibrated antenna temperature measured along with the scatterometry echoes, are combined with the infrared reflectances, with estimated errors, to produce an aggregate data set, that we process using a multivariate classification method to identify homogeneous taxonomic units in the multivariate space of the samples.In medium resolution data (from 20 to 100 km/pixel), sampling relatively large portions of the satellite’s surface, we find regional geophysical units matching both the major dark and bright features seen in the optical mosaic. Given the VIMS cubes and RADAR scatterometer passes considered in this work, the largest homogeneous type is associated with the dark equatorial basins, showing similar characteristics as each other on the basis of all the considered parameters.On the other hand, the major bright features seen in these data generally do not show the same characteristics as each other. Xanadu, the largest continental feature, is as bright as the other equatorial bright features, while showing the highest backscattering coefficient of the entire satellite. Tsegihi is very bright at 5 μm but it shows a low backscattering coefficient, so it could have a low roughness on a regional scale and/or a different composition. Another well-defined region, located southwest of Xanadu beyond the Tui Regio, seems to be detached from the surrounding terrains, being bright at 2.69, 2.78 and 5 μm but having a low radar brightness. In this way, other units can be found that show correlations or anti-correlations between the scatterometric response and the spectrophotometric behavior, not evident from the optical remote sensing data.     

Mineralogy and thermal properties of V-type Asteroid 956 Elisa: Evidence for diogenitic material from the Spitzer IRS (5-35 μm) spectrum

We present the thermal infrared (5-35 μm) spectrum of 956 Elisa as measured by the Spitzer Infrared Spectrograph (“IRS”; Houck, J.R. et al. [2004]. Astrophys. J. Suppl. 154, 18-24) together with new groundbased lightcurve data and near-IR spectra. From the visible lightcurve photometry, we determine a rotation period of 16.494 ± 0.001 h, identify the rotational phase of the Spitzer observations, and estimate the visible absolute magnitude (H_V) at that rotational phase to be 12.58 ± 0.04. From radiometric analysis of the thermal flux spectrum, we find that at the time of observation 956 Elisa had a projected radius of 5.3 ± 0.4 km with a visible albedo p_V = 0.142 ± 0.022, significantly lower than that of the prototype V-type asteroid, 4 Vesta. (This corresponds to a radius of 5.2 ± 0.4 km at lightcurve mean.) Analysis with the standard thermal model (STM) results in a sub-solar temperature of 292.3 ±  2.8 K and beaming parameter η = 1.16 ± 0.05. Thermophysical modeling places a lower limit of on the thermal inertia of the asteroid’s surface layer (if the surface is very smooth) but more likely values fall between 30 and depending on the sense of rotation.The emissivity spectrum, calculated by dividing the measured thermal flux spectrum by the modeled thermal continuum, exhibits mineralogically interpretable spectral features within the 9-12 μm reststrahlen band, the 15-16.5 μm Si-O-Si stretching region, and the 16-25 μm reststrahlen region that are consistent with pyroxene of diogenitic composition: extant diogenitic pyroxenes fall within the narrow compositional range Wo_2±1En_74±2Fs_24±1. Spectral deconvolution of the 9-12 μm reststrahlen features indicates that up to ≈20% olivine may also be present, suggesting an olivine-diogenite-like mineralogy. The mid-IR spectrum is inconsistent with non-cumulate eucrite as the major component on the surface of 956 Elisa, although cumulate eucrite material may be present at abundances lower than that of the diogenite component.Analysis of new near-IR spectra of 956 Elisa with the Modified Gaussian Model (MGM; Sunshine, J.M., Pieters, C.M., Pratt, S.F. [1990]. J. Geophys. Res. 95 (May), 6955-6966) results in two pyroxene compositions: 75% magnesian low-Ca pyroxene and 25% high-Ca pyroxene. High-Ca pyroxene is not evident in the mid-IR data, but may belong to a component that is underrepresented in the mid-IR spectrum either because of its spatial distribution on the asteroid or because of its particle size. High-Ca pyroxenes that occur as exsolution lamellae may also be more evident spectrally in the NIR than in the mid-IR. In any case, we find that the mid-IR spectrum of 956 Elisa is dominated by emission from material of diogenite-like composition, which has very rarely been observed among asteroids.