Phosphine on Jupiter and Saturn from Cassini/CIRS

The global distribution of phosphine (PH₃) on Jupiter and Saturn is derived using 2.5 cm⁻¹ spectral resolution Cassini/CIRS observations. We extend the preliminary PH₃ analyses on the gas giants [Irwin, P.G.J., and 6 colleagues, 2004. Icarus 172, 37-49; Fletcher, L.N., and 9 colleagues, 2007a. Icarus 188, 72-88] by (a) incorporating a wider range of Cassini/CIRS datasets and by considering a broader spectral range; (b) direct incorporation of thermal infrared opacities due to tropospheric aerosols and (c) using a common retrieval algorithm and spectroscopic line database to allow direct comparison between these two gas giants.The results suggest striking similarities between the tropospheric dynamics in the 100-1000 mbar regions of the giant planets: both demonstrate enhanced PH₃ at the equator, depletion over neighbouring equatorial belts and mid-latitude belt/zone structures. Saturn's polar PH₃ shows depletion within the hot cyclonic polar vortices. Jovian aerosol distributions are consistent with previous independent studies, and on Saturn we demonstrate that CIRS spectra are most consistent with a haze in the 100-400 mbar range with a mean optical depth of 0.1 at 10 μm. Unlike Jupiter, Saturn's tropospheric haze shows a hemispherical asymmetry, being more opaque in the southern summer hemisphere than in the north. Thermal-IR haze opacity is not enhanced at Saturn's equator as it is on Jupiter.Small-scale perturbations to the mean PH₃ abundance are discussed both in terms of a model of meridional overturning and parameterisation as eddy mixing. The large-scale structure of the PH₃ distributions is likely to be related to changes in the photochemical lifetimes and the shielding due to aerosol opacities. On Saturn, the enhanced summer opacity results in shielding and extended photochemical lifetimes for PH₃, permitting elevated PH₃ levels over Saturn's summer hemisphere.     

Diagnostics of Titan's stratospheric dynamics using Cassini/CIRS data and the 2-dimensional IPSL circulation model

The dynamics of Titan's stratosphere is discussed in this study, based on a comparison between observations by the CIRS instrument on board the Cassini spacecraft, and results of the 2-dimensional circulation model developed at the Institute Pierre-Simon Laplace, available at http://www.lmd.jussieu.fr/titanDbase [Rannou, P., Lebonnois, S., Hourdin, F., Luz, D., 2005. Adv. Space Res. 36, 2194-2198]. The comparison aims at both evaluating the model's capabilities and interpreting the observations concerning: (1) dynamical and thermal structure using temperature retrievals from Cassini/CIRS and the vertical profile of zonal wind at the Huygens landing site obtained by Huygens/DWE; and (2) vertical and latitudinal profiles of stratospheric gases deduced from Cassini/CIRS data. The modeled thermal structure is similar to that inferred from observations (Cassini/CIRS and Earth-based observations). However, the upper stratosphere (above 0.05 mbar) is systematically too hot in the 2D-CM, and therefore the stratopause region is not well represented. This bias may be related to the haze structure and to misrepresented radiative effects in this region, such as the cooling effect of hydrogen cyanide (HCN). The 2D-CM produces a strong atmospheric superrotation, with zonal winds reaching 200 m s⁻¹ at high winter latitudes between 200 and 300 km altitude (0.1-1 mbar). The modeled zonal winds are in good agreement with retrieved wind fields from occultation observations, Cassini/CIRS and Huygens/DWE. Changes to the thermal structure are coupled to changes in the meridional circulation and polar vortex extension, and therefore affect chemical distributions, especially in winter polar regions. When a higher altitude haze production source is used, the resulting modeled meridional circulation is weaker and the vertical and horizontal mixing due to the polar vortex is less extended in latitude. There is an overall good agreement between modeled chemical distributions and observations in equatorial regions. The difference in observed vertical gradients of C₂H₂ and HCN may be an indicator of the relative strength of circulation and chemical loss of HCN. The negative vertical gradient of ethylene in the low stratosphere at 15° S, cannot be modeled with simple 1-dimensional models, where a strong photochemical sink in the middle stratosphere would be necessary. It is explained here by dynamical advection from the winter pole towards the equator in the low stratosphere and by the fact that ethylene does not condense. Near the winter pole (80° N), some compounds (C₄H₂, C₃H₄) exhibit an (interior) minimum in the observed abundance vertical profiles, whereas 2D-CM profiles are well mixed all along the atmospheric column. This minimum can be a diagnostic of the strength of the meridional circulation, and of the spatial extension of the winter polar vortex where strong descending motions are present. In the summer hemisphere, observed stratospheric abundances are uniform in latitude, whereas the model maintains a residual enrichment over the summer pole from the spring cell due to a secondary meridional overturning between 1 and 50 mbar, at latitudes south of 40-50° S. The strength, as well as spatial and temporal extensions of this structure are a difficulty, that may be linked to possible misrepresentation of horizontally mixing processes, due to the restricted 2-dimensional nature of the model. This restriction should also be kept in mind as a possible source of other discrepancies.     

Waves in Jupiter's atmosphere observed by the Cassini ISS and CIRS instruments

The Cassini Imaging Science Subsystem (ISS) and Composite Infrared Spectrometer (CIRS) reported a North Equatorial Belt (NEB) wave in Jupiter's atmosphere from optical images [Porco, C.C., and 23 colleagues, 2003. Science 299, 1541-1547] and thermal maps [Flasar, F.M., and 39 colleagues, 2004. Nature 427, 132-135], respectively. The connection between the two waves remained uncertain because the two observations were not simultaneous. Here we report on simultaneous ISS images and CIRS thermal maps that confirm that the NEB wave shown in the ISS ultraviolet (UV1) and strong methane band (MT3) images is correlated with the thermal wave in the CIRS temperature maps, with low temperatures in the CIRS maps (upwelling) corresponding to dark regions in the UV1 images (UV-absorbing particles) and bright regions in the MT3 images (high clouds and haze). The long period of the NEB wave suggests that it is a planetary (Rossby) wave. The combined observations from the ISS and CIRS are utilized to discuss the vertical and meridional propagation of the NEB wave, which offers a possible explanation for why the NEB wave is confined to specific latitudes and altitudes. Further, the ISS UV1 images reveal a circumpolar wave centered at 48.5° S (planetocentric) and probably located in the stratosphere, as suggested by the ISS and CIRS observations. The simultaneous comparison between the ISS and CIRS also implies that the large dark oval in the polar stratosphere of Jupiter discovered in the ISS UV1 images [Porco, C.C., and 23 colleagues, 2003. Science 299, 1541-1547] is the same feature as the warm regions at high northern latitudes in the CIRS 1-mbar temperature maps [Flasar, F.M., and 39 colleagues, 2004. Nature 427, 132-135]. This comparison supports a previous suggestion that the dark oval in the ISS UV1 images is linked to auroral precipitation and heating [Porco, C.C., and 23 colleagues, 2003. Science 299, 1541-1547].     

Lightning storms on Saturn observed by Cassini ISS and RPWS during 2004-2006

We report on Cassini Imaging Science Subsystem (ISS) data correlated with Radio and Plasma Wave Science (RPWS) observations, which indicate lightning on Saturn. A rare bright cloud erupt at ∼35° South planetocentric latitude when radio emissions (Saturn Electrostatic Discharges, or SEDs) occur. The cloud consisting of few consecutive eruptions typically lasts for several weeks, and then both the cloud and the SEDs disappear. They may reappear again after several months or may stay inactive for a year. Possibly, all the clouds are produced by the same atmospheric disturbance which drifts West at 0.45 °/day. As of March 2007, four such correlated visible and radio storms have been observed since Cassini Saturn Orbit Insertion (July 2004). In all four cases the SEDs are periodic with roughly Saturn's rotation rate (h¹⁰m³⁹), and show correlated phase relative to the times when the clouds are seen on the spacecraft-facing side of the planet, as had been shown for the 2004 storms in [Porco, C.C., and 34 colleagues, 2005. Science 307, 1243-1247]. The 2000-km-scale storm clouds erupt to unusually high altitudes and then slowly fade at high altitudes and spread at low altitudes. The onset time of individual eruptions is less than a day during which time the SEDs reach their maximum rates. This suggests vigorous atmospheric updrafts accompanied by strong precipitation and lightning. Unlike lightning on Earth and Jupiter, where considerable lightning activity is known to exist, only one latitude on Saturn has produced lightning strong enough to be detected during the two and a half years of Cassini observations. This may partly be a detection issue.     

Jupiter's ammonia clouds—localized or ubiquitous?

From an analysis of the Galileo Near Infrared Imaging Spectrometer (NIMS) data, Baines et al. (Icarus 159 (2002) 74) have reported that spectrally identifiable ammonia clouds (SIACs) cover less than 1% of Jupiter. Localized ammonia clouds have been identified also in the Cassini Composite Infrared Spectrometer (CIRS) observations (Planet. Space Sci. 52 (2004a) 385). Yet, ground-based, satellite and spacecraft observations show that clouds exist everywhere on Jupiter. Thermochemical models also predict that Jupiter must be covered with clouds, with the top layer made up of ammonia ice. For a solar composition atmosphere, models predict the base of the ammonia clouds to be at 720 mb, at 1000 mb if N/H were 4×solar, and at 0.5 bar for depleted ammonia of 10⁻²×solar (Planet. Space Sci. 47 (1999) 1243). Thus, the above NIMS and CIRS findings are seemingly at odds with other observations and cloud physics models. We suggest that the clouds of ammonia ice are ubiquitous on Jupiter, but that spectral identification of all but the freshest of the ammonia clouds and high altitude ammonia haze is inhibited by a combination of (i) dusting, starting with hydrocarbon haze particles falling from Jupiter's stratosphere and combining with an even much larger source—the hydrazine haze; (ii) cloud properties, including ammonia aerosol particle size effects. In this paper, we investigate the role of photochemical haze and find that a substantial amount of haze material can deposit on the upper cloud layer of Jupiter, possibly enough to mask its spectral signature. The stratospheric haze particles result from condensation of polycyclic aromatic hydrocarbons (PAHs), whereas hydrazine ice is formed from ammonia photochemistry. We anticipate similar conditions to prevail on Saturn.     

Coupling photochemistry with haze formation in Titan's atmosphere, Part II: Results and validation with Cassini/Huygens data

The new one-dimensional radiative-convective/photochemical/microphysical model described in Part I is applied to the study of Titan's atmospheric processes that lead to haze formation. Our model generates the haze structure from the gaseous species photochemistry. Model results are presented for the species vertical concentration profiles, haze formation and its radiative properties, vertical temperature/density profiles and geometric albedo. These are validated against Cassini/Huygens observations and other ground-based and space-borne measurements. The model reproduces well most of the latest measurements from the Cassini/Huygens instruments for the chemical composition of Titan's atmosphere and the vertical profiles of the observed species. For the haze production we have included pathways that are based on pure hydrocarbons, pure nitriles and hydrocarbon/nitrile copolymers. From these, the nitrile and copolymer pathways provide the stronger contribution, in agreement with the results from the ACP instrument, which support the incorporation of nitrogen in the pyrolized haze structures. Our haze model reveals a new second major peak in the vertical profile of haze production rate between 500 and 900 km. This peak is produced by the copolymer family used and has important ramifications for the vertical atmospheric temperature profile and geometric albedo. In particular, the existence of this second peak determines the vertical profile of haze extinction. Our model results have been compared with the DISR retrieved haze extinction profiles and are found to be in very good agreement. We have also incorporated in our model heterogeneous chemistry on the haze particles that converts atomic hydrogen to molecular hydrogen. The resultant H₂ profile is closer to the INMS measurements, while the vertical profile of the diacetylene formed is found to be closer to that of the CIRS profile when this heterogenous chemistry is included.     

Characterising Saturn's vertical temperature structure from Cassini/CIRS

Thermal infrared spectra of Saturn from 10-1400 cm⁻¹ at 15 cm⁻¹ spectral resolution and a spatial resolution of 1°-2° latitude have been obtained by the Cassini Composite Infrared Spectrometer [Flasar, F.M., and 44 colleagues, 2004. Space Sci. Rev. 115, 169-297]. Many thousands of spectra, acquired over eighteen-months of observations, are analysed using an optimal estimation retrieval code [Irwin, P.G.J., Parrish, P., Fouchet, T., Calcutt, S.B., Taylor, F.W., Simon-Miller, A.A., Nixon, C.A., 2004. Icarus 172, 37-49] to retrieve the temperature structure and para-hydrogen distribution over Saturn's northern (winter) and southern (summer) hemispheres. The vertical temperature structure is analysed in detail to study seasonal asymmetries in the tropopause height (65-90 mbar), the location of the radiative-convective boundary (350-500 mbar), and the variation with latitude of a temperature knee (between 150 and 300 mbar) which was first observed in inversions of Voyager/IRIS spectra [Hanel, R., and 15 colleagues, 1981. Science 212, 192-200; Hanel, R., Conrath, B., Flasar, F.M., Kunde, V., Maguire, W., Pearl, J.C., Pirraglia, J., Samuelson, R., Cruikshank, D.P., Gautier, D., Gierasch, P.J., Horn, L., Ponnamperuma, C., 1982. Science 215, 544-548]. Uncertainties due to both the modelling of spectral absorptions (collision-induced absorption coefficients, tropospheric hazes, helium abundance) and the nature of our retrieval algorithm are quantified.Temperatures in the stratosphere near 1 mbar show a 25-30 K temperature difference between the north pole and south pole. This asymmetry becomes less pronounced with depth as the radiative time constant for the atmospheric response increases at deeper pressure levels. Hemispherically-symmetric small-scale temperature structures associated with zonal winds are superimposed onto the temperature asymmetry for pressures greater than 100 mbar. The para-hydrogen fraction in the 100-400 mbar range is greater than equilibrium predictions for the southern hemisphere and parts of the northern hemisphere, and less than equilibrium predictions polewards of 40° N.The temperature knee between 150-300 mbar is larger in the summer hemisphere than in the winter, smaller and higher at the equator, deeper and larger in the equatorial belts and small at the poles. Solar heating on tropospheric haze is proposed as a possible mechanism for this effect; the increased efficiency of ortho- to para-hydrogen conversion in the southern hemisphere is consistent with the presence of larger aerosols in the summer hemisphere, which we demonstrate to be qualitatively consistent with previous studies of Saturn's tropospheric aerosol distribution.     

Vertical profiles of HCN, HC3N, and C2H2 in Titan's atmosphere derived from Cassini/CIRS data

Mid-infrared limb spectra in the range 600-1400 cm⁻¹ taken with the Composite InfraRed Spectrometer (CIRS) on-board the Cassini spacecraft were used to determine vertical profiles of HCN, HC₃N, C₂H₂, and temperature in Titan's atmosphere. Both high (0.5 cm⁻¹) and low (13.5 cm⁻¹) spectral resolution data were used. The 0.5 cm⁻¹ data gave profiles at four latitudes and the 13.5 cm⁻¹ data gave almost complete latitudinal coverage of the atmosphere. Both datasets were found to be consistent with each other. High temperatures in the upper stratosphere and mesosphere were observed at Titan's northern winter pole and were attributed to adiabatic heating in the subsiding branch of a meridional circulation cell. On the other hand, the lower stratosphere was much colder in the north than at the equator, which can be explained by the lack of solar radiation and increased IR emission from volatile enriched air. HC₃N had a vertical profile consistent with previous ground based observations at southern and equatorial latitudes, but was massively enriched near the north pole. This can also be explained in terms of subsidence at the winter pole. A boundary observed at 60° N between enriched and un-enriched air is consistent with a confining polar vortex at 60° N and HC₃N's short lifetime. In the far north, layers were observed in the HC₃N profile that were reminiscent of haze layers observed by Cassini's imaging cameras. HCN was also enriched over the north pole, which gives further evidence for subsidence. However, the atmospheric cross section obtained from 13.5 cm⁻¹ data indicated a HCN enriched layer at 200-250 km, extending into the southern hemisphere. This could be interpreted as advection of polar enriched air towards the south by a meridional circulation cell. This is observed for HCN but not for HC₃N due to HCN's longer photochemical lifetime. C₂H₂ appears to have a uniform abundance with altitude and is not significantly enriched in the north. This is consistent with observations from previous CIRS analysis that show increased abundances of nitriles and hydrocarbons but not C₂H₂ towards the north pole.     

Jupiter's atmospheric temperatures: From Voyager IRIS to Cassini CIRS

Retrievals performed on Cassini Composite Infrared Spectrometer data obtained during the distant Jupiter flyby in 2000/2001 have been used to generate global temperature maps of the planet in the troposphere and stratosphere, but to higher latitudes than were shown previously by Flasar et al. [Flasar, F.M., 39 colleagues, 2004a. Nature 427, 132-135; Flasar, F.M., 44 colleagues, 2004b. Space Sci. Rev. 115, 169-297]. Similar retrievals were performed on Voyager 1 IRIS data to provide the first detailed IRIS map of the stratosphere, and high latitudes in the troposphere. Thermal winds were calculated for each data set and show strong vertical shears in the zonal winds at low latitudes, and meridional temperature gradients indicate the presence of circumpolar jets, as well. The temperatures retrieved from the two spacecraft were also compared with yearly ground-based data obtained over the intervening two decades. Tropospheric temperatures reveal gradual changes at low latitudes, with little obvious seasonal or short-term variation [Orton et al., 1994. Science 265, 625-631]. Stratospheric temperatures show much more complicated behavior over short timescales, consistent with quasi-quadrennial oscillations at low latitudes, as suggested in prior analyses of shorter intervals of ground-based data [Orton et al., 1991. Science 252, 537-542; Friedson, A.J., 1999. Icarus 137, 34-55]. A scaling analysis indicates that meridional motions, mechanically forced by wave or eddy convergence, play an important role in modulating the temperatures and winds in the upper troposphere and stratosphere on seasonal and shorter timescales. At latitudes away from the equator, the mechanical forcing can be derived simply from a temporal record of temperature and its vertical derivative. Ground-based observations with improved vertical resolution and/or long-term monitoring from spacecraft are required for this purpose, though the Voyager and Cassini data given indications that the magnitude of the forcing is very small.     

A photochemical model of Titan's atmosphere and ionosphere

A global-mean model of coupled neutral and ion chemistry on Titan has been developed. Unlike the previous coupled models, the model involves ambipolar diffusion and escape of ions, hydrodynamic escape of light species, and calculates the H₂ and CO densities near the surface that were assigned in some previous models. We tried to reduce the numbers of species and reactions in the model and remove all species and reactions that weakly affect the observed species. Hydrocarbon chemistry is extended to C₁₂H₁₀ for neutrals and C₁₀H⁺₁₁ for ions but does not include PAHs. The model involves 415 reactions of 83 neutrals and 33 ions, effects of magnetospheric electrons, protons, and cosmic rays. UV absorption by Titan's haze was calculated using the Huygens observations and a code for the aggregate particles. Hydrocarbon, nitrile, and ion chemistries are strongly coupled on Titan, and attempt to calculate them separately (e.g., in models of ionospheric composition) may result in significant error. The model densities of various species are typically in good agreement with the observations except vertical profiles in the stratosphere that are steeper than the CIRS limb data. (A model with eddy diffusion that facilitates fitting to the CIRS limb data is considered as well.) The CO densities are supported by the O⁺ flux from Saturn's magnetosphere. The ionosphere includes a peak at 80 km formed by the cosmic rays, steplike layers at 500-700 and 700-900 km and a peak at 1060 km (SZA = 60°). Nighttime densities of major ions agree with the INMS data. Ion chemistry dominates in the production of bicyclic aromatic hydrocarbons above 600 km. The model estimates of heavy positive and negative ions are in reasonable agreement with the Cassini results. The major haze production is in the reactions C₆H + C₄H₂, C₃N + C₄H₂, and condensation of hydrocarbons below 100 km. Overall, precipitation rate of the photochemical products is equal to 4-7 kg cm⁻² Byr⁻¹ (50-90 m Byr⁻¹ while the global-mean depth of the organic sediments is ∼3 m). Escape rates of methane and hydrogen are 2.9 and 1.4 kg cm⁻² Byr⁻¹, respectively. The model does not support the low C/N ratio observed by the Huygens ACP in Titan's haze.     

Long slit spectropolarimetry of Jupiter and Saturn

We present ground-based limb polarization measurements of Jupiter and Saturn consisting of full disk imaging polarimetry for the wavelength 7300 Å and spatially resolved (long-slit) spectropolarimetry covering the wavelength range 5200-9350 Å.For the polar region of Jupiter we find for λ = 6000 Å a very strong radial (perpendicular to the limb) fractional polarization with a seeing corrected maximum of about +11.5% in the South and +10.0% in the North. This indicates that the polarizing haze layer is thicker at the South pole. The polar haze layers extend down to 58° in latitude. The derived polarization values are much higher than reported in previous studies because of the better spatial resolution of our data and an appropriate consideration of the atmospheric seeing. Model calculations demonstrate that the high limb polarization can be explained by strongly polarizing (p ≈ 1.0), high albedo (ω ≈ 0.98) haze particles with a scattering asymmetry parameter of g ≈ 0.6 as expected for aggregate particles of the type described by West and Smith (West, R.A., Smith, P.H. [1991]. Icarus 90, 330-333). The deduced particle parameters are distinctively different when compared to lower latitude regions.The spectropolarimetry of Jupiter shows a decrease in the polar limb polarization towards longer wavelengths and a significantly enhanced polarization in strong methane bands when compared to the adjacent continuum. This is a natural outcome for a highly polarizing haze layer above an atmosphere where multiple scatterings are suppressed in absorption bands. For lower latitudes the fractional polarization is small, negative, and it depends only little on wavelength except for the strong CH₄-band at 8870 Å.The South pole of Saturn shows a lower polarization (p ≈ 1.0-1.5%) than the poles of Jupiter. The spectropolarimetric signal for Saturn decrease rapidly with wavelength and shows no significant enhancements in the fractional polarization in the absorption bands. These properties can be explained by a vertically extended stratospheric haze region composed of small particles <100 nm as suggested previously by Karkoschka and Tomasko (Karkoschka, E., Tomasko, M. [2005]. Icarus 179, 195-221).In addition we find in the V- and R-band a previously not observed strong polarization feature (p = 1.5-2.0%) near the equator of Saturn. The origin of this polarization signal is unclear but it could be related to a seasonal effect.Finally we discuss the potential of ground-based limb polarization measurements for the investigation of the scattering particles in the atmospheres of Jupiter and Saturn.     

Titan trace gaseous composition from CIRS at the end of the Cassini-Huygens prime mission

This paper reports on the results from an extensive study of all nadir-looking spectra acquired by Cassini/CIRS during the 44 flybys performed in the course of the nominal mission (2004-2008). With respect to the previous study (Coustenis, A., and 24 colleagues [2007]. Icarus 189, 35-62, on flybys TB-T10) we present here a significantly richer dataset with, in particular, more data at high northern and southern latitudes so that the abundances inferred here at these regions are more reliable. Our enhanced high-resolution dataset allows us to infer more precisely the chemical composition of Titan all over the disk. We also include improved spectroscopic data for some molecules and updated temperature profiles. The latitudinal distributions of all of the gaseous species are inferred. We furthermore test vertical distributions essentially for acetylene (C₂H₂) from CIRS limb-inferred data and from current General Circulation Models for Titan and compare our results on all the gaseous abundances with predictions from 1-D photochemical-radiative models to check the reliability of the chemical reactions and pathways.     

Saturn's latitudinal C2H2 and C2H6 abundance profiles from Cassini/CIRS and ground-based observations

Hydrocarbons in the upper atmosphere of Saturn are known, from Voyager, ground-based, and early Cassini results, to vary in emission intensity with latitude. Of particular interest is the marked increase in hydrocarbon line intensity near the south pole during southern summer, as the increased line intensity cannot be simply explained by the increased temperatures observed in that region since the variations between C₂H₂ and C₂H₆ emission in the south pole region are different. In order to measure the latitudinal variations of hydrocarbons in Saturn's southern hemisphere we have used 3 cm⁻¹ resolution Cassini CIRS data from 2006 and combined this with measurements from the ground in October 2006 at NASA's IRTF using Celeste, an infrared high-resolution cryogenic grating spectrometer. These two data sets have been used to infer the molecular abundances of C₂H₂ and C₂H₆ across the southern hemisphere in the 1-10 mbar altitude region. We find that the latitudinal acetylene profile follows the yearly average mean daily insolation except at the southern pole where it peaks in abundance. Near the equator (5° S) the C₂H₂ abundance at the 1.2 mbar level is (1.6±0.19)×¹⁰−7 and it decreases by a factor of 2.7 from the equator toward the pole. However, at the pole (∼87° S) the C₂H₂ abundance jumps to (1.8±0.3)×¹⁰−7, approximately the equatorial value. The C₂H₆ abundance near the equator at the 2 mbar level is (0.7±0.1)×¹⁰−5 and stays approximately constant until mid-latitudes where it increases gradually toward the pole, attaining a value of (1.4±0.4)×¹⁰−5 there. The increase in ethane toward the pole with the corresponding decrease in acetylene is consistent with southern hemisphere meridional winds [Greathouse, T.K., Lacy, J.H., Bézard, B., Moses, J.I., Griffith, C.A., Richter, M.J., 2005. Icarus 177, 18-31]. The localized increase in acetylene at the pole provides evidence that there is dynamical transport of hydrocarbons from the equator to the southern pole.     

On the vertical wind shear of Saturn's Equatorial Jet at cloud level

In this work we analyze and compare the vertical cloud structure of Saturn's Equatorial Zone in two different epochs: the first one close to the Voyagers flybys (1979-1981) and the second one in 2004, when the Cassini spacecraft entered its orbit around the planet. Our goal is to retrieve the altitude of cloud features used as zonal wind tracers in both epochs. We reanalyze three different sets of photometrically calibrated published data: ground-based in 1979, Voyager 2 PPS and ISS observations in 1981, and we analyze a new set of Hubble Space Telescope images for 2004. For all situations we reproduced the observed reflectivity by means of a similar vertical model with three layers. The results indicate the presence of a changing tropospheric haze in 1979-1981 (Ptop∼100 mbar, τ∼10) and in 2004 (Ptop∼50 mbar, τ∼15) where the tracers are embedded. According to this model the Voyager 2 ISS images locate cloud tracers moving with zonal velocities of 455 to 465 (±2) m/s at a pressure level of 360 ± 140 mbar. For HST observations, our previous works had showed cloud tracers moving with zonal wind speeds of 280±10 m/s at a pressure level of about 50±10 mbar. All these values are calculated in the same region (3°±2° N). This speed difference, if interpreted as a vertical wind shear, requires a change of per scale height, two times greater than that estimated from temperature observations. We also perform an initial guess on Cassini ISS vertical sounding levels, retrieving values compatible with HST ones and Cassini CIRS derived vertical wind shear, but not with Voyager wind measurements. We conclude that the wind speed velocity differences measured between 1979-1981 and 2004 cannot be explained as a wind shear effect alone and demand dynamical processes.     

Methane and its isotopologues on Saturn from Cassini/CIRS observations

High spectral resolution observations from the Cassini Composite Infrared Spectrometer [Flasar, F.M., and 44 colleagues, 2004. Space Sci. Rev. 115, 169-297] are analysed to derive new estimates for the mole fractions of CH₄, CH₃D and ¹³CH₄ of (4.7±0.2)×¹⁰⁻³, (3.0±0.2)×¹⁰⁻⁷ and (5.1±0.2)×¹⁰⁻⁵ respectively. The mole fractions show no hemispherical asymmetries or latitudinal variability. The analysis combines data from the far-IR methane rotational lines and the mid-IR features of methane and its isotopologues, using both the correlated-k retrieval algorithm of Irwin et al. [Irwin, P., and 9 colleagues, 2008. J. Quant. Spectrosc. Radiat. Trans. 109, 1136-1150] and a line-by-line approach to evaluate the reliability of the retrieved quantities. C/H was found to be enhanced by 10.9±0.5 times the solar composition of Grevesse et al. [Grevesse, N., Asplund, M., Sauval, A., 2007. Space Sci. Rev. 130 (1), 105-114], 2.25±0.55 times larger than the enrichment on Jupiter, and supporting the increasing fractional core mass with distance from the Sun predicted by the core accretion model of planetary formation. A comparison of the jovian and saturnian C/N, C/S and C/P ratios suggests different reservoirs of the trapped volatiles in a primordial solar nebula whose composition varies with distance from the Sun. This is supported by our derived D/H ratio in methane of (1.6±0.2)×¹⁰⁻⁵, which appears to be smaller than the jovian value of Lellouch et al. [Lellouch, E., Bézard, B., Fouchet, T., Feuchtgruber, H., Encrenaz, T., de Graauw, T., 2001. Astron. Astrophys. 370, 610-622]. Mid-IR emission features provided an estimate of , which is consistent with both the terrestrial ratio and jovian ratio, suggesting that carbon was accreted from a shared reservoir for all of the planets.     

Analysis of Cassini/CIRS limb spectra of Titan acquired during the nominal mission II: Aerosol extinction profiles in the 600–1420 cm spectral range

We have analyzed the continuum emission of limb spectra acquired by the Cassini/CIRS infrared spectrometer in order to derive information on haze extinction in the 3–0.02 mbar range (∼150–350 km). We focused on the 600–1420 cm⁻¹ spectral range and studied nine different limb observations acquired during the Cassini nominal mission at 55°S, 20°S, 5°N, 30°N, 40°N, 45°N, 55°N, 70°N and 80°N. By means of an inversion algorithm solving the radiative transfer equation, we derived the vertical profiles of haze extinction coefficients from 17 spectral ranges of 20-cm⁻¹ wide at each of the nine latitudes. At a given latitude, all extinction vertical profiles retrieved from various spectral intervals between 600 and 1120 cm⁻¹ display similar vertical slopes implying similar spectral characteristics of the material at all altitudes. We calculated a mean vertical extinction profile for each latitude and derived the ratio of the haze scale height (H_haze) to the pressure scale height (H_gas) as a function of altitude. We inferred H_haze/H_gas values varying from 0.8 to 2.4. The aerosol scale height varies with altitude and also with latitude. Overall, the haze extinction does not show strong latitudinal variations but, at 1 mbar, an increase by a factor of 1.5 is observed at the north pole compared to high southern latitudes. The vertical optical depths at 0.5 and 1.7 mbar increase from 55°S to 5°N, remain constant between 5°N and 30°N and display little variation at higher latitudes, except the presence of a slight local maximum at 45°N. The spectral dependence of the haze vertical optical depth is uniform with latitude and displays three main spectral features centered at 630 cm⁻¹, 745 cm⁻¹ and 1390 cm⁻¹, the latter showing a wide tail extending down to ∼1000 cm⁻¹. From 600 to 750 cm⁻¹, the optical depth increases by a factor of 3 in contrast with the absorbance of laboratory tholins, which is generally constant. We derived the mass mixing ratio profiles of haze at the nine latitudes. Below the 0.4-mbar level all mass mixing ratio profiles increase with height. Above this pressure level, the profiles at 40°N, 45°N, 55°N, at the edge of the polar vortex, display a decrease-with-height whereas the other profiles increase. The global increase with height of the haze mass mixing ratio suggest a source at high altitudes and a sink at low altitudes. An enrichment of haze is observed at 0.1 mbar around the equator, which could be due to a more efficient photochemistry because of the strongest insolation there or an accumulation of haze due to a balance between sedimentation and upward vertical drag.     

Methane absorption in the atmosphere of Jupiter from 1800 to 9500 cm and implications for vertical cloud structure

New measurements of the low-temperature near-infrared absorption of methane (Sihra, 1998, Laboratory measurements of near-infrared methane bands for remote sensing of the jovian atmosphere, Ph.D. thesis, University of Oxford) have been combined with existing, longer path-length, higher-temperature data of Strong et al. (1993, Spectral parameters of self- and hydrogen-broadened methane from 2000 to 9500 cm⁻¹ for remote sounding of the atmosphere of Jupiter, J. Quant. Spectrosc. Radiat. Trans. 50, 309-325) and fitted with band models. The combined data set is found to be more consistent with previous low-temperature methane absorption measurements than that of Strong et al. (1993, J. Quant. Spectrosc. Radiat. Trans. 50, 309-325) but covers the same wider wavelength range and accounts for both self- and hydrogen-broadening conditions. These data have been fitted with k-coefficients in the manner described by Irwin et al. (1996, Calculated k-distribution coefficients for hydrogen- and self-broadened methane in the range 2000-9500 cm⁻¹ from exponential sum fitting to band modelled spectra, J. Geophys. Res. 101, 26,137-26,154) and have been used in multiple-scattering radiative transfer models to assess their impact on our previous estimates of the jovian cloud structure obtained from Galileo Near-Infrared Mapping Spectrometer (NIMS) observations (Irwin et al., 1998, Cloud structure and atmospheric composition of Jupiter retrieved from Galileo NIMS real-time spectra, J. Geophys. Res. 103, 23,001-23,021; Irwin et al., 2001, The origin of belt/zone contrasts in the atmosphere of Jupiter and their correlation with 5-μm opacity, Icarus 149, 397-415; Irwin and Dyudina, 2002, The retrieval of cloud structure maps in the equatorial region of Jupiter using a principal component analysis of Galileo/NIMS data, Icarus 156, 52-63). Although significant differences in methane opacity are found at cooler temperatures, the difference in the optical depth of the atmosphere due to methane is found to diminish rapidly with increasing pressure and temperature and thus has negligible effect on the cloud structure inferred at deeper levels. Hence the main cloud opacity variation is still found to peak at around 1-2 bar using our previous analytical approach, and is thus still in disagreement with Galileo Solid State Imager (SSI) determinations (Banfield et al., 1998, Jupiter's cloud structure from Galileo imaging data, Icarus 135, 230-250; Simon-Miller et al., 2001, Color and the vertical structure in Jupiter's belts, zones and weather systems, Icarus 154, 459-474) which place the main cloud deck near 0.9 bar. Further analysis of our retrievals reveals that this discrepancy is probably due to the different assumptions of the two analyses. Our retrievals use a smooth vertically extended cloud profile while the SSI determinations assume a thin NH₃ cloud below an extended haze. When the main opacity in our model is similarly assumed to be due to a thin cloud below an extended haze, we find the main level of cloud opacity variation to be near the 1 bar level—close to that determined by SSI and moderately close to the expected condensation level of ammonia ice of 0.85 bar, assuming that the abundance of ammonia on Jupiter is (7±1)×¹⁰⁻⁴ (Folkner et al., 1998, Ammonia abundance in Jupiter's atmosphere derived from the attenuation of the Galileo probe's radio signal, J. Geophys. Res. 103, 22,847-22,855; Atreya et al., 1999, A comparison of the atmospheres of Jupiter and Saturn: deep atmospheric composition, cloud structure, vertical mixing, and origin, Planet. Space Sci. 47, 1243-1262). However our data in the 1-2.5 μm range have good height discrimination and our lowest estimate of the cloud base pressure of 1 bar is still too great to be consistent with the most recent estimates of the ammonia abundance of 3.5 × solar. Furthermore the observed limited spatial distribution of ammonia ice absorption features on Jupiter suggests that pure ammonia ice is only present in regions of localised vigorous uplift (Baines et al., 2002, Fresh ammonia ice clouds in Jupiter: spectroscopic identification, spatial distribution, and dynamical implications, Icarus 159, 74-94) and is subsequently rapidly modified in some way which masks its pure absorption features. Hence we conclude that the main cloud deck on Jupiter is unlikely to be composed of pure ammonia ice and instead find that it must be composed of either NH₄SH or some other unknown combination of ammonia, water, and hydrogen sulphide and exists at pressures of between 1 and 2 bar.     

The meridional phosphine distribution in Saturn's upper troposphere from Cassini/CIRS observations

The Cassini Composite Infrared Spectrometer (CIRS) has been used to derive the vertical and meridional variation of temperature and phosphine (PH₃) abundance in Saturn's upper troposphere. PH₃ has a significant effect on the measured radiances in the thermal infrared and between May 2004 and September 2005 CIRS recorded thousands of spectra in both the far (10-600 cm⁻¹) and mid (600-1400 cm⁻¹) infrared, at a variety of latitudes covering the southern hemisphere. Low spectral resolution (15 cm⁻¹) data has been used to constrain the temperature structure of the troposphere between 100 and 500 mbar. The vertical distributions of phosphine and ammonia were retrieved from far-infrared spectra at the highest spectral resolution (0.5 cm⁻¹), and lower resolution (2.5 cm⁻¹) mid-infrared data were used to map the meridional variation in the abundance of phosphine in the 250-500 mbar range. Temperature variations at the 250 mbar level are shown to occur on the same scale as the prograde and retrograde jets in Saturn's atmosphere [Porco, C.C., and 34 colleagues, 2005. Science 307, 1243-1247]. The PH₃ abundance at 250 mbar is found to be enhanced at the equator when compared with mid-latitudes. At mid latitudes we see anti-correlation between temperature and PH₃ abundance at 250 mbar, phosphine being enhanced at 45° S and depleted at 25 and 55° S. The vertical distribution is markedly different polewards of 60-65° S, with depleted PH₃ at 500 mbar but a slower decline in abundance with altitude when compared with the mid-latitudes. This variation is similar to the variations of cloud and aerosol parameters observed in the visible and near infrared, and may indicate the subsidence of tropospheric air at polar latitudes, coupled with a diminished sunlight penetration depth reducing the rate of PH₃ photolysis in the polar region.     

Compositional evidence for Titan's stratospheric tilt

Five years of Cassini CIRS infrared spectra have been used to determine the tilt of Titan's stratospheric symmetry axis with respect to the solid body rotation axis. Measurements of HCN abundance centred around 5 mbar (125 km altitude) at equatorial latitudes show the symmetry axis is tilted by 4.0±1.5^° in a direction 70±40^°W of the sub-solar point. This value is consistent with tilts determined from temperature and haze measurements by Achterberg et al. (2008a) and Roman et al. (2009). The consistency of results from three independent methods suggests that Titan's entire stratosphere is tilted and provides a powerful constraint on the underlying atmospheric dynamics.