Lunar soil characterization consortium analyses: Pyroxene and maturity estimates derived from Clementine image data

The mineralogy of a planetary surface is a diagnostic product of its formation and geologic evolution. Global assessment of lunar mineralogy at high spatial resolution has been a long standing goal of lunar exploration. Currently, the only global data available for such study is multispectral imagery from the Clementine mission. We use the detailed compositional, petrographic, and spectroscopic data of lunar soils produced by the Lunar Soil Characterization Consortium to explore the use of multispectral imaging as a diagnostic tool. We compare several statistically optimized formulations of links between spectral and mineral parameters and apply them to Clementine UV-VIS data. The most reliable results are for estimations of pyroxene abundance and maturity parameters (agglutinate abundance, Is/FeO). Estimations of different pyroxene composition (low-Ca versus high-Ca) appear good in a relative sense, but absolute values are limited by residual wavelength dependent Clementine photometric calibrations. Since the signal-to-noise of Clementine multispectral data is good at the 1-km scale, almost any combination of parameters that capture inherent spectral variance can provide spatially coherent maps, although the parameters may not actually be directly related to composition. Clementine estimates are useful for identifying scientific or exploration targets for imaging spectrometer sensors of the next generation that are specifically designed to characterize mineralogy.     

Minerals mapping of the lunar surface with Clementine UVVIS/NIR data based on spectra unmixing method and Hapke model

The distribution of minerals on the lunar surface is information which could contribute to studying lunar origin and evolution. In this paper, the distribution of clinopyroxene, orthopyroxene, olivine, ilmenite, and plagioclase on the lunar surface has been mapped based on Hapke radiative transfer model and linear unmixing of spectra with Clementine UVVIS/NIR data. The results have been validated on the basis of minerals modal abundance data of the Apollo samples, and problems in the minerals abundance mapping have been analyzed. The validation based on analysis data of Apollo samples indicates that plagioclase mapped in this paper represents the total abundance of plagioclase and agglutinitic glass. The minerals mapping results show that the lunar surface is mainly composed of pyroxene, plagioclase, agglutinitic glass, and ilmenite. Basalt in the lunar mare is mainly composed of clinopyroxene and ilmenite, and lunar highland is mainly composed of plagioclase and agglutinitic glass. Orthopyroxene is mainly distributed on the north of Mare Imbrium, on the south of Maria and Aitken Basin. According to our results, there is probably no large area of olivine distribution on the lunar surface which is different from earlier published results. Therefore, emphasis should be put on the olivine distribution in the minerals mapping using hyperspectral data such as M³ of Chandrayaan-1 and IIM of ChangE-1.     

A stratigraphic study of southern Oceanus Procellarum using Clementine multispectral data

In this paper, we use Clementine multispectral data to demonstrate techniques from which spectrally distinct mare basalts can be mapped, and estimates of basalt thickness obtained. The region studied incorporates a portion of southern Oceanus Procellarum from 17.5°N to 20.5°S and 289°E to 317°E, including the Marius Hills, Damoiseau, Cavalerius and Flamsteed areas. Flamsteed provides a test area from which we validate the mapping techniques used in this work. Unit boundaries and basalt thickness details from these analyses are applied to the stratigraphy of the Oceanus Procellarum Group defined by Whitford-Stark and Head (J. Geophys. Res. 85 (1980) 6579). A total of 13 basalts are recognised in the region, 10 of which are spectrally distinct, and three of which represent previously unrecognised Members of the Oceanus Procellarum Group. The average thickness of the basalts is between 160 and 625 m, ranging from tens to hundreds of metres near the mare/highland boundaries and consistently greater than several hundred metres closer to the centre of the mare. These values provide a range of basalt volume in the region of 0.7–2.8×10⁵ km³. This represents between 8% and 32% of the total volume of basalts in Oceanus Procellarum.     

An in-depth look at the lunar crater Copernicus: Exposed mineralogy by high-resolution near-infrared spectroscopy

Newly acquired, sequentially spaced, high-resolution near-infrared spectra across the central section of crater Copernicus’ interior have been analyzed using a range of complementary techniques and indexes.We have developed a new interpretative method based on a multiple stage normalization process that appears to both confirm and expand on previous mineralogical estimations and mapping. In broad terms, the interpreted distribution of the principle mafic species suggests an overall composition of surface materials dominated by calcium-poor pyroxenes and minor olivine but with notable exceptions: the southern rim displays strong ca-rich pyroxene absorption features and five other locations, the uppermost northern crater wall, opposite rim sections facing the crater floor, and the central peak Pk1 and at the foot of Pk3, show instead strong olivine signatures.We also propose impact glass an alternative interpretation to the source of the weak but widespread olivine-like spectral signature found in low-reflectance samples, since it probably represents a major regolith constituent and component in large craters such as Copernicus.The high quality and performance of the SIR-2 data allows for the detection of diagnostic key mineral species even when investigating spectral samples with very subdued absorption features, confirming the intrinsic high-quality value of the returned data.     

Geology and stratigraphy of King crater, lunar farside

Clementine and photographic data sets have been used to investigate the crustal stratigraphy and geology of King crater on the lunar farside (120°E, 5.5°N). Pre-existing topographic regimes or stress fields dominate many structures in the crater, which has excavated materials from depths of up to 14 km. The upper crust in the area is noritic anorthosite, grading to a more anorthositic signature with depth. A possible batholithic intrusion is also present in a 15-km-wide band, extending from the southern crater floor to at least 50 km north of King, and from near-surface levels down to at least the excavation depth of the crater. It is generally feldspathic, but is cut by mafic dykes now visible in the north wall. King also shows evidence for the presence of a cryptomare, exposed in regions of the peaks and in dark halo craters within the ejecta blanket. Localized olivine-bearing mineralogies are observed on the central peaks, suggesting isolated pockets of troctolitic mineralogies to have been present at 8- to 14-km depths. Copious volumes of crystalline melt produced from the impact event cover King’s floor to a maximum thickness of 30-60 m, and have pooled in a number of natural depressions outside of the main crater. The main pool in the pre-existing A1-Tusi crater has a minimum depth of 150 m. Domes on the crater floor are verified as nonvolcanic in origin, and did not act as a source for any of the lava-like materials in King.     

Individual lava flow thicknesses in Oceanus Procellarum and Mare Serenitatis determined from Clementine multispectral data

We use multispectral reflectance data from the lunar Clementine mission to investigate the impact ejecta deposits of simple craters in two separate lunar mare basalt regions, one in Oceanus Procellarum and one in Mare Serenitatis. Over 100 impact craters are studied, and for a number of these we observe differences between the TiO₂ (and FeO) contents of their ejecta deposits and the lava flow units in which they are located. We demonstrate that, in the majority of cases, these differences cannot plausibly be attributed to uncorrected maturity effects. These observations, coupled with morphometric crater relationships that provide maximum crater excavation depths, allow the investigation of sub-surface lava flow stratigraphy. We provide estimated average thicknesses for a number of lava flow units in the two study regions, ranging from ∼80 m to ∼600 m. In the case of the Serenitatis study area, our results are consistent with the presence of sub-surface horizons inferred from recent radar sounding measurements from the JAXA Kaguya spacecraft. The average lava flow thicknesses we obtain are used to make estimates of the average flux of volcanic material in these regions. These are in broad agreement with previous studies, suggesting that the variation in mare basalt types we observe with depth is similar to the lateral variations identified at the surface.     

Mineralogy and geochemistry of four lunar soils by laser-Raman study

Laser Raman spectroscopy is used to investigate four lunar soils, focusing on mineralogy of grains of <45 μm size. Apollo samples 14163, 15271, 67511, and 71501 were selected as endmembers to study, based on their soil chemistry, maturity, and sample locations. Typical Raman spectral features for major and minor lunar minerals are discussed on the basis of major vibrational modes. We used the Raman peak shift to calculate Mg/(Mg + Fe + Ca) and Ca/(Mg + Fe + Ca) for pyroxene and Mg/(Mg + Fe) for olivine, and thus obtained the compositional distributions of these two minerals in each of the four lunar soils. Classification of feldspar grains was made based on recognition of their Raman patterns. A Raman point-counting procedure was applied to derive mineral modes of the soils, and these are found to be consistent with published modal analysis of these soils. The compositional distributions of pyroxene and olivine grains in each soil sample, as well as the mineral modes, reflect characteristics of the main source materials for these soils. Raman patterns and peak positions also reflect shock effects on plagioclase and quartz, found in 14163.     

Mapping and compositional analysis of mare basalts in the Aristarchus region of the Moon using Clementine data

The process of accurately defining and outlining mare basalt units is necessary for constraining the stratigraphy and ages of basalt units,which are used to determine the duration and the flux of lunar volcanism.We use a combination of Clementine’s five-band ultraviolet/visible data and TiO2and FeO abundance distribution maps to define homogenous mare basalt units and characterize their compositional variations(with maturity)in the Aristarchus region.With 20 groups of distinct mare basaltic soils identified using the method in this paper,six additional spectrally defined areas and five basaltic units are constructed,and their mineralogic quantization values provide new constraints on their temporal and spatial evolution.Our results indicate that the Aristarchus region has diverse basalt units and a complex history of volcanic evolution.We also demonstrate that the techniques,from which spectrally distinct mare basalts can be mapped,performed well in this study and can be confidently expanded to other mare regions of the Moon.     

Exponential Gaussian approach for spectral modeling: The EGO algorithm I. Band saturation

Curve fitting techniques are a widespread approach to spectral modeling in the VNIR range [Burns, R.G., 1970. Am. Mineral. 55, 1608-1632; Singer, R.B., 1981. J. Geophys. Res. 86, 7967-7982; Roush, T.L., Singer, R.B., 1986. J. Geophys. Res. 91, 10301-10308; Sunshine, J.M., Pieters, C.M., Pratt, S.F., 1990. J. Geophys. Res. 95, 6955-6966]. They have been successfully used to model reflectance spectra of powdered minerals and mixtures, natural rock samples and meteorites, and unknown remote spectra of the Moon, Mars and asteroids. Here, we test a new decomposition algorithm to model VNIR reflectance spectra and call it Exponential Gaussian Optimization (EGO). The EGO algorithm is derived from and complementary to the MGM of Sunshine et al. [Sunshine, J.M., Pieters, C.M., Pratt, S.F., 1990. J. Geophys. Res. 95, 6955-6966]. The general EGO equation has been especially designed to account for absorption bands affected by saturation and asymmetry. Here we present a special case of EGO and address it to model saturated electronic transition bands. Our main goals are: (1) to recognize and model band saturation in reflectance spectra; (2) to develop a basic approach for decomposition of rock spectra, where effects due to saturation are most prevalent; (3) to reduce the uncertainty related to quantitative estimation when band saturation is occurring. In order to accomplish these objectives, we simulate flat bands starting from pure Gaussians and test the EGO algorithm on those simulated spectra first. Then we test the EGO algorithm on a number of measurements acquired on powdered pyroxenes having different compositions and average grain size and binary mixtures of orthopyroxenes with barium sulfate. The main results arising from this study are: (1) EGO model is able to numerically account for the occurrence of saturation effects on reflectance spectra of powdered minerals and mixtures; (2) the systematic dilution of a strong absorber using a bright neutral material is not responsible for band deformation. Further work is still required in order to analyze the behavior of the EGO algorithm with respect to the saturation phenomena using more complex band shapes than pyroxene bands.     

Crustal thickness of the Moon: New constraints from gravity inversions using polyhedral shape models

A new method is presented for estimating crustal thickness from gravity and topography data on the Moon. By calculating analytically the exterior gravitational field for a set of arbitrarily shaped polyhedra, relief along the crust-mantle interface can be inverted for that satisfies the observational constraints. As this method does not rely upon filtering the Bouguer anomaly, which was required with previous inversions performed in the spherical-harmonic domain, and as the dramatic variations in spatial quality of the lunar gravity field are taken into account, our crustal thickness model more faithfully represents the available data. Using our model results, we investigate various aspects of the prominent nearside impact basins. The crustal thickness in the central portion of the Orientale and Crisium basins is found to be close to zero, suggesting that these basins could have conceivably excavated into the lunar mantle. Furthermore, given our uncertain knowledge of the density of the crust and mantle, it is possible that the Humorum, Humboldtianum, Nectaris, and Smythii basins could have excavated all the way through the crust as well. The crustal structure for most of the young impact basins implies a depth/diameter ratio of about 0.08 for their excavation cavities. As noted in previous studies, however, the crustal structure of Imbrium and Serenitatis is anomalous, which is conceivably a result of enhanced rates of post-impact viscous relaxation caused by the proximity of these basins to the Procellarum KREEP Terrane. Impact basins older than Smythii show little or no evidence for crustal thinning, suggesting that these ancient basins were also affected by high rates of viscous relaxation resulting from higher crustal temperatures early in the Moon's evolution. The lithosphere beneath many young basins is found to be supporting a downward directed force, even after the load associated with the mare basalts is removed, and this is plausibly attributed to superisostatic uplift of the crust-mantle interface. Those basins that are close to achieving a pre-mare isostatic state are generally found to reside within, or close to, the Procellarum KREEP Terrane.     

Volatile retention from cometary impacts on the Moon

Impacts of comets and asteroids play an important role in volatile delivery on the Moon. We use a novel method for tracking vapor masses that reach escape velocity in hydrocode simulations of cometary impacts to explore the effects of volatile retention. We model impacts on the Moon to find the mass of vapor plume gravitationally trapped on the Moon as a function of impact velocity. We apply this result to the impactor velocity distribution and find that the total impactor mass retained on the Moon is approximately 6.5% of the impactor mass flux. Making reasonable assumptions about water content of comets and the comet size-frequency distribution, we derive a water flux for the Moon. After accounting for migration and stability of water ice at the poles, we estimate a total 1.3×10⁸-4.3×10⁹ metric tons of water is delivered to the Moon and remains stable at the poles over 1 Ga. A factor of 30 uncertainty in the estimated cometary impact flux is primarily responsible for this large range of values. The calculated mass of water is sufficient to account for the neutron fluxes poleward of 75° observed by Lunar Prospector. A similar analysis for water delivery to the Moon via asteroid impacts shows that asteroids provide six times more water mass via impacts than comets.     

Mineralogical characterization of Baptistina Asteroid Family: Implications for K/T impactor source

Bottke et al. [Bottke, W.F., Vokrouhlicky, D., Nesvorný, D., 2007. Nature 449, 48–53] linked the catastrophic formation of Baptistina Asteroid Family (BAF) to the K/T impact event. This linkage was based on dynamical and compositional evidence, which suggested the impactor had a composition similar to CM2 carbonaceous chondrites. However, our recent study [Reddy, V., Emery, J.P., Gaffey, M.J., Bottke, W.F., Cramer, A., Kelley, M.S., 2009. Meteorit. Planet. Sci. 44, 1917–1927] suggests that the composition of (298) Baptistina is similar to LL-type ordinary chondrites rather than CM2 carbonaceous chondrites. This rules out any possibility of it being related to the source of the K/T impactor, if the impactor was of CM-type composition. Mineralogical study of asteroids in the vicinity of BAF has revealed a plethora of compositional types suggesting a complex formation and evolution environment. A detailed compositional analysis of 16 asteroids suggests several distinct surface assemblages including ordinary chondrites (Gaffey SIV subtype), primitive achondrites (Gaffey SIII subtype), basaltic achondrites (Gaffey SVII subtype and V-type), and a carbonaceous chondrite. Based on our mineralogical analysis we conclude that (298) Baptistina is similar to ordinary chondrites (LL-type) based on olivine and pyroxene mineralogy and moderate albedo. S-type and V-type in and around the vicinity of BAF we characterized show mineralogical affinity to (8) Flora and (4) Vesta and could be part of their families. Smaller BAF asteroids with lower SNR spectra showing only a ‘single’ band are compositionally similar to (298) Baptistina and L/LL chondrites. It is unclear at this point why the silicate absorption bands in spectra of asteroids with formal family definition seem suppressed relative to background population, despite having similar mineralogy.     

A comparison of the ultraviolet to near-infrared spectral properties of Mercury and the Moon as observed by MESSENGER

Measurements of the disk-integrated reflectance spectrum of Mercury and the Moon have been obtained by the MESSENGER spacecraft. A comparison of spectra from the two bodies, spanning the wavelength range 220-1450 nm, shows that the absolute reflectance of Mercury is lower than that of the nearside waxing Moon at the same phase angle with a spectral slope that is less steep at visible and near-infrared wavelengths. We interpret these results and the lack of an absorption feature at a wavelength near 1000 nm as evidence for a Mercury surface composition that is low in ferrous iron within silicates but is higher in the globally averaged abundance of spectrally neutral opaque minerals than the Moon. Similar conclusions have been reached by recent investigations based on observations from both MESSENGER and Mariner 10. There is weak evidence for a phase-reddening effect in Mercury that is slightly larger in magnitude than for the lunar nearside. An apparent absorption in the middle-ultraviolet wavelength range of the Mercury spectrum detected from the first MESSENGER flyby of Mercury is found to persist in subsequent observations from the second flyby. The current model of space weathering on the Moon, which also presumably applies to Mercury, does not provide an explanation for the presence of this ultraviolet absorption.     

The transition from complex crater to peak-ring basin on the Moon: New observations from the Lunar Orbiter Laser Altimeter (LOLA) instrument

Impact craters on planetary bodies transition with increasing size from simple, to complex, to peak-ring basins and finally to multi-ring basins. Important to understanding the relationship between complex craters with central peaks and multi-ring basins is the analysis of protobasins (exhibiting a rim crest and interior ring plus a central peak) and peak-ring basins (exhibiting a rim crest and an interior ring). New data have permitted improved portrayal and classification of these transitional features on the Moon. We used new 128 pixel/degree gridded topographic data from the Lunar Orbiter Laser Altimeter (LOLA) instrument onboard the Lunar Reconnaissance Orbiter, combined with image mosaics, to conduct a survey of craters >50 km in diameter on the Moon and to update the existing catalogs of lunar peak-ring basins and protobasins. Our updated catalog includes 17 peak-ring basins (rim-crest diameters range from 207 km to 582 km, geometric mean = 343 km) and 3 protobasins (137-170 km, geometric mean = 157 km). Several basins inferred to be multi-ring basins in prior studies (Apollo, Moscoviense, Grimaldi, Freundlich-Sharonov, Coulomb-Sarton, and Korolev) are now classified as peak-ring basins due to their similarities with lunar peak-ring basin morphologies and absence of definitive topographic ring structures greater than two in number. We also include in our catalog 23 craters exhibiting small ring-like clusters of peaks (50-205 km, geometric mean = 81 km); one (Humboldt) exhibits a rim-crest diameter and an interior morphology that may be uniquely transitional to the process of forming peak rings. A power-law fit to ring diameters (D_ring) and rim-crest diameters (D_r) of peak-ring basins on the Moon [D_ring = 0.14 ± 0.10(D_r)^1.21±0.13] reveals a trend that is very similar to a power-law fit to peak-ring basin diameters on Mercury [D_ring = 0.25 ± 0.14(D_rim)^1.13±0.10] [Baker, D.M.H. et al. [2011]. Planet. Space Sci., in press]. Plots of ring/rim-crest ratios versus rim-crest diameters for peak-ring basins and protobasins on the Moon also reveal a continuous, nonlinear trend that is similar to trends observed for Mercury and Venus and suggest that protobasins and peak-ring basins are parts of a continuum of basin morphologies. The surface density of peak-ring basins on the Moon (4.5 × 10⁻⁷ per km²) is a factor of two less than Mercury (9.9 × 10⁻⁷ per km²), which may be a function of their widely different mean impact velocities (19.4 km/s and 42.5 km/s, respectively) and differences in peak-ring basin onset diameters. New calculations of the onset diameter for peak-ring basins on the Moon and the terrestrial planets re-affirm previous analyses that the Moon has the largest onset diameter for peak-ring basins in the inner Solar System. Comparisons of the predictions of models for the formation of peak-ring basins with the characteristics of the new basin catalog for the Moon suggest that formation and modification of an interior melt cavity and nonlinear scaling of impact melt volume with crater diameter provide important controls on the development of peak rings. In particular, a power-law model of growth of an interior melt cavity with increasing crater diameter is consistent with power-law fits to the peak-ring basin data for the Moon and Mercury. We suggest that the relationship between the depth of melting and depth of the transient cavity offers a plausible control on the onset diameter and subsequent development of peak-ring basins and also multi-ring basins, which is consistent with both planetary gravitational acceleration and mean impact velocity being important in determining the onset of basin morphological forms on the terrestrial planets.     

Dione’s spectral and geological properties

We present a detailed analysis of the variations in spectral properties across the surface of Saturn’s satellite Dione using Cassini/VIMS data and their relationships to geological and/or morphological characteristics as seen in the Cassini/ISS images. This analysis focuses on a local region on Dione’s anti-saturnian hemisphere that was observed by VIMS with high spatial resolution during orbit 16 in October 2005. The results are incorporated into a global context provided by VIMS data acquired within Cassini’s first 50 orbits. Our results show that Dione’s surface is dominated by at least one global process. Bombardment by magnetospheric particles is consistent with the concentration of dark material and enhanced CO₂ absorption on the trailing hemisphere of Dione independent of the geology. Local regions within this terrain indicate a special kind of resurfacing that probably is related to large-scale impact process. In contrast, the enhanced ice signature on the leading side is associated with the extended ejecta of the fresh impact crater Creusa (∼49°N/76°W). Although no geologically active regions could be identified, Dione’s tectonized regions observed with high spatial resolution partly show some clean H₂O ice implying that tectonic processes could have continued into more recent times.     

Formation of lunar mare domes along crustal fractures: Rheologic conditions, dimensions of feeder dikes, and the role of magma evolution

In this study we examine a set of lunar mare domes located in the Hortensius/Milichius/T. Mayer region and in northern Mare Tranquillitatis with respect to their formation along crustal fractures, their rheologic properties, the dimensions of their feeder dikes, and the importance of magma evolution processes during dome formation. Many of these domes display elongated summit vents oriented radially with respect to major impact basins, and several dome locations are also aligned in these preferential directions. Analysis of Clementine UV/VIS and Lunar Prospector gamma ray spectrometer data reveals that the examined mare domes formed from low-Si basaltic lavas of high FeO and low to moderate TiO₂ content. Based on their morphometric properties (diameter, height, volume) obtained by photoclinometric and shape from shading analysis of telescopic CCD images, we derive rheologic quantities (lava viscosity during eruption, effusion rate, duration of the effusion process, magma rise speed) and the dimensions of the feeder dikes. We establish three rheologic groups characterised by specific combinations of rheologic properties and dike dimensions, where the most relevant discriminative parameter is the lava viscosity η. The first group is characterised by and contains the domes with elongated vents in the Milichius/T. Mayer region and two similar domes in northern Mare Tranquillitatis. The second group with comprises the very low aligned domes in northern Mare Tranquillitatis, and the third group with the relatively steep domes near Hortensius and in the T. Mayer region. The inferred dike dimensions in comparison to lunar crustal thickness data indicate that the source regions of the feeder dikes are situated within the upper crust for six of the domes in northern Mare Tranquillitatis, while they are likely to be located in the lower crust and in the upper mantle for the other examined domes. By comparing the time scale of magma ascent with the time scale on which heat is conducted from the magma into the host rock, we find evidence that the importance of magma evolution processes during ascent such as cooling and crystallisation increases with lava viscosity. We conclude that different degrees of evolution of initially fluid basaltic magma are able to explain the broad range of lava viscosities inferred for the examined mare domes. The spectral data reveal that differences in TiO₂ content may additionally account for the systematic difference in lava viscosity between the two examined lunar regions. We show that the described mechanisms are likely to be valid also for other lunar mare domes situated near Cauchy and Arago, regarded for comparison. On the other hand, we find for the Gruithuisen and Mairan highland domes that despite their inferred high lava viscosities of , no significant magma cooling in the dike occurred during ascent, supporting previous findings that the highland domes were formed during a specific phase of non-mare volcanism by highly silicic viscous lavas.     

Lunar intrusive domes: Morphometric analysis and laccolith modelling

This study examines a set of lunar domes with very low flank slopes which differ in several respects from the frequently occurring lunar effusive domes. Some of these domes are exceptionally large, and most of them are associated with faults or linear rilles of presumably tensional origin. Accordingly, they might be interpreted as surface manifestations of laccolithic intrusions formed by flexure-induced vertical uplift of the lunar crust (or, alternatively, as low effusive edifices due to lava mantling of highland terrain, or kipukas, or structural features). All of them are situated near the borders of mare regions or in regions characterised by extensive effusive volcanic activity. Clementine multispectral UVVIS imagery indicates that they do not preferentially occur in specific types of mare basalt. Our determination of their morphometric properties, involving a combined photoclinometry and shape from shading technique applied to telescopic CCD images acquired at oblique illumination, reveals large dome diameters between 10 and more than 30 km, flank slopes below 0.9°, and volumes ranging from 0.5 to 50 km³. We establish three morphometric classes. The first class, In1, comprises large domes with diameters above 25 km and flank slopes of 0.2°-0.6°, class In2 is made up by smaller and slightly steeper domes with diameters of 10-15 km and flank slopes between 0.4° and 0.9°, and domes of class In3 have diameters of 13-20 km and flank slopes below 0.3°. While the morphometric properties of several candidate intrusive domes overlap with those of some classes of effusive domes, we show that a possible distinction criterion are the characteristic elongated outlines of the candidate intrusive domes. We examine how they differ from typical effusive domes of classes 5 and 6 defined by Head and Gifford [Head, J.W., Gifford, A., 1980. Lunar mare domes: classification and modes of origin. Moon Planets 22, 235-257], and show that they are likely no highland kipukas due to the absence of spectral contrast to their surrounding. These considerations serve as a motivation for an analysis of the candidate intrusive domes in terms of the laccolith model by Kerr and Pollard [Kerr, A.D., Pollard, D.D., 1998. Toward more realistic formulations for the analysis of laccoliths. J. Struct. Geol. 20(12), 1783-1793], to estimate the geophysical parameters, especially the intrusion depth and the magma pressure, which would result from the observed morphometric properties. Accordingly, domes of class In1 are characterised by intrusion depths of 2.3-3.5 km and magma pressures between 18 and 29 MPa. For the smaller and steeper domes of class In2 the magma intruded to shallow depths between 0.4 and 1.0 km while the inferred magma pressures range from 3 to 8 MPa. Class In3 domes are similar to those of class In1 with intrusion depths of 1.8-2.7 km and magma pressures of 15-23 MPa. As an extraordinary feature, we describe in some detail the concentric crater Archytas G associated with the intrusive dome Ar1 and discuss possible modes of origin. In comparison to the candidate intrusive domes, terrestrial laccoliths tend to be smaller, but it remains unclear if this observation is merely a selection effect due to the limited resolution of our telescopic CCD images. An elongated outline is common to many terrestrial laccoliths and the putative lunar laccoliths, while the thickness values measured for terrestrial laccoliths are typically higher than those inferred for lunar laccoliths, but the typical intrusion depths are comparable.     

The 0.7-5.3 μm IR spectra of Mercury and the Moon: Evidence for high-Ca clinopyroxene on Mercury

We present infrared spectra of Mercury and the Moon in the wavelength range 0.7-5.3 μm obtained with the SpeX spectrograph at the NASA Infrared Telescope Facility. The spectra were acquired from pole and terminator locations of Mercury's surface and of Mersenius C and the Copernicus central peak on the Moon. Spectra of both bodies were measured in close temporal succession and were reduced in the same manner with identical calibration stars to minimize differences in the reduction process. The Copernicus spectra display the expected absorption features due to mafic minerals in the near infrared and show spectral features in the SiO combination/overtone vibrational band region above 4 μm. The spectra of Mercury from longitude 170° and north and south mid-latitudes display a 1-μm absorption band indicative of high-Ca clinopyroxene, while a spectrum from longitude 260° and northern mid-latitudes does not. The Mercury spectra show a broad feature of low emittance over the full 3-5 μm thermal infrared region, but no narrow features in this spectral range. The longitude 260° spectrum shows excess thermal emission around 5 μm attributable to the existence of a thermal gradient in the insolated dayside regolith. The thermal-IR spectra suggest a significant difference in the compositional and/or structural properties of Mercury and the Moon that may be due to grain size, absorption coefficient, or the magnitude of near-surface thermal gradients. The results indicate that the composition of Mercury's surface is heterogeneous on regional scales, and that the near infrared wavelength range provides more discriminative information on the surface composition than the 2-4 μm region, where the solar reflected and thermally emitted radiation contribute approximately equally to the observed flux of these bodies.     

Mineralogical constraints on the high-silica martian surface component observed by TES

The Thermal Emission Spectrometer (TES) has observed a high-silica material in the dark regions of Mars that is spectrally similar to obsidian glass and may have a volcanic origin. An alternate interpretation is that the spectrally amorphous material consists of clay minerals or some other secondary material, formed by chemical alteration of surface rocks. The regions where this material is observed (e.g., Acidalia Planitia) have relatively high spectral contrast, suggesting that the high-silica material exists as coarse particulates, indurated soils or cements, within rocks, or as indurated coatings on rock surfaces. The geologic interpretation of this spectral result has major implications for understanding magmatic evolution and weathering processes on Mars. One of the complications in interpreting spectral observations of glasses and clay minerals is that both are structurally and compositionally complex. In this study, we perform a detailed spectroscopic analysis of indurated smectite clay minerals and relate their thermal emission spectral features to structural and crystal chemical properties. We examine the spectral similarities and differences between smectite clay minerals and obsidian glass from a structural-chemical perspective, and make further mineralogical interpretations from previous TES results. The results suggest that neither smectite clays nor any clay mineral with similar structural and chemical properties can adequately explain TES observations of high-silica materials in some martian dark regions. If the spectrally amorphous materials observed by TES do represent an alteration product, then these materials are likely to be poorly crystalline aluminosilicates. While all clay minerals have Si/O ratios ?0.4, the position of the emissivity minimum at Mars suggests a Si/O ratio of 0.4-0.5. The spectral observation could be explained by the existence of a silica-rich alteration product, such as Al- or Fe-bearing opal, an intimate physical mixture of relatively pure silica and other aluminosilicates (such as clay minerals or clay precursors), or certain zeolites. The chemical alteration of basaltic rocks on Mars to phyllosilicate-poor, silica-rich alteration products provides a geologically reasonable and consistent explanation for the global TES surface mineralogical results.     

Geomorphic knobs of Candor Chasma, Mars: New Mars Reconnaissance Orbiter data and comparisons to terrestrial analogs

High Resolution Imaging Science Experiment (HiRISE) imagery and digital elevation models of the Candor Chasma region of Valles Marineris, Mars, reveal prominent and distinctive positive-relief knobs amidst light-toned layers. Three classifications of knobs, Types 1, 2, and 3, are distinguished from a combination of HiRISE and Thermal Emission Imaging System (THEMIS) images based on physical expressions (geometries, spatial relationships), and spectral data from Compact Reconnaissance Imaging Spectrometer for Mars (CRISM). Type 1 knobs are abundant, concentrated, topographically resistant features with their highest frequency in West Candor, which have consistent stratigraphic correlations of the peak altitude (height). These Type 1 knobs could be erosional remnants of a simple dissected terrain, possibly derived from a more continuous, resistant, capping layer of pre-existing material diagenetically altered through recrystallization or cementation. Types 2 and 3 knobs are not linked to a single stratigraphic layer and are generally solitary to isolated, with variable heights. Type 3 are the largest knobs at nearly an order of magnitude larger than Type 1 knobs. The variable sizes and occasional pits on the tops of Type 2 and 3 knobs suggest a different origin, possibly related to more developed erosion, preferential cementation, or textural differences from sediment/water injection or intrusion, or from a buried impact crater. Enhanced color HiRISE images show a brown coloration of the knob peak crests that is attributable to processing and photometric effects; CRISM data do not show any detectable spectral differences between the knobs and the host rock layers, other than albedo. These intriguing knobs hold important clues to deducing relative rock properties, timing of events, and weathering conditions of Mars history.