水汽输送对雅鲁藏布江流域降水中稳定同位素的影响

利用NCEP/NCAR全球大气再分析格点资料和2005年西藏雅鲁藏布江流域4个站点（拉孜、奴各沙、羊村和奴下）降水中δ18O数据，分析了雅鲁藏布江流域降水中δ18O变化同水汽输送通量的关系。从空间上来看，雅鲁藏布江流域降水中δ18O同水汽输送通量呈明显的正相关，从下游至上游，随着水汽输送通量的减少，降水中的δ18O逐渐降低；从时间上来看，春季水汽通量较小，降水中的δ18O较高，而在夏季，水汽通量大，降水中的δ18O较低。在此基础上，又利用NCEP/NCAR气象数据建立水汽追踪模型，以羊村站为例对雅鲁藏布江流域降水的水汽输送过程进行了追踪模拟，并讨论了降水中δ18O变化同水汽源地以及输送过程的关系。结果发现，在季风降水之前的春季，降水中较高的δ18O主要受西风带水汽输送以及当地蒸发水汽的影响；在季风期间，降水中较低的δ18O主要受来自印度洋暖湿水汽输送的影响。      

A Geochemical study of the groundwater in the Misli basin and environmental implications

The aim of this study was to determine geochemical properties of groundwater and thermal water in the Misli Basin and to assess thermal water intrusion into shallow groundwater due to over-extraction. According to isotope and hydrochemical analyses results, sampled waters can be divided into three groups: cold, thermal, and mixed waters. Only a few waters reach water–rock chemical equilibrium. Thermal waters in the area are characterized by Na⁺–Cl⁻–HCO₃⁻, while the cold waters by CaHCO₃ facies. On the basis of isotope results, thermal waters in the Misli basin are meteoric origin. In particular, δ¹⁸O and δ²H values of shallow groundwater vary from −10.2 to −12.2‰ and −71.2 to −82‰, while those of thermal waters range from −7.8 to −10.1‰ and from −67 to −74‰, respectively. The tritium values of shallow groundwater having short circulation as young waters coming from wells that range from 30 to 70 m in depth vary from 10 to 14 TU. The average tritium activity of groundwater in depths more than 100 m is 1.59 ± 1.16, which indicates long circulation. The rapid infiltration of the precipitation, the recycling of the evaporated irrigation water, the influence of thermal fluids and the heterogeneity of the aquifer make it difficult to determine groundwater quality changes in the Misli Basin. Obtained results show that further lowering of the groundwater table by over-consumption will cause further intrusion of thermal water which resulted in high mineral content into the fresh groundwater aquifer. Because of this phenomenon, the concentrations of some chemical components which impairs water quality in terms of irrigation purposes in shallow groundwaters, such as Na⁺, B, and Cl⁻, are highy probably expected to increase in time.     

青藏高原那曲河流域降水及河流水体中氧稳定同位素研究

根据青藏高原中部那曲河流域1998年夏季测得的上下游中稳定同位素的日变化,并与同期观测的流域降水中稳定同位素比较,分析了河水中δ18O的变化特征,初步研究了该流域的稳定同位素水文循环过程.河水中δ18O的变化幅度远小于降水,它是降水中δ18O、降水量以及地表蒸发过程共同作用的结果.研究发现湖水对于稳定同位素变化起着显著的调节作用.河水中δ18O与流域降水中δ18O的差异可能反映了该流域强烈的地表和湖面蒸发作用.     

长江流域降水稳定同位素的云下二次蒸发效应

对长江流域443个GNIP的降水样品同位素原始资料,分降雪和降雨进行δ2H和δ18O线性回归,得到降雪样品的相关方程为δ2H=7.965δ18O+17.114,有最大的斜率和截距;而降雨样品根据降水量大小从<10mm至>300mm分为4组后,得到的相关方程随着降水量的减小,斜率和截距均减小,斜率从7.701减小为5.705,截距从7.812×10-3减小为-5.479×10-3。δ2H~δ18O相关方程的斜率及截距与气温、水汽压之间的关系表明,在降水从云层底部降落到地面的过程中,仅较小降雨事件有明显的二次蒸发现象,并伴随着同位素的分馏。长江流域较小降雨事件占有比例很小,仅为所有降水事件的6.32%,所以二次蒸发效应仅引起地区大气降水方程斜率和截距的微弱减小。研究表明,单个降水原始资料的同位素分析,能产生长期加权平均降水同位素分析得不到的宝贵信息。     

天山乌鲁木齐河流域山区降水δ18O和δD 特征及水汽来源分析

依据乌鲁木齐河流域山区3个站点实测次降水δ18O和δD数据以及气象观测资料,结合临近GNIP(Global Network of Isotopes in Precipitation)站点数据,对其降水δ18O和δD特征及水汽来源进行了分析。结果表明,大气降水中δ18O值波动范围大,但呈现明显的季节性变化:冬季降水δ18O较低,夏季降水δ18O较高。受流域山区气候和地理条件影响,从上游到下游各站点大气降水线截距和斜率均呈现逐渐减小趋势。大气降水中δ18O和δD与日均气温存在密切正相关关系,且温度与δ18O之间的相关性优于δD。降水中d-excess值也表现出季节性变化,冬季降水d-excess值高于夏季降水。利用HYSPLIT 4.0气团轨迹模型,得出夏季水汽主要来源西风环流输送,冬季受西风环流和极地气团共同影响。     

黄河流域夏季有效降水转化率

利用NCEP/NCAR再分析资料及中国实测雨量资料,分析发现黄河流域夏季整层降水转化率普遍较低,因考虑到整层中应有某一气压层具有最有利的水汽输送、抬升凝结和垂直运动条件,由此将该气压层定义为有效降水转化率层(简称有效层),降水与有效层可降水量之比称为有效降水转化率。通过分析黄河流域夏季各分区垂直速度与水汽等因子,确定上、中、下游夏季有效层分别为地面~500hPa、600~400hPa、850~600hPa。对比分析表明:夏季各区平均水汽收支与降水转化率,各自在整层和有效层上的逐年演变趋势均一致,峰谷相对应,且49年间降水转化率在有效层上的数值均大于整层的。夏季有效降水转化率在青藏高原上空及中游东部最高,高原东北侧最低,旱、涝年与多年平均状况下的分布形式虽然一致,但涝年的数值明显大于旱年。     

长江上游流域降水结构时空演变特性

为研究气候变化和人类活动背景下的长江上游流域降水结构时空分布特性,利用长江上游流域67个气象站点1961—2005年45年的日降水资料,分析了各种不同历时连续降水的时空演变特征。通过Trend Free Pre-Whitening方法消除降水时间序列中的自相关成分,利用非参数的Mann-Kendall法检验了降水结构的变化趋势。结果表明:① 长江上游流域及各分区各历时降水发生率随降水历时增加呈指数递减趋势,贡献率先增加后降低,以短历时降水为主;② 长江上游短历时（1 d和2 d）降水贡献率发生突变的时间在1976年,长历时（6 d和10 d）降水发生率发生突变的时间为1984年,贡献率发生突变的时间为1999年;③ 长江上游短历时降水集中出现的次数增加,降水强度增大,降水量占总降水量的比例较大,而长历时降水出现频次降低,降水量占总降水量比例下降,其中岷沱江流域、大渡河流域、长江干流区间通过了显著性检验。     

n-alkane distribution coupled with organic carbon isotope composition in the shell bar section, Qarhan paleolake, Qaidam basin, NE Tibetan Plateau

Lipids extracted from lacustrine deposits in the paleolake Qarhan of the Qaidam basin in the northeastern Tibetan Plateau were determined by conventional gas chromatography-mass spectrometry. Several series of biomarkers were identified, mainly including n-alkanes, n-alkan-2-ones, n-alkanoic acids, branched alkanes, triterpenoids and steroids, indicative of various biogenic contributions. On the basis of cluster analysis, the n-C₁₅, n-C₁₇, n-C₁₉ alkanes were proposed to be derived from algae and/or photosynthetic bacteria, the n-C₂₁, n-C₂₃, n-C₂₅ homologues from aquatic plants, and the n-C₂₉, n-C₃₁ homologues from vascular plants. In contrast, the n-C₂₇ alkane is not categorized in the n-C₂₉ and n-C₃₁ group of alkanes, probably due to more complex origins including both aquatic and vascular plants, and/or differential biodegradation. Stratigraphically, layers-2, 4 and 5 were found to show a close relationship in n-alkane distribution, associated with a positive shift in carbon isotope composition of bulk organic matter (δ¹³C_org), inferring a cold/dry period. Layers-1 and 6 were clustered together in association with a negative δ¹³C_org, excursion, probably indicating a relatively warm/humid climate. The potential coupling between the n-alkane distributions and δ¹³C_org, suggests a consequence of vegetation change in response to climate change, with the late MIS3 being shown to be unstable, thought to be the climatic optimum in the Tibetan Plateau. Our results suggest that the cluster analysis used in this study probably provides an effective and authentic method to investigate the n-alkane distribution in paleolake sediments.     

The Correlation of Inorganic C,O Isotopic Values for Lake Chenghai Sediments and Its Environmental Implications

As one of the lakes on the Yunnan-Guizhou plateau, Lake Chenghai, which is a typical closed lake with the precipitation accounting for one-third or more of the annual water input, has a high total salinity (almost like a saline lake). The inorganic C, O isotopic composition of lake sediments bears much sensitive information about environmental change in the catchment, while their correlations revealed the hydrological conditions under which the lake was closed. Their compositional variations are controlled by temperature, precipitation, photosynthesis, dissolving equilibrium of the carbonate system and hydrological condition. According to our research on inorganic C, O isotopic composition of Lake Chenghai sediments, we investigated the environmental change of this catchment several decades ago. The results showed that Lake Chenghai has kept good hydrological closing conditions in the past several decades, as indicated by the good correlation of inorganic C, O isotopic composition of sediments; and that the environmental change in this catchment shows a tendency of periodical evolution on a 10⁻¹¹-years scale, although the signal noise is relatively high at the bottom of the sediment core. And we also can extend C, O isotopes, a sensitive environmental indicator, to nearly saline lake environments with a high degree of mineralization.     

The variations of stable-carbon isotope ratios in Qilian juniper in northwestern China

This is the first study of δ¹³C values that considers elevational influences of the Qilian mountains of China. The δ¹³C values of different parts of the Qilian juniper (Sabina przewalskii Kom.) at different elevations of the Qilian mountains, China, were measured. Relatively constant differences in δ¹³C values existed between the tree leaves and the trunk wood. No strong dependency of δ¹³C values on elevation was found. The temporal changes of wood δ¹³C values with directions, elevations and height in the tree showed general similarity. These results suggest that the isotopic effects of environmental factors expressed initially at the site of photosynthesis, i.e., the leaves could be contained in the trunks of a tree. Regardless of elevation, direction or height in the tree, wood δ¹³C values have been decreasing during the past 60 years. A composite 600-year δ¹³C chronology developed from four trees showed that δ¹³C values remain relatively constant before 1800. After 1800 AD, however, δ¹³C values became significantly more negative. The trend in wood δ¹³C values was consistent with that obtained for δ¹³C values in atmospheric CO₂. The results showed that for Qilian juniper, tree-ring δ¹³C chronology could be established to ascertain fluctuations of the atmospheric δ¹³C.     

淮河流域致洪暴雨的异常水汽输送

为了从多方面提取对致洪暴雨有指示意义的异常信息,进一步提高对致洪暴雨的判别能力,利用Box-Cox变换将信号场方法引入致洪暴雨水汽条件气候异常的诊断,并具体分析了2003年、2005年和2007年淮河流域致洪暴雨850 hPa水汽通量场的气候异常特征。结果表明:淮河流域致洪暴雨期间,850 hPa经向水汽通量信号场105°E~125°E易形成以淮河流域为中心南正北负的双极型配置;850 hPa纬向水汽通量信号场低纬的显著信号反映出各条水汽输送通道的相对重要性因致洪暴雨而异。     

五种降水产品在疏勒河上游山区和中下游月尺度降水的适用性对比研究

降水产品为理解降水时空分布提供了新的视角,然而其在不同地区适用性差异很大,目前对不同降水产品在西北内陆河流域上游山区和中下游平原适用性的对比研究还十分有限。利用疏勒河流域及周边9个国家气象站2001-2013年和4个山区自建气象站2008-2013年降水观测数据,基于皮尔逊相关系数（R）、均方根误差（RMSE）、平均绝对误差（MAE）和相对偏差（BIAS）指标,对CMFD、ERA-Interim、GPCC、GPCP V2.3和JRA-55共五种常用降水产品的月尺度降水数据在疏勒河上游山区和中下游平原区的适用性进行了评估对比,结果表明：五种降水产品都可以较好地模拟疏勒河流域多年平均降水的空间分布,总体来说,降水产品在上游的评估的相对误差优于中下游,但绝对误差比中下游大,这与上游降水远大于中下游有关。各产品在上游和中下游的精度排序结果一致,均为CMFD > GPCC > ERA-Interim > GPCP V2.3 > JRA-55。CMFD效果最佳可能与融合了中国更多的地面降水资料有关,其在自建站的效果也表现最佳。不同产品在疏勒河上游山区和中下游月尺度的降水评估中表现较好,但尚不能满足流域水文过程分析和模拟的需要。     

北麓河多年冻土区降水及河水稳定同位素特征分析

为了进一步全面理解和探索青藏高原水文水循环过程,采用同位素方法并结合气象资料对青藏高原北麓河区域2011年6~12月降水和河水稳定同位素时空特征进行分析。探讨了北麓河降水同位素与日平均气温、降水量之间的相互关系,同时也对比分析了北麓河降水和河水的同位素变化特征。结果表明:北麓河降水同位素在整个观测期内总体受温度控制,但存在季节变化,其中6~9月降水同位素受到温度和降水量效应的共同控制,9月以后则主要受温度的影响。河水同位素与降水同位素相似的变化特征,体现了降水补给特征,另外降水量也能够影响河水同位素变化:降水量小则降水对其影响较小,反之则大。与北麓河降水线相比,河水δ18O~δD关系的斜率和截距偏大,揭示该区域河水除了受大气降水的补给外,还受到区域水体内循环和蒸发分馏作用的影响。     

雅鲁藏布江流域极端降水模拟及预估

为了解雅鲁藏布江流域汛期极端降水的变化规律,推算一定重现期的极端降水量分位数,通过百分位法、Hill图法、年交叉率法选取阈值,借助广义帕累托分布函数（GPD）对流域极端降水频率进行了分析。结果表明：99百分位时的阈值为流域内各站点的最佳阈值,且各站点超阈值序列通过了M-K的平稳性检验,无明显突变。拟合效果通过K-S检验,各站点拟合的极端降水理论频数和实测频数基本相符。尺度参数的大值区位于流域下游,表明该地区的极值波动大;形状参数正值区位于流域中上游地区,说明发生破纪录降水事件的概率较大,拟合结果与实际观测一致。从5年一遇和10年一遇的极端降水值来看,雅江流域除拉孜站外,其他地区降水极值均超过30 mm,日喀则地区的降水极值达50 mm;各地区20年一遇和30年一遇的降水极值增长的非常缓慢。通过与实际极端降水值对比分析得出,GPD拟合计算出的重现期水平基本符合实际,即具有一定的合理性。     

北极海冰对长江流域主汛期降雨的影响

针对极地冰雪显著影响中低纬气候的事实,利用1979-2017年长江流域116站降水资料和美国国家冰雪数据中心海冰资料,通过奇异值分解等统计学方法,研究北极海冰对长江流域主汛期降水的影响及可能的机制,结果表明:冬春季节,巴伦支海和鄂霍次克海海冰面积偏多、波佛特海海冰面积偏少时,主汛期长江上中游干流、汉江上游和雅砻江降水偏多;北极群岛、楚科奇海和拉普捷夫海以北海域海冰面积偏多时,主汛期两湖水系降水偏多,嘉陵江上游、汉江上游降水偏少;反之亦然。可能的机制为冬春季关键区海冰变化通过影响湍流热通量引发大气能量波动,这种波动以大气波列形式向东亚传播,影响东亚地区夏季的大气环流和水汽输送,从而间接影响长江流域主汛期降水。应用多元回归法,以关键区海冰面积作为预测因子建立4个流域内主汛期降水趋势预测模型,模型对预报区降水的定量预测有明显的波动,但对预报区总体的降水趋势有较好的预测效果。     

Controls, variation, and a record of climate change in detailed stable isotope record in a single bryozoan skeleton

The long-lived (about 20 yr) bryozoan Adeonellopsis sp. from Doubtful Sound, New Zealand, precipitates aragonite in isotopic equilibrium with seawater, exerting no metabolic or kinetic effects. Oxygen isotope ratios (δ¹⁸O) in 61 subsamples (along three branches of a single unaltered colony) range from −0.09 to +0.68‰ PDB (mean = +0.36‰ PDB). Carbon isotope ratios (δ¹³C) range from +0.84 to +2.18‰ PDB (mean = +1.69‰ PDB). Typical of cool-water carbonates, δ¹⁸O-derived water temperatures range from 14.2 to 17.5 °C. Adeonellopsis has a minimum temperature growth threshold of 14 °C, recording only a partial record of environmental variation. By correlating seawater temperatures derived from δ¹⁸O with the Southern Oscillation Index, however, we were able to detect major events such as the 1983 El Niño. Interannual climatic variation can be recorded in skeletal carbonate isotopes. The range of within-colony isotopic variability found in this study (0.77‰ in δ¹⁸O and 1.34 in δ¹³C) means that among-colony variation must be treated cautiously. Temperate bryozoan isotopes have been tested in less than 2% of described extant species — this highly variable phylum is not yet fully understood.     

1956-2016年渭河支流葫芦河流域径流及降水的年际变化特征

研究河流径流量和流域降水量的变化特征,对区域水资源规划与开发利用具有重要意义。基于葫芦河干流上下游的两个主要控制水文站实测年径流量及其流域年降水量资料,运用标准距平累计曲线法、小波分析法和Mann-Kendall等方法,研究了葫芦河干流年径流量和年降水量的年际变化趋势、周期性和突变性。结果表明：葫芦河上下游年径流量变化趋势一致性较好,流域年降水量变化趋势与径流量变化趋势基本对应,均呈下降趋势,但径流减少的速率远大于降水减少速率,且下游径流量的减少速率比上游更快。葫芦河上下游径流量变化的大周期一致,但下游径流小周期的转换要比上游径流和流域降水更频繁,上下游径流量与其流域降水量变化周期的年份对应关系不好,径流变化的主周期和次周期均小于降水的变化周期。葫芦河下游年径流量在1988年发生了突变,而上游径流量和流域降水量均无明显的突变点。     

1961-2010年西藏雅鲁藏布江流域降水量变化特征及其对径流的影响分析

采用1961-2010年雅鲁藏布江流域6个气象站近50 a降水量的实测数据,统计降水量的年、干季、湿季平均序列;结合流域6个水文站近50 a年径流序列资料,分析雅鲁藏布江流域降水变化特征及其对径流量的影响. 研究表明： 雅鲁藏布江流域1961-2010年近50 a年平均降水量表现为不显著增加,增加速率为3.3 mm·（10a）^-1,其中干季、湿季分别为1.9 mm·（10a）^-1 和1.4 mm·（10a）^-1,均为增加趋势;降水量的年代际变化在20世纪60年代相对偏多,70年代较平稳,而80年代为最少,到90年代有所回升,21世纪前10 a降水量处于不显著的增多态势. 雅鲁藏布江径流的变差系数C_V值在0.15~0.40之间,年际变化较小. 径流的年代际变化总体上存在一定的周期性波动,20世纪60年代是一个相对的丰水期,70年代减少,80年代达到最小值,之后径流有所回升,进入21世纪前10 a呈不显著增加趋势. 年、湿季尺度上径流量和降水量的相关显著,湿季作为径流主要形成期,其降水量的多寡直接影响流域径流量的丰枯,湿季降水量的增减影响着流域径流量的增减. 由此可见,降水变化是雅鲁藏布江天然径流最主要影响因子,最终也决定了雅鲁藏布江流域年径流量的丰枯.     

The Variation of Soil Organic Matter in a Forest-Cultivation Sequence Traced by Stable Carbon Isotopes

On the basis of different photosynthetic pathways.there is an obvious difference in δ^13C values between C3 and C4 plants,In terms of this characteristic,we analyzed the organic carbon content (forestlands:1.81%-16.00%;farmland:0.45%-2.22%) and δ^13C values(forestlands:-23.86‰--27.12‰;farmland:-19.66‰--23.26‰)of three profile-soil samples either in farmland or in forestland near the Maolan Karst virgin forest,where there were developed plant C3 plants previously and now are C4 plants.Results showed that the deforestation has accelerated the decomposition rate of soil organic matter and reduced the proportion of active components in soil organic matter and thus soil fertility.     

Theoretical Modelling of Water—Rock δD—δ18O Isotopic Exchange System and Source of OreForming Fluid：A Case Study on Jinduicheng Superlarge—Scale Molybdenum Deposti,Central China

Based on the theoretical modelling of water-rock δD-δ¹⁸O isotopic exchange process, the evolution and sources of ore-forming fluid in four metallogenic epochs of the Jinduicheng superlarge-scale porphyry-type molybdenum deposit were investigated. It was revealed that in the pre-metallogenic and early-metallogenic epochs, the ore-forming fluid was a residual fluid derived from magmatic water-wall rock interaction at middle to high temperatures (T = 250–500°C) and lower W/R ratios (0.1> = W/R>0.001), while in the metallogenic and postmetallogenic epochs, the ore-forming fluid was a residual fluid derived from meteoric water-wall rock interaction at middle to lower temperatures (T = 150–310°C) and relatively high W/R ratios (0.5>W/R≥0.1). The meteoric water played an important role in molybdenum mineralization, and at the main metallogenic epoch the W/R ratio reached its maximum value. This project was financially supported by both the National Natural Science Foundation of China and the Key Research Project of the Ministry of Geology and Mineral Resources of China.