Error assessment of climate variables for FAO-56 reference evapotranspiration

Meteorological stations, which measure all the required meteorological parameters to estimate reference evapotranspiration (ET_o) using the Food and Agriculture Organization Penman?CMonteith (FAO56-PM) method, are limited in Korea. In this study, alternative methods were applied to estimate these parameters, and the applicability of these methods for ET_o estimation was evaluated by comparison with a complete meteorological dataset collected in 2008 in Korea. Despite differences between the estimation and observation of radiation and wind speed, the comparison of ET_o showed small differences [i.e., mean bias error (MBE) varying ?0.22 to 0.25?mm?day^?1 and root-mean-square-error (RMSE) varying 0.06?C0.50?mm?day^?1]. The estimated vapor pressure differed considerably from the observed, resulting in a larger discrepancy in ET_o (i.e., MBE of ?0.50?mm?day^?1 and RMSE of 0.60?C0.73?mm?day^?1). Estimated ET_o showed different sensitivity to variations of the meteorological parameters??in order of vapor pressure?>?wind speed?>?radiation. It is clear that the FAO56-PM method is applicable for reasonable ET_o estimation at a daily time scale especially in data-limited regions in Korea.     

Deep Soil Moisture Storage and Transpiration in Forests and Pastures of Seasonally-Dry Amazonia

To assess the impacts of land-use changes on plant-available water (PAW) and evapotranspiration (ET), volumetric water content (VWC) was measured to 8 m beneath three, adjacent ecosystems for four years (1991–1994). Estimates of PAW, ET, and deep drainage were generated for mature evergreen forest, adjacent pasture, and capoeira (second-growth forest on abandoned pasture land). PAW between 0 and 8 m depth for forest, pasture, and capoeira ranged from a low of 56, 400, and 138 mm at the end of the 1992 dry season to a high of 941, 1116, and 1021 mm during the 1994 wet season. We found significant differences in deep (4–8 m) stocks of PAW when comparing pasture with both forest types. In contrast, mature forest and capoeira PAW were not significantly different from one another at any depth during the experiment. In all three ecosystems available soil moisture from 4–8 m was depleted during the 1991 dry season by plant water uptake and was not recharged to 1991 levels until 1994 due to an intervening 2-year, El Niño Southern Oscillation event. Water balance estimates (based on measurements to 8 m) showed an average 10% decrease in ET from pasture compared to mature forest. Less than 15 years after pasture abandonment, ET in second-growth forest recovered to rates nearly equaling the mature forest rate. In seasonally dry environments annual and interannual cycles of deep soil moisture recharge and depletion influence rates of transpiration and drainage. These deep cycles are not currently incorporated in models of regional and global moisture flux.     

1961—2010年云南干湿气候变化

利用15个站点1961—2010年日照时数、降水量和平均温度等气候资料,计算云南5个区域各季节相对湿润度指数,分析云南干湿气候变化特征。结果表明,相对湿润度指数可定量、准确地表达云南各区域自然气候干湿程度,能客观反映云南干湿气候的波动变化和区域性差别。20世纪90年代中期以来,云南干季、雨季潜在蒸散量呈增大变化趋势,同期降水量有减小的趋势变化,从而在气候变暖背景下引发云南气候的干旱化趋势。干季各地相对湿润度指数年际波动变化大,年代际差异明显;雨季各地干湿状况年际波动相对较小,且呈现明显的周期性波动变化趋势。云南5个区域的干湿气候变化既有一致性也有差异性：滇中和滇西南比较一致,滇西北与滇东南差异明显,滇西北与滇东北雨季差异突出、干季较为相似。     

The convective boundary layer over pasture and forest in Amazonia

Summary The coupling between different types of surface (tropical forest or grass) and the Convective Boundary Layer (CBL) has been investigated using observational (rawinsoundings) data collected over Rondônia in southwest Amazonia. The data reported here support the notion that deforestation may modify the dynamics of the boundary layer, in particular during the dry season. In this period the sensible heat fluxes are very high over pasture, creating a CBL around 550m deeper compared to that over the forest. The measurements showed the height of the fully developed CBL for pasture to be 1650m, compared to around 1100m for forest. During the wet season the height of the CBL is lower than during the dry season and has the same height (around 1000m) for forest and pasture sites. The CBL over pasture is hotter and drier than over forest during the dry season, but during the wet season the air temperatures and humidities are similar. Comparing the CBL growth during the dry and wet season, there is evidence that the CBL properties over the forest are not dependent on the surface characteristics, but over the pasture they are.     

Comparative measurements and seasonal variations in energy and carbon exchange over forest and pasture in South West Amazonia

Summary Comparative measurements of radiation flux components and turbulent fluxes of energy and CO₂ are made at two sites in South West Amazonia: one in a tropical forest reserve and one in a pasture. The data were collected from February 1999 to September 2002, as part of the Large Scale Biosphere-Atmosphere Experiment in Amazonia (LBA). During the dry seasons, although precipitation and specific humidity are greatly reduced, the soil moisture storage profiles down to 3.4m indicate that the forest vegetation continues to withdraw water from deep layers in the soil. For this reason, seasonal changes observed in the energy partition and CO₂ fluxes in the forest are small, compared to the large reductions in evaporation and photosynthesis observed in the pasture. For the radiation balance, the reflected short wave radiation increases by about 55% when changing from forest to pasture. Combined with an increase of 4.7% in long wave radiation loss, this causes an average reduction of 13.3% in net radiation in the pasture, compared to the forest. In the wet season, the evaporative fraction (E/R_n) at the pasture is 17% lower than at the forest. This difference increases to 24% during the dry season. Daytime CO₂ fluxes are 20–28% lower (in absolute values) in the pasture compared to the forest. The night-time respiration in the pasture is also reduced compared to the forest, with averages 44% and 57% lower in the wet and dry seasons, respectively. As the reduction in the nocturnal respiration is larger than the reduction in the daytime uptake, the combined effect is a 19–67% higher daily uptake of CO₂ in the pasture, compared to the forest. This high uptake of CO₂ in the pasture site is not surprising, since the growth of the vegetation is constantly renewed, as the cattle remove the biomass.     

The droughts of 1997 and 2005 in Amazonia: floodplain hydrology and its potential ecological and human impacts

It is well known that most of the severe droughts in Amazonia, such as that of 1997, are El Niño-related. However, in 2005, the Amazon was affected by a severe drought that was not El Niño-related, as most of the rainfall anomalies that have happened in southwestern Amazonia are driven by sea surface temperature anomalies in the tropical North Atlantic. Earlier studies have analyzed both droughts in terms of their meteorological causes and impacts in terra firme (non-flooded) forests. This study compares the hydrological effects of both droughts on the Amazonian floodplain and discusses their potential ecological and human impacts based on an extensive literature review. The results revealed that the effects of the 2005 drought were exacerbated because rainfall was lower and evaporation rates were higher at the peak of the dry season compared to the 1997 drought. This induced a more acute depletion of water levels in floodplain lakes and was most likely associated with higher fish mortality rates. Based on the fact that the stem growth of many floodplain species is related to the length of the non-flooded period, it is hypothesized that the 1997 drought had more positive effects on floodplain forest growth than the 2005 drought. The fishing community of Silves in central Amazonia considered both droughts to have been equally severe. However, the 2005 drought was widely broadcasted by the press; therefore, the governmental mitigation efforts were more comprehensive. It is suggested that the availability of new communication technology and greater public awareness regarding environmental issues, combined with the new legal framework for assessing the severity of calamities in Brazil, are among the primary factors that explain the difference in societal response between the two droughts.     

How well can CMIP5 simulate precipitation and its controlling processes over tropical South America?

Underestimated rainfall over Amazonia was a common problem for the Coupled Model Intercomparison Project phase 3 (CMIP3) models. We investigate whether it still exists in the CMIP phase 5 (CMIP5) models and, if so, what causes these biases? Our evaluation of historical simulations shows that some models still underestimate rainfall over Amazonia. During the dry season, both convective and large-scale precipitation is underestimated in most models. GFDL-ESM2M and IPSL notably show more pentads with no rainfall. During the wet season, large-scale precipitation is still underestimated in most models. In the dry and transition seasons, models with more realistic moisture convergence and surface evapotranspiration generally have more realistic rainfall totals. In some models, overestimates of rainfall are associated with the adjacent tropical and eastern Pacific ITCZs. However, in other models, too much surface net radiation and a resultant high Bowen ratio appears to cause underestimates of rainfall. During the transition season, low pre-seasonal latent heat, high sensible flux, and a weaker influence of cold air incursions contribute to the dry bias. About half the models can capture, but overestimate, the influences of teleconnection. Based on a simple metric, HadGEM2-ES outperforms other models especially for surface conditions and atmospheric circulation. GFDL-ESM2M has the strongest dry bias presumably due to its overestimate of moisture divergence, induced by overestimated ITCZs in adjacent oceans, and reinforced by positive feedbacks between reduced cloudiness, high Bowen ratio and suppression of rainfall during the dry season, and too weak incursions of extratropical disturbances during the transition season.     

Increasing trend of northeast monsoon rainfall over the equatorial Indian Ocean and peninsular India

Peninsular India and Sri Lanka receive major part of their annual rainfall during the northeast monsoon season (October–December). The long-term trend in the northeast monsoon rainfall over the Indian Ocean and peninsular India is examined in the vicinity of global warming scenario using the Global Precipitation Climatology Project (GPCP) dataset available for the period 1979–2010. The result shows a significant increasing trend in rainfall rate of about 0.5 mm day^?1 decade^?1 over a large region bounded by 10 °S–10 °N and 55 °E–100 °E. The interannual variability of seasonal rainfall rate over peninsular India using conventional rain gauge data is also investigated in conjunction to the Indian Ocean dipole. The homogeneous rain gauge data developed by Indian Institute of Tropical Meteorology over peninsular India also exhibit the considerable upward rainfall trend of about 0.4 mm day^?1 decade^?1 during this period. The associated outgoing longwave radiation shows coherent decrease in the order of 2 W?m^?2 decade^?1 over the rainfall increase region.     

The influence of the land surface on the transition from dry to wet season in Amazonia

Summary Analysis of the fifteen years of European Centre for Medium Range Weather Forecasts (ECMWF) reanalysis suggests that the transition from dry to wet season in Southern Amazonia is initially driven by increases of surface latent heat flux. These fluxes rapidly reduce Convective Inhibition Energy (CINE) and increase Convective Available Potential Energy (CAPE), consequently providing favourable conditions for increased rainfall even before the large-scale circulation has changed. The increase of rainfall presumably initiates the reversal of the cross-equatorial flow, leading to large-scale net moisture convergence over Southern Amazonia. An analysis of early and late wet season onsets on an interannual scale shows that a longer dry season with lower rainfall reduces surface latent heat flux in the dry and earlier transition periods compared to that of a normal wet season onset. These conditions result in a higher CINE and a lower CAPE, causing a delay in the increase of local rainfall in the initiating phase of the transition and consequently in the wet season onset. Conversely, a wetter dry season leads to a higher surface latent heat flux and weaker CINE, providing a necessary condition for an earlier increase of local rainfall and an earlier wet season onset. Our results imply that if land use change in Amazonia reduces rainfall during dry and transition seasons, it could significantly delay the wet season onset and prolong the dry season.     

Possible climatic impacts of tropical deforestation

Large-scale conversion of tropical forests into pastures or annual crops will likely lead to changes in the local microclimate of those regions. Larger diurnal fluctuations of surface temperature and humidity deficit, increased surface runoff during rainy periods and decreased runoff during the dry season, and decreased soil moistrue are to be expected.It is likely that evapotranspiration will be reduced because of less available radiative energy at the canopy level since grass presents a higher albedo than forests, also because of the reduced availability of soil moisture at the rooting zone primarily during the dry season. Recent results from general circulation model (GCM) simulations of Amazonian deforestation seem to suggest that the equilibrium climate for a grassy vegetation in Amazonia would be one in which regional precipitation would be significantly reduced.Global climate changes probably will occur if there is a marked change in rainfall patterns in tropical forest regions as a result of deforestation. Besides that, biomass burning of tropical forests is likely adding CO₂ into the atmosphere, thus contributing to the enhanced greenhouse warming.     

Development of temperatures in the Kingdom of Bahrain from 1947 to 2005

A new look is focused in this study on the analysis of mean temperatures for Bahrain, as observed at its International Airport for the 59 years extending from 1947 to 2005. The temporal trends indicate significant warming of the dry-season temperatures of 0.166°C decade^?1. In particular, the summer months of May to July and October demonstrate statistically significant trends of 0.172 to 0.247°C decade^?1. There is a tendency for the wet season months to show both decreases and increases in their temperatures though the temporal trends are not significant. The decade of 1991-2000 emerged as a period of conspicuous warming as well as increase in the occurrence of unusual mean temperatures and the number of months per year with above-average temperature. No significant trend in intraannual and intraseasonal temperature variabilities is discerned, but the wet season shows predominantly higher within-season variability in temperatures as compared to the dry season. Further analyses have been carried out on the available extreme temperature data for the period 1981-2005 in an attempt to search for a possible source of climatic and/or non-climatic factors, such as intensifying desertification and rapid urbanization. By and large, the rates of diurnal temperature ranges have increased due to significantly higher rates of increasing maximum in comparison to increasing minimum temperatures. The warming rate of the overall dry season during the day is seven times that during night. However, the nocturnal temperature for the overall wet season has warmed significantly at a rate more than three times that of the overall dry season. There is a sufficient evidence that sources of rapid urbanization around the area of records seem to be a major contributor to the observed rates of temperature. Both the urbanization and the effect of the large water body of the Gulf surrounding the Island of Bahrain seem to have offset the effect of desertification on temperature changes.     

Stable carbon and nitrogen isotopic characteristics of PM2.5 and PM10 in Delhi,India

This study presents the chemical composition (carbonaceous and nitrogenous components) of aerosols (PM_2.5 and PM₁₀) along with stable isotopic composition (δ¹³C and δ¹⁵N) collected during winter and the summer months of 2015–16 to explore the possible sources of aerosols in megacity Delhi, India. The mean concentrations (mean?±?standard deviation at 1σ) of PM_2.5 and PM₁₀ were 223?±?69 µg m^?3 and 328?±?65 µg m^?3, respectively during winter season whereas the mean concentrations of PM_2.5 and PM₁₀ were 147?±?22 µg m^?3 and 236?±?61 µg m^?3, respectively during summer season. The mean value of δ¹³C (range: ??26.4 to ??23.4‰) and δ¹⁵N (range: 3.3 to 14.4‰) of PM_2.5 were ??25.3?±?0.5‰ and 8.9?±?2.1‰, respectively during winter season whereas the mean value of δ¹³C (range: ??26.7 to ??25.3‰) and δ¹⁵N (range: 2.8 to 11.5‰) of PM_2.5 were ??26.1?±?0.4‰ and 6.4?±?2.5‰, respectively during the summer season. Comparison of stable C and N isotopic fingerprints of major identical sources suggested that major portion of PM_2.5 and PM₁₀ at Delhi were mainly from fossil fuel combustion (FFC), biomass burning (BB) (C-3 and C-4 type vegitation), secondary aerosols (SAs) and road dust (SD). The correlation analysis of δ¹³C with other C (OC, TC, OC/EC and OC/WSOC) components and δ¹⁵N with other N components (TN, NH₄⁺ and NO₃^?) are also support the source identification of isotopic signatures.

     

Biogenic hydrogen sulphide emissions and non-sea sulfate aerosols over the Indian Sundarban mangrove forest

Temporal variations in atmospheric hydrogen sulphide concentrations and its biosphere-atmosphere exchanges were studied in the World’s largest mangrove ecosystem, Sundarbans, India. The results were used to understand the possible contribution of H₂S fluxes in the formation of atmospheric aerosol of different size classes (e.g. accumulation, nucleation and coarse mode). The mixing ratio of hydrogen sulphide (H₂S) over the Sundarban mangrove atmosphere was found maximum during the post-monsoon season (October to January) with a mean value of 0.59?±?0.02 ppb and the minimum during pre-monsoon (February to May) with a mean value of 0.26?±?0.01 ppb. This forest acted as a perennial source of H₂S and the sediment-air emission flux ranged between 1213?±?276 μg S m^?2 d^?1(December) and 457?±?114 μg S m^?2 d^?1 (August) with an annual mean of 768?±?240 μg S m^?2d^?1. The total annual emissions of H₂S from the Indian Sundarban were estimated to be 1.2?±?0.6 Tg S. The accumulation mode of aerosols was found to be more enriched with non-sea salt sulfate with an average loading of 5.74 μg m^?3 followed by the coarse mode (5.18 μg m^?3) and nucleation mode (1.18 μg m^?3). However, the relative contribution of Non-sea salt sulfate aerosol to total sulfate aerosol was highest in the nucleation mode (83%) followed by the accumulation (73%) and coarse mode (58%). Significant positive relations between H₂S flux and different modes of NSS indicated the likely link between H₂S, a dominant precursor for the non-sea salt sulfate, and non-sea sulfate aerosol particles. An increase in H₂S emissions from the mangrove could result in an increase in enhanced NSS in aerosol and associated cloud albedo, and a decrease in the amount of incoming solar radiation reaching the Sundarban mangrove forest.     

Spatiotemporal variability of reference evapotranspiration and its contributing climatic factors in Yunnan Province, SW China, 1961–2004

Evapotranspiration is an important flux term in the water cycle that integrates atmospheric demand and surface conditions. Using the FAO Penman–Monteith method, we calculated monthly reference evapotranspiration (ET0) for 119 stations during 1961–2004 over Yunnan Province (YP), southwest China. Linear trend analysis shows that area-averaged annual and seasonal ET0 rates declined, with most remarkable decreases during pre-monsoon (?1.5 mm decade^?1, Mar–May) and monsoon (?0.6 mm decade^?1, Jun–Aug) seasons. Most of the stations with negative trends were concentrated in the eastern and northern parts of YP. Over the 44–year period, wind speed (WS), relative sunshine duration (SD) and relative humidity (RH) all showed decreasing trends, whereas maximum temperature (TMX) increased slightly. Multivariate regression analysis indicated that the variability of ET0 rates is most sensitive to the variations of SD, followed by RH, TMX and WS. The temporal evolution of these contributing factors was not stable during the study period, with an increasing contribution of SD and a decreasing contribution of TMX after the 1970s. Temporally changing contributions of climatic variables to ET0 should be taken into account when evapotranspiration rates are calculated with equations that rely on parameterization of climatic variables. Linking the changing contributions of climatic variables to ET0 rates to circulation features may help to better understand how ET0 responds to regional climatic change.     

Asian dust depositions over the Asian region during March 2010 estimated by ADAM2

The Asian Dust Aerosol Model 2 with the MM5 meteorological model has been employed to estimate the dust emission, dust concentration, and wet and dry deposition of dust in the Asian region for the month of March in 2010. It is found that the model simulates quite reasonably the dust (PM₁₀) concentrations both in the dust source region and the downstream region of Korea. The starting and ending times of most dust events and their peak concentration occurrence times are well simulated. The monthly mean maximum surface dust concentration (PM₁₀) is found to be 267???g?m^?3 in the domain of central northern China (CNC). Monthly total maximum dust emission of more than 32?t km^?2 and that of deposition of more than 25.4?t km^?2 (dry deposition of 24?t km^?2 and wet deposition of 1.4?t km^?2) are found to occur in the domain CNC, whereas the monthly mean minimum surface dust concentration (PM₁₀) is found to be 0.2???g?m^?3 in the domain of the Tibetan Plateau, where the monthly total dust emission (4?kg?km^?2) and the monthly total dust deposition (9?kg?km^?2) are found to be minimum. This monthly total dust deposition of 9?kg?km^?2 (dry deposition of 7?kg?km^?2 and wet deposition of 2?kg?km^?2) is as large as 2.25 times of that of emission (4?kg?km^?2), suggesting net dust influx toward the Tibetan Plateau from the surrounding dust source regions. It is also found that the ratio of the total dust deposition to the total dust emission in the source region increases toward the downstream direction from 0.4 in the upstream source region of Taklimakan to 0.80 in the downstream source region of northeastern China. More than 90% of the total dust deposition is found to be contributed by dry deposition due to the lack of precipitation in the dust source region. The monthly mean dust concentration (PM₁₀) is found to decrease with distance away from the dust source region. The monthly mean dust concentration of 62???g?m^?3 over the Yellow Sea (YES) decreases to 4.3???g?m^?3 over the Northwestern Pacific Ocean (NWP). The monthly total dust deposition in the downstream region is also found to decrease away from the source region from 2.33?t km^?2 (dry deposition of 1.36?t km^?2 and wet deposition of 0.97?t km^?2) over the domain YES to 1.45?t km^?2 (dry deposition of 0.16?t km^?2 and wet deposition of 1.30?t km^?2) over the domain NWP. A large amount of the total dust deposition over the seas is contributed by wet deposition (more than 90%), causing a small decreasing rate of the total dust deposition with distance from the source region. The estimated dust deposition could adversely impact the eco-environmental system significantly in the downstream regions of the Asian dust source region, especially over the seas.     

Validation of TRMM-3B42 precipitation product over the tropical Indian Ocean using rain gauge data from the RAMA buoy array

In the present study, an attempt has been made to validate the Tropical Rainfall Measuring Mission (TRMM) Multisatellite Precipitation Analysis (TMPA)-3B42 recently released version 7 product over the tropical Indian Ocean using surface rain gauges from the National Oceanic and Atmospheric Administration/Pacific Marine Environmental Laboratory Research Moored Array for African–Asian–Australian Monsoon Analysis and Prediction buoy array available since late 2004. The validation exercise is carried out at daily scale for an 8-year period of 2004–2011. Results show statistically significant linear correlation between these two precipitation estimates ranging from 0.40 to 0.89 and the root-mean-square error varies from about 1 to 22 mm day^?1. Although systematic overestimation of precipitation by the TMPA product is evident over most of the buoy locations, the TMPA noticeably underestimates higher (more than 100 mm day^?1) and light (less than 0.5 mm day^?1) precipitation events. The highest correlation is observed during the southwest monsoon season (June–September) even though bias is the maximum possibly due to relatively lower fraction of stratiform precipitation during the monsoon season than other seasons. Furthermore, the TMPA estimates slightly underestimate or misses intermittent warm precipitation events as compared to the precipitation radar derived precipitation rates.     

Single and dual crop coefficients and crop evapotranspiration for wheat and maize in a semi-arid region

In this study, weighing lysimeters were used to investigate the daily crop coefficient and evapotranspiration of wheat and maize in the Fars province, Iran. The locally calibrated Food and Agriculture Organization (FAO) Penman–Monteith equation was used to calculate the reference crop evapotranspiration (ET_o). Micro-lysimetry was used to measure soil evaporation (E). Transpiration (T) was estimated by the difference between crop evapotranspiration (ET_c) and E. The single crop coefficient (K _c) was calculated by the ratio of ET_c to ET_o. Furthermore, the dual crop coefficient is composed of the soil evaporation coefficient (K _e) and the basal crop coefficients (K _cb) calculated from the ratio of E and T to ET_o, respectively. The maximum measured evapotranspiration rate for wheat was 9.9 mm?day^?1 and for maize was 10 mm?day^?1. The total evaporation from the soil surface was about 30 % of the total wheat ET_c and 29.8 % of total maize ET_c. The single crop coefficient (K _c) values for the initial, mid-, and end-season growth stages of maize were 0.48, 1.40, and 0.31 and those of wheat were 0.77, 1.35, and 0.26, respectively. The measured K _c values for the initial and mid-season stages were different from the FAO recommended values. Therefore, the FAO standard equation for K _c-_mid was calibrated locally for wheat and maize. The K _cb values for the initial, mid-, and end-season growth stages were 0.23, 1.14, and 0.13 for wheat and 0.10, 1.07, and 0.06 for maize, respectively. Furthermore, the FAO procedure for single crop coefficient showed better predictions on a daily basis, although the dual crop coefficient method was more accurate on seasonal scale.     

A semi-continuous measurement of gaseous ammonia and particulate ammonium concentrations in PM<Subscript>2.5</Subscript> in the ambient atmosphere

Ammonia has a short residence time in the atmosphere and rapidly neutralizes acid gases that occur near its source, requiring a rapid measurement system for ammonia and particulate ammonium concentrations to better understand their sources, temporal variation of ammonia emissions, and the formation of secondary ammonium aerosols. A semi-continuous measurement system, consisting of a diffusion scrubber, a particle growth chamber, an air-liquid separator, and a fluorescent detector, was developed to determine both gaseous ammonia (NH₃) and particulate ammonium (NH ₄ ⁺ ) in PM_2.5 in the ambient atmosphere of Gwangju, South Korea, during the months of March, April, July, and September of 2007. During the sampling periods, the average concentrations of ammonia and ammonium were found to be 2.33?±?1.29 μg/m³ and 1.89?±?0.99 μg/m³, respectively. Although the average gaseous ammonia concentration was highest in March, the particulate ammonium concentration was higher during the warmer season, reaching 2.08?±?1.07 μg/m³ and 2.32?±?0.94 μg/m³ in April and July, respectively, while only 1.68?±?0.61 μg/m³ in March and 1.24?±?0.99 μg/m³ in September. It is proposed that the higher availability of acid species during the warmer months produced a significant amount of particulate ammonium sulfate. Diurnal fluctuation of ammonia and ammonium during the warmer months showed that their peak time occurred at approximately 10:00 am. Both ammonia and ammonium concentrations were better correlated during the warmer months than during the cooler months. Further, the data suggest that the ammonia and ammonium were measured under well dispersed conditions, and multiple sources contributed to the ammonia at the sampling site.     

Rainwater Chemistry and Wet Deposition over the Wet Savanna Ecosystem of Lamto (Côte d'Ivoire)

From the IGAC-DEBITS Africa network (IDAF), data sets on precipitation chemistry collected from the ‘wet savanna ecosystem’ site of Lamto (Côte d'Ivoire), are analyzed (1995–2002). Inorganic (Ca^{2 +}, Mg^{2 +}, Na⁺, K⁺, NH₄ ⁺, Cl^?, SO₄ ^{2 ?}, NO₃ ^?) and organic (HCOO^?, CH₃COO^?) ions content were determined using Ion Chromatography. The analyzed 631 rainfall events represent 8420.9 mm of rainfall from a 9631.1 mm total. The precipitation chemistry at Lamto is influenced by four main sources: natural biogenic emissions from savanna soils (NO _x and NH₃), biomass burning (savanna and domestic fires), terrigeneous particles emissions from dry savanna soils, and marine compounds embedded in the summer monsoon. The inter-annual variability of the weighted volume mean concentration of chemical species linked with wet deposition fluctuates by ～ 20% over the period. Ammonium concentration is found to be the highest (17.6 μ eq.l^{? 1}) from all IDAF sites belonging to the West Africa ecosystems. Ammonia sources are from domestic animals, fertilizers and biomass burning. In spite of the high potential acidity of 30.5 μ eq.l^{? 1} from NO₃ ^?, SO₄ ^{2 ?}, HCOO^? and CH₃COO^?, a relatively weak acidity is measured: 6.9 μ eq.l^{? 1}. The 40% acid neutralization is explained by the acid gas – alkaline soil particles interaction. The remaining neutralization is from inclusion of gaseous ammonia. When results from Lamto, are compared with those from Banizoumbou (dry savanna) and Zoetele (equatorial forest), a regional view for wet tropospheric chemistry processes is obtained. The high concentration of the particulate phase in precipitation emphasizes the importance of multiphases processes between gases and particles in the atmospheric chemistry of the West Africa ecosystems. For example, the nss Ca^{2 +} precipitation content, main indicator of terrigeneous particles, goes from 30.8 μ eq.l^{? 1} in dry savanna to 9.2 μ eq.l^{? 1} at Lamto and 8.9 μ eq.l^{? 1} in the Cameroon forest. A similar gradient is obtained for rainfall mineral particles precipitation content with contribution of 80% in dry savanna, 40% in wet savanna, and 20% in the equatorial forest.     

Parameterisation of incoming longwave radiation over glacier surfaces in the semiarid Andes of Chile

A good understanding of radiation fluxes is important for calculating energy, and hence, mass exchange at glacier surfaces. This study evaluates incoming longwave radiation measured at two nearby glacier stations in the high Andes of the Norte Chico region of Chile. These data are the first published records of atmospheric longwave radiation measurements in this region. Nine previously published optimised parameterisations for clear sky emissivity all produced results with a root mean square error (RMSE) ~20 W?m^?2 and bias within ±5 W m^?2, which is inline with findings from other regions. Six optimised parameterisations for incoming longwave in all sky conditions were trialled for application to this site, five of which performed comparably well with RMSE on daytime data <18 W?m^?2 and bias within ±6 W?m^?2 when applied to the optimisation site and RMSE <20 W?m^?2 and bias within ±10 W m^?2 when applied to the validation site. The parameterisation proposed by Mölg et al. (J Glaciol 55:292-302, 2009) was selected for use in this region. Incorporating the proposed elevation modification into the equation reduced the bias in the modelled incoming longwave radiation for the validation site. It was found that applying the parameterisation optimised in the original work at Kilimanjaro produced good results at both the primary and validation site in this study, suggesting that this formulation may be robust for different high mountain regions.