Tephrochronology of the western Gulf of Mexico for the last 185,000 years

Tephra in 31 piston cores from the western Gulf of Mexico and 7 piston cores from the equatorial Pacific were analyzed by electron microprobe. Six ash layers in the western Gulf of Mexico were easily distinguished by TiO₂, FeO, and CaO contents and correlated by geochemistry in order to determine the distribution pattern for each ash layer. Correlation by geochemistry is an easier, more accurate method than biostratigraphic correlation; some of the tephras were miscorrelated by biostratigraphy. The six tephras were dated by geochemical identification in a piston core with oxygen-isotope stratigraphy and the ages are Y5 (30,000 yr B.P.), Y6 (65,000 yr B.P.), Y8 (84,000 yr B.P.), X2 (110,000 yr B.P.), W1 (136,000 yr B.P.), and W2 (185,000 yr B.P.). Data from this study corroborated correlations of the Y8 tephra in the western Gulf of Mexico with the D layer in the eastern equatorial Pacific Ocean. None of the other five layers in the Gulf of Mexico, however, were found in the Pacific Ocean. The limited distribution of the Y5, Y6, X2, and W2 ash layers close to Mexico indicates possible sources in Mexico. Tephra from the late Pleistocene La Primavera pumice in Mexico, however, does not correlate with the marine tephra.     

A history of violence: magma incubation,timing and tephra distribution of the Los Chocoyos supereruption (Atitlán Caldera,Guatemala)

The climactic Los Chocoyos (LCY) eruption from Atitlán caldera (Guatemala) is a key chronostratigraphic marker for the Quaternary period given the extensive distribution of its deposits that reached both the Pacific and Atlantic Oceans. Despite LCY tephra being an important marker horizon, a radioisotopic age for this eruption has remained elusive. Using zircon (U–Th)/He geochronology, we present the first radioisotopically determined eruption age for the LCY of 75 ± 2 ka. Additionally, the youngest zircon crystallization ²³⁸U–²³⁰Th rim ages in their respective samples constrain eruption age maxima for two other tephra units that erupted from Atitlán caldera, W-Fall (130 ⁺¹⁶/₋₁₄ ka) and I-Fall eruptions (56 ^+8.2/_−7.7 ka), which under- and overlie LCY tephra, respectively. Moreover, rim and interior zircon dating and glass chemistry suggest that before eruption silicic magma was stored for >80 kyr, with magma accumulation peaking within ca. 35 kyr before the LCY eruption during which the system may have developed into a vertically zoned magma chamber. Based on an updated distribution of LCY pyroclastic deposits, a new conservatively estimated volume of ~1220 ± 150 km³ is obtained (volcanic explosivity index VEI > 8), which confirms the LCY eruption as the first-ever recognized supereruption in Central America.     

Derivation of the Chortis and Chiapas blocks from the western Gulf of Mexico in the latest Cretaceous–Cenozoic: the Pirate model

Currently, two basic models describe the genesis of the Caribbean Plate: (i) a Pacific model that derives the Caribbean Plate off southern Mexico and (ii) an in situ model. The Pacific model requires the 1100–1400 km sinistral displacement recorded across the Cayman Trough to pass through the Gulf of Tehuantepec into the Middle America Trench, but no evidence of such a connection exists. The in situ model is inconsistent with the 1100–1400 km displacement across the Cayman Trough. A way through this impasse is indicated by the northwestward curvature of active oblique reverse to sinistral transcurrent faulting in southeast Mexico. Extending this potential solution back to ca. 80 Ma forms the basis of the new Pirate model, in which the Caribbean Plate and the Chortis and Chiapas blocks are derived from the northwest by anticlockwise rotation during the latest Cretaceous and Cenozoic. Following passage of the Chortis Block, the northern and southern parts of the Yucatan block collided along the intra-Yucatan suture, producing the 11–9 Ma Chiapas fold-and-thrust belt. The Pirate model accounts for the N-trending segment of the Laramide Sierra Madre Oriental–Zongolica foldbelts by anticlockwise drag, Palaeogene palaeocanyons, the second, 66–40 Ma phase of rifting in the western Gulf of Mexico, and post-10 Ma extension in the Chortis Block (Chortis–Sula rift province). Impingement of the East Pacific Rise on the Middle America Trench led to modification of the Pirate model involving subduction erosion of the ～200 km-wide, Eocene–Oligocene forearc at ca. 25 Ma, opening of the Gulf of California at ca. 6 Ma, and birth and ESE movement of the Southern Mexico block (<5 Ma) followed by its fragmentation. The Pirate mechanism indicates that the North American Plate is relatively weak and so tears and rotates into the trailing edge of the Caribbean Plate.     

Humid Pleistocene−Holocene transition and early Holocene in sub‐tropical northern Mexico and possible Gulf of California forcing

A new geochemical record from the paaleolake Santiaguillo documents the hydrological variability of sub‐tropical northern Mexico over the last ～14 cal. ka. Summer‐season runoff, lake water salinity and deposition of sediments by aeolian activity were reconstructed from concentrations of K, Ca and Zr/K in bulk sediments. More‐than‐average runoff during c. 12.3–9.3 cal. ka BP represented an interval of enhanced summer precipitation. Arid intervals of c. 14–12.3 cal. ka BP and c. 6–4.3 cal. ka BP were characterized by average and more‐than‐average aeolian activity. Comparison with proxy records of summer as well as winter precipitation from tropical and sub‐tropical North America and sea surface temperatures from the Atlantic and Pacific provides insight into the source of moisture and possible forcing. The wet Pleistocene?Holocene transition and early Holocene was contemporary with warmer conditions in the Gulf of California. We suggest that the Atlantic had minimal influence on the summer precipitation of the western part of sub‐tropical northern Mexico and that the source of moisture was dominantly Pacific.     

High‐resolution study of Icelandic tephras in the Kangerlussuaq Trough,southeast Greenland,during the last deglaciation

Tephra abundance data and geochemistry in Late‐glacial and Holocene sediments on the East Greenland shelf are presented. Two well‐known tephras were identified from electron microprobe analysis of tephra shards picked from ash peaks in the cores. These are the Vedde Ash and Saksunarvatn Ash, which probably were deposited on the shelf after transport on drifting ice. The radiocarbon dates (marine reservoir corrected by −550 yr) that constrain the timing of deposition of the tephra layers compare well with the terrestrial and ice‐core ages of the tephras without requiring additional reservoir correction to align them with the known tephra ages. Several prominent tephra layers with a composition of Ash Zone 2 tephra punctuate the deglacial sediments. These tephra peaks coincide with significant light stable isotope events (signifying glacial meltwater) and fine‐grained sediments poor in ice‐rafted detritus. We interpret the Ash Zone 2 tephra peaks as sediment released from the Greenland Ice Sheet during strong melting pulses of the deglaciation. Copyright © 2002 John Wiley & Sons, Ltd.     

Quaternary volcanic ash zones on the Iceland Plateau,southern Norwegian Sea

Four Quaternary volcanic ash zones in the southern Norwegian Sea have been investigated in core P57-7 from the Iceland Plateau. Both the geochemical composition and morphological variation of each ash layer have been studied. The four volcanic ash zones appear in the light oxygen isotope stages 1, 5, 7 and 11. The ash zones are composed of transparent platy grains, light brown transparent grains, brown blocky and black blocky grains and white/transparent pumice, and each zone shows a distinct stratigraphic evolution. The geochemical results show a mixture of basaltic and silicic grains in each ash zone, and that each zone contains grains from more than one eruption. The geochemical investigations strongly suggest that all the ashes are derived from Iceland. The youngest ash zone includes two layers, which based on their geochemical composition and stratigraphic position are correlated with the ¹⁴C-dated Vedde Ash (10 600 yr BP) and Saksunarvatn Ash (9 100 yr BP). Possible sources on Iceland for these layers are discussed.     

Reconstruction of hydrocarbons accumulation in sediments affected by the oil refinery industry: the case of Tehuantepec Gulf (Mexico)

The Isthmus of Tehuantepec corresponds to the shortest distance (~200?km) between the Gulf of Mexico and the Pacific Ocean in Southern Mexico, and the main economical activity of this region is oil extraction and refining. Polycyclic aromatic hydrocarbons (PAHs) and total petroleum hydrocarbons (TPHs) were determined in a ²¹⁰Pb dated sediment core collected from the continental shelf of Tehuantepec Gulf, in the vicinity of the oil refinery of Salina Cruz, Oaxaca, the main oil refining facility of the country. The sediments were mostly of coarse nature and hence PAHs and TPHs concentrations throughout the core (61?C404???g?g^?1 and 29?C154?mg?kg^?1, respectively) were below international quality benchmarks. Depth profiles of both PAHs and TPHs concentrations showed increasing trends since the early 1900s but the higher values were found from the 1950s to present. PAH congener ratios showed that these contaminants had both petrogenic and pyrolitic sources, although the former has been predominant since the 1970s. The Salina Cruz refinery started operations in 1978 but the oil industry activities in the Tehuantepec Isthmus go back to the beginning of the twentieth century with the operation of Minatitlan refinery in the Gulf of Mexico, and the Gulf of Tehuantepec being the main conduit for oil distribution in the Pacific coast. The observed changes in contaminant distributions described well the oil industry development in the area.     

The influence of air mass source on the seasonal isotopic composition of precipitation, eastern USA

As part of the AIRMoN program, daily precipitation samples have been collected since the early 1990s throughout the eastern and central United States. Using precipitation stable isotope (δ¹⁸O and δD) and HYSPLIT back trajectory analysis of 591 samples collected by the AIRMoN program from Florida, Illinois, Pennsylvania, Tennessee, Vermont, and West Virginia, amount weighted seasonal average isotopic compositions were calculated for precipitation from Continental, Pacific, Gulf of Mexico, Arctic, North Atlantic, and Mid Atlantic sources. Our results suggest that these sources are isotopically distinct and variable at and among most sites during most seasons. However, in many instances, the isotopic differences of the sources require dramatic changes in precipitation amounts from these sources to modify the seasonal average isotopic composition at a particular site. The relative importance of each source type to the seasonal average isotopic composition is highly variable among and within sites. The largest differences in the isotopic compositions of different sources are in winter and spring precipitation from the high latitude sites. At the Vermont location, the seasonal average isotopic composition is potentially quite sensitive to the relative amounts of precipitation from Arctic and Gulf of Mexico sources.     

Latitudinal and downcore (0–750 ka) changes in n-alkane chain lengths in the eastern equatorial Pacific

The n-alkane C₃₁/(C₂₉ + C₃₁) ratios from surface sediments in the eastern equatorial Pacific (EEP) exhibit higher values to the north and lower values to the south across the southern edge (2–4°N) of the Intertropical Convergence Zone (ITCZ). Since plants tend to synthesize longer chain length n-alkanes in response to elevated temperature and/or aridity, the higher C₃₁/(C₂₉ + C₃₁) ratios at northern sites suggest a higher contribution of vegetation under hot and/or dry conditions. This is consistent with the observation that northern sites receive higher levels of plant waxes transported by northeasterly trade winds from northern South America, where hot and dry conditions prevail. Furthermore, from a sediment core covering the past 750 ka (core HY04; 4°N, 95°W) we found that C₃₁/(C₂₉ + C₃₁) ratios exhibit a long-term decrease from MIS (marine oxygen isotope stage) 17 to 13. During this period, the zonal SST (sea-surface temperature) gradient in the equatorial Pacific increased, suggesting an increase in Walker circulation. Such intensified Walker circulation may have enhanced moisture advection from the equatorial Atlantic warm pool to the adjacent northern South America, causing arid regions in northern South America to contract, which may explain long-term decrease in n-alkane chain lengths.     

Calcium carbonate dissolution history in late quaternary deep-sea sediments,Western Gulf of Mexico

Calcium carbonate dissolution has been studied in eight piston cores from the western Gulf of Mexico ranging in depth from 965 to 3630. The degree of dissolution throughout the cores was determined by studies of foraminiferal test fragmentation, benthonic foraminiferal abudance, calcium carbonate concentration, and various relationships between solution-resistant and solution-susceptible species. The paleoclimatic history recorded in these cores is similar to those defined previously in the Gulf of Mexico and equatorial Atlantic. Two mesgascopically distinct ash layers and well-defined planktonic foraminiferal subzones permit precise intercore correlation of dissolution horizons. All cores demonstrate intense dissolution during several subzones, especially during the early-middle Y, X1, and W1. Other less consistent dissolution horizons occur in various cores. Sedimentation rates increase while calcite concentrations decrease during glacial episodes suggesting increased dilution by terrigenous materials. Despite this, glacial episodes show greater dissolution and worse preservation of foraminiferal tests. Therefore, increased dissolution of calcium carbonate during glacial episodes must be a function of some mechanism that more than compensates for the increased rate of burial by terrigenous sediments. Dissolution is dissolution processes are not responsible for the observed effects. The oxidation of organic material may be the primary mechanism controlling the dissolution of calcium carbonate in the western Gulf of Mexico.     

Methane-derived authigenic carbonates from the northern Gulf of Mexico — MD02 Cruise

Authigenic carbonates were sampled in piston cores collected from both the Tunica Mound and the Mississippi Canyon area on the continental slope of the northern Gulf of Mexico during a Marion Dufresne cruise in July 2002. The carbonates are present as hardgrounds, porous crusts, concretions or nodules and shell fragments with or without carbonate cements. Carbonates occurred at gas venting sites which are likely to overlie gas hydrates bearing sediments. Electron microprobe, X-ray diffraction (XRD) and thinsection investigations show that these carbonates are high-Mg calcite (6–21 mol% MgCO₃), with significant presence of framboidal pyrite. All carbonates are depleted in ¹³C (δ¹³C = − 61.9 to − 31.5‰ PDB) indicating that the carbon is derived mainly from anaerobic methane oxidation (AMO). Age estimates based on ¹⁴C dating of shell fragments and on regional sedimentation rates indicate that these authigenic carbonates formed within the last 1000 yr in the Mississippi Canyon and within 5500 yr at the Tunica Mound. The oxygen isotopic composition of carbonates ranges from + 3.4 to + 5.9‰ PDB. Oxygen isotopic compositions and Mg²⁺ contents of carbonates, and present in-situ temperatures of bottom seawater/sediments, show that some of these carbonates, especially from a core associated with underlying massive gas hydrates precipitated in or near equilibrium with bottom-water. On the other hand, those carbonates more enriched in ¹⁸O are interpreted to have precipitated from ¹⁸O-rich fluids which are thought to have been derived from the dissociation of gas hydrates. The dissociation of gas hydrates in the northern Gulf of Mexico within the last 5500 yr may be caused by nearby salt movement and related brines.     

The age,origin, and volcanological significance of the Y-5 ash layer in the Mediterranean

The Y-5 ash is the most widespread layer in deep-sea sediments from the eastern Mediterranean. This ash layer was previously correlated with the Citara-Serrara tuff on Ischia Island and dated at approximately 25,000 yr B.P. New data on the glass chemistry of the Y-5 ash and pyroclastic deposits from the Neopolitan volcanic province suggest that the layer is correlative with the large-volume Campanian ignimbrite and not with the deposit from Ischia Island. The volume of the Y-5 ash is approximately 65 km³ which is comparable in magnitude to the volume of the Campanian ignimbrite. An interpolated age of approximately 38,000 yr B.P. is estimated based on sedimentation rates derived from δ¹⁸O stratigraphy. There is a discrepancy between this estimate and previously reported radiocarbon ages which range from 24,000 to 35,000 yr B.P. We propose that the “Campanian tuff ash layer” should be adopted as the full stratigraphic name for the Y-5 ash. The deep-sea ash layer is divisible into two units in proximal localities, probably correlating with two major phases of the eruption: plinian and ignimbrite.     

Diatoms in Southeast Pacific surface sediments reflect environmental properties

Diatom abundance and assemblage composition determined for 47 surface sediment samples from the Southeast Pacific (50°S–15°N), combined with existing data for the Peru and Chile margins, demonstrate responses to regional temperature, upwelling, and productivity. High diatom abundances (# valves/g) mark the eastern equatorial Pacific upwelling and the coastal upwelling areas, in particular the upwelling centers off Peru. Freshwater diatoms reflect the low-salinity tongue off the Chilean fjords. Diatom species composition distinguishes between coastal and eastern equatorial Pacific upwelling conditions, and records sea-surface temperatures. Q-mode factor analysis defines five floral assemblages. Factors 1 and 4 determined by the genus Chaetoceros (F1) and Thalassionema (F4) reflect coastal and equatorial upwelling conditions, respectively. Factors 2 and 3 characterized by the genus Thalassiosira and Azpetia nodulifera can be associated with El Niño conditions. A 5th factor, described by Paralia sulcata, records a near-shore upwelling center off Point Concepción, central Chile. Statistical transfer functions relate diatom species percentages to sea-surface temperature and productivity with error estimates of ±0.9 °C and ±23 gC/m² yr, respectively, and provide new tools for estimating past temperature and productivity along the west coast of South America.     

Paleoclimate reconstruction derived from speleothem strontium and δC in Central Florida

Variability of strontium and carbon isotopes are reported from a speleothem from Central Florida, USA. Thermal ionization mass spectrometry of uranium–thorium isotopes indicate the speleothem was precipitated during the last 4000 years. Sr concentrations are negatively correlated with δ¹³C, a relationship inferred to record changes in soil productivity. Coeval changes in the Sr content and δ¹³C signals, as induced by soil productivity, are explained by changing precipitation above the cave. Both proxies record a 170–180-year solar cycle that has also been found in the Gulf of Mexico marine records and elsewhere. Consequently, this result provides evidence of an extraterrestrially driven modulator of precipitation in Central Florida.     

Reconstruction of atmospheric CO2 from ice-core data and the deep-sea record of ontong Java plateau: the Milankovitch chron

We provide a reconstruction of atmospheric CO₂ from deep-sea sediments, for the past 625000 years (Milankovitch chron). Our database consists of a Milankovitch template of sea-level variation in combination with a unique data set for the deep-sea record for Ontong Java plateau in the western equatorial Pacific. We redate the Vostok ice-core data of Barnola et al. (1987). To make the reconstructions we employ multiple regression between deep-sea data, on one hand, and ice-core CO₂ data in Antarctica, on the other. The patterns of correlation suggest that the main factors controlling atmospheric CO₂ can be described as a combination of sea-level state and sea-level change. For best results squared values of state and change are used. The square-of-sea-level rule agrees with the concept that shelf processes are important modulators of atmospheric CO₂ (e.g., budgets of shelf organic carbon and shelf carbonate, nitrate reduction). The square-of-change rule implies that, on short timescales, any major disturbance of the system results in a temporary rise in atmospheric CO₂.     

Late Holocene dune accretion and episodes of persistent drought in the Great Plains of Northeastern Colorado

The Great Plains of the Mid West USA contain dunefields which display stratigraphic evidence of episodic sand drift throughout the Holocene and, in some cases, the Late Pleistocene. Widespread aeolian activity has been linked to persistent megadroughts caused by a weakening of the tropical moisture-laden circulation from the Gulf of Mexico and equatorial Pacific. Infrared stimulated luminescence (IRSL) dating has been applied to two exposures in the Fort Morgan dunefield of northeastern Colorado where radiocarbon-dated buried soils provide ages for land surface stability. IRSL ages show that sand drift occurred episodically during the Late Holocene at 4.85, 2.37, 1.06, 0.80, 0.6–0.53 and 0.37 ka.     

An alternative Pangea reconstruction for Middle America with the Chortis Block in the Gulf of Mexico: tectonic implications

Understanding Pangea breakup requires a robust reconstruction, and this article focuses on the Middle America sector of the supercontinent. Although most Pangean reconstructions locate the Yucatan Block along the southern USA, the Chortis Block is generally placed off southern Mexico (Pacific model), undergoing sinistral relative motion during the Mesozoic and Cenozoic. However, the Pacific model is inconsistent with the absence of a Cenozoic fault linking the Cayman transforms and the Middle America Trench. We present an alternative Pangean reconstruction, where both the Yucatan and Chortis Blocks are placed in the future Gulf of Mexico, moving Mexico westwards along the Mojave–Sonora megashear to accommodate overlap with South America. Subsequent Mesozoic and Cenozoic evolution is inferred to have occurred in two stages: (i) Jurassic clockwise rotation along the Mojave–Sonora and West Florida megashears, followed by (ii) Cenozoic anticlockwise rotation along the Sierra Madre Oriental and East Yucatan megashears. The first stage is linked to the breakup of Pangea where the Gulf of Mexico formed as a pull-apart basin. The second stage is related to the evolution of the Caribbean where the Chortis and Yucatan Blocks rotated into the trailing side of the Caribbean Plate (pirate model). The new reconstruction is consistent with major parameters, such as (i) gravity, magnetic, and palaeomagnetic data; (ii) the westward continuation of the Cayman transform faults through the Chiapas foldbelt and along the N–S front of the Sierra Madre Oriental foldbelt; (iii) the 27–19 Ma removal of the southern Mexican forearc; (iv) offset of the Cretaceous volcanic arc (Guerrero-Suina); (v) the deflection of the Laramide orogen (Sierra Madre Oriental–Zongolica–Colon); and (vi) the continuity of Cretaceous platformal carbonates containing Caribbean fauna across Middle America. In this latter context, the Motagua high-pressure belt is interpreted as a Cretaceous extrusion zone into the upper plate above a subduction zone rather than as an oceanic suture.     

Some observations on the stable carbon isotope composition of dissolved and particulate organic carbon in the marine environment

δ¹³C_PDB compositions for 39 samples of dissolved organic carbon (DOC) from the Gulf of Mexico-Caribbean Sea-Atlantic Ocean system, the South Pacific and Ross Sea are reported. Deep water values are similar with a mean of ?21.8%. attesting to the homogeneity of the oceanic DOC pool. In Antarctic waters, a 5%. difference between DOC and particulate organic carbon (POC), with POC having values similar to modern plankton (δ¹³C_PDB approx ?27%.) supports the idea of the transient nature of POC as compared to DOC.Total, lipid, acid hydrolyzed, amino acid and residue fractions of POC are about 5, 3, 7, 5 and 3%. respectively, more negative in 2000 m water as compared to surface water samples from the Gulf of Mexico.     

Organic carbon 13C12C variations in estuarine sediments

The δC¹³ value for sedimentary organic carbon in four estuaries of the Gulf of Mexico increases with radial distance from the river mouth. Mass balance calculations indicate that terrestrial organic carbon is limited to sediments within a relatively short distance from the river mouth. This distance is a function of the discharge rate of the river. For the Mississippi River, terrestrial organic carbon is limited to sediments within 69 km of the mouth of Pass à Loutre and 61 km of South Pass. These data indicate that the low δC¹³ (< ?22%.) values reported for Pleistocene sediments in the Gulf of Mexico may be the result of factors in addition to the postulated large influx of terrestrial organic carbon.     

Source mechanism of the tsunamis of 19 and 21 September 1985, in Mexico

The major earthquake measuring 8.1 on the Richter scale which struck the west coast of Mexico on Thursday 19 September 1985, generated a small tsunami. A major aftershock on 21 September, with a magnitude of 7.5 also produced a small tsunami. Both tsunamis propagated across the Pacific and were recorded by several tide stations in Central America, Colombia, Ecuador, French Polynesia, Samoa, and Hawaii. No reports of damage were received from any of the stations, and only minor damage due to the first tsunami was reported from the source region.A survey was made by the International Tsunami Information Center (ITIC) of the coastal area affected, from Manzanillo to Zihuatanejo. Tsunami runup measurements were taken and interviews with local residents in the coastal areas were conducted.A source mechanism study of the tsunamis was undertaken using seismic and geologic data and empirical relationships. Earthquake and tsunami energies were estimated and the tsunami genertion areas defined.The earthquake energies were estimated to be 5.61 × 10²⁴ erg for the 19 September event and 9.9 × 10²³ erg for the 21 September event. Tsunami energies were estimated to be 0.7 × 10²⁰ erg for the first event and 0.56 × 10²⁰ erg for the second event. The source area of the first tsunami was determined to be approximately one-half of the earthquake source area, or approximately 7500 km², while the source area of the second tsunami was estimated to be equal to the earthquake area.The relatively small tsunamis generated by these large earthquakes are attributed to the shallow angle of subduction of the Cocos plate underneath the North American plate for this particular region, and to the small vertical component of crustal displacements. However, the angle of subduction increases further south and local earthquakes from that area have the potential of producing large tsunamis on the west coast of Mexico.This paper was presented at the 4th International Symposium on Natural and Man-made Coastal Hazards held in Ensenada, Mexico, August 1988.